Shear-thickening flow of suspensions of carbon nanofibers in aqueous PVA solutions

The suspensions of carbon nanofibers in aqueous poly(vinyl alcohol) solutions were prepared in the presence of spherical carbon black particles, and the steady-shear viscosity and dynamic viscoelasticity were measured for complex suspensions. Although the single suspensions of carbon black are highly stable, the flocculation of carbon nanofibers is promoted by the addition of carbon black particles. The complex suspensions show remarkable shear thickening in the steady-flow and strain hardening in oscillatory shear with large amplitude. The nonlinear responses strongly depend on the carbon black concentration, whereas the dynamic viscoelasticity at low strains in the linear ranges is not significantly influenced. As the highly elastic effects arise from the long-range motion of particles, the possible mechanism may be the orientation of nanofibers in strong shear fields. The suspensions show the time-dependent behavior of viscosity when the time-scale of measurements is shorter than that of structural recovery to the isotropic states.     

Turbulent heat transfer to dilute aqueous suspensions of titanium dioxide in pipes

An experimental investigation into turbulent heat transfer to pseudoplastic titanium dioxide suspensions in pipes has been carried out. Existing heat transfer correlations, including the analogy equations between heat and momentum transfer, generally predict higher Nusselt and Stanton numbers than those observed experimentally. However, a simplified heat transfer model based on the consideration of the laminar sub-layer at the wall and the turbulent core correlates the heat transfer results for heating as well as cooling. The limitations of the existing analogy equations between heat and momentum transfer are discussed.     

Rheology of low viscosity,high concentration brown coal suspensions

The paper describes how the theology of low concentration brown coal suspensions can be exploited to produce high concentration, low viscosity suspensions which are attractive as a potential coal-water fuel. Brown coal suspensions with solid concentrations approaching those of bituminous black coal have been prepared. The high inherent water content ( 60 wt %) and macroporosity of the brown coal have been reduced by thermal and chemical means. The hydrophobicity of the coal surface has been increased sufficiently to reduce the tendency for swelling and water uptake. This, together with densification, has allowed the solids content to be progressively improved from 30 wt % solids with raw coal to 65 wt% solids with modified coals while maintaining the viscosity of the suspension at a low level. The high solid concentration was achieved without additives.     

Elastico-viscous properties of deflocculated china clay suspensions — concentration effects

Summary The physical properties of deflocculated china clay suspensions are studied in a combined steady and low-amplitude oscillatory shear flow. Concentration effects are examined and it is shown that, with increasing concentration, an initial shear thinning region is followed by a shear thickening one. Qualitative agreement is obtained between theory and experiment for a range of concentrations of suspensions, all of which exhibit marked elastic properties. The experimental results were obtained using a Weissenberg Rheogoniometer.

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Zusammenfassung Es werden die physikalischen Eigenschaften deflockulierter Suspensionen von Porzellanerde in einer kombinierten stationären und oszillatorischen Scherströmung mit niedriger Amplitude studiert. Der Einfluß der Konzentration wird untersucht, und es wird gezeigt, daß mit wachsender Konzentration sich an den anfänglich allein vorhandenen Bereich mit Scherentzähung ein Bereich mit Scherverzähung anschließt. Zwischen Theorie und Experiment wird eine qualitative Übereinstimmung in einem Konzentrationsbereich gefunden, in dem ausgeprägte viskoelastische Eigenschaften vorhanden sind. Die experimentellen Ergebnisse werden mit Hilfe eines Weissenberg-Rheogoniometers erhalten.

