Study on cross-section clad profile in coaxial single-pass cladding with a low-power laser

In this paper, a model of cross-section clad profile on the substrate in coaxial single-pass cladding with a low-power laser was studied. The static model of powder mass concentration distribution at cold-stream conditions was defined as a Gaussian function. In coaxial single-pass cladding with a low-power laser, since the influence of surface tension, gravity and gas flow on the clad bead could be neglected, the cross-section profile of the clad bead deposited by a low-power laser on the substrate was dominated by the powder concentration at each point on the pool and the time when the material was liquid at this point. The height of each point on the cross-section clad profile was defined as a definite integration of a Gaussian function from the moment at which the melt pool was just arriving at the point to the moment at which the point left the melt pool. In the presented experiment, powder of Steel 63 (at 0.63 wt% C) was deposited on a substrate of Steel 20 (at 0.20 wt% C) at the laser power of 135 W. The experimental results testified the model.     

Formation of a ripple pattern at a water/silicon interface using an oscillating bubble

A single femtosecond laser pulse was irradiated at a water/silicon interface, and the processed surface was investigated. Rings surrounded by ripples were found within the irradiated spot. The diameter of the rings ranged from 500 nm to 10 μm. It is proposed that acoustic waves, caused by the oscillating motion of bubbles near the water/silicon interface, deformed the melting silicon surface. In the present work, a pulse (pulse width: 150 fs) was tightly focused in water to induce optical breakdown, and a bubble was generated at an arbitrary spot. When the power density was below the ablation threshold and above the melting threshold at the silicon surface and set above the breakdown threshold at the focus in water, a pattern was generated at a specific place and with a specific size. PACS 79.20.Ds; 42.62.Cf     

Trapping of positive muons by vacancies in non-stoichiometric compounds

A direct evidence for trapping of positive muons by vacancies was found by using the longitudinal field method., 65.5 at. %Cu-34.5 at. %Al, 51at. %Al-49at. %Ni and 52 at. %Al-48at. %Ni polycrystalline samples were studied. The forward/backward asymmetry was measured as a function of time at room temperature changing the magnetic field from 0 to 70 Oe. At H=0, a relaxation function of Kubo-Toyabe type was found. Analysing the data, it was found that positive muons are trapped by vacancies in these materials.     

Peculiarities of Er3+ photoluminescence in halogen-doped amorphous silica

The spectra and photoluminescence kinetics of Er³⁺ ions embedded in amorphous fluorine- and chlorine-doped silica matrices synthesized by surface-plasma chemical vapor deposition were investigated at 27–300 K. Luminescence was excited with an Ar⁺ laser at a wavelength of 514.5 nm and with a diode laser at a wavelength of 975 nm. Narrow and well-expressed components of Stark sublevels with a small contribution of inhomogeneous broadening intrinsic to Er³⁺ ions in crystalline rather than amorphous matrices were revealed and identified in photoluminescence spectra. The structure of Stark sublevels was well-resolved at low temperatures. The presence of the well-resolved Stark structure in spectra was indicative of stable anion complex formation in Er³⁺ environment presumably associated with halogen incorporation. This environment was formed at a stage of the low-temperature plasma-chemical synthesis and was destroyed at glass fusion.     

XPS studies for NaCl deposited on the Ni(111) surface

Vapor deposited NaCl on the Ni(111) surface was characterized by XPS. Three types of NaCl were found on the surface. First, the NaCl interacted strongly with Ni giving the Nals peak at 1072.2 eV, the C12p peak at 198.8 eV and the NaKLL peak at 494.3 eV. The 494.3 eV peak shifted to 493.4 eV when measured at ∼ 500 K. The energy of the NaKLL peak and the modified Auger parameter for sodium were nearer to those for Na metal than to those for bulk NaCl. The species was assigned to NaCl which was freed from the potential of the NaCl crystal and which had a weakened NaCl bond. The other types were characterized by using H₂O as a probe. One set of the peaks, the Nals peak at 1072.8 eV, the C12p peak at 199.6 eV and the NaKLL peak at 497.7 eV, was assigned to NaCl which was in the form of a very thin crystal. The other set, the Nals peak at 1073.5 eV, the C12p peak at 200.1 eV and the NaKLL peak at 498.5 eV, was obtained during crystal growth of NaCl as large islands upon annealing. The energies suffered from the charging effect. The effect of coadsorbing oxygen was also studied.     

