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1.
We present the second part of the investigation of the high sensitivity absorption spectrum of nitrous oxide by CW-Cavity Ring Down Spectroscopy near 1.5 μm. In a first paper [A.W. Liu, S. Kassi, P. Malara, D. Romanini, V.I. Perevalov, S.A. Tashkun, S.M. Hu, A. Campargue, J. Mol. Spectrosc. 244 (2007) 33-47] devoted to the 6000-6833 cm−1 region, more than 6000 line positions of five isotopologues (14N216O, 15N14N16O, 14N15N16O, 14N217O, and 14N218O), were rovibrationally assigned to a total of 68 bands. The achieved noise equivalent absorption (αmin ∼ 2 × 10−10 cm−1) allowed for the detection of lines with intensity weaker than 2 × 10−29 cm/molecule. In this contribution, the investigated region was extended down to 5905 cm−1 and additional recordings allowed accessing small spectral sections uncovered in our preceding recordings. A deeper analysis based on the predictions of the effective Hamiltonian model has allowed assigning a total of 3149 transitions and lowering the percentage of lines left unassigned from 51% to 28%. It led to the analysis of 35, 6, 7, and 6 bands for the 14N216O, 15N14N16O, 14N15N16O, and 14N218O isotopologues, respectively. Forty-two of these 54 bands are newly observed, while the rotational analysis of the twelve others is significantly extended and improved. Most of the bands were found unperturbed and their line positions could be reproduced within the experimental uncertainty (about 1 × 10−3 cm−1). The corresponding spectroscopic parameters are reported. Local rovibrational perturbations induced by either intrapolyad or interpolyad couplings were found to affect five hot bands of 14N216O. Their detailed analysis is presented.  相似文献   

2.
In the present paper, an abrupt heterojunction photodetector based on Hg1 − xCdxTe (MCT) has been simulated theoretically for mid-infrared applications. A semi-analytical simulation of the device has been carried out in order to study the performance ratings of the photodetector for operation at room temperature. The energy band diagram, carrier concentration, electric field profile, dark current, resistance–area product, quantum efficiency and detectivity have been calculated and optimized as a function of different parameters such as device thickness, applied reverse voltage and operating wavelength. The effect of energy band offsets in conduction and valance band on the transportation of minority carriers has been studied. The influences of doping concentration, electron affinity gradient and the pn junction position within heterostructure on potential barrier have been analyzed. The optical characterization has been carried out in respect of quantum efficiency, and detectivity of the heterojunction photodetector. In present model the Johnson–Nyquist and shot noise has been considered in calculation of detectivity. The simulated results has been compared and contrasted with the available experimental results. Results of our analytical-cum-simulation study reveal that under suitable biasing condition, the photodetector offers a dark current, ID ≈ 6.5 × 10−12 A, a zero-bias resistance–area product, R0A ≈ 11.3 Ω m2, quantum efficiency, η ≈ 78%, NEP = 2 × 10−12 W Hz1/2 and detectivity D* ≈ 4.7 × 1010 mHz1/2/W.  相似文献   

3.
The current status of some decay data used in nuclear astrophysics and cosmochronology is presented. The half-life of 79Se has been evaluated as 3.6(3) × 105 yr. The total energy of non-neutrino radiation released in act of 37Ar decay has been obtained being 2.709 (16) keV per disintegration. The recommended half-life values of the long-lived radionuclides (T 1/2 ≳ 106 yr) of 26Al, 40K, 53Mn, 60Fe, 87Rb, 93Zr, 98Tc, 107Pd, 129I, 135Cs, 146Sm, 176Lu, 182Hf, 187Re, 205Pb, 232Th, 235U, 238U, 244Pu, and 247Cm are given based on the evaluations published until 2010.  相似文献   

