Electric-field-induced phase transition in single-crystal lead zinc niobate

The behavior of lead zinc niobate, a relaxor ferroelectric, in electric fields has been studied by dielectric, optical transmittance, and small-angle light scattering techniques. A field-induced transition from an averaged cubic to macrodomain ferroelectric phase has been found. A comparison is made with the properties of the phase induced in lead magnoniobate, a classical relaxor. Fiz. Tverd. Tela (St. Petersburg) 40, 527–530 (March 1998)     

Phase polymorphism and electro-optical properties of a ferroelectric liquid crystal containing the biphenyl system

ABSTRACT

In this article we present results concerning phase transitions and physical properties of the ferroelectric phase of the compound (S)-4-(1-methylheptyloxy)biphenyl–4'-(heptyloxy phenyl)-4-carboxylate (MHOBOPO7). The compound has the following phases: smectic ferroelectric C (SmC*), chiral nematic N*, and two defected phases, TGB_C and blue phase. The mesomorphic properties were investigated by means of three complementary methods: differential scanning calorimetry, polarizing light optical microscopy, and transmitted light intensity. The electro-optical measurements were carried out on an ordered sample in a middle electric field during very slow cooling from the nematic phase to the ferroelectric phase.     

The intermediate glassy phase in a ferroelectric with dislocations

This paper examines, in the mean-field approximation, the phase transitions in an elasto-isotropic cubic ferroelectric crystal with randomly distributed ring dislocations. It is found that a transition to the dipole-glass phase with chaotic, spontaneous unit-cell dipole moments, characterized by the Edwards-Anderson nonlocal parameter, precedes the transition to the ferroelectric phase. Also determined are the features of the thermodynamic parameters of the crystal at the phase-transition points. Zh. éksp. Teor. Fiz. 116, 986–1000 (September 1999)     

Formation and structure of a soliton in an antiferroelectric liquid crystal in an electric field

The soliton structure in an antiferroelectric liquid crystal in an electric field is calculated in the discrete phenomenological Landau model for phase transitions. The anticlinic structure of the antiferroelectric crystal gives rise to nontrivial features of the soliton structure and the stability of the soliton. The soliton is topologically stable in a metastable state if the electric field is much higher than the field of antiferroelectric-helix unwinding. A structural transition with a step-like change in the orientation of molecules occurs as the soliton field varies. A peculiar soliton (synclinic pair) can be formed if the barrier between the anti- and ferroelectric structures is large. The calculation shows the possibility of a large electroclinic effect in the soliton, i.e., a variation in the molecular tilt angle in an electric field in the vicinity of the transition of the structure to the synclinic state.     

Influence of disorder in crystal structure on ferroelectric phase transitions

A new model of ferroelectric phase transitions in disordered crystals is developed. The model takes into account the nonequivalence of the structural environment of identical ions, which alters the balance of forces governing ferroelectric structural instability. In contrast with its predecessors, the new model can be used for qualitative and, in many cases, quantitative predictions of the temperature range of the diffuse ferroelectric phase transition and the value of the disorder-induced shift of the average transition temperature as a function of the degree of disorder and chemical composition. This conclusion is confirmed by a comparison of the theoretical results with an abundance of known experimental facts. Zh. éksp. Teor. Fiz. 111, 1817–1832 (May 1997)     

A novel type of incommensurate phase in quartz: The elongated-triangle phase

We present evidence for a thermodynamically stable incommensurate elongated-triangle (ELT) phase in quartz, observed by transmission electron microscopy at the α-β structural transition. The phase sequence on cooling is: incommensurate equilateral-triangle (EQT) phase (ferroelectric)—incommensurate ELT (ferroelectric and ferroelastic)— uniform α phase. The ELT blocks could be responsible for the large light scattering in the vicinity of the α-gb transition. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 5, 376–381 (10 September 1996) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Low temperature,high pressure Raman study of SbSBr

Abstract

We have measured the Raman spectra of the quasi-one-dimensional crystal SbSBr as a function of pressure at 295, 70, 37 and 25 K.

The pressure coefficients of the observed Raman modes have been determined and used to distinguish inter-from intrachain modes. Spectral features characteristic of the ferroelectric phase have been attributed to impurities or lattice imperfections and not to the presence of the ferroelectric phase, providing indication that the para-to ferroelectric phase transition occurs below 25 K.     

