Absolute coverage and isostemc heat of adsorption of deuterium on Pt(111) studied by nuclear microanalysis

The absolute coverage (θ) of deuterium adsorbed on Pt(111) in the ranges 180< T<440 K and 5 × 10^?6 < P < 5 × 10^?2 Pa D₂ has been determined by nuclear microanalysis using the D(³He, p)⁴He reaction. From these data, the isosteric heat of adsorption (E_a) has been determined to be 67 ± 7 kJ mol^?1 at θ ? 0.3. This heat of adsorption yields values of the pre-exponential for desorption (10^?5 to 10^?2 cm² atom^?1 s^?1) that lie much closer to the normal range for a second order process than those determined from previous isosteric heat measurements. The E_a versus θ relationship indicates that the adsorbed D atoms are mobile and that there is a repulsive interaction of 6–8 kJ mol^?1 at nearest neighbour distances. At 300 K the coverage decreases to ? 0.05 monolayer (? 8 × 10¹³ D atoms cm^?2) as P→ 0, apparently invalidating a recent model of site exchange in the adsorbed layer.     

Effect of electron irradiation on the paramagnetic state of La0.67Ca0.33MnO3

The effect of point defects on the magnetic properties of La_0.67Ca_0.33MnO₃ polycrystals and single crystals has been studied. The magnetic susceptibility χ _dc of the initial samples and samples irradiated by electrons to the maximum dose F = 9 × 10¹⁸ cm^?2 has been measured in the temperature region 80 K < T < 650 K. Local variations of Mn-O-Mn bond angles and lengths result in a nonmonotonic dose dependence of the Curie temperature T _C. At high doses of electron irradiation, F ≥ 5 × 10¹⁸ cm^?2, the temperature of the transition from the ferromagnetic to polaron state in a single crystal is found to increase. In the paramagnetic region close to T _C, ferromagnetically ordered polarons are observed to exist, while at T > 1.2T _C, localization of e _g electrons initiates formation of paramagnetic polarons with a higher magnetic moment. Electron irradiation stimulates persistence of magnetic polarons up to higher temperatures T > 2T _C.     

Ferromagnetism of (Pb,Sn, Mn) Te under high pressure

Results of measurements of the magnetic susceptibility in the p-type diluted magnetic semiconductor [(PbTe)_1-x(SnTe)_x]_1-y(MnTe)_y with x = 0.72, y = 0.03 are presented. The temperature of the ferromagnetic ordering T_c increases (for hole concentration 3×10²⁰ cm^-3) < p < 7 × 10²⁰ cm^-3 or decreases (p > 7 × 10²⁰ cm^-3) as hydrostatic pressure is applied. The pressure causes an increase in the concentration of carriers responsible for the interactions between Mn ions. The observed shift of T_c with pressure is interpreted on the basis of the RKKY interaction mechanism and points out the importance of the band structure behavior in consideration of magnetic properties of the semiconductor.     

Low temperature heat capacity and magnetic excitation of HoAl2 in a magnetic field

The specific heat of single crystalline HoAl₂ in magnetic fields up to 7.5 T has been measured for the temperature range 1.5–16 K. In addition the energy of a magnetic excitation in a magnetic field of 5 T at 4.2 K has been determined by inelastic neutron scattering. The results have been interpreted with a cubic crystalline electric field and an exchange interaction using the same parameter set B₄=-0.85×10^-4 meV, B₆=+0.71× 10^-6 meV and T_C=31.5 K previously obtained by magnetization measurements.     

Room temperature minority carrier lifetime and efficiency of p-type GaAs1−xPx

Using sine wave modulated laser excitation, the optical phase shift of the luminescence of vapor grown Zn doped GaAs_1?xP_x layers was measured. From such measurements the minority carrier lifetime can be derived. This lifetime was measured as a function of doping level for crystals with a composition sufficiently remote from the cross-over composition (0.30 < x < 0.35 to ascertain that only a small fraction of the minority carriers is in the indirect minima. In addition, luminescence efficiency measurements were made using cathode ray excitation. From the lifetime and efficiency results it is concluded that for p < 2 × 10¹⁹cm^-3 the lifetime, being between 1 and 3 ns, is dominated by nonradiative transitions. For the radiative transitions a rate constant of 4.5 × 10^-11cm³s^-1 was determined. This value compares reasonably well with values known for GaAs, about 7 × 10^-11cm³s^-1. The efficiency of a few strongly doped samples (p > 10¹⁹cm^-3) may be depressed by self-absorption of the luminescence. In addition, a few samples with a higher phosphorus content, up to x = 0.45, were measured. Their lifetimes being mainly determined by indirect transitions are also in the low nanosecond range. This stands in contrast with the longer lifetimes (up to 150 ns at p < 10¹⁷ cm^-3) of indirect bandgap material (x ≈ 0.8).     