4.
Ceramic samples of bismuth ferrite and solid solutions of Bi1 − x A x FeO3 type (where A = Lu, Yb, Tm, Er, Ho, Dy, Tb, Gb, Eu, Sm, Nd, Pr, La; 0.05 ≤ x ≤ 0.20; Δx = 0.05) were prepared. Spectra of the real part of electrical conductivity were studied within the range 10−4–10−6 Hz. The dependence of the samples’ thermal stability and electrical conductivity on the size of the substituting ions was established.  相似文献   

5.
R. Jimenez  A. Rivera  A. Varez  J. Sanz   《Solid State Ionics》2009,180(26-27):1362-1371
The dependence of Li mobility on structure and composition of Li0.5 − xNaxLa0.5TiO3 perovskites (0 ≤ x ≤  0.5) has been investigated by means of neutron diffraction, nuclear magnetic resonance and impedance spectroscopy. At 300 K, all samples display a rhombohedral superstructure (R-3c S.G.), where octahedra are out of phase tilted along [111] direction of the ideal cubic cell. The elimination of the octahedral tilting is responsible for the rhombohedral–cubic transformation, detected near 1000 K. In these perovskites, La and Na cations are randomly distributed in A sites, but Li ions are fourfold coordinated at unit cell faces of the cubic perovskite. Lithium conductivity, σ300 K, decreases with the sodium content, decreasing from values typical of fast ionic conductors, 10− 3 S/cm, to those of good insulators, 10− 10 S/cm, when the interconnectivity between vacant A sites is lost (x > 0.3). In samples with x < 0.3, dc conductivity displays a non-Arrhenius behaviour, decreasing activation energy from ~ 0.37 to 0.25 eV when the sample is heated between 77 and 500 K. The temperature dependence of BLi factors shows the existence of two regimes for Li motion. Below 373 K, Li ions remain partially located near square oxygen windows that connect contiguous A sites, but above 400 K, extended Li motions become dominant. The additional decrease of activation energy from 0.25 to 0.16 eV (low-temperature 7Li NMR value), should require the full elimination of octahedral tilting which is only produced above 1000 °C.  相似文献   

6.
The phases, microstructure, and magnetic properties of Co80Zr18−xNbxB2 (x=1, 2, 3, and 4) melt-spun ribbons were investigated. The small substitution of Nb for Zr in the Co–Zr–B melt-spun ribbons resulted in the improvement of magnetic properties, especially the coercivity. The main effect of added Nb on the coercovity of Co–Zr–Nb–B melt-spun ribbons, originated from modification of the grain size of Co11Zr2 phase. The coercivity of the Co–Zr–Nb–B melt-spun ribbons depends on the annealing temperature. The optimal magnetic properties of Hc=5.1 kOe, and (BH)max=3.4 MGOe were obtained in the Co80Zr15Nb3B2 melt-spun ribbons annealed at 600 °C for 3 min.  相似文献   

7.
The Fe3+-spin in alums of type (Fe x , A11-x )NH4(SO4)2 · 12 H2O interacts (i) with the crystal lattice viaLS-coupling, and (ii) with the spins of the adjacent Fe3+-ions via magnetic dipole-dipole interaction. These interactions lead to a time fluctuation of the spin direction, characterized by correlation times τ c and τ′ c of increasing order. The times may be deduced from the57Fe-Mössbauer spectra of the alums, τ c from the width, and τ′ c ≈τ c from the position of the hyperfine structure lines. The theoretical interpretation of the Mössbauer spectra is relatively simple, when (i) the spin-lattice interaction gets frozen in, and (ii) a strong applied magnetic fieldH a decouples the spins of the Fe3+-ion and the57Fe-nucleus. The spectra were taken, therefore, at 4.2 °K and 8 kOe≦H a ≦ 54 kOe. According to the 1/r 3-dependence of the magnetic dipole-dipole interaction τ c should be related tox, the Fe-concentration, τ c ·x≈τ0=const. Forx≧0.5 our experimental results are in agreement with this rule when τ0=(1.5±0.5) · 10?9 s. For an alum withx=0.26, however, the observed spectra cannot be explained in terms of temporal spin fluctuations, at least not in the framework of the models which are available now. Here, presumedly, the electron spins of adjacent Fe3+-ions are coupled to more or less isolated and, consequently, relatively stationary spin clusters of various sizes, leading to many time independent internal magnetic fields. A treatment of this proposal is in preparation.  相似文献   

