共查询到20条相似文献,搜索用时 15 毫秒
1.
Differential scanning calorimetry (DSC) and x-ray diffraction (XRD) are employed to investigate the effects of nickel on the crystallization of the amorphous Zr70Cu20Ni10 alloy. We have found that the crystallization process of the amorphous Zr70Cu20Ni10 alloy is strongly influenced by the addition of nickel. Addition of 10 at% Ni to the Zr70Cu30 amorphous alloy makes the crystallization process proceed from a single-stage mode to a double-stage mode. The activation energy for crystallization of the amorphous Zr70Cu20Ni10 alloy is calculated to be about 388kJ·mol-1 on the basis of the Kissinger equation. The effects of nickel on the crystallization of the amorphous Zr70Cu20Ni10 alloy are discussed in terms of the genetics of metals. 相似文献
2.
测量了块体金属玻璃Zr46.75Ti8.25Cu7.5Ni10Be27.5在退火前后其电阻值随温度的变化,测量的温度范围为1.5—300K.样品在退火前后都发现有超导现象.零磁场下其超导转变温度Tc分别为1.84和3.76K.在5—300K温度范围内,原始样品具有负的电阻温度系数.如果取Zr, Ti, Cu, Ni及Be分别贡献出1.5, 1.5, 0.5, 0.5及两个传导
关键词:
块体金属玻璃
超导
电阻温度系数 相似文献
3.
4.
研究了Zr65Cu17.5Ni10Al7.5合金定向凝固过程中组织形态的演变特征,探索了不同的凝固方向与重力场方向间的相互取向关系对凝固组织形态的影响.存在着一个临界抽拉速度Vfc,当抽拉速度大于该临界值时组织方向性变差.该合金本身的物理性质决定了它具有一个较小的临界值(Vfc=5mm/min).不同的凝固方向与重力场的相对取向关系改变了液-固界面前沿的浮力对流状态.当凝固方
关键词: 相似文献
5.
Woyun Long Xueqiong OuyangZhiwei Luo Jing LiAnxian Lu 《Physica B: Condensed Matter》2011,406(3):503-507
Amorphous Zr50Al15−xNi10Cu25Yx alloy powders were fabricated by mechanical alloying at low vacuum with commercial pure element powders. The effects on glass forming ability of Al partial substituted by Y in Zr50Al15Ni10Cu25 and thermal stability of Si3N4 powders addition were investigated. The as-milled powders were characterized by X-ray diffraction, scanning electron microscopy and differential scanning calorimeter. The results show that partial substitution of Al can improve the glass forming ability of Zr50Al15Ni10Cu25 alloy. Minor Si3N4 additions raise the crystallization activation energy of the amorphous phase and thus improve its thermal stability. 相似文献
6.
Sun Liling Wu Tianjiao Wang Wenkui Zhang Jun Utsumi Wataru Okada Taku 《中国科学G辑(英文版)》2005,48(2):716-722
The phase transitions in Pd40Ni10Cu30P20 bulk metallic glass (BMG) have been studied under high pressure and high temperature (HP & HT) by X-ray diffaction measurements
with synchrotron radiation source. We found that the BMG underwent a phase transitions of amorphous-crystalline-amorphous
at 10 GPa upon heating. The parallel experiments were carried out at 7 GPa, while we did not observe the amorphous-crystalline-amorphous
transitions by increasing temperature. Quenching the melted BMG at 7 GPa, it was found that the phase crystallized from the
melt differed from the primary phase crystallized from the starting amorphous solid upon heating suggesting there existed
a distinct mechanism in two cases. 相似文献
7.
8.
将Zr55Al10Ni5Cu30块体非晶合金在715 K等温退火30 min, 引入少量纳米晶, 然后于室温以不同的应变速率进行轧制, 用差示扫描量热仪考察不同应变量样品的热稳定性和自由体积演化. 结果表明:即使轧制到95%的最大应变量, 样品的热稳定性也几乎没有发生改变. 在各种应变速率下, 随着应变量的增加, 自由体积含量持续上升. 但随着应变速率的增加, 相同应变量下自由体积的含量先上升后降低, 该规律与单一非晶态结构合金在塑性变形过程中自由体积的变化情况截然不同. 相似文献
9.
