Surface modification of poly(propylene carbonate) by oxygen ion implantation

Poly(propylene carbonate) (PPC) was implanted by oxygen ion with energy of 40 keV. The influence of experimental parameters was investigated by varying ion fluence from 1 × 10¹² to 1 × 10¹⁵ ions/cm². XPS, SEM, surface roughness, wettability, hardness, and modulus were employed to investigate structure and properties of the as-implanted PPC samples. Eight chemical groups, i.e., carbon, CH, COC, CO, OCO, CO, , and groups were observed on surfaces of the as-implanted samples. The species and relative intensities of the chemical groups changed with increasing ion fluence. SEM images displayed that irradiation damage was related strongly with ion fluence. Both surface-recovering and shrunken behavior were observed on surface of the PPC sample implanted with fluence of 1 × 10¹⁵ ions/cm². As increasing ion fluence, the surface roughness of the as-implanted PPC samples increased firstly, reached the maximum value of 159 nm, and finally decreased down the minimum value. The water droplet contact angle of the as-implanted PPC samples changed gradually with fluence, and reached the minimum value of 70° with fluence of 1 × 10¹⁵ ions/cm². The hardness and modulus of the as-implanted PPC samples increased with increasing ion fluence, and reached their corresponding maximum values with fluence of 1 × 10¹⁵ ions/cm². The experimental results revealed that oxygen ion fluence closely affected surface chemical group, morphology, surface roughness, wettability, and mechanical properties of the as-implanted PPC samples.     

Electronic structure of the Sb-induced Si(1 1 3)2 × 5 surface

The surface electronic structure of Sb/Si(1 1 3)2 × 5 was investigated by angle-resolved photoemission spectroscopy experiments. This reveals Sb/Si(1 1 3)2 × 5 to have three surface bands with anisotropic two-dimensional characteristics. The band widths of the surface bands along is larger than along . The number of surface bands of Sb/Si(1 1 3)2 × 5 and their band dispersions along and are quite analogous with those of Sb/Si(1 1 3)2 × 2 composed of Sb adatom and Si tetramer chains. The electronic structure analogy suggests that Sb/Si(1 1 3)2 × 5 and Sb/Si(1 1 3)2 × 2 have common building blocks such as Sb adatom and Si tetramer chains.     

МЕТОД ОБРАБОТКИ ДВУХ МЕРНЫХ СПЕКТРОВ СОВП АДЕНИЙ И ЕГО ПРИМЕНЕНИЕ К АНА ЛИЗУ γ-γ-СОВПАДЕНИЙ НА Ge(Li)-ДЕТЕКТОРАХ ПРИ РА СПАДЕ155Tb

The method of data processing of two-dimensional coincidence spectra is described and its application for the --coincidence spectra analysis in¹⁵⁵Tb is shown. The existence of levels with energies 86·5; 105·3; 118·0; 235·2; 266·6; 268·6; 286·8; 326·0; 367·7; 427· 4; 451·3; 488·8 keV in¹⁵⁵Gd nucleus is proved on the basis of --coincidences measured in¹⁵⁵Tb decay with Ge(Li)-detectors. Two new transitions with energies of 192 and 163 keV were found.     

Decay of Re186

The decay of Re 186 was investigated with a double focusing spectrometer and scintillation spectrometer. Four transitions were observed with energies of 122·7±0·1 keV, 137·2 keV, 632·2±1·5 keV and 768·2±1·5 keV and the relative-ray intensities 18, 246, 0·9 and 1 respectively. TheK-conversion coefficients determined for low-energy transitions are in good agreement with the theoretical values ( _K ^122·7 =0·53±0·05, _K ^137·2 =0·44±0·02). The relative intensities of theK, L, M andN conversion lines were also determined for these transitions:KL _I +IIL _III M=1·20±0·201·32±0·20 1±0·150·57±0·08 for 122·7 keV transition,KL _I +IIL _III MN=1·57±0·081· 72±0080·70±0·030·20±0·01 for 137·2 keV transition. In the beta spectrum two groups were observed with the end points of 1076±3 keV and 939±3 keV and relative intensities 74±4% and 21±4% respectively. For the branching ofK-capture it was found that 1·5% populates the 122·7 keV level and 3·5% the ground state. The decay scheme from the present results is proposed.The authors would like to thank M. Buriánek and V. Kopiva for help in the measurements.     