8.
The compounds Tb0.35Dy0.45Er0.2Fe2 − x Co x (0 ≤ x ≤ 2) are synthesized in both polycrystalline and single-crystal states. The composition of the new multicomponent alloys with compensated magnetic anisotropy is calculated in the framework of the single-ion magnetic anisotropy model with allowance for the data on the temperature dependences of the magnetic anisotropy constants for RFe2 single crystals. The synthesized compounds are characterized using metallographic, chemical, X-ray diffraction, and thermomagnetic methods. A combined analysis of the magnetic and magnetoelastic properties is also carried out. It is established that the high magnetostriction characteristics of the rare-earth intermetallic compounds Tb0.35Dy0.45Er0.2Fe2 − x Co x with a structure of Laves phases are observed in the region of the spin-reorientational phase transition whose temperature can be varied by properly choosing the Co content. It is found that, in the room-temperature region, the magnetic susceptibility (dλ/dH) of the composition with x = 1.3 reaches levels in excess of the value of dλ/dH for terphenol D due to the compensation of magnetic anisotropy. Original Russian Text ? I.S. Tereshina, S.A. Nikitin, G.A. Politova, A.A. Opalenko, E.A. Tereshina, I.V. Telegina, 2009, published in Fizika Tverdogo Tela, 2009, Vol. 51, No. 1, pp. 85–90.  相似文献   

9.
The experimental data on inclusive spectra of the π+ mesons produced in p + A collisions at the incident proton momentum of 400 GeV/c obtained by G. Leksin group at FNAL are analyzed in the framework of z-scaling. Self-similarity of the hadron production in the low-p T cumulative region is verified. Scaling function ψ(z) for the Li, Be, C, Al, Cu, Ta nuclei is constructed. It is expressed via the invariant cross section and average multiplicity density of charged particles. Results of the analysis of the low-p T data are compared with the high-p T data sets obtained by J. Cronin, R. Sulyaev and D. Jaffe groups. A microscopic scenario of p + A interactions in terms of momentum fractions x 1, x 2 is discussed. Indication on self-similarity of the cumulative pion production in p + A collisions over a wide kinematical range has been found. Based on the universality of the shape of the scaling function the inclusive cross sections of the π+ mesons produced in p + A collisions on the Li, Be, C, Al, Cu, Ta targets in deep-cumulative region (x 2 ? 1/A) are predicted.  相似文献   

10.
 We construct the incipient infinite cluster measure (IIC) for sufficiently spread-out oriented percolation on ℤ d × ℤ+, for d +1 > 4+1. We consider two different constructions. For the first construction, we define ℙ n (E) by taking the probability of the intersection of an event E with the event that the origin is connected to (x,n)  ℤ d × ℤ+, summing this probability over x  ℤ d , and normalising the sum to get a probability measure. We let n → ∞ and prove existence of a limiting measure ℙ, the IIC. For the second construction, we condition the connected cluster of the origin in critical oriented percolation to survive to time n, and let n → ∞. Under the assumption that the critical survival probability is asymptotic to a multiple of n −1, we prove existence of a limiting measure ℚ, with ℚ = ℙ. In addition, we study the asymptotic behaviour of the size of the level set of the cluster of the origin, and the dimension of the cluster of the origin, under ℙ. Our methods involve minor extensions of the lace expansion methods used in a previous paper to relate critical oriented percolation to super-Brownian motion, for d+1 > 4+1. Received: 13 December 2001 / Accepted: 11 July 2002 Published online: 29 October 2002 RID="*" ID="*" Present address: Department of Mathematics and Computer Science, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. E-mail: rhofstad@win.tue.nl  相似文献   

