The soft mode properties in Raman spectra of improper ferroelastics Hg2Cl2 and Hg2Br2

The temperature dependence of the frequency and intensity of the soft mode line appearing in the Raman spectra of Hg₂Cl₂, Hg₂Br₂ below the critical point T_c was studied. A proportionality between the scattering cross section of the soft mode and the square of its frequency v_sm was established. A strong stress-induced increase of the intensity and frequency of the soft mode line was observed near T_c, the relative shift of v_sm being ～30% at ～0.5 kg/mm² stress and T_c?T=5°K.     

Softening of acoustic and optical modes in ferroelastic phase in Hg2Br2

The softening of an acoustic and an optical phonons in Hg₂Br₂ has been investigated by means of the light scattering technique.It has been observed that the cube of the frequency of the soft optical phonon varies proportionally with the temperature below T_c.An expression for the relation of the elastic constant C₆₆ to the temperature has been derived from the phenomenological thermodynamic potential function. The observed temperature dependence of the elastic constant and the optical phonon frequency is described when we assume that the order parameter Q varies as $\text{Q ∝ [T ? T}{}_0\text{]}{}^{\mathrm{<mtext>1</mtext><mtext>6</mtext>}}$.     

NMR study of one-dimensional ionic conductor with hollandite-type structure. II. Frequency dependence of spin-lattice relaxation time of 27Al

Frequency dependence of spin-lattice relaxation time T₁ of ²⁷Al in one-dimensional K⁺ ion conductor, K-Al-priderite, was measured at 45 K in the frequency range from 10.1 MHz to 55 MHz. It is found that T₁ is proportional to ω^1.49±0.05 and agrres well with the $\text{ω}{}^{\mathrm{<mtext>3</mtext><mtext>4</mtext>}}$ dependence derived by the continuum diffusion model. The intrinsic activation energy is determined to be 0.058 eV by doubling the slope E_NMR=0.029 eV of the d(ln T₁)/dT curve in the low temperature region. The frequency dependence of T₁ in the high temperature region measured in the frequency range from 11.5 MHz to 20.8 MHz shows a tendency that the frequency dependence becomes smaller than the $\text{ω}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ dependence as temperature is raised above 450 K.     

Neutron diffraction in a random two-component magnetic system: CsMn0.96Co0.04Cl3.2D2O

Neutron diffraction expriment has been performed on the quasi-one-dimensional antiferromagnet, CsMn_0.96Co_0.04Cl₃.2D₂O, in which two different magnetic ions with competing spin anistropies are randomly distributed. Magnetic scattering data show that the easy spin axis tilts substantially (～ 40° from the easy axis of Mn salt to that of Co salt at 3.8 K) even for such a dilute mixture. The magnetic ordering temperature T_N can be definitely determined owing to the absence of the diffuse Bragg intensity at T_N, to be 4.80 ± 0.02 K. The obtained value of the critical index, β = 0.23 ± 0.02 is found to be considerably smaller in magnitude than both of those found in the Mn and Co salts. Some possible origins for the small β are discussed. The concentration dependence of T_N IS analyzed in terms of the impurity-linked chain model with $\text{|J}{}_{\mathrm{<mtext>MnCo</mtext>}}\text{|}\text{k}\text{= 14.7}\text{K}$.     

A monte-carlo/molecular dynamics study of the diffusional recombination kinetics of C(a) + O(a) → CO(g) on Pt(111)

The diffusion constants for C and O adsorbates on Pt(111) surfaces have been calculated with Monte-Carlo/Molecular Dynamics techniques. The diffusion constants are determined to be D_C(T)=(3.4 × 10^?3e^{$\text{?13156}\text{T}$})cm²s^?1 for carbon and D_O(T) = (1.5×10^?3 e^{$\text{?9089}\text{T}$}) cm² s^?1 for oxygen. Using a recently developed diffusion model for surface recombination kinetics an approximate upper bound to the recombination rate constant of C and O on Pt(111) to produce CO_(g) is found to be (9.4×10^?3 e^{$\text{?9089}\text{T}$}) cm² s^?1.     

Spin waves in an Invar alloy (Fe0.65Ni0.35)

The spin wave dispersion relation in an Invar alloy Fe_0.65Ni_0.35 has been measured at 4.2 K in the [111] direction by neutron inelastic scattering.Well defined magnon groups have been observed up to an energy transfer of about 80 meV. The spin wave dispersion is well described by ?ω=Dq²(1?βq²) with $\text{D=143}\text{meV}\text{A}\text{?}$ and $\text{β=0.12}\text{A}\text{?}{}^2$. The value of D is in accord with the value extrapolated from other neutron scattering results at higher contents of Ni and disagrees with spin wave resonance results.No trace of γ-iron type antiferromagnetic order could be detected at 4.2 K in this alloy by elastic neutron scattering measurements.     

