EPR spectra of NaCl:V2+ and KCl:V2+ above room temperature

Measurements above 300 K of the temperature variation of EPR spectra in NaCl and KCl, doped with divalent vanadium, are analysed. A new isotropic spectrum in KCl:V²⁺, which appears above 500 K, due to vanadium in cubic surroundings, is reported.     

EPR of V2+ in SrCl2

The X-band EPR spectrum of SrCl₂:V has been measured at liquid nitrogen temperature. A signal associated with V²⁺ in a site of trigonal symmetry is observed. The EPR data have been explained using the spin hamiltonian $\textcolor{red}{}\text{= μ}{}_{\mathrm{\beta }}\text{H}\text{g}\text{?}\text{S}\text{+ D[S}{}^2{}_{\mathrm{z}}\text{?}\text{1}\text{3}\text{S(SH)] +}\text{S}\text{A}\text{?}\text{I}$, with D ? hv, g_∥ = 1.957 ± 0.004, g₆ = 1.954 ± 0.004, A_∥ = 230 ± 5 MHz, A₆ = 235 ± 5 MHz. This V²⁺ defect is similar to those previously reported in fluoride crystals with the fluorite structure.     

Λ0 hyperon polarization in inclusive production by 24 GeV protons on platinum

We report a search for Λ⁰ polarization in inclusive production by 24 GeV protons on platinum made on data taken at CERN. These data show Λ⁰ polarization of the same direction and magnitude and with the same p_T dependence as found at 300 GeV at Fermilab.     

Nuclear acoustic resonance of V51 in a single crystal of V3Si above and below the martensitic transformation

The EFG and the Knight shift anisotropy of V⁵¹ in a single crystal of V³Si have been measured both above and below the martensitic transformation temperature T_m, using the nuclear acoustic resonance technique. Deviations of the axial symmetry of the EFG tensor have been found below T_m. The orientation of the tetragonal c axis in the crystal is also given.     

Spin and lifetime of the ω− hyperon

A total of 101 ω^? decays have been found in K^?p interactions at 10 and $\text{16 GeV}\text{c}$. The decay angular distribution has been fitted under the assumptions that the ω^? has spin either $\text{1}\text{2}\text{or}\text{3}\text{2}$. It has been found that the probability of isotropy (spin$\text{1}\text{2}\text{)}$ is less than one in a thousand, whereas the probability for spin $\text{3}\text{2}$ is about 70%. Thus, we exclude the spin $\text{1}\text{2}$ assignment. The lifetime of the ω^? is found to be (1.41_?0.24^+0.15) × 10^?10s, in agreement with our earlier result based on about $\text{1}\text{5}$ of the present sample.     

V4+ in SrTiO3: A Jahn-Teller impurity

EPR results of V⁴⁺, with $\text{S =}\text{1}\text{2}$, in SrTiO₃ are reported. The tetragonal local symmetry of the impurity ion is related to strong T_2g × ?_g coupling as evidenced by intensity variations in the presence of stress. At 4.2 K the V⁴⁺ EPR behaviour is related to the intrinsic local strain in SrTiO₃.     

Absolute frequency measurements of the 0002-0000, 2001-0000, and 1201-0000 bands of N2O by heterodyne spectroscopy

The absolute frequencies of 39 lines in the 00⁰2-00⁰0, 20⁰1-00⁰0, and 12⁰1-00⁰0 bands of N₂O in the range 4300–4800 cm^?1 have been measured by heterodyne frequency techniques. The lines were each measured in Doppler-limited absorption, with a color-center laser as a tunable probe of the N₂O and two stabilized CO₂ lasers as reference frequencies. New rovibrational constants have been fitted to these measurements. Tables of calculated transition frequencies are given, with estimated absolute uncertainties as small as 10^?4 cm^?1. The pressure shifts of four lines have been measured, and the values fall within the range of 0 to ?2 MHz/kPa (0 to ?0.2 MHz/Torr).     

