Ordering of gas bubbles during light ion gas implantation

There have been interesting observations about ordering of microstructures during irradiation. The formation of void lattices is amongst the better known examples. Ordering has also been observed in small gas filled bubbles formed during low energy light ion implantation in the energy range 30–100 keV. The basic underlying mechanism for ordering of gas bubbles has not been clearly understood so far. We identify in this paper a basic instability in the growth kinetics of such bubbles which can develop during irradiation. This instability is shown to be associated with the interstitial production due to the high pressure inside these bubbles and their differential bias due to the strain field interactions with vacancies and interstitials. It is shown that such an instability leads to a selection of a wavelength scale which agrees with the observed lattice parameter.     

Suppression of the coalescence of gas bubbles in aqueous electrolyte solutions: dependence on the external pressure and velocity of gas flow through a column with liquid

An experiment on laser diagnostics of gas bubbles moving in aqueous solutions of different electrolytes has revealed that efficient suppression of gas bubble coalescence (collapse) occurs at certain concentrations of cation?anion pairs. It is experimentally proven that there is an optimal ion composition at which the coalescence is suppressed in a wide range of velocities of gas particle flow through a column with liquid. It is shown that the threshold ion concentrations corresponding to the onset of coalescence suppression decrease with an increase in the external pressure in the liquid. The results obtained can be used in oil production technologies to solve the problem of burning associated oil gas in torches.     

Rising of gas bubbles in an aqueous medium in presence of surfactants

Summary Experiments based on the direct comparison of the gas-bubble rising times in a surfactant aqueous solution, in respect to those in pure water, give support to the hypothesis that a rising path of many metres is needed to reach the saturation of the adsorption process on bubbles (0.2÷0.3) cm in diameter. A maximum is evidenced in thet/t ₀ ratiovs. surfactant concentration at the highest concentrations tested. An explanation, on a qualitative basis, of the appearance of the observed maximum is proposed. Work presented at the IV Congress of the CNR (National Research Council) National Group of the Atmosphere and Ocean Physics, Rome, June 22–24, 1987.     

The effect of ultrasound on the electrolytic conductivity of aqueous sulphate and nitrate solutions

The electrolytic conductivity of aqueous sulphate and nitrate solutions of various metals such as sodium, magnesium, calcium, etc, have been measured with and without the propagation of ultrasonic waves at 2.4 MHz. The propagation of ultrasound of equal intensities has different effects on different sulphate and nitrate solutions. In all cases a marked increase in the conductivity was observed. The change in electrolytic conductivity showed a gradual fall when recorded in terms of increasing order of atomic weight/number of the metal ions. The trend was repeated at all acoustic pressures used; however, with decreasing acoustic power the dependence of conductivity on atomic weight/number became less apparent. Attempts have been made to interpret this phenomenon on the basis of Debye and other related effects.     

Glucose content detection in aqueous solutions with near-infrared polarization spectrometry

The absorbance using diffuse reflectance in the polarization spectroscopy was expressed using the empirical expressions that fitted the Monte Carlo simulation results. The absorbance spectra of glucose solutions indicated that the partition among H₂O molecular species changed partly to the other ones depending on the glucose content. In saline water and phosphate-buffered saline water, there appears an action opposite to the transition in dissolution of glucose by the destruction of water species due to the presence of Na⁺ and Cl^? ions. The sensitivity of glucose concentration in them was found to be higher in the cross-polarization than in the parallel one owing to the increased travelling distance caused by multiscattering.     

Kinetics of fluorescence polarization for solid bichromophore solutions in intense pulse excitation

The kinetics of fluorescence polarization in intense pulse excitation of solid disordered solutions of bichromophores that consist of complex molecules of two types between which there can be inductiveresonance transfer of electron-excitation energy is theoretically investigated. Variants of fluorescence excitation by single pulses and pulse trains are considered. The lifetime of the fluorescence of a given solution increases with the intensity of the exciting pulses. The possibility of controlling the duration of fluorescence attenuation for donor molecules incorporated into the bichromophores by the action of luminescence radiation at the frequency of acceptor-molecule absorption on the solution is demonstrated. Belarusian State University, 4, F. Skorina Ave., Minsk, 220050, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii Vol. 65, No. 4, pp. 546–550, July–August, 1998.     