The specific heat of undercooled liquid Ni80Fe10Cu10 alloy was experimentally measured by electromagnetic levitation drop calorimeter, and also numerically simulated by the molecular
dynamics method. The achieved maximum undercooling is up to 252 K (0.15 T
L) in the experiments, and the measured result is 41.67 J mol−1 K−1. The simulation provides calculated data within 0∼702 K undercooling range, which is much broader than the experimental regime.
The simulated value is 37.02 J mol−1 K−1. Although there exists a difference of 4.65 J mol−1 K−1 between them, the result is quite acceptable for simulation. Furthermore, the liquid structure of undercooled Ni80Fe10Cu10 alloy is studied in terms of the total and partial pair distribution functions, which display that the ordered degree of
atoms enhances from a normal liquid to metastable state. 相似文献
10.
进行了10—27 GPa应力范围内Zr51Ti5Ni10Cu25Al9金属玻璃的平面冲击实验以研究其高压-高应变率加载下的塑性行为.由样品自由面粒子速度剖面的分析获得了冲击加载过程的轴向应力,并通过轴向应力与静水压线的比较获得剪应力.实验结果表明,尽管存在明显的松弛效应,但Zr基金属玻璃的Hugoniot弹性极限随着冲击应力的增加而增加.然而,塑性波阵面上的剪应力则显示先硬化而后软化现象,而且软化的幅度随冲击应力的增加而增加.冲击加载下Zr基金属玻璃的上述剪应力变化特征与分子动力学模拟结果比较一致,但与压剪实验结果和一维应力冲击实验结果明显不同. 相似文献
11.
12.
13.
Enthalpy recovery is not only an important characteristic of physical aging of glass, but also a good tool to investigate
the physical aging. Using differential scanning calorimeter (DSC), the enthalpy recovery of Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass (BMG) was studied. The typical characteristics of enthalpy recovery of glass including the sub-T
g peak and ‘overshot’ were found in BMG. The evolution of the sub-T
g peak and ‘overshot’ were described by the free volume theory and Hodge’s model, respectively. It was found that the former
failed to describe the enthalpy recovery in the BMG, while the latter could give a qualitative explanation. In combination
with the dynamics in the BMG, the origin of the enthalpy recovery in the BMG was discussed. The results show that BMGs are
an ideal material to investigate the physical aging. The further understanding of physical aging of BMGs is useful to clarify
the nature of glass and improve the application and device of new types of BMGs.
Supported by the National Natural Science Foundation of China (Grant No. 50671118) 相似文献
14.
A comparative study of the structure and crystallization of bulk metallic amorphous rod Pr60Ni30Al10 and melt-spun metallic amorphous ribbon Al87Ni10Pr3 总被引:1,自引:0,他引:1
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Pr-based bulk metallic amorphous (BMA) rods (Pr60Ni30Al10) and Al-based amorphous ribbons (Al87Ni10Pr3) have been prepared by using copper mould casting and single roller melt-spun techniques, respectively. Thermal parameters deduced from differential scanning calorimeter (DSC) indicate that the glass-forming ability (GFA) of Pr60Ni30Al10 BMA rod is far higher than that of Al87Ni10Pr3 ribbon. A comparative study about the differences in structure between the two kinds of glass-forming alloys, superheated viscosity and crystallization are also made. Compared with the amorphous alloy Al87Ni10Pr3, the BMA alloy Pr60Ni30Al10 shows high thermal stability and large viscosity, small diffusivity at the same superheated temperatures. The results of x-Ray diffraction (XRD) and transmission electron microscope (TEM) show the pronounced difference in structure between the two amorphous alloys. Together with crystallization results, the main structure compositions of the amorphous samples are confirmed. It seems that the higher the GFA, the more topological type clusters in the Pr-Ni-Al amorphous alloys, the GFAs of the present glass-forming alloys are closely related to their structures. 相似文献
15.
