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1.
The title complex of nickel (II) with 3,5-dimethylbenzoic acid, m-methylbenzoic acid and 1,10- phenanthroline was synthesized and characterized. Crystal data for this complex: triclinic, space group
P1, a=1.198 5(2) nm, b=1.315 3(2) nm, c=1.531 8(3) nm, α=92.602(3)°, β=103.292(3)°, γ=114.849(3)°, V=2.104 7(6)
nm3, Dc=1.361 g·cm-3, Z=2, F(000)=902, final GooF=1.071,
R1=0.067 2, wR2=0.155 5. The crystal structure shows that the nickel ion is coordinated with four nitrogen atoms of two 1,10-phenanthroline molecules and two oxygen atoms of one 3,5-dimethyl benzoic acid molecule, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex was also investigated. CCDC: 286966. 相似文献
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The title complex has been synthesized by using terephthalic acid (PTA), 1,10-phenanthroline (phen) and copper monohydrate. It crystallizes in monoclinic space group C2/c with a=2.959 0(2) nm, b=1.466 4(10) nm, c=1.764 3(12) nm, β=105.593(11)°, V=7.372(9)
nm3, Dc=1.489 g·cm-3, Z=8, F(000)=3 416, R1=0.043 6,
wR2= 0.151 9. The crystal structure shows that the copper atom is coordinated with four nitrogen atoms from two phens and one oxygen atom from one terephthalic acid, forming a distorted square-pyramid coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 277047. 相似文献
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The title complex has been synthesized with m-chlorobenzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous in the solvent mixture of water and methanol. Crystal data for this complex: triclinic, space group P1, a=0.870 7(3) nm, b=1.284 4(4) nm, c=1.692 9(5) nm; α=75.430(5)°, β=77.562(5)°, γ=86.346(5)°, V=1.789 4(9) nm3, Dc=1.456 g·cm-3, Z=2, F(000)=806. Final GooF=1.065, R1=0.068 4, wR2=0.127 5. The crystal stru-cture shows that the Cobaly ion is coordinated with four nitrogen atoms from two 1,10-phenanthroline molecules and two oxygen atoms from one m-chlorobenzoic acid molecule and one water molecule respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 619087. 相似文献
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One Complex{CdI(phen)(H2O)[C8H11O2(COO)]}·H2O with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid [C7H8(COOH)2], hydriodic acid and 1,10-phenanthroline(phen) has been synthesized by means of hydrothermal way and characterized. It crystallizes in the triclinic space group P1, with a=0.975 4(2) nm, b=0.990 0(2) nm, c=1.319 1(3) nm, α=89.146(4)°, β=69.800(3)°, γ=68.718(3)°, V=1.105 0(4) nm3, Dc=1.914 g·cm-3, Z=2, F(000)=620, Final R1=0.033 2, wR2=0.085 7, GooF=1.092. The crystal structure shows that the cadmium ion is coordinated with two oxygen atoms from one C7H10(COOH)2 molecule, two nitrogen atoms from the 1,10-phenanthroline, one oxygen atom from one water molecule and one iodine ion, respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 648242. 相似文献
7.