11.
The problem of boundness of a + b + c d four-particle Coulomb systems (quadrions) is studied versus the masses of the particles involved. Inequalities that make it possible to deduce that, if some reference quadrions form a bound state, the same is true for a large number of quadrions formed by particles having various masses were derived. A compendium of calculations for energies of reference systems that possess various symmetries [positronium molecules (e + e + e e ) and quadrions of the a + b + b b , a + b + a b , and a + a + b c types] is given, and groups of bound asymmetric quadrions corresponding to them are determined. An inequality for kinetic energies of particles that makes it possible to find out, by using asymmetric reference systems, whether specific quadrions are bound is obtained. It is shown that the boundness of many quadrions is ensured by the boundness of respective three-particle systems. The entire body of the present results permits proving that, of the total number of 406 quadrions containing electrons, muons, pions, kaons, protons, deuterons, and tritons and their antiparticles, 227 quadrions are bound.  相似文献   

12.
The structure of the mixed fluorites Ca1−x SrxF2 and Sr1−x BaxF2, as well as the structure of the Eu2+ impurity center in these crystals, is calculated within the framework of the virtual-crystal method realized in the shell model and pair-potential approximation. The phenomenological dependence of the position of the lower level of the 4f 65d configuration of the Eu2+ ion on distance to the Eu2+-ligand is derived. The dependences of the Stokes shift and the Huang-Rhys factor on x are calculated for the yellow luminescence in Sr1−x BaxF2:Eu2+. The value of x at which the lower level of the 4f 65d configuration of the Eu2+ ion in Sr1−x BaxF2:Eu2+ falls within the conduction band is found. __________ Translated from Fizika Tverdogo Tela, Vol. 45, No. 5, 2003, pp. 823–826. Original Russian Text Copyright ? 2003 by Nikiforov, Zakharov, Chernyshev, Ugryumov, Kotomanov.  相似文献   

13.
At RIKEN (The Institute of Physical and Chemical Research) in Japan, we have performed experiments to study the productions and decays of the heaviest elements produced by one-neutron emission channels of 208Pb and 209Bi based heavy-ion-induced fusion reactions. A gas-filled-type recoil separator has been used for collecting evaporation residues of the reactions separating them from high intensity beam particles. The reactions studied were 208Pb(58Fe,n)265Hs, 208Pb(64Ni,n)271Ds, 209Bi(64Ni,n)272Rg, 208Pb(70Zn, n) 277112, and 209Bi(70Zn,n)278113. In studies of the first four reactions we have provided the independent confirmations of the productions and their decays of the isotopes, 265Hs, 271Ds, 272Rg, and 277112, as well as the decay properties of their decay daughters, previously studied by Hofmann et al., a group of Gesellschaft für Schwerionenforschung (GSI), Germany. In the last reaction, we observed two decay chains originated from the isotope 278113, assigned firstly by generic correlation of the alpha decay chains connected into the previously known decay of 266Bh and 262Db via previously unknown alpha decays of 278113, 274Rg and 270Mt.  相似文献   

