The role of carrier mobility in holographic recording in LiNbO3

We investigate the role of carrier mobility in holographic recording in LiNbO₃ crystals. Both normal holographic recording (single wavelength, single trap) and two-center recording are considered, and the differences between the performances of the two methods are explained. We show that increasing mobility by using stoichiometric crystals or by doping with Mg does not improve sensitivity considerably, but does reduce M/# by at least one order of magnitude. Received: 22 February 2001 / Revised version: 5 March 2001 / Published online: 27 April 2001     

Intrinsic photorefractive centers in LiNbO3:Fe

In LiNbO₃:Fe,Me crystals (Me = K, Mg, Zn) elementary holograms are recorded and erased with frequency-doubled, ordinarily polarized pulses of a Q-switched Nd:YAG laser. At high light intensities (I > 10⁹ Wm^–2) holographic sensitivities and saturation values of refractive index changes grow with increasing intensity and a contribution to photo-conductivity appears increasing quadratically withI. The intensity-dependent parts of the holographic quantities are diminished by increasing the lithium content of the samples or by doping the crystals with magnesium or zinc. Experimental results can be described by a two-center charge transport model, which is the Fe^2+/3+ model supplemented by shallow traps, namely niobium ions occupying lithium sites.     

Light-induced refractive index changes in LiNbO3:Ti waveguides

Holographic measurements of light-induced refractive index changes in LiNbO₃Ti waveguides are reported. The results demonstrate that Fe²⁺ centers are stabilized against oxidation in the region of large Ti concentration near the surface thus increasing the sensitivity to optical damage considerably. This undesired effect may be largely abolished by additional in-diffusion of protons.     

Charge transport processes in LiNbO3:Fe at high intensity laser pulses

Light-induced refractive index changes in LiNbO₃:Fe crystals are investigated at high light intensities (>10⁹ Wm^–2). Holographic gratings are recorded and erased with frequency-doubled pulses of a Q-switched Nd:YAG laser. We find new intensity dependent contributions to the holographic sensitivity, to the photoconductivity, and to the saturation value of refractive index change. Light-induced absorption changes are also detected. These results indicate that the Fe²⁺/Fe³⁺ charge transport model, well established for low intensities, has to be modified for high intensities by assuming additional centers which trap and supply electrons.     

Dark build-up of holograms in BaTiO3 after recording

Holograms recorded under suitable conditions in photorefractive BaTiO₃ exhibit an unusual dark build-up. The diffraction efficiency increases by some orders of magnitude after the recording beams are switched off, and then steadily decreases afterwards. An interpretation of this effect in terms of a two-center charge transport model is given.     

Structure and nonvolatile holographic recording of Mg:Ce:Cu:LiNbO3 crystals

A series of Mg:Ce:Cu:LiNbO₃ crystals has been grown by Czochralski method. Their infrared transmittance spectra and ultraviolet-visible absorption spectra were measured and discussed to investigate their defect structure. The nonvolatile holographic recording of Mg:Ce:Cu:LiNbO₃ crystals was characterized by the two-photon fixed method. We found that the recording time of Mg:Ce:Cu:LiNbO₃ crystals became shorter and nonvolatile diffraction efficiency decreases with the increase of Mg doping concentration, especially doping with Mg approaches and exceeds the so-called threshold. And the nonvolatility vanishes when the concentration of MgO exceeds 4 mol%. The intrinsic and extrinsic defects were discussed to explain the nonvolatile holographic properties in the Mg:Ce:Cu:LiNbO₃ crystals.     