Crystallization Behavior of Amorphous Poly(l-Lactide)

Amorphous poly(l-lactide) (PLLA) was annealed in two different ways: amorphous samples were heated at a given temperature to induce crystallization (one-step annealing); and amorphous samples were first crystallized at a low temperature and subsequently annealed at a higher temperature than the crystallization temperature. Samples thus prepared were measured by DSC. The original amorphous sample exhibited an exothermic peak at about 100°C (exothermic peak I), an exothermic peak just below the melting point (exothermic peak II), and an endothermic peak when it was melted. Exothermic peak I was caused by cold crystallization. When the melting points of PLLA samples, heat-treated in various ways, were plotted as a function of annealing temperature, there was discontinuity at about 120°C. From analyses of wide-angle X-ray diffraction patterns, it was found that when amorphous PLLA was crystallized at a temperature below 120°C, crystallites of the β-form formed, and when annealed at a temperature above 120°C, crystallites of the α-form grew. Thus, exothermic peak I was attributed to cold crystallization of the β-form, and peak II was caused by the phase transition of the β-form to a more stable form.     

Effect of output coupling ratio on the performance of ring-cavity Brillouin fiber laser

We present a single-wavelength Brillouin fiber laser utilizing a ring-cavity configuration. Performances and characteristics of the laser system have been investigated at different output coupling ratios. The optimum output power of the system stood at 7.3 mW, which was obtained at 90% output coupling ratio. A low Brillouin threshold power of 0.9 mW was obtained at 10% output coupling ratio when the Brillouin pump was set at its maximum power of 24 mW.     

Temperature dependence of interband transition energy in InGaAsN strain-compensated quantum-well and ridge-waveguide lasers fabricated with pulsed anodic oxidation

Ridge-waveguide InGaAsN triple-quantum-well strain-compensated lasers grown by metal organic chemical vapor deposition were fabricated with pulsed anodic oxidation. The laser’s output power reached 145 mW in continuous-wave mode at room temperature for a 4-?m -stripe-width laser. Continuous-wave single longitudinal mode operation was maintained at a high injection current level with a wavelength of 1287.3 nm at room temperature. Single longitudinal mode operation at 1317.2 nm was achieved at twice the threshold current at 100 °C. The band gap of InGaAsN in the quantum wells at different temperatures was calculated and compared to the measured temperature-dependent laser wavelength.     

Dependence of loudness growth on skirts of excitation patterns

Over a range of 50 dB, the loudness of a 100-Hz tone was measured in the presence of a broadband noise with a low-frequency cutoff at 200 Hz. The noise was varied in intensity along along with the tone so that the signal-to-noise ratio remained constant at either 0 or--10 dB. Listeners judged the loudness of the tone by loudness matching, magnitude estimation, and magnitude production. The noise markedly decreased the tone's rate of loudness growth but not the range over which loudness grows. The overall decrease in steepness of the 100-Hz loudness function was greater than that previously reported at higher frequencies. It is hypothesized that the decrease was greater because the spread of excitation at 100 Hz was more effectively contained than at higher frequencies. Support for this hypothesis is given by measures of intensity discrimination at 100 Hz.     

Helium trapping at dislocations,precipitates and grain boundaries

Helium bubble formation was observed in austenitic stainless steels by transmission electron microscopy following implantation of 30 to 1000 appm helium at room temperature and annealing at 700 to 800°C. Helium bubble distributions at dislocations and at various grain boundaries and precipitates were studied. It was found that interfacial dislocations play a dominant role in bubble nucleation at grain and interphase boundaries but not at Tic-matrix interfaces. Particularly high trapping of helium was observed at Tic precipitate-matrix interfaces which is attributed to an inhomogeneous ripening mechanism.     

Directly diode-pumped holmium fiber lasers

Sensitizer-free holmium-doped silica and fluoride mid-infrared fiber lasers are pumped using a high-power diode laser operating at 1148 nm. A maximum output power of 162 mW at 2.86 microm was produced at a slope efficiency of 24% using Ho(3+), Pr(3+)-doped fluoride fiber. Using Ho(3+)-doped silica fiber, a maximum output power of 55 mW at 2.1 microm was generated at a slope efficiency of 27%, a value limited by the presence of pump excited state absorption.     