A molecular dynamics (MD) simulation study has been performed for the rapid solidification of Cu70Ni30 adopting the quantum Sutton-Chen many-body potentials. By analyzing the bond-types and the relation of atomic average energy
versus temperature, it was demonstrated that as cooling rate being 2×1012 K/s, the Cu70Ni30 formed fcc crystal structures and freezing point was found. In addition, having analyzed the transformation of microstructures
and the detail of crystal growth by using atomic trace and visual method, not only could the formation of binary disordered
solid solution be showed, but also the solidification of liquid metals and the crystal growth processes could be, further
understood. 相似文献
16.
The atomic configurations of liquid and glassy Mg65Cu25Y10 alloy have been simulated in the temperature range of 300 K to 2000 K via ab initio molecular dynamics. The variations of pair correlation function (PCF), structure factor (SF), coordination number (CN) and bond pairs with the temperature for this alloy are characterized. It has been shown that the atoms are near densely packed and icosahedral type of short-range order (SRO) is predominant in the glass state. Icosahedral medium range order (MRO) can be formed by vertex or intercross connection of icosahedral SROs. In this work, an icosahedral MRO which is composed of 55 atoms has been found. It has been also clarified that Mg and Cu occupy the centre or vertex, and Y atoms only occupy the vertex of the icosahedron in this glassy alloy. It is believed that these findings have implication for understanding the glass forming mechanism of magnesium based metallic glasses. 相似文献
17.
18.
H. Wang G.A. Sun B. Chen Y.Q. Fu X.L. Wang X.T. Zu H.H. Shen Y.P. Liu L.B. Li G.Q. Pan L.S. Sheng Q. Tian 《Physica B: Condensed Matter》2012,407(17):3437-3440
Stress-induced martensitic transformation of as-sputtered and post-annealed Ti50.1Ni40.8Cu9.1 thin films was investigated using in-situ synchrotron X-ray diffraction (S-XRD) technique. For the as-deposited film, in-situ S-XRD analysis showed a martensitic transformation from parent phase to martensite during initial loading, followed by reorientation of martensite variants via detwinning. This detwinning process induced a strong 〈0 2 0〉 fiber texture along the loading direction and a strong 〈0 0 2〉 fiber texture perpendicular to the loading direction. For the 650 °C annealed film, there is only elastic deformation, followed by a martensitic transformation during deformation. 相似文献
19.
以1at% Ag元素分别等量替代Zr57Cu20Al10Ni8Ti5金属玻璃的各个组元,利用差示扫描量热升温分析获得不同试样的热力学参数,并结合不同尺寸(Φ8,Φ10,Φ12)吸铸试样的X-射线衍射分析结果,考察、验证元素替代后合金的实际玻璃形成能力及热稳定性的变化规律.经比较发现,Ag替代Ti元素,其玻璃形成能力显著提高(直径实际增大4 mm),同时热稳定性也明显改善,且临界冷却速率也明显降低,而Ag替代其他组元却无明显规律.针对玻璃形成能力的相关数据比较分析表明,本文结果未显示符合其Inoue的尺寸准则,混合焓判据也未显示出明显符合的现象.通过对堆垛密度的计算发现,1 at% Ag替代Ti元素后使金属玻璃体系内部的堆垛密度增加.通过动力学分析,从晶化激活能、晶化反应速率常数两方面探讨了元素替代对玻璃形成能力和热稳定性的作用机理. 相似文献
20.
The magnetic contribution to the thermoelectric power was separated for the metallic glass Fe20Ni60B10Si10 which exhibits the ferro-paramagnetic transition at Tc = 455 K remarkably below the crystallization threshold Tx = 670 K. Results are compared with the predictions of the Kasuya theory. 相似文献