Inclusive π0 production at very large pT at the ISR

Inclusive π⁰ production at 90° has been studied at the ISR at $\text{s}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 52.7}\text{and}\text{62.4}\text{GeV}$ over the p_T range from 7 to 15 GeV/c. The two photons from π⁰ decay yielded overlapping electromagnetic showers in the liquid-argon-Pb plate calorimeter detector system. Any direct photon production is included in these measurements. For large values of p_T, the cross section is observed to decrease with p_T more slowly than the p_T^?8 behaviour which has been observed at lower values of p_T.     

Pion production at large transverse momentum

A constituent interchange model is used to give a natural explanation of the observed energy dependence of ISR data for π° production at 90°. It is predicted that at large fixed p_T and sufficiently high energy the cross section will become constant, with a p_T dependence of (p_T²)^?2.5. It is also tentatively suggested that the e⁺e^? annihilation structure function $\text{ν}\text{W}{}_2$ should behave like ω^?1.5 near ω = 0.     

Temperature and pressure dependence of the elastic property of GeS2 glass

The sound velocities in GeS₂ glass have been measured by means of ultrasonic interferometry as a function of temperature or pressure up to 1.8 kbar. The bulk modulus K_s = 117.6 kbar and shear modulus G = 60.60 kbar were obtained for GeS₂ glass at 15°C and 1 atm. The temperature derivatives of both sound velocities and elastic moduli are negative :

$\text{(}\text{?ν}{}_1\text{?T}\text{)}$

_p =

$\text{?1.54 × 10}{}^{\mathrm{?4}}\text{km}\text{sec}$

°C,

$\text{(}\text{?ν}{}_1\text{?T}\text{)}$

_p =

$\text{?1.27× 10}{}^{\mathrm{?4}}\text{km}\text{sec}$

°C and

$\text{(}\text{?K}{}_{\mathrm{s}}\text{?T}\text{)}$

_p =

$\text{?1.27 × 10}{}^{\mathrm{?2}}\text{kbar}\text{°C}$

,

$\text{(}\text{?G}\text{?T}\text{)}$

_p = ?1.23 × 10^?2 kbar/°C,

$\text{(}\text{?Y}\text{?T}\text{)}$

_p = ?2.93 × 10^?2 their pressure derivatives are positive:

$\text{(}\text{?ν}{}_1\text{?P}\text{)}$

_T = 4.43× 10^?2km/kbar,

$\text{(}\text{?ν}{}_1\text{?P}\text{)}$

_T =

$\text{0.633 × 10}{}^{\mathrm{?2}}\text{km}\text{kbar}$

and (?K_s?P0)_T=6.81,

$\text{(}\text{?G}\text{?P)}{}_{\mathrm{T}}$

= 1.03, (?Y?T_T= 3.57. The Grüneisen parameter, γ_th= 0.298, and the second Grüneisen parameter, δ_s = 3.27, have also been calculated from these data. The elastic behavior of GeS₂ glass has proved to be normal despite the structural similarity among the tetrahedrally coordinated SiO₂, GeO₂ and GeS₂ glasses.     

Lithium aluminum nitride,Li3AlN2 as a lithium solid electrolyte

Single phase of Li₃AlN₂ was prepared from the mixture of Li₃N/AlN = 1.2 to 1.5 in molar ratio at 700°C and at 900°C. It crystalizes in the cubic system derived from antifluorite-type structure having the lattice parameter $\text{a = 9.470}\text{A}\text{?}$. It is a pure ionic conductor having conductivity of 5 × 10^?8ω^?1cm^?1 at room temperature and an activation energy of 52 kJ/ mol. Its decomposition voltage was 0.85 V at 104°C. The TiS₂/Li₃AlN₂/Li cell could be discharged at a constant current of 45 μA/cm² at 104°C.     