High-sensitivity read-write volume holographic storage in reduced KNbO3 crystals

Reduced KNbO₃ is a photoconductive ferroelectric in which holograms can be recorded by the photorefractive effect. Read-write volume hologram storage and erase sensitivities ofS ⁻¹=100 J/cm² andS ⁻¹=84 J/cm² (S=d(Δn)/d(I₀t)‖_t=0) have been measured at zero applied electric field, where the charge transport is shown to be due to diffusion of photoexcited electrons. By applying an electric field along thec-axis, the migration length of the photoexcited electrons becomes comparable to the holographic grating spacing. This leads to storage sensitivities comparable to high-resolution photographic plates. Experimental data on storage and erase sensitivity as a function of the grating spacing, applied electric field, writing light intensity and temperature are reported and interpreted on the basis of the theoretical results of Young et al. and Amodei. Changes of the intensity ratio of the writing beams by self diffraction (beam coupling), reflections from surfaces and the residual dark conductivity are assumed to cause experimental results which deviate from the theoretical models. It is shown, that in reduced KNbO₃ and other ferroelectric photoconductors having photocarrier transport lengths much larger than the unit cell dimension, photovoltaic currents do not contribute significantly to the build-up of space-charges leading to the photorefractive effect.     

Material characterization by holographic methods

After an introduction to the theoretical fundamentals, different holographic techniques for material characterization are presented: Isotropic and anisotropic diffraction measurements, interferometric techniques, holographic microphotometry, isotropic and anisotropic holographic scattering and self-diffraction experiments, beam-coupling topography and neutron holography.     

Quasinondestructive holographic recording in photochromic LiNbO3

We have observed quasinondestructive holographic storage with a continuous-wave laser at lambda = 532 nm in near-stoichiometric LiNbO3 doped with Tb and Fe. This crystal showed an exceptionally long grating decay time and also exhibited a fast color change upon exposure to ultraviolet (UV) light. It was demonstrated that the grating recorded from the UV-exposed, colored state can be continuously read out over 9 h at a reading intensity as high as 8 mW/cm(2). In addition, the written grating could be easily erased with UV illumination which returned the crystal back to the original colored state.     

Performance improvement of a holographic double-exposure interferometer by heating of the photorefractive recording crystal

A holographic double-exposure interferometer for quasi real-time analysis is realized, utilizing a photorefractive BTO:Cd crystal for hologram recording. Heating of the crystal reduces the time required to reach the steady-state working situation. Light-induced absorption losses are reduced by heating as well. Additionally, the diffraction efficiency is increased by this method. A sixfold increase in the light intensity of the reconstructed interferogram is achieved. Received: 2 December 1998 / Revised version: 28 January 1999 / Published online: 7 April 1999     

Two-center holographic recording in highly doped LiNbO3 crystals

In this paper, we report the observation of electron tunneling during two-center recording in LiNbO₃:Fe:Mn doped with high Fe concentration. Unlike tunneling in the singly doped lithium niobate that erases the hologram, the effect in two-center recording can improve the diffraction efficiency of the hologram after the recording while it is kept in the dark. A detailed study of this effect in LiNbO₃:Fe:Mn is presented both theoretically and experimentally. We show that the hologram strength may increase or decrease due to tunneling, depending on the experimental condition of recording. PACS 42.40.-i; 42.70.Ln; 42.40.Lx     

Thermal fixing of holographic gratings in planar LiNbO3:Ti:Fe waveguides

3 :Ti:Fe waveguides are thermally fixed during hologram recording at elevated temperatures. Different guides are fabricated by titanium indiffusion using iron-doped and nominally pure y-cutLiNbO₃ substrates and characterization is performed by dark-mode spectroscopy. The refractive index modulation of gratings written and simultaneously fixed at 180 °C is investigated as a function of propagation depth, titanium and iron concentration. The experimental results are compared with those obtained for unfixed holograms recorded at room temperature. Received: 21. July 1997/Revised version: 13 October 1997     

Optical holographic memory using angular-rotationally phase-coded multiplexing in a LiNbO3:Fe crystal

We propose a new holographic memory scheme based on random-phase-coded multiplexing in a photorefractive LiNbO₃:Fe crystal. Experimental results show that rotating a diffuser placed as a random-phase modulator in the path of the reference beam provides a simple yet effective method of increasing the holographic storage capabilities of the crystal. Combining this rotational multiplexing with angular multiplexing offers further data-storage possibilities. The advantage of using post-image versus pre-image phase modulation of the object beam is demonstrated. Received: 15 August 2000 / Published online: 10 January 2001     