Self-induced transparency of hydrogen-containing ferroelectrics for extremely short pulses in the vicinity of the curie temperature

Nonlinear propagation of extremely short (carrierless) electromagnetic pulses in a KDP-type ferroelectric is investigated at temperatures close to the phase transition point. It is demonstrated that, although weak monochromatic signals undegro a sharp attenuation at these temperatures, an extremely short high-power pulse can propagate in the self-induced transparency regime and the associated soliton is stable to transverse perturbations.     

Ferroelectric phase transition in deuterated dihydrogen phosphate,studied by infrared spectroscopy

Abstract

The temperature dependence of polar phonon spectra of K(H_1?X D_X)₂ PO₄ single crystal with x = 0.9 for the electric field polarised parallel and perpendicular to the ferroelectric axis is reported between 7 and 300 K, in the para- and ferroelectric phase.     

Effects of gordon-haus jitter on soliton transmission

Abstract

The bit error rate (BER) performance of an optical soliton communication system is analyzed. Based on the jitter variance equation and the chi-square distribution for the amplified spontaneous emission noise, an analytic expression for the BER calculation is obtained. We have investigated the effects of Gordon-Haus jitter, which is due to the random phase shift of the soliton individual central wavelength induced by the amplified spontaneous emission noise of the amplifiers. Very good agreement has been obtained between our theory and the reported experimental results.     

Phase transitions induced in NaNbO3 crystals by varying the direction of an external electric field

The anisotropic behavior of the electrostatic field characterizing the phase transition from an antiferroelectric state to a ferroelectric state is studied for the first time with NaNbO₃ as an example. Structural changes taking place in the crystal as the direction of the electrostatic field is varied are studied and electrostatic field magnitude-direction phase diagrams are determined. Fiz. Tverd. Tela (St. Petersburg) 39, 1084–1087 (June 1997)     

Hard soliton excitation regime: Stability investigation

The problem of the stability of one-dimensional solitons in the hard regime of soliton excitation, where the matrix element of the four-wave interaction has an additional smallness, is studied. It is that shown for optical solitons striction can weaken the Kerr nonlinearity. It is shown that solitons with a finite amplitude discontinuity at the critical soliton velocity, equal to the minimum phase velocity of linear waves, are unstable while solitons with a soft transition remain stable with respect to one-dimensional perurbations. Two-and three-dimensional solitons near threshold are unstable with respect to modulation perturbations. Zh. éksp. Teor. Fiz. 116, 299–317 (July 1999)     

Emergence of heterophase structures near phase transitions in photoferroelectric materials

The present study shows that under intense illumination, various spatially nonuniform states may emerge near structural phase transitions in systems with semiconducting properties. Different traveling and stationary autosoliton states are studied, and so is a periodic heterophase structure with alternating para-and ferroelectric phases, which results from a redistribution of electrons on trapping levels. The problem is solved for the one-dimensional case. The emergent behavior is related to the dynamics of the ferroelectric semiconductor as a whole and is an example of synergistic behavior. Zh. éksp. Teor. Fiz. 111, 1465–1476 (April 1997)     

Ferroic phase transitions in β-LiNH4SO4

Abstract

The paper reviews the results of experimental and theoretical studies of ferroic phase transitions in β-LiNH₄SO₄ and its deuterated analogue. β-LiNH₄SO₄ undergoes succesive phase transitions: a paraelectric - ferroelectric phase transition at T₁ ? 462 K, a ferroelectric - ferroelastic phase transition at T₂ ? 283 K and a transition from one ferroelastic phase to the other at T₃ ? 28 K. Attention is focused on the influence of the order of phase transitions on the pattern of ferroelectric and ferroelastic domain structure, and also on the role played by the dynamics of molecular groups in the mechanism of transitions. The pre-transition effect connected with the ferroelectric-paraelectric transition: heterophase, capable of accounting for anomalies in different physical properties present 1-3 K below T₁ is shown. The anomalous temperature variation of spontaneous polarisation of the crystal is discussed within the framework of the phenomenological model of weak ferroelectrics.     