V+注入锐钛矿TiO2第一性原理研究

用金属离子注入方法在锐钛矿TiO₂薄膜中掺杂了V⁺，采用全势线性缀加平面波方法计算了锐钛矿TiO₂及V⁺掺杂TiO₂超原胞的电子结构，通过紫外-可见吸收光谱测试方法检测了注入不同剂量的V⁺对TiO₂薄膜吸收光谱的影响.理论计算和实验结果表明，锐钛矿TiO₂薄注入V⁺后，带隙宽度变小，吸收光谱发生红移，并且TiO 关键词： +注入')" href="#">V⁺注入 2')" href="#">TiO₂ 全势线性缀加平面波方法 能带结构     

Resonant cross-relaxation between Cr3+ and V3+ in Al2O3

Cross-relaxation, which occurs when a V³⁺ transition is resonant with a monitored Cr³⁺ transition, leads to a marked reduction of the spin-lattice relaxation time of Cr³⁺ in Al₂O₃. Measurements and an analysis of the temperature dependence of this effect give a value of 8.34 ± 0.49 cm^?1 for the zero-field splitting of V³⁺, an ion which is strongly coupled to the lattice.     

Vibronic laser action of V2+:CsCaF3

CW laser operation has been achieved with the vibronic solid-state material V²⁺:CsCaF₃ at 80 K. The laser is tunable between 1.24 and 1.33 μm with a potential long wavelength extension.     

K0πand K*0Σ+ photoproduction off the proton

The exclusive reactions γp → K ^*0Σ⁺(1189) and γp → K ⁰π⁰Σ⁺(1189) , leading to the p 4π⁰ final state, have been measured with a tagged photon beam for incident energies from threshold up to 2.5GeV. The experiment has been performed at the tagged photon facility of the ELSA accelerator (Bonn). The Crystal Barrel and TAPS detectors were combined to a photon detector system of almost 4π geometrical acceptance. Differential and total cross-sections are reported. At energies close to the threshold, a flat angular distribution has been observed for the reaction γp → K ⁰π⁰Σ⁺ suggesting dominant s -channel production. Σ^*(1385) and higher-lying hyperon states have been observed. An enhancement in the forward direction in the angular distributions of the reaction γp → K ^*0Σ⁺ indicates a t -channel exchange contribution to the reaction mechanism. The experimental data are in reasonable agreement with recent theoretical predictions.     

V2控制Buck变换器等效建模与分岔分析

通过对V²控制Buck变换器电路进行降阶处理, 利用不同工作模式, 推导了两个边界电压, 建立了V²控制Buck变换器的等效一阶同步映射迭代模型, 研究了它的非线性分岔行为. 通过稳定性和工作模式分析, 推导了V²控制Buck变换器从稳定的周期1工作状态到次谐波振 荡状态转移以及从电感电流不连续导电模式 (DCM) 到连续导电模式 (CCM) 转移的条件. 研究结果表明, 当电路参数变化时, V²控制Buck 变换器发生了倍周期分岔和边界碰撞分岔, 不同的参数变化有着不同的分岔路由. 搭建了仿真和实验电路, 仿真和实验结果验证了等效迭代模型的有效性和理论分析的正确性. 关键词： 2控制')" href="#">V²控制 迭代模型 分岔 工作模式     

氨分子在000和201带的选择光离解

本文利用脉冲紫外激光(UV)选择激发氨分子到?¹A″₂电子激发态的两个最低振动能级ν′₂=0和ν′₂=1(ν₂振动),然后检测新生态H原子的飞行谱(TOF),研究了氨分子的光碎片动力学。光谱证实了最近所测的离解能D₀⁰(H-NH₂)=4.645eV;绝大多数生成的NH₂(X²B₁)基处于非振动激发,但是具有围绕a惯性轴的高度转动激发。通过NH₃(?)的ν′₂=1光离解产生的NH₂(X)基具有较高的内部激发,并且显示了在N=K_a转动能级上的反转布居。 关键词：     

Al~(3+)/Mo~(6+)双离子取代ZrV_2O_7中Zr~(4+)/V~(5+)实现近零膨胀

采用固相烧结法制备了Zri_(1-x)Al_(2-x)V_(2-x)Mo_xO_7(0≤x≤0.9),并通过调整Al~(3+)/Mo~(6+)对ZrV_2O_7中的Zr~(4+)/V~(5+)离子替代量来实现近零膨胀,对于较小的x值(x≤0.3),材料保持了与ZrV_2O_7相同的立方相结构.随着Al~(3+)/Mo~(6+)替代量的增加,(Al/Zr)~-和(Mo/V)~+之间的库仑相互作用逐渐加强,这种库仑相互作用导致材料中未发生畸变的立方相晶体结构逐渐减少.当x≥0.7时,材料中立方相晶体结构完全消失.在425-750 K温度区间内,Zr_(0.5)Al_(0.5)M_(0.6)O_7展示出近零膨胀性质(-0.39×l0~(-6)K~(-1)).Zr_(0.5)Al_(1.5)V_(1.5)Mo_(0.5)O_7的低热膨胀性能可能与Al~(3+)/Mo~(6+)对ZrV_2O_7中Zr~(4+)/V~(5+)部分替代引起部分晶体结构发生的畸变及其对未替代部分的晶格结构的影响有关.     