Specific heat of NaNO2 near its transition points

Using an a.c. technique, the specific heat of NaNO₂ was measured as a function of temperature near its antiferroelectric-to-paraelectric phase transition point (T_N). The transition was found to be of the second order. The critical exponents are; α = 0·38 for ? = 2 × 10^?4 ～ 1 × 10^?1, and α′ = 0·18 for ? = ?2 × 10^?4 ～ ?3 × 10^?3. The critical exponents deduced from the scaling-law relations are roughly close to the values obtained from a random phase approximation for a system with an isotropic interaction. However, a difference was recognized between the observed exponent for the specific heat and the values theoretically given for T > T_N by the random phase approximation for a system with a short-range interaction or for a system with a long-range dipolar interaction. A thermodynamical analysis was made by using the generalized Pippard relation, and the present result was found to be consistent with the pressure dependence of the antiferroelectric transition point.     

NMR and magnetic susceptibility study of rapidly quenched Ni100-XPX metallic glasses

In order to investigate the electronic structure of the rapidly quenched Ni_100-XP_X metallic glass system (18 ≦ x ≦ 22), NMR and magnetic susceptibility measurements have been carried out for temperatures 4.2 °K ≦ T ≦ 295 °K and magnetic fields H ≦ 20 kOe. The ³¹P Knight shift and relaxation rate behavior demonstrate a metalloid concentration dependence which is consistent with earlier work on the ternary NiPdP and NiPtP metallic glass systems. A consideration of the trends in the magnetic susceptibility indicates that, relative to the Fermi energy, the d-states associated with Ni are higher (the number of d-holes are greater) than those for Pd or Pt.     

Magnetic moment of pressure quenched cadmium sulfide

Magnetic moment measurements of CdS polycrystalline samples, pressure quenched from above the semiconducting to conducting transition pressure (40 kbars) at rates approaching 10⁶ bars/sec, have been made in a vibrating sample magneto-meter to fields approaching 1000 Oersted. The samples exhibit the complex magnetic behavior of low field diamagnetism (χ > - 5 × 10^-5cgsunits) transforming at fields of several hundred Oersted to positive magnetism (χ > + 3 × 10^-4cgsunits). This magnetic behavior contrasts with unquenched samples which yield the normal diamagnetism of CdS (χ = - 1.5 × 10^-6cgsunits). These anomalous magnetic effects are observed at both room temperatures and LN₂ temperatures at atmospheric pressure.     

Search for macroscopic CP violating forces using a neutron EDM spectrometer

The search for CP violating forces between nucleons in the so-called axion window of force ranges λ between 2 × 10^?5 m and 0.02 m is interesting because only little experimental information is available there. Axionlike particles would induce a pseudo-magnetic field for neutrons close to bulk matter. A laboratory search investigates neutron spin precession close to a heavy mirror using ultracold neutrons in a magnetic resonance spectrometer. From the absence of a shift of the magnetic resonance we established new constraints on the coupling strength of axion-like particles in terms of the product g _s g _p of scalar and pseudo-scalar dimensionless constants, as a function of the force range λ, g _s g _p λ² ≤ 2 × 10^?21 [cm²] (C.L.95%) for 10^?4 cm < λ < 1 cm. For 0.1 cm < λ < 1 cm previous limits are improved by 4 to 5 orders of magnitude.     

Magnetocrystalline anisotropy and inversion degree of manganese-ferrous-ferrites

Torque measurements have been performed at 4 and 77 K on single crystals of Mn_1?xFe_2+xO₄ (0<x<0.05) and MnFe_2?xTi_xO₄ (0<x<0.1). The crystals were either quenched or slowly cooled causing a change of inversion by 0.1. It is found that the magnetic anisotropy due to the ferrous ions in the Ti-doped samples is 80 per cent larger than in the Mn_1?xFe_2+xO₄ crystals. In both crystal series the ferrous ion anisotropy in the slowly cooled crystals is 70 per cent higher than in the quenched crystals. The K₁ of MnFe₂O₄ at 4 K is found to decrease from ?3.6 × 10⁵ erg/cm³ after show cooling, down to ?2.6 × 10⁵ erg/cm³ after quenching.     