Random shearing direction models for isotropic turbulent diffusion

Recently, a rigorous renormalization theory for various scalar statistics has been developed for special modes of random advection diffusion involving random shear layer velocity fields with long-range spatiotemporal correlations. New random shearing direction models for isotropic turbulent diffusion are introduced here. In these models the velocity field has the spatial second-order statistics of an arbitrary prescribed stationary incompressible isotropic random field including long-range spatial correlations with infrared divergence, but the temporal correlations have finite range. The explicit theory of renormalization for the mean and second-order statistics is developed here. With the spectral parameter, for –<<4 and measuring the strength of the infrared divergence of the spatial spectrum, the scalar mean statistics rigorously exhibit a phase transition from mean-field behavior for <2 to anomalous behavior for with 2<<4 as conjectured earlier by Avellaneda and the author. The universal inertial range renormalization for the second-order scalar statistics exhibits a phase transition from a covariance with a Gaussian functional form for with <2 to an explicit family with a non-Gaussian covariance for with 2<<4. These non-Gaussian distributions have tails that are broader than Gaussian as varies with 2<<4 and behave for large values like exp(–C _c |x|^4–), withC _c an explicit constant. Also, here the attractive general principle is formulated and proved that every steady, stationary, zero-mean, isotropic, incompressible Gaussian random velocity field is well approximated by a suitable superposition of random shear layers.     

Identification and intensity analysis on forbidden magnetic dipole emission lines of highly charged Al, Ar, Ti and Fe ions in LHD

Forbidden lines arising from magnetic dipole (M1) transitions in ground and 2s2p excited configurations of highly charged Al, Ar, Ti and Fe ions have been observed in the large helical device (LHD). Argon was puffed using a piezo-electronic valve and other metallic materials were injected using an impurity pellet injector into LHD plasma for the observation. The M1 transitions in vacuum ultraviolet (VUV) and visible regions are identified by analyzing their Doppler broadening, temporal intensity behavior and spatial intensity distribution. Wavelengths of these M1 transitions are determined with high accuracy and compared with previous experimental and calculated values. The line intensity ratios of the M1 transition to the allowed (E1) transition such as (ArX 5533 Å/165 Å, TiXIV 2118 Å/122 Å and FeXVIII 975 Å/94 Å) and 2s2p - (ArXV 5944 Å/221 Å) are measured as a function of electron density. Results on the ArX and ArXV are compared with a simple level-population calculation. As a result, the density dependence of the ratio is well explained mainly by a competition between two decay processes of the collisional de-excitation and the radiative decay due to the forbidden line emission, although a clear discrepancy between the experimental and calculated absolute values appears for the ArX ratio. Contribution of fast proton impact excitation, which is brought by 180 keV neutral beam injection (NBI) for plasma heating, is also analyzed with the calculation for the F-like ions of ArX, TiXIV and FeXVIII.     

One-dimensional defects in iodine adlayers on Pt(1 0 0)

One-dimensional defect structures of closed-packed adlayers of iodine on Pt(1 0 0) were studied with scanning tunneling microscopy (STM). On the terraces of the Pt(1 0 0) surface we observed rotational domains with line defects running in [0 1 0] directions, in coexistence with nearly defect-free domains. In addition to these prevailing line defects (A-defects) with a local coverage lower than that of a defect-free surface, we report on much less frequently observed line defects with higher local coverages (B- and C-defects). The strong dependence of the concentration of these defects on the adsorption temperature is governed by the decrease of the overall iodine coverage with increasing temperature. Iodine adsorption at ∼1100 K leads to self-organization of A-defects in quasi-periodic arrangements. The relevance of these defects as important structural elements of commensurate superstructures of iodine on Pt(1 0 0) is stressed.     

Selective surface chemistry of allyl alcohol and allyl aldehyde on Si(1 0 0)2×1: Competition of [2 + 2] CC cycloaddition with O-H dissociation and with [2 + 2] CO cycloaddition in bifunctional molecules

Competition between the CC functional group with the OH group in allyl alcohol and with the CO group in allyl aldehyde in the adsorption and thermal chemistry on Si(1 0 0)2×1 has been studied by X-ray photoelectron spectroscopy (XPS) and temperature-programmed desorption (TPD), as well as density-functional theory (DFT) calculations. The similarities found in the C 1s and O 1s spectra for both molecules indicate that the O-H dissociation product for allyl alcohol and [2 + 2] CO cycloaddition product for allyl aldehyde are preferred over the corresponding [2 + 2] CC cycloaddition products. Temperature-dependent XPS and TPD studies further show that thermal evolution of these molecules gives rise to the formation of ethylene, acetylene, and propene on Si(1 0 0)2×1, with additional CO evolution only from allyl alcohol. The formation of these desorption products also supports that the [2 + 2] CC cycloaddition reaction does not occur. In addition, the formation of SiC at 1090 K is observed for both allyl alcohol and allyl aldehyde. We propose plausible surface-mediated reaction pathways for the formation of these thermal evolution products. The present work illustrates the crucial role of the Si(1 0 0)2×1 surface in selective reactions of the Si dimers with the O−H group in allyl alcohol and with the CO group in allyl aldehyde over the CC functional group common to both molecules.     