Correlations of high transverse momentum π0 pairs produced at the CERN ISR

Correlations of two π⁰ mesons with transverse momenta up to 10 GeV/c have been measured utilizing apparatus with large azimuthal acceptance. The data are analysed in the context of constituent scattering models, and also compared with a simple “back-ground” hypothesis.     

The vibration-rotation spectrum of D12CP in the region of the ν2 band: The spectroscopic constants for the states 0000, 0110, 0200, and 0220 and the bond lengths of the molecule

The vibration-rotation spectrum of DCP has been recorded with a resolution of 0.004 cm^?1 in the spectral region extending from 575 to 475 cm^?1. The fundamental band ν₂ and the “hot” bands from the vibrational level (01¹0) to the levels (02⁰0) and (02²0) have been identified and analyzed. A total of 347 infrared transitions have been measured and their wavenumbers together with 13 microwave or millimeter-wave frequencies have been fit simultaneously to obtain 15 spectroscopic constants including those arising from l-type doubling and l-type resonance. The agreement between the calculated and measured wavenumbers of nonblended lines is usually within 1 × 10^?4 cm^?1. These constants, used in conjunction with the ones previously obtained for the molecule, allow the calculation of the anharmonicity constants x₂₂ and g₂₂ and of the second-order vibration-rotation interaction constants γ₂₂ and γ₁₁. Although many of the γ's are still missing because an insufficient number of bands have been analyzed, the equilibrium bond lengths for the molecule have been recalculated using the improved set of first-order vibration-rotation interaction constants: r_e(CH) = 1.06596(11)Å and r_e(CP) = 1.540452(18)Å.     

Inclusive V0 production in pp interactions at 12 GeV/c

Results are presented on the inclusive reactions $\text{p}\text{p}\text{→}\text{K}{}^0\text{X}\text{,}\text{p}\text{p}\text{→ Λ}\text{X and}\text{p}\text{p}\text{→}\text{Λ}\text{X}$ at an incident antiproton momentum of 12 GeV/c in BEBC. The cross sections are studied as functions of the Feynman scaling variable x, the rapidity, the transverse momentum of the V⁰ and the missing mass squared. The dependence of the Λ and $\text{Λ}$ polarization on x are also studied. Comparisons with proton-proton data at 12 GeV/c are also made. Finally, events with two detected V⁰ are analyzed in order to study correlations arising from the production of two strange neutral particles.     

Theoretical investigations of the local distortion and electron paramagnetic resonance parameter for CdCl2：V^2＋ and CsMgX3：V^2＋（X=Cl,Br） systems

This paper systematically investigates the local distortion and electron paramagnetic resonance (EPR) parameter for CdCl 2 :V 2+ and CsMgX 3 :V 2+ (X=Cl, Br) systems on the basis of the complete energy matrix, in which not only the contributions due to the spin–orbit coupling of the central ions but also that of the ligands are considered. To describe the difference of overlapping between d-orbits and p orbit, two spin–orbit coupling coefficients are introduced. By simulating the crystal field parameter and EPR parameter, the local distortion parameters are studied and the relationships between the EPR parameter and the spin–orbit coupling coefficients as well as divergent parameter are discussed. These results show that the local structures exhibit compression distortion for CdCl 2 :V 2+ and elongation distortions for CsMgX 3 :V 2+ (X=Cl, Br), respectively. It notes that the empirical formula R ≈ R H + (r i-r h )/2 is not suitable for CdCl 2 :V 2+ and CsMgX 3 :V 2+ (X=Cl, Br) systems. The contributions of ligand to spin–orbit coupling interaction cannot be neglected for strong covalent systems, especially for V 2+ doped in CsMgBr 3 :V 2+ .