Assignments of methanol laser lines by frequency measurements and Fourier transform spectroscopy

We have measured the frequencies of four CH₃OH far-infrared laser lines that were previously known only by wavelength measurement. Two of these lines turned out to be doublets, bringing the total number of measured lines to six. We can now confirm the assignments of five of them and definitely disprove the assignments proposed for the sixth.In particular we confirm the assignments for the four strong laser lines at 205 and 208 µm pumped by the 9-P(34) CO₂ laser line. These lines share a common upper level in the first excited CO-stretch state, and terminate in the upper and lower levels of a hybrid state with J=5. Heterodyne frequency measurements and conventional microwave spectroscopy show that both lines are split into two components approximately 3.5 MHz apart. The origin of this further splitting is interpreted as a perturbed K-splitting.Work supported by Consiglio Nazionale delle Ricerche -Italia     

Frequency measurements of far infrared cw lasing lines in optically pumped CHCl2F

The wavelengths, frequencies, and relative polarizations of 15 FIR cw lasing lines obtained by optically pumping CHCl₂F with a cw CO₂ laser have been measured. The lines are in the wavelength range from 340.3 to 905.4 m and were pumped by P- and R-branch laser lines in the 9 m band of CO₂.Supported in part by a joint grant with the U. S. National Science Foundation grant # INT80-19014 and the Brazilian Consellio Nacional de Pesquisas (CNPq)Contribution of the U. S. Government, not subject to copyright.     

Far infrared laser lines produced by methanol and its isotopic species: A review

Methanol (CH₃OH) is considered today one of the most important active media for the generation of laser radiation in the far-infrared (FIR) spectral region. Together with ten of its other isotopic species, it is responsible for the major part of the laser lines generated by the optical pumping technique. Due to the extreme importance of those molecules as laser generators, we understood that there was a necessity of a comprehensive work which would include as much pratical information as possible about each line.Chang et al⁽¹⁾ early recognized methanol as a source of strong FIR laser lines. Since then, more than 100 papers were published containing information about new laser emission. Recently, Moruzzi et al⁽¹¹⁴⁾ presented a review of 575 lines produced by¹²CH₃OH. In the present paper, we have extended the review to the various isotopic modifications of this molecule (namely¹³CH₃OH, CD₃OH,¹³CD₃OH, CD₃OD,¹³CD₃OD, CH₃OD, CH ₃ ¹⁸ OH, CH₂DOH, CH₂DOD and CHD₂OH), a total of nearly 2000 lines with wavelengths ranging from 19µm to 3030µm.     

Frequency measurements of far infrared12CH3OH laser lines

We have measured the frequencies of 12 known and 3 new submillimeter laser lines obtained by pumping¹²CH₃OH with a cw waveguide CO₂ laser in a Fabry-Perot far infrared resonator. We have also measured the relative polarization and the pumping CO₂ frequency offset for each line.Supported in part by a joint grant with the U.S. National Science Foundation # INT80-19014 and the Brazilian Conselho Nacional de Pesquisas (CNPq).Work of the U.S. Government; not subject to U.S. copyright.     

New far infrared laser lines obtained by optically pumping13CD3OD

We have obtained laser action on 34 far infrared lines for the first time in fully deuterated methyl alcohol with the¹³C isotope (¹³CD₃OD), and we have measured the frequency of 13 lines. The molecule was pumped by a cw CO₂ laser. We have measured the wavelength, the relative polarization, the relative intensity of most lines, the frequency, and the CO₂ pump frequency offset of the strongest lines. The new lines are distributed in the wavelength region from 75.27 m to 464.7 m.Supported in part by a joint grant with the U.S. National Science Foundation grant # INT 80-19014 and the Brazilian Conselho Nacional de Pesquisas (CNPq).     

Scattering-parameter measurements of laser diodes

An accurate and simple technique for measuring the input reflection coefficient and the frequency response of semiconductor laser diode chips is proposed and demonstrated. All the packaging parasitics could be obtained accurately using a calibrated probe, and the impedance of the intrinsic diode chip is deduced from the directly measured reflection coefficient. The directly measured impedance of a laser diode is affected strongly by the short bond wire. In the frequency response (S ₂₁) measurements of semiconductor laser diode chips, the test fixture consists of a microwave probe, a submount, and a bond wire. The S-parameters of the probe could be determined using the short-open-match (SOM) method. Both the attenuation and the reflection of the test fixture have a strong influence on the directly measured frequency response, and in our proposed technique, the effect of test fixture is completely removed.     