Low temperature thermal properties of PbI2

The heat capacity and thermal conductivity of a large (56.5 g) crystal of PbI₂ have been measured in the temperature region 0.5 < T < 3.9°K. Analysis of the heat capacity data yields a value of the limiting apparent Debye characteristic temperature θ₀^c = 99.4 (±0.3)°K, which corresponds to an average lattice wave velocity of 1.151 (±0.005) × 10⁵ cm sec^?1. It is consistent with a wave velocity estimated from neutron scattering experiments, but not with one determined from Brillouin spectra. The heat capacity data also show that dispersion of the low frequency waves is not unusual, as might have been expected for a layer-type crystal. The apparent thermal conduction is found to be surprisingly small in the crystal.     

Minimum metallic conductivity in a thin crystal

Electrical conductivities of thin crystals of Bi₂(Te,S)₃ measured from 4.2°K to 300°K fall into four regions: 1) σ < 1.3×10^?5 S with positive temperature coefficient of conductivity; 2) 1.3×10^?5 S < σ < 1.4×10^?5 S with temperature independent conductivity; 3) 1.4×10^?5 S σ < 4×10^?5 S with negative temperature coefficient of conductivity, and 4) σ > 4×10^?5 S with hardly any temperature dependence. A disproportionately high fraction of samples falls into the second range; 1.3×10^?5 S < σ < 1.4×10^?5 S.     

Searching for effects of neutrino magnetic moments at reactors and accelerators

The sensitivity of the νe elastic scattering experiments to possible effects of nonzero neutrino magnetic moment (μ) is analyzed and the optimal experimental condition under which such effects are relatively enhanced are found. New, somewhat more restrictive than the previously derived bounds on μ, are obtained on the basis of existing data by the use of selfconsistent statistical analyses: μ_νe < 1.52 × 10^?10e/2m_e and μ_νμ < 1.19 × 10^?9e/2m_e. These bounds are expected to be improved approximately by an order of magnitude in experiments planned to be performed in the near future.     

Diffusion and correlation effects in iron-doped CoO

The diffusion of ⁵⁹Fe and ⁶⁰Co has been measured in pure CoO and dilute iron-doped CoO, (Co_1?cFe_cO, as a function of temperature (1000–1400°C) and oxygen partial pressure P_{o2), (10^?7 ≦ Po2 ≦ 0 21 atm) The enhancement factors for the diffusivities of iron and cobalt are nearly identical, which suggests that the primary cause of the enhancement is the increased concentration of charge-compensating cation vacancies with the addition of iron. The Fe ions dissolved in CoO appear to exist as a mixture of Fe²⁺ and Fe³⁺ ions, the fraction of iron ions in the three-plus state decreases with decreasing Po2 The simultaneous diffusion of ⁵²Fe and ⁵⁹Fe has been measured as a function of (itpo; at 1200°C The correlation factor for Fe impurity diffusion determined from the isotope-effect measurements is about the same as that for self-diffusion in CoO at high (itPo2} (2 × 10^?3 ≦ p_o2 ≦ 0 21 atm), but increases slightly with decreasing p_O2 Both the enhancement-effect and isotope-effect experiments suggest that the nearestneighbor interactions between Fe ions and vacancies is small, and that the dissolved Fe ions do not have strongly bound electron holes.     

Size effect on the structure and magnetic properties of SmMn2O5 nanorods

Three sizes of SmMn₂O₅ nanorods that are labeled with (<L_C>) × axial lengths of 58(17) nm × 25(6) nm, 92(21) nm × 32(8) nm, and 126(25) nm × 52(13) nm were fabricated by the hydrothermal method. All the samples exhibited an antiferroicmagnetic (AFM) peak at approximately 6 K, which was associated with Sm magnetic ordering and no size independence. Another AFM magnetic ordering that belongs to the Mn ion was found with <L_C> = 58 nm, 92 nm, and 126 nm at 26 K, 28 K, and 30 K, respectively. The spin-orbit interaction increases with size in the magnetic susceptibility experiment. All the samples displayed a hysteresis loop at 2 K. The coercivity decreases as the size increases. The effects of the size on the crystal structure were elucidated from the Raman spectra of the <L_C> = 92 and 126 nm samples at various temperatures. The 126 nm sample displayed a red-shift for the Ag mode with warming, revealing that the Mn–O bonds are more sensitive to temperature in larger SmMn₂O₅ nanorods. These results demonstrate that the size effect importantly affects the structure and magnetic properties in SmMn₂O₅ multiferroic nanorods.     