Proton scattering from 9Be between 6 and 30 MeV and the structure of 9Be

Differential cross-section excitation functions at lab scattering angles 86.9°, 120.0°, 140.0° and 160.0° were measured for ⁹Be(p, p_o)⁹Be, ⁹Be(p, p₂)⁹Be and ⁹Be(p, d₀)⁸Be at proton lab energies from 6 to 15 MeV in 100 keV steps. A broad anomaly was observed in the ⁹Be(p, p₀)⁹Be excitation functions. Differential cross-section angular distributions were measured for ⁹Be(p, p₀)⁹Be and ⁹Be(p, p₂)⁹Be at lab energies of 13.0, 14.0, 15.0, 21.35 and 30.3 MeV and for ⁹Be(p, d₀)⁸Be at 13.0, 14.0, 15.0 and 21.35 MeV. Angular distributions of polarization analysing powers for ⁹Be($\text{p}$,p₀)⁹Be, ⁹Be(p, p₂)⁹Be and ⁹Be($\text{p}$, d₀)⁸Be were measured at 8.0, 11.0, 12.0, 13.0 and 15.0 MeV. A spherical optical-model (SOM) analysis of the elastic scattering angular distribution data from 13.0 to 30.3 MeV showed that an energy dependence of only V_R and W_s (volume real and surface imaginary depths) is sufficient to reproduce the measurements. Coupled-channels (CC) analyses were made with a quadrupole-deformed optical-model potential and strong coupling of $\text{3}\text{2}{}^{\mathrm{?}}$, $\text{5}\text{2}{}^{\mathrm{?}}$ and $\text{7}\text{2}{}^{\mathrm{?}}$ levels of a $\text{K =}\text{3}\text{2}$ ground-state rotational band of ⁹Be. The ⁹Be(p, p₀)⁹Be and ⁹Be(p, p₂)⁹Be data from 13.0 to 30.3 MeV were analyzed simultaneously at each energy, varying only V_R and W_s with energy, for a potential deformation of β = 1.1. Both SOM and CC analyses indicated the same energy dependence in V_R, while W_s averaged 3.5 MeV lower in CC than in SOM, with both energy dependences consistent with previous analyses of nucleon scattering from 1p shell nuclei.     

Spin-wave scattering from A γ-Fe47Mn53alloy

Spin waves in the antiferromagnetic alloy γ-Fe_0.5Mn_0.5 have been studied at $\text{295° K(}\text{T}\text{T}{}_{\mathrm{N}}\text{= 0.63)}$ by the inelastic neutron scattering technique. We observed an isotropic dispersion and obtained a value for the spin-wave velocity of 255 ± 30 meV Å (3.88 ± 0.50 × 10⁶ cm/sec), which is the order of the spin-wave velocity in Cr (a typical itinerant antiferromagnet). The energy gap at q = 0 was found to be 7.0 ± 0.5 meV. These results suggest the existence of a long-range spin ordering in the conduction electrons of this alloy.     

Determination of the atomic-state population in A Kr-Br2 mixture

The atomic-state populations of the 5s[1$\text{1}\text{2}$]° metastable level of Kr and of the 5s²P_{$\text{3}\text{2}$} resonant level of Br in a Kr-Br₂ mixture have been determined as functions of current strength. Occurrence of energy transfer from the Kr-level to the Br-level has been verified.     

Characterization of LiFeCl4 and AgFeCl4 ionic conductors

LiFeCl₄ and AgFeCl₄ are obtained by direct reaction between LiCl or AgCl and FeCl₃ at 300°C and 400°C respectively. Both compounds are monoclinic with $\text{a = 7.02 (1)}\text{A}\text{?}$, $\text{b = 6.33 (1)}\text{A}\text{?}$, $\text{c = 12.72 (4)}\text{A}\text{?}$, β = 92° (30') for LiFeCl₄ and $\text{a = 10.60 (5)}\text{A}\text{?}$, $\text{b = 6.30 (5)}\text{A}\text{?}$, $\text{c = 12.34 (10)}\text{A}\text{?}$, β = 106° (1) for AgFeCl₄.LiFeCl₄ is clearly isotypic of LiAlCl₄. Magnetic measurements characterize in both cases Fe³⁺ ions in a high spin tetrahedral situation. LiFeCl₄ becomes antiferromagnetic at low temperature (T_N?10 K). AgFeCl₄ reveals a more complex situation. On contrary to the silver derivative, LiFeCl₄ is a good ionic conductor with activation energy of 0.78 eV in the solid state below 105°C, and a sharp increase in the lithium mobility at this temperature.     

Absorption spectra of Ni2+ in (NH4)2Mg(SO4)2·6H2O and Co2+ in Na2Zn(SO4)2·4H2O

Optical absorption spectra of Ni²⁺ in (NH₄)₂Mg(SO₄)₂·6H₂O and Co²⁺ in Na₂Zn(SO₄)₂·4H₂O single crystals have been studied at room and liquid nitrogen temperatures. From the nature and position of the observed bands, a successful interpretation could be made assuming octahedral symmetry for both the ions in the crystals. The splitting observed for ${}^3\text{T}{}_{\mathrm{1g}}\text{(F)}$ band in Ni²⁺ and ${}^4\text{T}{}_{\mathrm{2g}}\text{(F)}$ band in Co²⁺ at liquid nitrogen temperature have been explained as due to spin-orbit interaction. The extra band observed at 16,325 cm^-1 in the case of Ni²⁺ at low temperature has been interpreted to be the superposition of vibrational mode of SO^2-₄ radical on ${}^3\text{T}{}_{\mathrm{1g}}\text{(F)}$ band. The observed band positions in both the crystals have been fitted with four parameters B, C, Dq and ζ.     