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c phase lag in oscillatory testing - D(t – t) deformation history - F, G non-dimensional complex functions of - complex conjugate ofF - G dynamic rigidity - i - I % increase in mean couple under superposed shear rates - I ₁ moment of inertia of the top platen (i.e. cone) - J amplitude ratio, ₁/ ₁ - K ₁ restoring constant of the torsion bar - q steady shear rate - r, , spherical polar coordinates - t current time - v _i velocity vector - w/w concentration by weight - W a function of andt - ₁ angular amplitude of the motion of the plate - shear rate - /q - apparent viscosity - dynamic viscosity - ^* complex dynamic viscosity - ₀ limiting viscosity at small rates of shear - ₀ gap angle in cone and plate system - ₁, ₂, ₃, ₄,µ ₀ relaxation time constants - shear stress - ₀ unperturbed shear stress - ₁, ₂ kernel functions - angular frequency of oscillation - steady angular velocity of the plate With 16 figures     

Evolution of shock waves in polydisperse gas suspensions with a nonuniform particle concentration distribution

The results of a numerical investigation of the laws of shock wave propagation in polydisperse (two-fraction) gas suspensions with a non-uniform initial particle concentration distribution are presented. Examples of shock wave propagation in extended layers of a gas suspension with linearly increasing, linearly decreasing and sinusoidal laws of variation of the particle concentration are considered. It is shown that when shock waves pass through layers of a gas suspension with increasing and decreasing laws of variation of the particle concentration, respectively, amplification and attenuation of the waves are observed; when shock waves travel through gas suspensions with a periodic law of variation of the particle concentration the pressure distribution behind the wave fronts is nonmonotonic. The solutions corresponding to polydisperse and monodisperse gas suspensions with an effective particle size are examined. The nonequilibrium and thermodynamic-equilibrium solutions are compared.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 183–190, September–October, 1991.     

Effects of anionic additives on the rheological behavior of aqueous calcium montmorillonite suspensions

Three different experimental measurements, namely, rheology, particle sizing, and x-ray diffraction (XRD), were used to study the effect of anionic additives on the properties of bentonite suspensions. The three additives were sodium carboxymethylcellulose, xanthan gum, and sodium dodecyl sulfate. Flow curves were obtained from shear stress–shear rate measurements, and the viscoelastic properties were determined from oscillatory and transient measurements. Mineralogical data were evaluated by XRD and the particle size analysis performed by light scattering technique. The presence of the surfactant modifies the face-to-face interactions and yields changes of the mixtures rheological behavior at low deformation rates. Polymers act by coating each clay particle and prevent their agglomeration. Therefore, the additives are responsible for the mechanisms of destructuration and structure reorganization as well as the mixtures viscous and viscoelastic behavior.     

Effect of solids concentration in dense suspensions of silica-iron(III) oxide and water

The rheological properties of dense suspensions, of silica, iron (III) oxide and water, were studied over a range of solids concentrations using a viscometer, which was modified so as to prevent settling of the solid components. Over the conditions studied, the material behaved according to power—law flow relationships. As the concentrations of silica and iron(III) oxide were increased, an entropy term in the flow equation was identified which had a silica dependent and an iron (III) oxide dependent component. This was attributed to a tendency to order into some form of structural regularity. A, A, B, C pre-exponential functions (K Pa^–n s^–1) - C _ox volume fraction iron (III) oxide - Q activation energy (kJ mol^–1) - R gas constant (kJ mol^–1 K^–1) - R _v silica/water volume ratio - T temperature (K) - n power-law index - H enthalpy (kJ mol^–1) - S entropy change (kJ mol^–1 K^–1) - shear strain rate (s^–1) - shear stress (Pa)     

LIF measurements of concentration profiles in the aqueous mass boundary layer

 A laser-induced fluorescence (LIF) technique is described to measure vertical concentration profiles of gases in the aqueous mass boundary layer at a free water surface. The technique uses an acid-base reaction of the fluorescence indicator fluorescein at the water surface to visualize the concentration profiles. The technique is capable of measuring two-dimensional vertical concentration profiles at a rate of 200 frames/s and a spatial resolution of 16 μm. The mass boundary layer at a free surface is characterized by significant fluctuations. Direct surface renewal is observed. The mean profiles also support rather surface renewal models than turbulent diffusion models. Received: 21 May 1997/Accepted: 18 December 1997     