Magneto-volume effect in invar-type amorphous Fe—B alloys

Amorphous Fe_100-xB_x(11.5 ≦ x ≦ 22) alloys having the invar characteristics were prepared by a single roller quenching method to investigate the magneto-volume effect. Forced volume magnetostriction, ?ω/?H, increased remarkably with decreasing boron content and the maximum value obtained was about 90 × 10^?10 Oe^?1 at 11.5 at.% boron. The estimated value of the pressure dependence of the Curie temperature, ?T_c/?P, was considerably large, being comparable to those of crystalline FeNi invar alloys. The ?T_c/?P curve plotted as a function of T_c approximately fitted Wohlfarth's expression.     

The magnetic field dependence of the low temperature (0.1K to 3K) residual specific heat of Pr<Subscript>2−<Emphasis Type="Italic">x</Emphasis></Subscript>Ce<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>CuO<Subscript>4−δ</Subscript>

Measurements are presented of the low temperature specific heat of three polycrystalline samples of Pr_2?x Ce _x CuO₄ in magnetic fields of 0, 2 and 4 Tesla. The residual specific heat contribution in zero field seems to have a form αT ⁿ (n<1) for all of the samples, whether superconducting or non-superconducting. The behaviour in magnetic fields is similar to that reported for other high Tc superconductors where a change in exponent of the residual term occurs at some crossover temperature in magnetic fields.     

Transport and magnetic properties of multiwall carbon nanotubes before and after bromination

Bulk samples of oriented carbon nanotubes were prepared by electric arc evaporation of graphite in a helium environment. The temperature dependence of the conductivity σ(T), as well as the temperature and field dependences of the magnetic susceptibility χ(T, B) and magnetoresistance ρ(B, T), was measured for both the pristine and brominated samples. The pristine samples exhibit an anisotropy in the conductivity σ_∥(T)/σ_⊥>50, which disappears in the brominated samples. The χ(T, B) data were used to estimate the carrier concentration n ₀ in the samples: n _0ini ～3×10¹⁰ cm^?2 for the pristine sample, and n _0Br～10¹¹ cm^\t—2 for the brominated sample. Estimation of the total carrier concentration n=n _e+n _p from the data on ρ(B, T) yields n _ini=4×10¹⁷ cm^?3 (or 1.3×10¹⁰ cm^?2) and n _Br=2×10¹⁸ cm^?3 (or 6.7×10¹⁰ cm^?2). These estimates are in good agreement with one another and indicate an approximately fourfold increase in carrier concentration in samples after bromination.     

Temperature and concentration quenching of mid-IR photoluminescence in iron doped ZnSe and ZnS laser crystals

Concentration dependences of the mid-IR kinetic of luminescence at ⁵E?⁵T₂ transition in Fe:ZnSe and Fe:ZnS laser samples were studied in 14–300 K temperature ranges. Radiation lifetime in Fe:ZnSe samples measured using low doped samples with iron concentration 0.1×10¹⁸ cm^?3 was estimated to be 57 μs. The magnetic susceptibility for higher doped (C_Fe=38 and 112×10¹⁸ cm^?3) Fe:ZnSe samples was found to consist of a paramagnetic Curie–Weiss behavior arising from the weakly interacting Fe²⁺ ions and a diamagnetic ZnSe contribution plus a temperature-independent, field-dependent contribution possibly arising from very small amounts of aggregated Fe.     

Investigation of acceptor centers in semiconductors with the diamond crystal structure by the μ − SR method

The residual polarization of negative muons in crystal silicon samples with phosphorus (P: 1.6×10¹³ cm⁻³) and antimony (Sb: 2×10¹⁸ cm⁻³) impurities is investigated. The measurements are made in a 1000 G magnetic field oriented in a direction transverse to the muon spin in the temperature range 4–300 K. The relaxation rate and shift of the precession frequency in the silicon sample with the phosphorus impurity are measured more accurately than previously. It is found that in antimony-doped silicon the acceptor center _μ A1 at temperatures below 30 K can be in both ionized and neutral states. The experimental data are interpreted on the basis of spin-lattice relaxation of the magnetic moment of an acceptor center, formation of acceptor-donor pairs, and recombination of charge carriers at the acceptor. Preliminary measurements showed a nonzero residual polarization of negative muons in germanium. Pis’ma Zh. éksp. Teor. Fiz. 68, No. 1, 61–66 (10 July 1998)