Frequency measurements of CF2CHF and SO2 laser lines and a new far infrared laser line of HDCO

The emission frequencies of several optically pumped far infrared laser lines of CH₂CHF, SO₂ and HDCO molecules have been measured by mixing them with a harmonic of a millimeter-wave synthesizer operating in the range 78–118 GHz. A new line of HDCO at 1886 GHz has been found.     

A vibrationally compensated far infrared laser interferometer for plasma density measurements

A modulated far-infrared laser interferometer which is presently operating on the PDX experiment at Princeton is described. The interferometer geometry permits the characterization of inside D, outside D as well as circular discharges. To achieve this versatility, a titanium corner cube reflector, mounted inside the PDX vacuum vessel is used in conjunction with a second visible wavelength interferometer for vibration corrections. In addition, the use of room temperature quasi-optical Schottky diodes in the far-infrared interferometer is reported. The minimum detectable line average density of the system is 5×10¹¹ cm^–3.     

Surface resistance and far infrared absorptivity at T=7 K of highTc YBaCuO superconductors

A surface resistance as small as R_S=3×10^–2 Ohms has been computed at T=8 K, for v=0.6 Thz (v=20 cm^–1), for an YBaCuO film deposited on an MgO substrate. The calculations are made with the refractive index computed from the Far IR transmission spectra of a 400 Å thick film.Still lower values are obtained with another sample, 300 Å thick of exceptional quality (R_S=1.2×10^–2 Ohms).     

Far infrared laser thermal spectroscopy of superconductors

An optically pumped far infrared laser provides fixed photon energies near the superconducting gap, making it possible to carry out experiments where the temperature is swept through T_c. Such thermal measurements in thin films of V₃Si show both known and unexplained features, with some of the latter perhaps due to a second gap. The thermal technique shows potential for the study of superconductors.Work supported by the U.S. Department of Energy under Contract No. DE-AS05-79ER10436.     

基于飞秒光频梳的双频He-Ne激光器频率测量

利用光纤飞秒光频梳和外腔可调谐半导体激光器, 建立了一套双频He-Ne激光器频率测量系统. 选用铷钟作为系统的频率基准, 通过将外腔半导体激光锁定至光频梳使得其频率溯源至铷钟, 再利用外腔可调谐半导体激光与双频He-Ne激光器输出的正交偏振激光拍频, 同时测量两路正交偏振激光频率. 将可调谐半导体激光器锁定至光频梳第1894449个梳齿, 其绝对频率为473612190000.0±2.7 kHz, 相对不确定度为5.7×10^-12. 对商品双频He-Ne激光器进行频率测量实验, 双频He-Ne激光器水平方向偏振激光频率均值为473612229934 kHz, 竖直方向偏振激光频率均值为473612232111 kHz, 平均时间为1024 s的相对Allan标准差为5.2×10^-11, 频差均值为2.177 MHz, 标准偏差为2 kHz.     

Investigation on infrared laser absorption spectroscopy measurement of acetylene trace quantities

A laser-based infrared spectrometer was developed for use in high-resolution spectroscopic analysis of trace gases in the atmosphere. Continuous wave, broadly tunable coherent infrared radiation was generated from 8 to 19 μm in a gallium selenide crystal by laser difference-frequency mixing. Measurements of acetylene trace concentrations using laser absorption spectroscopy are reported. The measurements have been performed by using the P(21), Q(11), and R(9) lines of the ν₅ band, respectively, in order to investigate optimal detection conditions: a trade-off choice between higher line absorption strength for sensitive detection and better spectral discrimination from lines overlapping for open path trace-gas monitoring applications. Minimum detectable concentrations are compared under different experimental conditions. The ν₅ R(9) line seems to be close to optimum in terms of absorption strength and freedom from spectral interference for spectroscopic detection of acetylene trace concentration at atmospheric pressure.     