The complex has been synthesized and characterized by spectroscopic techniques and single-crystal X-ray analysis. The crystal is orthorhombic , space group P212121 with a=1.6620(3)nm, b=1.7300(4)nm, c=0.5450(1)nm and Z=4. In the crystal lattice, the molecules create a two-dimensional network structure through hydrogen bonds. The C-H…O intermolecular hydrogen bonds connect the title complex to form layer super-molecular plane structure perpendicular to the axis b, with the layers stacked by the Van der Waals interaction. CCDC: 195309. 相似文献
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The title complex has been synthesized by the reaction of silicotungstic acid, 1,10-phenanthroline (phen) monohydrate and cupric acetate. The crystal structure belongs to triclinic system, space group P1 with a=1.158 46(15) nm, b=1.658 8(2) nm, c=1.664 4(2) nm, α=82.090(2)°, β=76.001(2)°, γ=86.531(2)°, and V=3.072 6(7) nm3, Dc=3.887 g·cm-3, Z=2, F(000)=3 196. R1=0.086 7, wR2=0.185 8. The structure shows that the copper(Ⅱ) atom is coordinated with two nitrogen atoms from the one phen and three oxgygen atoms from three water, forming a distorted square-pyramid configuration The cyclic voltametric behavior of the complex is also reported. CCDC: 298807. 相似文献
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The crystal structure of the title complex with the stoichiometric formula [Cu(PTA)(Phen)2](p-MBA)(H6O) (Phen=1,10-phenanthroline, PTA=terephthalic acid, p-MBA=p-toluic acid) has been determined by single-crystal X-ray diffraction. The crystal (C48H40CuN4O10, Mr=896.38) belongs to the monoclinic space group C2/c, with the following crystallographic parameters: a=1.778 6(3) nm, b=1.912 5(3) nm, c=1.389 9(2) nm, β=114.686(2)°, V=4.295 7(12) nm3, Dc=1.386 g·cm-3, Z=4, μ(Mo Kα)=0.574 mm-1, F(000)=1 860, final GooF=1.019, R=0.054 0, wR=0.148 3 for 2 644 observed reflections (I>2σ(I)). The crystal structure shows that the copper(Ⅱ) ion is coordinated with two oxygen atoms from one terephthalic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 298809. 相似文献
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One dimensional chain nickel(Ⅱ) coordination polymer has been synthesized with 2,4,6-trimethylbenz-oic acid, 4,4′-bipyridine and nickel perchlorate anhydrous, and characterized in the solvent mixture of water and methyl-alcohol. Crystal data for this complex: monoclinic, space group C2/c, a=2.154 7(7) nm, b=1.131 9(2) nm, c=1.655 7(8) nm, β=129.66(3)°, V=3.108 7(19) nm3, Dc=1.370 g·cm-3, Z=4, F(000)=1 360, final GooF=1.042, R1=0.034 4, wR2=0.078 7. The crystal structure shows that the nickel ion is coordinated with two nitrogen atoms of two 4,4′-bipyridine molecules and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two water molecules, respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 649415. 相似文献
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A complex [Ni(α-furacrylic acid)2(4,4′-bipy)(H2O)5]n with α-furacrylic acid, 4,4′-bipy and Nickel perchl-orate has been synthesized by means of hydrothermal way and characterized. Crystal data for this complex: monoclinic, space group P21/c, a=1.122 2(2) nm, b=1.084 1(2) nm, c=1.081 6(2) nm, β=98.37(3)°, V=1.301 8(5) nm3, Dc=1.524 g·cm-3, Z=2, μ(Mo Kα)=0.813 mm-1, F(000)=624, S=1.073, R1=0.041 2, wR2=0.093 4. The crystal structure shows that the Nickel(Ⅱ) ion is coordinated with two nitrogen atoms of two 4,4′-bipy molecules and four oxygen atoms from four water molecules, respectively, giving a distorted octahedral coordination geometry. Adjacent Nickel(Ⅱ) ion are bridged by 4,4′-bipy groups and the adjacent Ni(Ⅱ)…Ni(Ⅱ) distance is 1.122 2 nm. The Nickel(Ⅱ) ion isn′t coordinated with α-furacrylic acid .The complex molecules form 2D structure through hydrogen bonds. The cyclic voltametric behavior of the complex was also investigated. CCDC: 658849. 相似文献
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配合物Cu(3,5-DMBA)2(phen)的合成、晶体结构及电化学性质 总被引:2,自引:0,他引:2
