Fractal-time stochastic processes and dynamic functions of polymeric systems

Dynamic material functions of polymeric systems are calculated via a defect-diffusion model. The random motion of defects is modelled by a fractaltime stochastic process. It is shown that the dynamic functions of polymeric solutions can be approximated by the defect-diffusion process of the mixed type. The relaxation modulus of Kohlrausch type is obtained for a fractal-time defect-diffusion process, and it is shown that this modulus is capable of portraying the dynamic behavior of typical viscoelastic solutions.The Fourier transforms of the Kohlrausch function are calculated to obtain and. A three-parameter model for and is compared with the previous calculations. Experimental measurements for five polymer solutions are compared with model predictions. D rate of deformation tensor - G(t) mechanical relaxation modulus - H relaxation spectrum - I(t) flux of defects - P _n (s) probability of finding a walker ats aftern-steps - P generating function ofP _n (s) - s(t) fraction of surviving defects - , () gamma function (incomplete) - ₀ zero shear viscosity - ^* () complex viscosity - frequency - t _n n-th moment - F[] Fourier transform - f ^* (u) Laplace transform off(t) - , components of ^* - G _f, _f ^* fractional model - G ₃, ₃ ^* three parameter model - complex conjugate ofz - material time derivative ofD     

Shear viscosity behavior of highly concentrated suspensions at low and high shear-rates

A method is proposed for determining the shear viscosity behavior of highly concentrated suspensions at low and high shear-rates through the use of a formulation that is a function of three parameters signifying the effects of particle size distribution. These parameters are the intrinsic viscosity [], a parametern that reflects the level of particle association at the initiation of motion and the maximum packing concentration _m. The formulation reduces to the modified Eilers equation withn = 2 for high shear rates. An analytical method was used for the calculation of maximum packing concentration which was subsequently correlated with the experimental values to account for the surface induced interaction of particles with the fluid. The calculated values of viscosities at low and high shear-rates were found to be in good agreement with various experimental data reported in literature. A brief discussion is also offered on the reliability of the methods of measuring the maximum packing concentration. _r = /₀ relative viscosity of the suspension - volumetric concentration of solids - k _n coefficient which characterizes a specific effect of particle interactions - _m maximum packing concentration - _r,0 relative viscosity at low shear-rates - [] intrinsic viscosity - n, n parameter that reflects the level of particle interactions at low and high shear-rates, respectively - _r, relative viscosity at high shear-rates - (_m)_s, (_m)_i, (_m)_l packing factors for small, intermediate and large diameter classes - v _s, v_i, v_l volume fractions of small, intermediate and large diameter classes, respectively - _si, _sl coefficient to be used in relating a smaller to an intermediate and larger particle group, respectively - _is, _il coefficient to be used in relating an intermediate to a smaller and larger particle group, respectively - _ls, _li coefficient to be used in relating a larger to a smaller and intermediate particle group, respectively - _m0 maximum packing concentration for binary mixtures - _m,e measured maximum packing concentration - _m,c calculated maximum packing concentration     

Viscoelastic swirling flow with free surface in cylindrical chambers

The flow of a viscoelastic liquid driven by the steadily rotating bottom cover of a cylindrical cup is investigated. The flow field and the shape of the free surface are determined at the lowest significant orders of the regular domain perturbation in terms of the angular velocity of the bottom cap. The meridional field superposed on a primary azimuthal field shows a structure of multiple cells. The velocity field and the shape of the free surface are strongly effected by the cylinder aspect ratio and the elasticity of the liquid. The use of this flow configuration as a free surface rheometer to determine the first two Rivlin-Ericksen constants is shown to be promising.Nomenclature R, ,Z Coordinates in the physical domain D - , , Coordinates in the rest stateD ₀ - r, ,z Dimensionless coordinates in the rest stateD ₀ - Angular velocity - Zero shear viscosity - Surface tension coefficient - Density - Dimensionless surface tension parameter - ₁, ₂ The first two Rivlin-Ericksen constants - Stream function - Dimensionless second order meridional stream function - ^* Dimensionless second normal stress function - 2 Dimensionless sum of the first and second normal stress functions - N ₁,N ₂ The first and second normal stress functions - n Unit normal vector - D Stretching tensor - A _n nth order Rivlin-Ericksen tensor - S Extra-stress - u Velocity field - U Dimensionless second order meridional velocity field - V Dimensionless first order azimuthal velocity field - p Pressure - Modified pressure field - P Dimensionless second order pressure field - J Mean curvature - a Cylinder radius - d Liquid depth at rest - D Dimensionless liquid depth at rest - h Free surface height - H Dimensionless free surface height at the second order     