Dual yielding in capillary suspensions

Rheological measurements were performed to examine the yielding behavior of capillary suspensions prepared by mixing cocoa powder as dispersed phase, vegetable oil as the continuous primary fluid, and water as the secondary fluid. Here, we investigated the yielding behavior of solid-fluid-fluid systems with varying particle volume fraction, ?, spanning the regime from a low volume fraction (? = 0.25) to a highly filled regime (? = 0.65) using dynamic oscillatory measurements. While for ? ≤ 0.4 with a fixed water volume fraction (? _w ) of 0.06 as the secondary fluid, capillary suspensions exhibited a single yield point due to rupturing of aqueous capillary bridges between the particles, while capillary suspensions with ? ≥ 0.45 showed a two-step yielding behavior. On plotting elastic stress (G^′ γ) as a function of applied strain (γ), two distinct peaks, indicating two yield stresses, were observed. Both the yield stresses and storage modulus at low strains were found to increase with ? following a power law dependence. With increasing ? _w (0 – 0.08) at a fixed ? = 0.65, the system shifted to a frustrated, jammed state with particles strongly held together shown by rapidly increasing first and second yield stresses. In particular, the first yield stress was found to increase with ? _w following a power law dependence, while the second yield stress was found to increase exponentially with ? _w . Transient steady shear tests were also performed. The single stress overshoot for ? ≤ 0.4 with ? _w = 0.06 reflected one-step yielding behavior. In contrast, for high ? (≥ 0.45) values with ? _w = 0.06, two stress overshoots were observed in agreement with the two-step yielding behavior shown in the dynamic oscillatory measurements. Experiments on the effect of resting time on microstructure recovery demonstrated that aggregates could reform after resting under quiescent conditions.     

Pulse propagation in particulate suspensions

The propagation of finite pulses of high-frequency in a suspension composed of a distribution of incompressible particles in an incompressible fluid is examined by using the technique of modulated simple-wave theory. The differential equation which governs the propagation of high-frequency pulses is derived and its consequences are examined. The properties of small amplitude high-frequency pulses are examined in detail.     

Settling phenomena in flocculated suspensions

Summary A series of experiments on the batch settling of suspensions of micron-sized polyvinyl chloride spheres flocculated with potassium alum shows that the form of the settling curve is determined by the initial concentration of solids and the degree of flocculation. The characteristics of the settling curve, and the possibility that it is influenced by the height of the settling column of solids, can be predicted from yield stress measurements. The various forms of settling curve were also obtained with china clay suspensions although the solids concentrations producing comparable curves were appreciably less.

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Zusammenfassung Eine Reihe von Versuchen über das Absetzen von suspendierten mikrogroßen PVC-Kügelchen, die mit Kalium-Alaun ausgeflockt sind, zeigen eine AbhÄngigkeit dieses Prozesses von der Anfangskonzentration der Festkörper sowie dem Flockungsgrad.Die Charakteristiken der Absetzkurve und die Möglichkeit ihrer Beeinflussung durch die Höhe der absetzenden FestkörpersÄule kann mit Hilfe von Fließgrenzenmessungen vorausgesagt werden.Die verschiedenen Formen der Absetzkurven wurden auch mit Kaolinsuspensionen erhalten, jedoch bei viel geringerer Konzentration.

     

Negative thixotropy in ferric-oxide suspensions

Negative thixotropy was observed in suspensions of ferric-oxide particles in mineral oil, in that viscosity increased with time under shear. The enhanced viscosity under the shear was retained under rest, and it decreased gradually by application of shear at lower shear-rate.The ferric-oxide powders used are acicular submicron maghemite and hematite. The dispersing medium is a heavy mineral oil. The suspensions were prepared with a ball mill in 33% by particle weight using a dispersing agent.A qualitative interpretation was made for the development of the phenomenon with a floc model in which suspensions of acicular particles form bulky structures with larger volume fraction of flocs phase at higher rate of shear, accompanied with increase of viscosity. The expanded structures, then, shrink again at lower shear-rate due to the inter-particle attractions.     