Soft modes and phonon interactions in studied by neutron scattering

The low frequency lattice dynamics and its relationship to the second order paraelectric-to-ferroelectric transition in Sn₂P₂S₆ is studied. The dispersion branches of the acoustic and lowest lying optical phonons in the a^*-c^* plane have been obtained in the ferroelectric phase, for x-polarized phonons. Close to the phase transition a considerable softening is found for the lowest optical mode (P_x), comparable to the behaviour observed in previous Raman investigations. As found previously in Sn₂P₂Se₆, a strong coupling between the TO(P_x) and TA(u_xz) phonons is observed, although, apparently, not strong enough to lead to an incommensurate phase. The soft TO(P_x) mode at the zone center is observed. The temperature dependence of its frequency and damping shows that the transition is not entirely displacive. At low temperatures an unusual apparent negative LO-TO splitting is observed which is shown to arise from the coupling of the x-polarized soft mode to the nearby z-polarized optical phonon. For comparison, the soft TO(P_x) dispersion in the a^*-b^* plane is measured in both the paraelectric and ferroelectric phases. Consistent frequency changes and LO-TO splitting are observed, revealing a significant interaction between the TA(u_yx) and LA(u_xx) acoustics branches and the TO and LO soft optic branches, respectively. In contrast, the nearby y-polarized optic branch shows almost no temperature dependence. Finally, the influence of piezoelectric effects on the limiting acoustic slopes in the ferroelectric phase is discussed. Received: 11 May 1998 / Revised and Accepted: 15 June 1998     

Factory-roof-shaped phase front at the paraelectric-ferroelectric transition in KD PO : an incoherent interface

The phase front during the 218 K transition in KD₂PO₄ crystals under a thermal gradient perpendicular to the c ferroelectric axis is observed to have a factory-roof shape. This shape is studied versus the magnitude of G_e in samples cut with faces in (100), (010), (001) planes or in ( 0), (110), (001) ones. A geometric approach as well as the calculation of the elastic-strain energy caused by lattice misfits along the phase front demonstrate the incoherent interface nature of the phase front. Furthemore, the results and their interpretation allow to predict the sign of the lattice deformation u _xx ( > 0). Received 25 April 2002 Published online 29 November 2002     

Ferroelectric phase transition in Langmuir-Blodgett films of copper phthalocyanine

A ferroelectric phase transition is observed in Langmuir-Blodgett films prepared from substituted copper phthalocyanine molecules. The linear and nonlinear dielectric properties of the films and the switching of their spontaneous polarization are investigated in the temperature range of the phase transition. The observed features can be explained by the Landau-Ginzburg model of a first-order phase transition. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 9, 625–631 (10 November 1999)     

Dielectric relaxation in ferroelectric (CH3)2NH2AL(so4)2 · 6H2O crystal

Abstract

This paper presents the results of the investigation of dielectric dispersion and ultrasonic velocity in the ferroelectric (CH₃)₂NH₂Al(SO₄)₂ · 6H₂O crystal. The crystal shows a critical slowing down process of polarization with an extremely long relaxation time of the dipole system (τ = 1.6 · 10^?7s at the phase transition point). The dielectric response over the frequency range up to 56 GHz in the paraelectric phase can be well described in terms of a monodispersive Debye-type formula. The activation energy of dipoles in the paraelectric phase is 0.11 eV = 8.5 kT_c . The results show that the proper ferroelectric phase transition is nearly critical and of the order-disorder type.     

Relaxation processes in the incommensurate phase of a crystal with defects

The nature of the relaxation of the incommensurate superstructure of a ferroelectric to the equilibrium state is investigated experimentally. It is shown that near a phase transition the temperature dependence of the relaxation time of the incommensurate phase of the defective crystal is exponential. This law agrees qualitatively with the notion of domain wall motion in an inhomogeneous medium containing “random local phase-transition temperature” type defects. Fiz. Tverd. Tela (St. Petersburg) 41, 513–515 (March 1999)     

Atomic 6p-Tl0 centers in ferroelectric Rb2ZnCl4 crystals

Abstract

Several Tl⁰ (6s²6p ¹)-type paramagnetic centers, produced by low temperature X-ray irradiation, were observed and studied by electron spin resonance (ESR) in the orthorhombic ferroelectric phase of thallium doped Rb₂ZnCl₄ crystals. The centers were formed by electron trapping at Tl⁺ ions localized substitutionally at Rb⁺ sites. The number and properties of the observed centers account for the tripling of the unit cell in the ferroelectric phase.