14.
Ab initio configuration interaction wavefunctions and energies are reported for the ground state and many low-lying singlet and triplet states of magnesium chlorin and chlorin, and are employed in an analysis of the electronic absorption spectra of these systems.In chlorin, the calculated visible spectrum consists of two 1(π, π1) states, the lower energy, y-polarized state exhibiting moderate absorption intensity in contrast to the very weak absorption of the higher energy x-polarized state. The configurational composition of both states is well described by the four-orbital model. Five 1(π, π1) states are responsible for the Soret band envelope. A moderately intense y-state lies under the low energy edge of the band envelope, while two x-polarized states of moderate and strong intensity, respectively, are responsible for the band maximum. The final two 1(π, π1) states lie at the high energy edge of the Soret band and introduce a measure of asymmetry into the band envelope. Two 1(n, π1) states of very weak oscillator strength are also found in this region of the spectrum. All the Soret states are of complex configurational composition, and several of the higher lying states contain contributions from doubly excited configurations.The calculated visible spectrum of magnesium chlorin also consists of two 1(π, π1) states, with the weakly absorbing x-polarized state lying approximately 200 cm?1 lower in energy than the moderately intense y-polarized state. The configurational composition of both states is well described by the four-orbital model. Four 1(π, π1) states constitute the bulk of the intensity in the Soret band envelope. In distinction to chlorin, the moderately intense 1(π, π1) state at the low energy edge of the band envelope is x-polarized. Two intense 1(π, π1) states of y- and x-polarization, respectively, constitute the band maximum region, and a single x-polarized state of moderately strong intensity can be assigned to the high energy shoulder of the band envelope. Two other weakly absorbing 1(π, π1) states are also found in this region, along with another weakly absorbing state of mixed in-plane and out-of-plane polarization. No clearly defined 1(n, π1) states are observed. As was the case for chlorin, all the Soret states are of complex configurational composition, and some of the higher energy states contain significant contributions from doubly excited configurations.Chlorin and magnesium chlorin both possess three 3(π, π1) states which lie below S1 and a single 3(π, π1) which lies slightly above S2. All four of the low-lying 3(π, π1) states in each molecule are well described by the four-orbital model, with T1 being essentially a single configuration in each case. The remainder of the 3(π, π1) states are clustered in the same energetic region as the comparable 1(π, π1) Soret states, with comparably complex configurational compositions.Dipole moments and charge distributions for low-lying singlet and triplet states are also reported, and are used to rationalize chemical reactivity characteristics.  相似文献   

15.
31P nuclear magnetic resonance (NMR) shifts on the order of thousands of parts per million are observed for olivine LiMPO4 (M = Mn, Fe, Co, Ni) samples, a promising class of Li ion rechargeable battery electrode materials. Variable-temperature 31P NMR measurements of shift are used to determine that the supertransferred hyperfine interaction is the dominant mechanism giving rise to these unusually large observed 31P shifts. Various models for predicting 31P and 7Li shifts in LiMPO4 (M = Mn, Fe, Co, Ni) were investigated. Alloys of LiFe1−x Mn x PO4, where x varies from 0 to 1, were also investigated by 7Li NMR. Covalency constants, calculated from variable-temperature NMR shifts and magnetic susceptibility data, are determined for the P–O–M bonds in LiMPO4 (M = Mn, Fe, Co, Ni) and compared to the covalency constants of the Li–O–M bond. The sign and relative magnitude of the covalency constants are discussed in terms of positive and negative spin densities at the nuclei of interest. The covalency constants for the Li–O–M and P–O–M bonds were measured for Li1.8Na0.2FeMn2(PO4)3 and compared to the covalency constants measured in the olivine LiMPO4 (M = Mn, Fe, Co, Ni) samples. The Li1.8Na0.2FeMn2(PO4)3 structure has a volume per transition metal atom and Li–O–M bond distances that are similar to those of the olivine LiMPO4 (M = Mn, Fe, Co, Ni) samples. Authors' address: Jeffrey A. Reimer, Department of Chemical Engineering, University of California Berkeley, Berkeley, CA 94720, USA  相似文献   