Spin and lifetime of the ω− hyperon

A total of 101 ω^? decays have been found in K^?p interactions at 10 and $\text{16 GeV}\text{c}$. The decay angular distribution has been fitted under the assumptions that the ω^? has spin either $\text{1}\text{2}\text{or}\text{3}\text{2}$. It has been found that the probability of isotropy (spin$\text{1}\text{2}\text{)}$ is less than one in a thousand, whereas the probability for spin $\text{3}\text{2}$ is about 70%. Thus, we exclude the spin $\text{1}\text{2}$ assignment. The lifetime of the ω^? is found to be (1.41_?0.24^+0.15) × 10^?10s, in agreement with our earlier result based on about $\text{1}\text{5}$ of the present sample.     

Temperature dependence of the ESR spectra of Mn2+ in iron pyrite (FeS2)

The first observation of the ESR spectra of Mn²⁺, entering substitutionally for Fe²⁺ in the Van Vleck paramagnet FeS₂ (polycrystals), is reported. The data from 5 to 295 K fits the spin-Hamiltonian $\text{h}{}_{\mathrm{s}}\text{= gβ}\text{H}\text{·}\text{S}$ + $\text{[S}{}^{\mathrm{<mtext>2</mtext>}}{}_{\mathrm{z}}\text{?}\text{1}\text{3}\text{S(S + 1)] + A}\text{S}\text{·}\text{I}$, with g = 2.000 ± 0.001, A/β = ?95.0 ± 0.5 Oe and D/β varying from 50 Oe (5K) to 59 Oe (295 K). The temperature dependence of D can be described in terms of a single phonon-mode with frequency ? 145 cm^?1.     

Crystal growth,structure, electron paramagnetic resonance and magnetic properties of (NH4)2V3O8

A method to grow single crystals of ammonium vanadate (IV, V) (NH₄)₂V₃O₈ has been devised. The crystal structure is tetragonal P4bm; residual factor is R = 0.030. Cell parameters are $\text{a = 8.891 ± 0.004}\text{A}\text{?}$ and $\text{c = 5.582 + 0.002}\text{A}\text{?}$. The V⁵⁺ atom lies at the center of a triangular pyramide (VO₄ tetrahedron) while the V⁴⁺ atom is on A 4-fold rotation axis at the center of a square-based pyramide VO₅ whose symmetry point group is almost C_4v with the short V = O bond lying along the 4-fold axis parallel to the c edge of the tetragonal cell. Crystals are thin platlets with (001) cleavage planes. The platlets have very often a square or rectangular shape limited by {100} or {110} planes. Each single crystal was not large enough to record a good e.p.r. spectrum, but by sticking on the same quartz plate a score of them it was possible to gather enough crystals so to record correct spectra and by orienting the plate to obtain resonance lines separately for g_∥ = 1.9263 et g_τ = 1.9755. Measurements at 283 K on powder samples gave times for spin-spin relaxation T₂ = 0.4 × 10^?7s and for spin-lattice relaxation T₁ = 1.6 × 10^?7s. The magnetic structure is characterized by an exchange narrowing ω_e = 3 × 10¹⁰rad/s which corresponds to a transition temperature of about 0.5 K. Static susceptibility measurements at high magnetic field show a paramagnetic behaviour with an antiferromagnetic interaction which is interpreted in the magnetic space group P_2c4bm as the interaction between V⁴⁺ ions from consecutive planes parallel to (001).     

Classical behaviour of the soliton density in Rb2ZnCl4 studied by 87Rb NMR

The temperature dependence of the soliton density n_s(T) which has been studied in Rb₂ZnCl₄ by ⁸⁷Rb NMR could be fitted to a classical formula using only one fit parameter. From our data we cannot confirm recent experimental results which yield a critical exponent $\text{1}\text{2}$ for the soliton density. The results are discussed with respect to the free energy where the soliton density acts as the order parameter. Moreover, couplings to other degrees of freedom, e.g. the elastic strains, are considered.     

87Rb NMR lineshape study of the incommensurate phase in Rb2ZnBr4

On going from the paraelectric (P) to the incommensurate (I) phase the ⁸⁷Rb $\text{1}\text{2}$ → $\text{1}\text{2}$ NMR lines in Rb₂ZnBr₄ broaden into a continuum which is limited by two edge singularities. The observed line shape and its temperature dependence are well described by the frequency distribution function predicted by the “plane wave” modulation model of the I phase. The anomalous temperature dependence of T₁ shows the presence of the phason branch in the I phase.