Accelerated aging of unidirectional hybrid composites under the long-term elevated temperature and moisture concentration

Despite their high performances, composites with polymer matrix are very sensible to the increase in temperature and moisture concentration. During long years of services, both phenomena cause a critical transient hygrothermal transverse stresses, particularly at first-ply; i.e. at two edges of the composite plates. Therefore, significant degradation of hygrothermal characteristics and ultimate strengths of materials are occurred. To get an explicit relation between the durability and the damage probability of the composite, quadratic failure criterion in stress space is used. This criterion enables us to find a direct relation between transient hygrothermal stresses produced by the increase in temperature and moisture concentration and the ultimate strengths. It is necessary to calculate the strength ratio R from initial to saturation time for each condition imposed of temperature and moisture concentration. The strength ratio gives a point of view on the damage probability of the composite plates, where the rupture occurs if R = 1. In order to limit the consequences of simultaneous effects of temperature and moisture concentration, unidirectional hybrid composites in graphite epoxy was proposed. To reach this aim, hygrothermal transverse stresses are calculated through the thickness of unidirectional hybrid plate. Finally, the strength ratio was evaluated along of the plate with a gradual increase in temperature and moisture concentration.     

The effect of pH,ionic strength,and temperature on the rheology and stability of aqueous clay suspensions

The effect of pH level, ionic strength, and temperature on the theology and stability of aqueous suspensions of attapulgite clay was systematically investigated. A Rheometrics Mechanical Spectrometer with cone and plate fixtures was used to measure the steady shear viscosity of the system. The edge charges of the clay particles can be adjusted by changing the pH level of the suspending medium so as to influence the flocculation state and, consequently, the rheological behavior of the suspension. This pH effect may be counteracted by the ionic strength effect at both very high and very low pH levels where the ionic strength is high enough to cause flocculation of the electrostatically stabilized suspension. The temperature effect study indicates that the relative contribution of Brownian motion and shear flow to the viscosity is dependent on the flocculation state of the suspension.     

Observations on the rheological response of alkali activated fly ash suspensions: the role of activator type and concentration

This paper reports the influence of activator type and concentration on the rheological properties of alkali-activated fly ash suspensions. A thorough investigation of the rheological influences (yield stress and plastic viscosity) of several activator parameters, including: (i) the cation type and concentration of alkali hydroxide and (ii) the alkali-to-binder ratio (n) and silica modulus (M_s), and (iii) the volume of the activation solution, on the suspension rheology is presented. The results indicate a strong dependence on the cation and its concentration in the activation solution. The viscosity of the activation solution and the volumetric solution-to-powder ratio are shown to most strongly influence the plastic viscosity of the suspension. The suspension yield stress is predominantly influenced by the changes in fly ash particle surface charge and the ionic species in the activator. A shift from non-Newtonian to Newtonian flow behavior is noted in the case of silicate-based suspensions for M_s?≤?1.5. This behavior, which is not observed at higher M_S values, or when the fly ash is dispersed in hydroxide solutions or pure water, is hypothesized to be caused by colloidal siliceous species present in this system, or surface charge effects on the fly ash particles. Comparisons of the rheological response of alkali-activated suspensions to that of portland cement-water suspensions are also reported.     

Shear thickening in electrically-stabilized colloidal suspensions

A theory is presented for the onset of shear thickening in colloidal suspensions of particles, stabilized by an electrostatic repulsion. Based on an activation model, a critical shear stress can be derived for the onset of shear thickening in dense suspensions for a constant potential and a constant charge approach of the spheres. Unlike previous models, the total interaction potential is taken into account (sum of attraction and repulsion). The critical shear stress is related to the maximum of the total interaction potential scaled by the free volume per particle. A comparison with experimental investigations shows the applicability of the theory.