Heat transport in a parabolic tube of circular cross-section

The local temperature has been determined for a viscous liquid flowing through a paraboloidal tube. Wall temperature and inlet temperature have been considered constant. The liquid flow was considered as creeping flow and its velocity distribution was determined by solving the biharmonic differential equation of the stream function. The local temperature was evaluated numerically from the analytical results.

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Wärmetransport im Paraboloidrohr

Zusammenfassung Es wird die lokale Temperatur in einer viskosen Strömung durch ein Paraboloidrohr bestimmt. Dabei wird konstante Wand- und Einlauftemperatur angenommen. Die kriechende Strömungsgeschwindigkeit wurde aus der Lösung der biharmonischen Differentialgleichung der Stromfunktion bestimmt. Die lokale Temperatur wurde aus den analytischen Ergebnissen für einige Paraboloidrohre numerisch bestimmt.

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Nomenclature ₁ F ₁ confluent hypergeometric function - diffusivity - T(, , ) temperature - T _w temperature at the paraboloidal wall - T _i temperature at the inlet - u(, ) flow velocity of viscous liquid in -direction - volumetric flow - eigenvalues of confluent hypergeometric function - streamfunction - _o wall of paraboloidal tube - _o inlet of paraboloidal tube - , , paraboloidal coordinates     

Modelling of heat transfer by conduction in a transition region between a porous medium and an external fluid

We study the modelling of purely conductive heat transfer between a porous medium and an external fluid within the framework of the volume averaging method. When the temperature field for such a system is classically determined by coupling the macroscopic heat conduction equation in the porous medium domain to the heat conduction equation in the external fluid domain, it is shown that the phase average temperature cannot be predicted without a generally negligible error due to the fact that the boundary conditions at the interface between the two media are specified at the macroscopic level.Afterwards, it is presented an alternative modelling by means of a single equation involving an effective thermal conductivity which is a function of point inside the interfacial region.The theoretical results are illustrated by means of some numerical simulations for a model porous medium. In particular, temperature fields at the microscopic level are presented.Roman Letters _sf interfacial area of thes-f interface contained within the macroscopic system m² - A _sf interfacial area of thes-f interface contained within the averaging volume m² - C _p mass fraction weighted heat capacity, kcal/kg/K - g vector that maps to _s , m - h vector that maps to _f , m - K _eff effective thermal conductivity tensor, kcal/m s K - l _s,l _f microscopic characteristic length m - L macroscopic characteristic length, m - n _fs outwardly directed unit normal vector for thef-phase at thef-s interface - n outwardly directed unit normal vector at the dividing surface. - R ₀ REV characteristic length, m - T _i macroscopic temperature at the interface, K - error on the external fluid temperature due to the macroscopic boundary condition, K - T ^* macroscopic temperature field obtained by solving the macroscopic Equation (3), K - V averaging volume, m³ - V _s,V _f volume of the considered phase within the averaging volume, m³. - _mp volume of the porous medium domain, m³ - _ex volume of the external fluid domain, m³ - _s , _f volume of the considered phase within the volume of the macroscopic system, m³ - dividing surface, m² - x, z spatial coordinates Greek Letters _s, _f volume fraction - ratio of the effective thermal conductivity to the external fluid thermal conductivity - ^* macroscopic thermal conductivity (single equation model) kcal/m s K - _s, _f microscopic thermal conductivities, kcal/m s K - spatial average density, kg/m³ - microscopic temperature, K - ^* microscopic temperature corresponding toT ^*, K - spatial deviation temperature K - error in the temperature due to the macroscopic boundary conditions, K - ^* _i macroscopic temperature at the interface given by the single equation model, K - spatial average - ^s , ^f intrinsic phase average.     

