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1.
A. D. Grebenyuk V. I. Vinogradova A. K. Tashmukhamedova 《Chemistry of Natural Compounds》2006,42(5):585-587
New derivatives of dibenzo-24-crown-8-dicarboxylic acid diamide with salsoline, salsolidine, and anabasine moieties were prepared
by condensation of the alkaloids with 4′,4″(5″)-dibenzo-24-crown-8-dicarboxylic acid dichloride.
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Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 471–473, September–October, 2006. 相似文献
2.
Vadim A. Pestunovich Nataliya F. Lazareva Alexander I. Albanov 《Monatshefte für Chemie / Chemical Monthly》2006,137(8):1005-1013
Summary. The first representative of the N-silylmethylamides of phosphoric acid O=P[NMe(CH2SiMe
n
(OEt)3-n
]3 have been synthesized by interaction of MeNHCH2SiMe
n
(OEt)3-n
(n = 2, 3) with POCl3. The interaction of the N,N′,N″-trimethyl-N,N′,N″-tris[(ethoxydimethyl- silyl)methyl]triamide phosphoric acid with BF3·Et2O or BCl3 results in the formation of the N,N′,N″-trimethyl-N,N′,N″-tris[(fluorodimethyl-silyl)methyl]triamide phosphoric acid or N,N′,N″-trimethyl-N,N′,N″-tris[(chlorodimethylsilyl)methyl]triamide phosphoric acid. NMR data show on the tetracoordinate state of silicon in these
products.
Professor Vadim Aleksandrovich Pestunovich, our chief, teacher and friend died on July 4th, 2004 相似文献
3.
T. V. Tyumkina I. F. Nuriev L. M. Khalilov V. R. Akhmetova U. M. Dzhemilev 《Chemistry of Natural Compounds》2009,45(1):61-65
The structure of a new compound was determined using PMR and 13C NMR spectroscopy (HHCOSY, HSBC, HMBC, ROESY) as 2-[3′-methoxy,4-O-β-D-galactopyranos-1-yl)benzyl]-3-(3″,4″-dimethoxybenzyl)-4hydroxybutyric acid, which was isolated for the first time from
seeds of Scotch thistle Onopordum acanthium L.
*For No. XII, see [1].
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 53–55, January–February, 2009. 相似文献
4.
D. N. Dybtsev I. E. Sokolov E. V. Peresypkina V. P. Fedin 《Russian Chemical Bulletin》2007,56(2):225-230
Two new scaffold-like metal-organic coordination polymers, [Zn2ndc2bpe]·DMF and [Zn2ndc2dedpbp] ·4DMF (ndc is 2,6-naphthalenedicarboxylate, bpe is trans-bis(4-pyridyl)ethylene, and dedpbp is 4,4′-diethynyl-4″,4′″-dipyridylbiphenyl), were synthesized by heating stoichiometric
amounts of zinc(II) nitrate, H2ndc, and bpe or dedpbp in DMF. The structures of the polymers were established by X-ray diffraction. Coordination of linear
dicarboxylate ligands to zinc cations gives rise to planar square-grid networks, and additional coordination of the bifunctional
nitrogen-containing ligands results in the formation of scaffold-like triply interpenetrating structures with a primitive
cubic topology.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 219–223, February, 2007. 相似文献
5.
A new chromone-substituted dihydrotriflavonol, (2S,3S)[6-{(3S) 3″,5″-dihydroxy-6″-methoxydihydrochromone}5,3′,4′,5′-tetrahydroxy-7-methoxy-3-O-8-dihydroflavone]2 3-O-8[6-{(3S) 3″,5″-dihydroxy-6″methoxydihydrochromone}3,5,3′,4′,5′-pentahydroxy-7-methoxydihydroflavonol] was isolated from the leaves
of Anogeissus pendula. The structure was determined by UV, 1H NMR, 13C NMR, HMBC, and CD data. 相似文献
6.
E. D. Khairitdinova E. M. Tsyrlina L. V. Spirikhin N. I. Fedorov M. S. Yunusov 《Chemistry of Natural Compounds》2005,41(5):575-577
The known alkaloids deltaline, methyllycaconitine, elasine, and the new norditerpene alkaloid alpinine were isolated from
the aerial part of Delphinium alpinum. The structure of the last was proposed as 1α,6β, 16β-trimethoxy-7-hydroxy-8-ethoxy-14α-propionyloxy-4β-(2″-methyl)succinylanthranoyloxymethyl-N-ethylaconitane
on the basis of PMR, 13C NMR, IR, and mass spectra.
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Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 469–471, September–October, 2005. 相似文献
7.