Measurement of water cloud particle size with a dual-polarization pulsed bistatic lidar

A new bistatic lidar was developed for measuring water cloud particle size at the base of lower clouds. The lidar uses a pulsed Nd:YAG laser at 532 nm and a receiver having a polarization analyzer located at a suitable scattering angle. Cloud particle size (mode radius of the assumed size distribution) was derived from the ratio of the polarization components of the scattered light based on the single scattering Mie theory. The experiment was performed on board the research vessel Mirai in the northwestern Pacific. Particle size at the bottom of maritime cumulus and stratus was measured, and the difference between the internal structures of cumulus and stratus was observed. The effect of multiple scattering was studied by changing the observing scattering angle. The effect was not significant when the penetration depth was less than 50 m.     

Monaural level discrimination under dichotic conditions

The ability to make judgments about the stimulus at one ear when a stimulus is simultaneously presented to the other ear was tested. Specifically, subjects discriminated the level of a 600 Hz target tone presented at the left ear while an identical-frequency distractor was simultaneously presented at the other ear. When there was no distractor, threshold was 0.7 dB. Threshold increased to 1.1 dB when a distractor with a fixed phase and level was introduced contra-aurally to the target. Further increases in threshold were observed when an across-presentation variability was introduced into the distractor phase (threshold of 1.6 dB) or level (threshold of 5.8 dB). When both the distractor level and phase varied, the largest threshold of 7.3 dB was obtained. These increases in threshold cannot be predicted by common binaural models, which assume that a target stimulus at one ear can be processed without interference from the stimulus at the nontarget ear. The measured thresholds are consistent with a model that utilizes two binaural dimensions that roughly correspond to the loudness and the position of a fused binaural image. The results show that, with binaurally fused tonal stimuli, subjects are unable to listen to one ear.     

8.30 μm singly resonant ZnGeP2 optical parametric oscillators pumped by a Tm,Ho:GdVO4 laser

A single resonator 8.30 μm ZnGeP₂ (ZGP) optical parametric oscillators (OPO) was reported in the paper. The OPO was pumped by a 10.2-W Tm,Ho:GdVO₄ laser at 8 kHz in a Q-switch mode, a 170-mW idler was obtained at 8.30 μm, and the output power of the idler and signal wave was 1.0 W, corresponding to an optical-optical conversion efficiency of 10.3% and a slope efficiency of 20.9%. Tm,Ho:GdVO₄ laser was pumped by a 30-W fiber-coupled laser diode (LD) at the center wavelength of 801 nm. The output wavelength of Tm,Ho:GdVO₄ laser was at 2.05 μm, and the energy per pulse of 1.28 mJ in 18 ns was achieved at 8 kHz with the peak power of 71.1 kW.     

Field ion microscope observations of surface rearrangement and oxide formation at clean rhenium surfaces heated in oxygen

The interaction between oxygen and clean, well-ordered rhenium surfaces has been investigated in the field ion microscope over a wide range of temperatures. The surface structure of vacuum annealed specimens was extensively modified by the presence of adsorbed oxygen. At partial monolayer coverages, surface metal atom rearrangement was inhibited, particularly at {112?2}, but at coverages near saturation, facets were produced at {101?0} at a lower temperature than on the clean surface, resulting in the exposure of an increased proportion of closepacked surface structures and suggesting a change in the rearrangement mechanism at high coverages. The production of facets at the major poles was temperature and coverage dependent as a result of the varying influence of adsorbed oxygen on surface free energy. A decrease in oxygen coverage was observed at 1200–1300 K on near-saturated surfaces, which may be associated with the formation of volatile ReO₃ from regions where oxygen concentration exceeds a critical value. There was little evidence of the production of a discrete surface oxide phase formed on specimens heated in the presence of gas phase oxygen, but a reduction in specimen radius as a result of volatile oxide formation was observed at pressures greater than 10^?4 Torr and temperatures above 1400 K. It is concluded that the final structure of rhenium surfaces heated in oxygen is dependent upon the rate of oxide formation, the effective oxygen coverage during oxidation, and the extent of surface rearrangement.     