A copper(Ⅱ) complex Cu(3,5-DMBA)2(phen) has been synthesized by self-assembly of 3,5-dimethylbenzoic acid, 1,10-phenanthroline and copper perchlorate. Crystal data for this complex: Monoclinic, space group C2/c with a=2.348 3(5) nm, b=0.984 4(2) nm, c=1.138 4(2) nm, β=103.02(3)°, V=2.563 9(9) nm3, Dc=1.404 g·cm-3, Z=4, F(000)=1 124, final GooF=1.051, R1=0.035 0, wR2=0.099 8. The crystal structure shows that the copper atom is coordinated with two oxygen atoms from two 3,5-dimethylbenzoic acids and two nitrogen atoms from the 1,10-phenanthroline, forming a square-planar structure. The result of the cyclic voltametric behavior analysis shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 650387. 相似文献
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The title complex has been synthesized by o-acetamidobenzoic acid and 2,2′-bipyridine(bipy) in the mixture solvent of water and methanol. It crystallizes(C28H26CuN4O7, Mr=594.07) in Triclinic space group P1 with a=0.805 3(4) nm, b=0.845 5(4) nm, c=2.001 8(9) nm; α=100.797(8)°, β=93.054(7)°, γ=97.297(7)°, V=1.323 9(10) nm3, Dc=1.490 g·cm-3, Z=2, F(000)=614. R1=0.035 9, wR2=0.080 5. The crystal structure shows that the copper atom is coordinated with four oxygen atoms from two o-acetamidobenzoic acid and two nitrogen atoms from the 2,2′-bipyridine, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 619084. 相似文献
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A copper(Ⅱ) complex [Cu2(m-MBA)4(2,2′-bipy)2(H2O)]·H2O with m-methylbenzoic acid (m-MBA), 2,2′-bipyridine (2,2′-bipy) and water molecule has been synthesized by means of hydrothermal way and characterized. Crystal data for this complex: monoclinic, space group C2/c, a=2.591 8(5) nm, b=1.414 2(3) nm, c=1.790 8(4) nm, β=131.80(3)°, V=4.893 3(17) nm3, Dc=1.379 g·cm-3, Z=4, F(000)=2 104 , Final GooF=1.034, R1=0.065 6, wR2=0.197 6. The crystal structure shows that two neighboring copper(Ⅱ) ions are linked together by two bridging-chelating m-methylbenzoic acid groups, one bridging water molecule, forming a cage structure and the Cu(Ⅱ)-Cu(Ⅱ) bond distance is 0.366 7 nm. Each copper(Ⅱ) ion is coordinated with two nitrogen atoms of one 2,2′-bipyridine molecule and four oxygen atoms from three m-methylbenzoic acid molecules and one water molecule, repectiveley, forming a distorted octahedral coordination geometry. The cyclic voltammetric behavior of the Complex was also investigated. CCDC: 648619. 相似文献
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A novel copper(II) complex [Cu(NPA)2(Im)2(H2O)]·H2O has been synthesized (NPA=N-phenylanthranilic acid and Im=imidazole) and characterized by IR, elemental analysis and X-ray single crystal diffraction methods. It Crystallizes in Triclinic system, space group P1 with a=0.987 9(2) nm, b=1.075 7(3) nm, c=1.559 7(5) nm, α=104.18(10)°, β=108.14(10)°, γ=92.69(10)°, V=1.513 39(7) nm3, Z=2, Dc=1.447 g·cm-3, F(000)=684, R1=0.028 0, wR=0.083 1. The Cu(II) ion in the title complex is coordinated with two oxygen atoms from two N-phenylanthranilic acid in monodenate mode, two nitrogen atoms form two imidazole, and one oxygen atom from water, forming a distorted square-pyramid coordination geometry. CCDC: 638653. 相似文献
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The new compound was prepared by the reaction of Cd(ClO4)2·6H2O,1,10-phenanthroline (phen)and picric acid (HPA)(ratio 1∶3∶2) in methanol-aqueous solution refluxing for 4 hours. The crystals used for X-ray analysis was obtained by slow evaporation of the solution at room temperature. The crystal compound is in triclinic with space group with a=1.1363(4)nm,b=1.2593(2)nm,c=1.3972(4)nm,α=93.97(2)?,β=100.84(3)?,γ=106.29(2)?,Z=2,V=1.8690(9)nm3,Dc=1.715g·cm-3, μ(MoKα)=0.677mm-1,F(000)=972,R=0.0907,wR=0.2240. In the complex, the Cd(Ⅱ) cation is octahedrally coordinated to two 1,10-phenanthroline ligands and two water molecules in cis disposition. As outer sphere, picrate anions are combined with inner by hydrogen bond and static electricity interaction. 相似文献