Supersonic air flow past a sphere with account for vibrational relaxation

A numerical solution is obtained for the problem of air flow past a sphere under conditions when nonequilibrium excitation of the vibrational degrees of freedom of the molecular components takes place in the shock layer. The problem is solved using the method of [1]. In calculating the relaxation rates account was taken of two processes: 1) transition of the molecular translational energy into vibrational energy during collision; 2) exchange of vibrational energy between the air components. Expressions for the relaxation rates were computed in [2]. The solution indicates that in the state far from equilibrium a relaxation layer is formed near the sphere surface. A comparison is made of the calculated values of the shock standoff with the experimental data of [3].Notation uV_max, vV_max velocity components normal and tangential to the sphere surface - V_max maximal velocity - P V _max ² pressure - density - TT temperature - e_viRT vibrational energy of the i-th component per mole (i=–O₂, N₂) - =rb–1 shock wave shape - a _f the frozen speed of sound - HRT/m gas total enthalpy     

Transport in ordered and disordered porous media I: The cellular average and the use of weighting functions

In this work we consider transport in ordered and disordered porous media using singlephase flow in rigid porous mediaas an example. We defineorder anddisorder in terms of geometrical integrals that arise naturally in the method of volume averaging, and we show that dependent variables for ordered media must generally be defined in terms of thecellular average. The cellular average can be constructed by means of a weighting function, thus transport processes in both ordered and disordered media can be treated with a single theory based on weighted averages. Part I provides some basic ideas associated with ordered and disordered media, weighted averages, and the theory of distributions. In Part II a generalized averaging procedure is presented and in Part III the closure problem is developed and the theory is compared with experiment. Parts IV and V provide some geometrical results for computer generated porous media.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A_e area of entrances and exits for the-phase contained within the macroscopic system, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor, m² - L general characteristic length for volume averaged quantities, m - characteristic length (pore scale) for the-phase - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - N unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p0 reference pressure in the-phase, N/m² - p traditional intrinsic volume averaged pressure, N/m² - r0 radius of a spherical averaging volume, m - r position vector, m - r position vector locating points in the-phase, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v traditional superficial volume averaged velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V/V, volume average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

Flow through a helically coiled annulus

In this paper the flow is studied of an incompressible viscous fluid through a helically coiled annulus, the torsion of its centre line taken into account. It has been shown that the torsion affects the secondary flow and contributes to the azimuthal component of velocity around the centre line. The symmetry of the secondary flow streamlines in the absence of torsion, is destroyed in its presence. Some stream lines penetrate from the upper half to the lower half, and if is further increased, a complete circulation around the centre line is obtained at low values of for all Reynolds numbers for which the analysis of this paper is valid, being the ratio of the torsion of the centre line to its curvature.Nomenclature A =constant - a outer radius of the annulus - b unit binormal vector to C - C helical centre line of the pipe - D rL - g 1000 - K Dean number=Re² - L 1+r sin - M (L ²+ ² r ²)^1/2 - n unit normal vector to C - P, P pressure and nondimensional pressure - p ₀, p pressures of O(1) and O() - Re Reynolds number=aW ₀/ - (r, , s), (r, , s) coordinates and nondimensional coordinates - nonorthogonal unit vectors along the coordinate directions - r ₀ radius of the projection of C - t unit tangent vector to C - V _r, V , V _s velocity components along the nonorthogonal directions - V_r, V, V _s nondimensional velocity components along - W ₀ average velocity in a straight annulus Greek symbols , curvature and nondimensional curvature of C - U, V, W lowest order terms for small in the velocity components along the orthogonal directions t - _r, , _s first approximations to V _r , V, V _s for small - =/=/ - kinematic viscosity - density of the fluid - , torsion and nondimensional torsion of C - , stream function and nondimensional stream function - nondimensional streamfunction for U, V - a inner radius of the annulus After this paper was accepted for publication, a paper entitled On the low-Reynolds number flow in a helical pipe, by C.Y. Wang, has appeared in J. Fluid. Mech., Vol 108, 1981, pp. 185–194. The results in Wangs paper are particular cases of this paper for =0, and are also contained in [9].     