Wetting transition on grain boundaries in Al contacting with a Sn-rich melt

The contact angle at the intersection of a grain boundary in Al bicrystals with the solid Al/liquid Al–Sn interphase boundary has been measured for two symmetric tilt <011> {001} grain boundaries with tilt angles of 32° and 38.5°. The temperature dependencies (T) present the evidence of the grain boundary wetting phase transition at T_w. The observed hysteresis is consistent with the assumption that the wetting transition is of first order. The determined discontinuity in the temperature derivative of the grain boundary energy is–5.6 J/m²K (T w1=617°C) for the boundary with a low energy (=38.5°) and –17 J/m²K (T w2=604°C) for the grain boundary with a high energy (=32°).     

Density functional theory study of the near edge X-ray absorption fine structure and infrared spectroscopy of acetylene and benzene on group IV semiconductor surfaces

The near edge X-ray absorption fine structure and infrared spectroscopy of acetylene and benzene adsorbed on C(1 0 0)-2 × 1, Si(1 0 0)-2 × 1 and Ge(1 0 0)-2 × 1 surfaces is studied with density functional theory calculations. Time dependent density functional theory calculations of the near edge X-ray absorption fine structure with a modified exchange-correlation functional agree well with experiment, and show that the spectral features arise from excitation to π^∗, and orbitals, where X represents C, Si or Ge. The excitation energies are dependent on the surface, and for acetylene, the location of the π^∗ band also varies with the surface. Calculations of the vibrational modes show the CH stretching frequencies for carbon atoms bonded directly to the surface vary significantly between the three surfaces, while those for carbon atoms not bonded to the surface do not change significantly.     

Quantum‐Chemical Investigation of Hydrogen Bonds in Porphin

Using the DFT Becke–Lee–Yang–Parr exchangecorrelation threeparametric functional (B3LYP), we have calculated the geometry, the electron density distribution, and the vibration frequencies for pyrrole, porphin, and their 13 analogs with a regularly varying structure. It is shown that the determining role in the change in the frequencies of stretching and outofplane deformation vibrations of porphin compared to pyrrole is played by intramolecular hydrogen bonds at the porphyrin macroring center. We have separately considered and compared with the data for porphin complexes of pyrrole with different intermolecular hydrogen bonds: with an aromatic ring (NH··· cluster formed by the pyrrole selfaggregation in the liquid state) and an unshared electron pair (NH···OH₂ and NH···NC₄H₄ clusters). The degree of participation of the NH group in the hydrogen bonds increases in the series NH··· cluster, porphin, NH···OH₂ and NH···NC₄H₄ clusters.     

Effect of low-voltage spark discharge parameters on the spectral line intensities of sulfur and halogens

The influence of various circuit parameters on the spectral line intensities of sulfur and the halogens when excited in a low-voltage spark discharge have been investigated. The intensities were maximum for a discharge current of 6–8 A and a 1.0–1.5 mm spark gap. In ac spark discharges the maximum intensities occurred with capacitances of 20–50F and an inductance of 15H for primary circuit resistance of 200 ohm, and with 50–100F and 30–60H for 400 ohm. The intensities attained with dc sparks were higher than those with ac sparks. The intensity increased if the specimen served as the cathode and, in this case, occurred with capacitances of 100–800F and inductances of 30–60H for an ignition frequency of 12 sec^–1.     