Laser Doppler velocimetry measurement at a hard-to-reach intake port of a two-stroke engine

To understand better the complex scavenging process in ported two-stroke engines, optical set-ups were designed for velocity measurements at the exit of an intake port of a motoring and firing single-cylinder propane-fueled two-stroke engine by laser Doppler velocimetry. The radial velocity component was measured at the center of one port at engine speeds of 600, 900, and 1200 rpm. Laser beams entered the engine from the top through a quartz window and the light scattered by the seed particles was collected at 90° through the exhaust ports and a side window. The noise produced by the piston head was analyzed and separated from the signal generated by the seed particles. Analysis of the results from this engine showed that, in general, differences in both magnitude and the shape of the plotted results were observed when the engine was firing. A backflow into the intake system was observed at 600 rpm; this backflow decreased in strength, shifted in crank angle at 900 rpm, and eventually was eliminated at an engine speed of 1200 rpm.     

Diode-pumped Nd:YVO<Subscript>4</Subscript>-Nd:YLF blue laser at 488 nm by intracavity sum-frequency-mixing

We report a laser architecture to obtain continuous-wave blue radiation at 488 nm. A 808 nm diodepumped the Nd:YVO₄ crystal emitting at 914 nm. A part of the pump power was then absorbed by the Nd:YVO₄ crystal. The remaining was used to pump the Nd:YLF crystal emitting at 1047 nm. Intracavity sum-frequency mixing at 914 and 1047 nm was then realized in a LBO crystal to reach the blue radiation. We obtained a continuous-wave output power of 514 mW at 488 nm with a pump laser diode emitting 19.6 W at 808 nm.     

Interaction of acetic acid with ethylenediamine on a Ni(111) surface studied by XPS

The interaction of ethylenediamine with a Ni(111) surface was investigated in the temperature range 170–420 K by means of X-ray photoelectron spectroscopy. Molecularly absorbed species were predominant below 290 K giving the C1s and the N 1s peaks at 286.4 and 399.9 eV (at 250 K) and at 286.0 and 399.7 eV (at 290 K), respectively. The amount dehydrogenated species increased during heating up to 420 K resulting in a variation of the N 1s binding energy as 399.7 → 397.7 → 397.5 → 397.7 eV. The variation was correlated with successive dehydrogenation reactions such as

The interaction of acetic acid with molecularly absorbed ethylenediamine below 200 K brought about the appearance of the N 1s peak at 401.9 eV assignable to the ammonium form of nitrogen at the expense of the N 1s peak at 400.1 eV. The remaining N 1s peak is located at 399.6 eV. Ethylenediamine absorbed at 290 K, showing the N 1s peak at 399.7 eV, gave no ammonium form even after interaction with acetic acid at 220 K. These results indicate that a part of ethylenediamine was unidentate and the rest was bidentate (chelating) on the Ni(111) surface at 250 K and all of the molecules were bidentate at 290 K. When acetic acid was adsorbed on a clean Ni(111) surface at 165 K, formation of an acetyl group was indicated besides acetate.     

Experimental analysis of a diesel engine driven water-to-water heat pump

The paper describes the experimental analysis of a diesel driven water-to-water heat pump. The system was developed utilising commercially available equipment with, wherever possible, a minimum of modifications.Heat was extracted from water at ambient temperature by the evaporator and delivered to water at the condenser. Heat from the engine cooling water and exhaust system was also recovered, at a power less than that of the condenser, but at greater temperature. Therefore three distinct streams of heated water were available. The system was of medium size with a total output ranging from 7.5 to 13.5 kW. The system and component performance was determined over a range of compressor speeds, evaporating and condensing pressures. The heating coefficient of performance ranged between 2.7 and 7.3 while the ratio of the total heat output to the heating value of fuel supplied to the engine was found to be between 1.3 and 2.6.     

An experimental study of the diffusion-controlled self-ignition of hydrogen in a channel

The pulsed outflow of hydrogen into channels of circular and rectangular cross sections with a surface area of 20 mm² was experimentally studied. It was revealed that the shock wave formed during the outflow of a pulsed jet is the reason why it ignites at the contact surface. The range of initial pressures of hydrogen at which it ignites was determined and the dependence of the distance from the diaphragm at which a flame arises at the contact surface on the pressure in the shock wave front for circular and rectangular cross section channels was obtained.