Kinetics and mechanisms of ultrasonic degradation of volatile chlorinated aromatics in aqueous solutions

Ultrasonic decompositions of chlorobenzene (ClBz), 1,4-dichlorobenzene and 1-chloronaphthalene were investigated at 500 kHz in order to gain insight into the kinetics and mechanisms of the decomposition process. The disappearance of ClBz on sonication is almost simultaneously accompanied by the release of chloride ions as a result of the rapid cleavage of carbon–chlorine bonds with a concomitant release of CO, C₂H₂, CH₄ and CO₂. The intermediates resulting from attack of HO^√ radicals were detected but in a quite low yield (less than 2 μM). The generation of H₂O₂ on sonolysis is not significantly affected by the presence of aqueous ClBz while the generation of NO₂⁻ and NO₃⁻ is inhibited initially due to the presence of ClBz which diffuses into the gas–bubble interfaces and inhibits the interactions between free radicals and nitrogen. Moreover, brown carbonaceous particles are present throughout the ultrasonic irradiation process, which are consistent with soot formation under pyrolytic conditions. These important features suggest that, at the relatively high initial substrate concentrations used in this study, ultrasonic degradation of ClBz takes place predominantly both within the bubbles and within the liquid–gas interfaces of bubbles where it undergoes high-temperature combustion. Under these conditions, the oxidation of ClBz by free radical HO^√ outside of bubbles is a minor factor (though results of recent studies suggest that attack by HO^√ is more important at lower initial substrate concentrations). The sonochemical decomposition of volatiles follows pseudo-first-order reaction kinetics but the degradation rates are affected by operating conditions, particularly initial substrate concentration and ultrasonic intensity.     

Sonolysis of surfactants in aqueous solutions: an accumulation of solute in the interfacial region of the cavitation bubbles

The sonolysis of surfactants (such as sodium dodecylbenzenesulfonate (DBS), sodium dodecylsulfate (SDS), and polyethylene glycol monostearate), sodium 4-toluenesulfonate (STS), and 1-hexanol in aqueous solutions was investigated under an argon atmosphere with ultrasound of 200 kHz in order to compare the scavenging efficiency of the hydroxyl radical and the accumulation in the gas-liquid interfacial region of the cavitation bubbles. The degradation rate of the solute follows the order 1-hexanol > DBS and SDS > STS. The scavenging efficiency of the hydroxyl radical by non-volatile surfactants was much greater than that of the non-volatile and hydrophilic solute (e.g., STS). The surfactant was accumulated in a relatively high ratio in the interfacial region. The degradation of surfactants occurred by reaction with the hydroxyl radical and also by pyrolysis at high temperature. On the other hand, STS, due to its non-volatile and hydrophilic properties, was principally present in the bulk solution and the degradation by pyrolysis was not observed at the investigated concentration ranges.     

Kinetics of carbon nanopillar formation on a pyrolytic graphite surface during reactions induced by a focused electron beam

The results from a series of height measurements of carbon nanopillars formed during residual hydrocarbon deposition on a pyrographite surface by a focused electron beam in an SEM are presented. The high initial velocity of the pillars’ vertical growth can be explained by the dominant role of surface diffusion in the influx of molecules to the irradiated area. It is shown that progressive contamination of the substrate at distances up to several micrometers from the point of impact of the primary beam delays growth, and, in the case of long-time exposure, results in the evaporation of the pillars.     

In-water gas combustion in linear and annular gas bubbles

A new pulsed-cyclic method of in-water gas combustion was developed with separate feed of fuel gas and oxygen with the focus on development of new technologies for heat generators and submerged propellers. The results of calorimetric and hydrodynamic measurements are presented. In-water combustion of acetylene, hydrogen, and propane was tested with the operation frequency of 2–2.5 Hz and with a linear injector. The combustion dynamics of combustion of stoichiometric mixture with propane (C₃H₈+5O₂) was studied for a bubble near a solid wall; the produced gas bubble continues expansion and oscillations (for the case of linear and annular bubbles). It was demonstrated that gas combustion in annular bubbles produces two same-magnitude pulses of force acting on the wall. The first pulse is produced due to expansion of combustion products, and the second pulse is produced due to axial cumulative processes after bubble collapse. This process shapes an annular vortex which facilitates high-speed convective processes between combustion products and liquid; and this convection produces small-size bubbles.     