Photoemission study of the Li/Ge(1 1 1)-3 × 1 reconstruction

In this article we report our findings on the electronic structure of the Li induced Ge(1 1 1)-3 × 1 reconstruction as determined by angle-resolved ultraviolet photoelectron spectroscopy (ARUPS) and core-level spectroscopy using synchrotron radiation. The results are compared to the theoretical honeycomb-chain-channel (HCC) model for the 3 × 1 reconstruction as calculated using density functional theory (DFT). ARUPS measurements were performed in both the and directions of the 1 × 1 surface Brillouin zone at photon energies of 17 and 21.2 eV. Three surface related states were observed in the direction. In the direction, at least two surface states were seen. The calculated band structure using the single-domain HCC model for Li/Ge(1 1 1)-3 × 1 was in good agreement with experiment, allowing for the determination of the origin of the experimentally observed surface states. In the Ge 3d core-level spectra, two surface related components were identified, both at lower binding energy with respect to the Ge 3d bulk peak. Our DFT calculations of the surface core-level shifts were found to be in fair agreement with the experimental results. Finally, in contrast to the Li/Si(1 1 1)-3 × 1 case, no double bond between Ge atoms in the top layer was found.     

The second hyperpolarizability of CdTe nanocrystals using polarization-resolved degenerate four-wave mixing

Polarization-resolved forward degenerate four-wave mixing (DFWM) in a nonresonant region revealed the effective third-order nonlinear susceptibility of colloidal CdTe nanocrystals (NCs) with the size near the Bohr radius and various concentrations. The second hyperpolarizabilities, and , of the CdTe NCs were ∼1.15 × 10⁻⁴¹ m⁵/V² and ∼3.01 × 10⁻⁴² m⁵/V² from the measurement of the concentration-dependent third-order nonlinear susceptibility of CdTe NCs, respectively. The ratio (/) of the hyperpolarizabilities was ∼0.26, which indicated a large contribution of an electronic polarization process to the third-order nonlinearity of CdTe NCs.     

A novel deposition method to grow ZnO nanorods: Spray pyrolysis

ZnO layers were deposited by chemical spray pyrolysis (CSP) using zinc chloride aqueous solutions onto indium tin oxide (ITO) glass substrates at growth temperatures in the region of 400–580 C. The layers were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and low-temperature () photoluminescence (PL) measurements. The flat film of ZnO obtained at 400 C evolves to a structured layer by raising the temperature up to 500 C. Deposition around 550 C and above results in a layer comprising well-shaped hexagonal ZnO nanorods with diameter of 100–150 nm and length of up to 1 micron. XRD shows strong c-axis orientation of ZnO being in accordance with the SEM study. Deposition of nanorods was successful using ITO with grain size around 100 nm, whereas on fine-grained ITO (grain size < 50 nm) with smooth surface fat crystals with diameter up to 400 nm and length of about 300 nm were formed. Sharp near band edge (NBE) emission peaks centered at 3.360 and 3.356 eV dominated the PL spectra of ZnO at , originating from the exciton transition bound to neutral donors. PL and XRD results suggest that ZnO rods prepared by spray pyrolysis are of high optical and crystalline quality.     

Gas formation in liquid in initial stages of a pulsed discharge

Gas formation in electrolytes with=10^–2–10^–4–1cm^–1, distilled water = 10^–5-1.5 ·10^{–6 –1}cm^–1, and chemically pure n-hexane in the initial stages of formation of discharge with rectangular voltage pulses of 0.67 and 1.85 sec duration is investigated. The experimental results are compared with the results of approximate calculations.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 11, pp. 42–47, November, 1972.The authors thank V. V. Ryumin for taking part in the discussion of the results and V. V. Lopatin for participation in the experiments with electron-optical light amplifier.     

Reaction of cyanide ions with copper on Si surfaces and its use for Si cleaning

A Si cleaning method has been developed by use of potassium cyanide (KCN) dissolved in methanol. When silicon dioxide (SiO₂)/Si(1 0 0) specimens with 10¹⁴ atom/cm² order copper (Cu) contaminants are immersed in 0.1 M KCN solutions of methanol at 25 °C, the Cu concentration is reduced to below the detection limit of total X-ray fluorescence spectrometer of ∼3 × 10⁹ atoms/cm². X-ray photoelectron spectra show that the thickness of the SiO₂ layers is unchanged after cleaning with the KCN solutions. 10¹⁴ cm⁻² order Cu contaminants on the Si surface can also be removed below ∼3 × 10⁹ atoms/cm², without causing contamination by potassium ions. UV spectra show that Cu-cyano complex ions are formed in the KCN solutions after the cleaning. The main Cu species in the KCN solutions is ions with the concentration of []:[Cu⁺] = 1:1.6 × 10²³. Even when the KCN solutions are contaminated with 64 ppm Cu²⁺ ions in the solutions, which form ions, the cleaning ability does not decrease, showing that ions are not re-adsorbed. The KCN solutions can also passivate defect states such as Si/SiO₂ interface states, leading to the improvement of characteristics of Si devices.