D. V. Kuznetsov S. A. Andreev A. K. Tashmukhamedova 《Chemistry of Natural Compounds》2006,42(5):515-516
Diazonium salts were prepared by diazotization of 4′-amino-, 4′,4″-, and 4′,5″-diaminodibenzo-18-crown-6. Their coupling products
with kojic acid (5-hydroxy-2-hydroxymethyl-γ-pyrone) were synthesized for the first time: 4′-(6-aza-5-hydroxy-2-hydroxymethyl-γ-pyronyl)-, 4′,4″-di-(6-aza-5-hydroxy-2-hydroxymethyl-γ-pyronyl)-, and 4′,5″-di-(6-aza-5-hydroxy-2-hydroxymethyl-γ-pyronyl)-dibenzo-18-crown-6.
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Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 415–416, September–October, 2006. 相似文献
8.
Seon-Mi Seo Hak-Ju Lee Oh-Kyu Lee Hyun-Jin Jo Ha-Young Kang Don-Ha Choi Ki-Hyon Paik M. Khan 《Chemistry of Natural Compounds》2008,44(4):419-423
A new furofuran lignan (1) along with four knownones (2-5) were isolated from the bark of Magnolia kobus. Their structures were elucidated as (+)-2α-(3’,4’-dimethoxyphenyl)-6α-(3″-hydroxy-4″,5″-dimethoxyphenyl)-3,7-dioxabicyclo[3.3.0]octane
(1), (+)-sesamin (2), (+)-yangambin (3), (+)-kobusin (4), and (+)-eudesmin (5) on the basis of their comprehensive spectroscopic analysis, including 2D NMR, and by comparison of their spectral data with
those of related compounds.
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 338–341, July–August, 2008. 相似文献
9.
4′,4″(5″)-(Dibenzo-18-crown-6)diarylacetohydroxamic acids were obtained by the reaction of DB18C-6 with β-nitrostyrenes under
the influence of polyphosphoric acid.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 838–840, June, 2006. 相似文献
10.
Euchrenone a2 (7) isolated from the roots ofEuchresta japonica has been synthesised from 3-prenylphloroacetophenone (1) by other workers. We carried out its cyclodehydrogenation with dichloro dicyano quinone (DDQ) to obtain 6-acetyl-5,7-dihydroxy-2,2-dimethylchromene
(2) which was ethoxymethylated in the 7-position to give 6-acetyl-7-ethoxymethoxy-5-hydroxychromene (3). Chalcone condensation of3 and 4-ethoxymethoxy-3-C-prenylbenzaldehyde (4) gave 4,6′-bisethoxymethoxy-2′-hydroxy-6″, 6″-dimethyl-3-C-prenylpyrano (2″, 3″–4,3) chalcone (5) which cyclised with methanolic sodium acetate to give protected 5,4′-bisethoxymethoxy-6″, 6″-dimethyl-3′-C-prenylpyrano (2″, 3″–7,8) flavanone (6). Deprotection of6 with 4% methanolic HCl yielded (7) with melting point and spectral data identical to that of the natural compound. 相似文献
11.
D. N. Olennikov A. V. Stolbikova A. V. Rokhin V. B. Khobrakova 《Chemistry of Natural Compounds》2011,47(2):190-193
The homogeneous polysaccharide S
b
RP-1″ with MW 110 kDa was isolated during an investigation of water-soluble polysaccharides from Scutellaria baicalensis roots.
Its aqueous solution gave a positive reaction with iodine and exhibited high specific rotation ([α]D +188.0°). Chemical, chromatographic, and spectral methods established that S
b
RP-1″ was a slightly branched glucan containing in the main chain α-(1 → 4)-glucopyranose units, 8.3% of which were branched
at the C-6 atom with single α-glucopyranose units. Glucan S
b
RP-1″ was shown to exhibit immunostimulating activity using an azathioprine model of immunosuppression. 相似文献
12.
V. I. Zhuravlev N. V. Lifanova T. M. Usacheva E. P. Vydrina 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2008,82(4):675-676
The results of experimental studies of the dielectric properties of 2,3-butanediol are reported. Static dielectric constant
ɛs was measured at 1 MHz; dielectric constant ɛ′ and dielectric loss ɛ″ were determined by the balance method over the frequency
range 2–37.5 GHz and the temperature range 293–423 K.
Original Russian Text ? V.I. Zhuravlev, N.V. Lifanova, T.M. Usacheva, E.P. Vydrina, 2008, published in Zhurnal Fizicheskoi
Khimii, 2008, Vol. 82, No. 4, pp. 780–781. 相似文献
13.