中、远红外双波段激光器发射光谱测量与评估

在分析中远红外双波段(氟化氘与一氧化碳)激光器发射光谱的基本特征和分光型谱仪存在高级次光谱混叠等问题的基础上,选定Tensor37干涉型遥测光谱仪并利用黑体标定出仪器响应函数;对中、远红外双波段激光器光谱进行了模拟测量和实际测量,分析评估了双波段激光器的谱线成分、峰值变化、测量精度和相对强度等,为双波段激光器的介质参数计算、运转参数优化以及红外应用提供有效数据。     

利用外腔改善半导体激光器列阵的远场特性

采用一个由快轴准直透镜和一个高反射率平面镜组成的简单外腔,在腔长为几个cm时实现了半导体激光器列阵中部分单元的锁相运行;DLA远场出现了3个瓣,每瓣发散角为10 mrad左右,对比度为50%;通过控制部分单元的输出,可以抑制旁瓣的能量.     

Response of metal-insulator-metal point contact diodes to visible laser light

Video response and mixing behaviour of metal-insulator-metal point contact diodes have been investigated for visible laser light. Thermally enhanced tunneling is shown to dominate the dc detection behavior of those diodes, while mixing of frequencies being more than several MHz apart is a more complex phenomenon involving thermal, field-and photo-assisted tunneling. In further experiments the potential of point contact diodes for optical heterodyne spectroscopy was examined. Two green laser lines of 122 GHz frequency difference were mixed with the second harmonic of an appropriate microwave frequency, generated simultaneously on the diode. The modestS/N ratio achieved has to be assigned to the different behaviour of metal-insulator-metal diodes in the visible and rf range.     

New possibilities for frequency stabilization of far infrared lasers

All spectrometers based on the use of a far infrared laser present the drawback of the laser frequency uncertainty. Even if the knowledge of the laser frequency is very precise, a shift of the laser cavity length is always present, limiting the spectrometer frequency accuracy to 500 kHz.The goal of this paper is to give a solution to this drawback in demonstrating the feasibility of a frequency stabilization of the far infrared laser.     

Frequency stabilization and measurements of 543 nm HeNe lasers

In this paper we report our investigations on the frequency stabilization and frequency measurements of 543 nm HeNe laser. It contains following four different works. (1) Using a metal laser tube we have built an iodine-stabilized 543 nm HeNe laser by the Frequency-Modulation (FM) spectroscopy. The signal-to-noise ratio of the hyperfine spectrum reached 2 × 10^–12 at 1 s sampling time. (2) We have built a compact iodine-stabilized 543 nm HeNe laser system using the third-harmonic locking technique. Stability better than 1 × 10^–12 for sampling time >1 s is obtained. We also suggest the b₁₀ line for the future recommendation. (3) We constructed the Lamb-dip stabilized He-²⁰Ne and He-²²Ne lasers and measured their frequency stability, reproducibility, and absolute frequencies. The results suggest that the Lamb-dip stabilized lasers are appropriate for secondary wavelength standards. We have also deduced the isotope shift of Ne atom at 543 nm. (4) We have developed two two-mode stabilized 543 nm HeNe lasers using the bang-bang control method. The Allan variance is 1 × 10^–11 at 1 s sampling time.     

Measurement of frequency differences between visible laser lines up to 170GHz using metal-insulator-metal point contact diodes

Frequency differences of up to 170 GHz between a cw dye laser and a krypton laser at 568 nm were measured by mixing laser and microware radiation with a metalinsulator-metal point contact diode. Beat signals are well above noise and there is still great potential for improvement when better microwave oscillators are used. From the measurements reported it follows that the diode can be used for determining still higher frequency differences of visible laser radiation.     

Optically pumped cw CH2DOH fir laser: New lines and frequency measurements

We have measured the output powers and relative polarizations of 66 cw FIR laser lines from CH₂DOH (including 50 not previously reported), which were optically pumped by a CO₂ laser. The frequencies of 43 of these lines were measured relative to stabilized CO₂ lasers.     

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简要介绍了EAST装置远红外激光干涉仪光源——DCN激光器的工作原理、结构和相关改进。DCN激光器采用He、CD4、D2和N24种工作气体。实验过程中,通过调节气体压强和阴极电流、改变各种工作气体配比等手段优化DCN激光器输出功率。实验结果显示：输出功率随电流的增大会达到饱和,在电流为1.0A输出功率达到最大;输出功率随压强先增大后减小,在压强为32Pa时达到最大值;工作气体的最佳配比为He： CD4： D2： N2=2：3：5：3。