An exact solution for non-darcy free convection from a horizontal line source of heat

In this paper we consider the free convection from a horizontal line source of heat which is embedded in an unbounded porous medium saturated with a fluid at rest under gravity. The convective fluid and the porous medium are in local thermal equilibrium.

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Eine exakte Lösung der nicht-darcy'schen freien Konvektion von einer horizontalen, linienförmigen Wärmequelle

Zusammenfassung In dem Aufsatz wird die freie Konvektion von einer horizontalen, linienförmigen Wärmequelle untersucht, die in ein unbegrenztes poröses Medium eingebettet ist. Die Poren des porösen Mediums sind mit einem Fluid gefüllt, das unter Schwerkrafteinfluß ruht. Das strömende Fluid und das poröse Medium sind örtlich im thermischen Gleichgewicht.

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Nomenclature c _p specific heat of convective fluid - F _o parameter,=/(vl>g - g acceleration due to gravity - k thermal conductivity of the saturated porous medium - l typical length scale of body - Q heat flux per unit length of a line source - Ra Rayleigh number, =gQl/²c_p - Ra _x local Rayleigh number, =xg Qx/ a²c_p - T temperature - T temperature of ambient fluid - u, x andy components of velocity - x, y coordinates vertically upwards and normal to axis of plume - X, Y non-dimensional coordinates vertically upwards and normal to axis of plume Greek symbols equivalent themal diffusivity - coefficient of thermal expansion - similarity variable - non-dimensional temperature - x permeability of porous medium - viscosity of convective fluid - v kinematic viscosity of convective fluid - density of convective fluid - stream function - non-dimensional stream function - the Forchheimer's coefficient     

The dynamic and steady shear properties of synovial fluid and of the components making up synovial fluid

Steady-shear and dynamic properties of a pooled sample of cattle synovial fluid have been measured using techniques developed for low viscosity fluids. The rheological properties of synovial fluid were found to exhibit typical viscoelastic behaviour and can be described by the Carreau type A rheological model. Typical model parameters for the fluid are given; these may be useful for the analysis of the complex flow problems of joint lubrication.The two major constituents, hyaluronic acid and proteins, have been successfully separated from the pooled sample of synovial fluid. The rheological properties of the hyaluronic acid and the recombined hyaluronic acid-protein solutions of both equal and half the concentration of the constituents found in the original synovial fluid have been measured. These properties, when compared to those of the original synovial fluid, show an undeniable contribution of proteins to the flow behaviour of synovial fluid in joints. The effect of protein was found to be more prominent in hyaluronic acid of half the normal concentration found in synovial fluid, thus providing a possible explanation for the differences in flow behaviour observed between synovial fluid from certain diseased joints compared to normal joint fluid.Nomenclature A Ratio of angular amplitude of torsion head to oscillation input signal - G Storage modulus - G Loss modulus - I Moment of inertia of upper platen — torsion head assembly - K Restoring constant of torsion bar - N ₁ First normal-stress difference - R Platen radius - S ⁽ⁱ⁾ Geometric factor in the dynamic property analysis - t ₁ Characteristic time parameter of the Carreau model - X, Y Carreau model parameters - Z () Reimann Zeta function of - Carreau model parameter - Shear rate - Apparent steady-shear viscosity - ^* Complex dynamic viscosity - Dynamic viscosity - Imaginary part of the complex dynamic viscosity - ₀ Zero-shear viscosity - ₀ Cone angle - Carreau model characteristic time - Density of fluid - Shear stress - Phase difference between torsion head and oscillation input signals - ₀ Zero-shear rate first normal-stress coefficient - Oscillatory frequency