16.
Critical behavior in the La0.6Sr0.4Mn0.8Fe0.1Cr0.1O3 ceramics was studied using magnetization methods. Results show that the paramagnetic–ferromagnetic transition is of second order. Based on the critical behavior analysis using the Banerjee criterion and the Kouvel–Fisher method, we find the critical exponents: β=0.395±0.010, γ=1.402±0.010, and δ=5.208±0.007, for which the magnetic interaction is satisfied within the three-dimensional Heisenberg model. Results indicate the presence of short-range interactions. The magnetic entropy change (−ΔSM) reached maximum values of 1.75, 1.45, 1.15, 0.8 and 0.43 J Kg−1 K−1 under a magnetic field variation of 5, 4, 3, 2 and 1 T, respectively. Nevertheless, these (−ΔSM) values are much low for any potential application at this moment. The nature of this phenomenon is discussed in relation to the characteristics of the magnetic phase transition and critical exponents.  相似文献   

17.
The difference of the energies of levels Δ n = E lev(2+0 n ) − E lev(0+0 n ) at n = 1, 2, and 3 and the multipole-mixture parameter δ for (2+02−2+01) and (2+03−2+01) transitions are contrasted against the structure of the K π = 02+ and 03+ rotational bands that was calculated on the basis of the quasiparticle-phonon model. The values of (Δ2 − Δ1), (Δ3 − Δ1), and (Δ2 − Δ3) are found to correlate with the sign of the parameter δ and with the calculated structure of the K π = 02+ and 03+ bands. Original Russian Text ? A.M. Demidov, L.I. Govor, V.A. Kurkin, I.V. Mikhailov, 2009, published in Yadernaya Fizika, 2009, Vol. 72, No. 2, pp. 236–240.  相似文献   

18.
R.H Dalitz  A Gal 《Annals of Physics》1978,116(1):167-243
The physical factors relevant for the production of various low-lying Λ-hypernuclear states ΛAZ1 through the K?π? and K?π0 reactions, in flight or from rest, on the corresponding target nuclei AZ and A(Z + 1) are discussed, on the basis of the shell model for these nuclei and hypernuclei, together with the characteristics of the dominant γ-transitions resulting from the excited states thus produced. Detailed consideration is given for a number of hypernuclei of specific interest, including the cases of Λ7He, ΛLi for A = 7, 9 and 10, ΛBe for A = 9 and 10, ΛB for A = 10, 11, and 12, ΛC for A = 12, 13, 14, and 15, ΛN for A = 14 and 15, and Λ16O. The importance of (γ, π?) correlation studies for the determination of hypernuclear spin values is stressed, with the discussion of several examples.  相似文献   

19.
A possibility of applying the Padé approximations to calculation of rotational-level energies of degenerate vibrational states is studied for linear molecules with various quantum numbers of the vibrational angular momentum 1. The calculations of rotational energy levels for the CO 2 molecule show that the Padé form has a better predictability as compared to a power series. Spectroscopic constants of the Padé approximations for the vibrational states (0400, 0420, 0440), (1400, 1420, 1440), (1510, 1530, 1550), and (0600, 0620, 0640, 0660) for the CO 2 molecule are determined. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 54–57, September, 2006.  相似文献   

20.
The results of recent experiments performed at KEK, Brookhaven National Laboratory, the Institute for High-Energy Physics (Protvino), and CERN to study the reaction π pπ 0 π 0 n are analyzed in detail. For S-wave pion-pion scattering in the channel of isospin I=0, new data are obtained for the phase shift δ 0 0 and the inelasticity parameter η 0 0 . Difficulties that arise in using, for the amplitudes of the S and D waves of the final π 0 π 0 system, physical solutions selected on the basis of partial-wave analyses are discussed. It is noteworthy that other solutions are preferable in principle in the region of the invariant mass m of the π 0 π 0 system above 1 GeV. With the aim of clarifying the situation and further studying the properties of the f 0(980) resonance, it is proposed to perform, in the reaction π pπ 0 π 0 n, an especially careful examination of the m region in the vicinity of the threshold. __________ Translated from Yadernaya Fizika, Vol. 67, No. 7, 2004, pp. 1380–1391. Original Russian Text Copyright ? 2004 by Achasov, Shestakov.  相似文献   

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