New azo-dye-doped polymer systems as dynamic holographic recording media

Polymer materials show their impact on optical storage technology for developing high information density and fast access-type memories with a high read-out efficiency. New azo-dye-doped polymer materials have been developed and used for recording dynamic holograms. Dynamic holograms with reasonably high diffraction efficiency have been recorded at 468 nm, and the efficiency of the Write, Read and Erase (WRE) cycle in these azo-dye-doped polymer materials was determined. Significant observations in these materials are: (i) there is no need to change the polarization of the writing beam to erase the recorded holograms, (ii) the whole WRE cycle is very fast (3–6 s) and (iii) recording of more than 250 WRE cycles without any fatigue of the recording materials is possible.     

Photoconductivity and light-induced absorption in KNbO3:Fe

Measurements of photoconductivity and light-induced absorption in KNbO₃: Fe are performed at different light intensities and crystal temperatures. The results are interpreted in terms of a two-center charge transport model. Different model parameters may be evaluated from the experimental data. A complete set of parameters is suggested explaining the dependences of photoconductivity and light-induced absorption on light intensity and temperature for the KNbO₃: Fe crystal investigated.     

Refractive-index change and sensitivity improvement in holographic recording in LiNbO3:Ce:Cu crystals with green light

Nonvolatile holographic recording is performed with green light in LiNbO3:Ce:Cu crystals. The refractiveindex change and the recording sensitivity are times better than those obtained by recording with red light,and higher optical fixing efficiency is obtained. Correspondingly, theoretical investigations are given.     

Conductivity and light-induced absorption in BaTiO3

A charge transport model including deep and shallow traps explains both the nonlinear relation between photoconductivity and light intensity and the light-induced absorption in BaTiO₃. A correlation between measurements of photoconductivity and light-induced absorption as a function of temperature yields parameters for the shallow center, among them thermal activation energy and generation rate.     

Influence of auxiliary violet light on holographic kinetics at low and high recording intensities in bacteriorhodopsin film

The photochromic bacteriorhodopsin (BR) film can be used as a rewritable holographic recording medium. Due to the saturation absorption and the scattering and reflecting lights from the BR film, the grating contrast-ratio of the hologram is diminished during the hologram recording. When the intensity of the recording light is low, the influence of the saturation absorption and the scatter and reflection of BR film on the grating contrast-ratio is weak. But for the case of intense recording light, this influence is more serious. It is found that the influence of the auxiliary violet light on the holographic kinetics of diffraction efficiency is distinct under different recording intensities. At the low recording light intensity, the steady diffraction efficiency is increased and the peak diffraction efficiency is suppressed by the auxiliary violet light. But for intense recording light, the steady diffraction efficiency and the peak diffraction efficiency are both increased by the auxiliary violet light. Based on the two-state model of BR photochromism, we give a good theoretical explanation to the above phenomena.     

Polarized-light-controlled holographic recording in an azobenzene-doped polymer film

A new polarized-light-controlled holographic recording based on the optical enhancement/restraint of self-diffraction has been demonstrated in an azobenzene-doped polymer film. It is found that a continuous variation of the polarization status as well as of the intensity of the pumping light results in a continuous variation of self-diffraction efficiency. The mechanism originates from the photo-induced anisotropy and polarization-dependent absorption. Both positive and negative replicas of an incident image were presented in real time by means of this incoherent–coherent optical conversion technique. Received: 30 March 2000 / Revised version: 28 September 2000 / Published online: 27 April 2001     

Space charge field limitations in photorefractive LiNbO3:Fe crystals

We use holographic techniques for the investigation of strongly oxidized LiNbO₃:Fe crystals with small Fe²⁺ concentrations and compare the results with theoretical predictions. Experimental evidence is presented for enhanced phase shifts between light intensity pattern and refractive index grating and for limitations of optically induced space charge fields in photovoltaic crystals due to the low concentration of filled traps. Our findings do not support the model of a nonlocal photovoltaic effect in LiNbO₃.