Kinetics and mechanism of copper fracture during deformation in surface-active baths

Relations have been derived here between the macroscopic characteristics of liquid metal embrittlement (durability _c under creep and strain _c prior to rupture under tension) and the parameters which characterize the micromechanism of fracture (surface energy at the crystal bath interface, energy of grain boundaries, temperature, structure of the crystal-bath interface, etc.), on the basis of test data indicating that the subcritical stage of microcrack development governs the fracture process, and on the assumption that transition to supercritical fracture occurs when the crack angle at the tip opens to its critical width _c. It is also shown here that, as the rate of subcritical crack development changes by three orders of magnitude, the magnitude of the critical angle _c changes only by a factor of 3.0 and may, to the first approximation, be regarded as independent of the bath composition. The values of _c and _c calculated according to this approximation agree closely enough with values based on tests.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 22–29, July, 1976.     

From ordered bubbles to random stripes: Pattern formation in a hydrodynamic lattice gas

A two-component momentum-conserving lattice gas with competing interactions is introduced in two dimensions. One interaction acts at short range and produces interfaces with surface tension. The second interaction, the negative of the first, acts at rangea and produces modulated structures with approximate wavelength 2a. Depending on particle density, species concentration, and relative interaction strength, the equilibrium patterns formed by the model range from isotropic mixed and unmixed phases to hexagonally-ordered bubbles to randomly-oriented stripes. A Ginzburg-Landau equation is proposed that qualitatively captures the basic features of these phase transitions.     

Caffeine as non-toxic corrosion inhibitor for copper in aqueous solutions of potassium nitrate

Different electrochemical methods were employed in order to confirm the ability of caffeine (1,3,7-trimethylxanthine) to inhibit the corrosion processes of copper in aqueous potassium nitrate solutions in the absence and in the presence of chloride. Some experiments were repeated in potassium perchlorate in order to compare the influence of the medium. The interaction between the organic compound and the electrode surface occurs independently of the electrode potential. However, maximum interaction was observed at 0.0 V (Ag/AgCl) in aerated solutions, and at −0.25 V (Ag/AgCl) in deaerated solutions.The presence of the organic compound adsorbed on the electrode surface was confirmed by comparing the voltammograms of copper electrode in the absence and presence of 1.5 mmol L⁻¹ of dissolved caffeine. The same results were observed by comparing polarization curves in the absence and in the presence of caffeine.Anodic currents decrease noticeably in the presence of the organic compound. Chronoamperometric experiments were conclusive to prove the inhibitor capability of caffeine to decrease the corrosion dissolution processes of copper under anodic polarization.     

Ultrasound assisted reduction of graphene oxide to graphene in l-ascorbic acid aqueous solutions: Kinetics and effects of various factors on the rate of graphene formation

The reduction of graphene oxide (GO) to graphene (rGO) was achieved by using 20 kHz ultrasound in l-ascorbic acid (l-AA, reducing agent) aqueous solutions under various experimental conditions. The effects of ultrasound power, ultrasound pulse mode, reaction temperature, pH value and l-AA amount on the rates of rGO formation from GO reduction were investigated. The rates of rGO formation were found to be enhanced under the following conditions: high ultrasound power, long pulse mode, high temperature, high pH value and large amount of l-AA. It was also found that the rGO formation under ultrasound treatment was accelerated in comparison with a conventional mechanical mixing treatment. The pseudo rate and pseudo activation energy (E_a) of rGO formation were determined to discuss the reaction kinetics under both treatment. The E_a value of rGO formation under ultrasound treatment was clearly lower than that obtained under mechanical mixing treatment at the same condition. We proposed that physical effects such as shear forces, microjets and shock waves during acoustic cavitation enhanced the mass transfer and reaction of l-AA with GO to form rGO as well as the change in the surface morphology of GO. In addition, the rates of rGO formation were suggested to be affected by local high temperatures of cavitation bubbles.