N. J. Sayfullina A. K. Tashmukhamedova Kh. M. Shakhidoyatov 《Chemistry of Heterocyclic Compounds》2007,43(3):282-285
During the reaction of the amides of benzo-and dibenzocrown thiocarboxylic acids with methyl iodide in the presence of potassium
hydroxide they exhibit anomalous behavior leading to the nitriles of benzo-and dibenzocrown carboxylic acids. The nitriles
of benzo-15-crown-5-, benzo-12-crown-4-, and dibenzo-18-crown-6-4′-carboxylic acids and the dinitriles of dibenzo-18-crown-6-and
dibenzo-24-8-4′,4″(5″)-dicarboxylic acids were obtained.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 357–360, March, 2007. 相似文献
14.
N. M. Kurochkina V. E. Baulin E. N. Pyatova I. S. Ivanova A. Yu. Tsivadze 《Russian Journal of Coordination Chemistry》2010,36(4):241-248
Sodium and potassium complexes with 4′-(4‴-benzo-15-crown-5)methyloxy-2,2′:6′,2″-terpyridine (L1) and 4′-(4′-benzo-15-crown-5)oxy-2,2′:6′,2″-terpyridine (L2) and heteronuclear Na, K, Ca, and transition metal complexes with L1 were synthesized. The structure of the complexes was proposed on the basis of elemental analysis data, IR spectra, and the
results of earlier X-ray diffraction studies of L2, [NaL1NCS], and [Na2{Cu(L1)2}(NCS)3]NCS · CH3CN. 相似文献
15.
The absorption spectra in dilute dichloromethane solution at 300 K of four Oligotiophenes (OT), namely 2,2′:5′,2″-Terthiophene,
2,2′:5′,2″:5″,2″′-Quaterthiophene, 4,4″′-Didodecyl-2,2′:5′,2″:5″,2″′-quaterthiophene and 5,5′′′′′-Dihexyl-2,2′:5′,2′′:5′′,2′′′:5′′′,2′′′′:5′′′′,2′′′′′-sexithiophene,
have been studied both experimentally and theoretically by using a combination of molecular dynamics simulations, time-dependent
density functional theory (TD-DFT) and perturbed matrix method calculations. A deep analysis of the theoretical results, affected
by a systematic although not dramatic underestimation of the absorption maxima due to the well-documented TD-DFT limitations,
clearly indicates that both the environmental (solvent) and thermal effects significantly alter the Oligotiophenes photophysical
properties mainly because of the wide repertoire of the S0–S1 energy gaps and electronic densities experienced in solution by the different conformers actually populated. In particular,
all the investigated OT display a very high flexibility resulting in a very high repertoire of sampled conformations. The
comparison of the calculated and experimental lineshape of the S0–S1 electronic transition has clearly indicated that for a correct modeling of OT spectral features, the lack of an exhaustive
sampling of semiclassical configurational space of the overall system, i.e., solute in interaction with the solvent, might
result in an incomplete picture even in the presence of well-documented important aspects such as reliable definition of excited
electronic states and the inclusion of quantum vibronic effects. 相似文献
16.
Vadim A. Pestunovich Nataliya F. Lazareva Alexander I. Albanov 《Monatshefte für Chemie / Chemical Monthly》2006,57(7):1005-1013
The first representative of the N-silylmethylamides of phosphoric acid O=P[NMe(CH2SiMe
n
(OEt)3-n
]3 have been synthesized by interaction of MeNHCH2SiMe
n
(OEt)3-n
(n = 2, 3) with POCl3. The interaction of the N,N′,N″-trimethyl-N,N′,N″-tris[(ethoxydimethyl- silyl)methyl]triamide phosphoric acid with BF3·Et2O or BCl3 results in the formation of the N,N′,N″-trimethyl-N,N′,N″-tris[(fluorodimethyl-silyl)methyl]triamide phosphoric acid or N,N′,N″-trimethyl-N,N′,N″-tris[(chlorodimethylsilyl)methyl]triamide phosphoric acid. NMR data show on the tetracoordinate state of silicon in these
products. 相似文献
17.
N. M. Logacheva V. E. Baulin E. N. Pyatova I. S. Ivanova A. Yu. Tsivadze 《Russian Journal of Coordination Chemistry》2009,35(9):648-656
Complexes of Co(II), Ni(II), Zn(II), and Cu(II) perchlorates and hexafluorophosphates with 4′-(4″-benzo-15-crown-5)oxy-2,2′:6′,2″-terpyridine
(L) [M(L)2](ClO4)2 · 3H2O and [M(L)2](PF6)2 · 2H2O were synthesized. The spectral criteria of ligand coordination through the terpyridine nitrogen atoms were established.
An assumption concerning the benzo-15-crown-5 conformation in the ligand molecule in the synthesized complexes was made. The
extraction and ion-selective properties of L were studied. 相似文献
18.
M. S. Yunusov E. M. Tsyrlina E. D. Khairitdinova L. V. Spirikhin A. Yu. Kovalevsky M. Yu. Antipin 《Russian Chemical Bulletin》2000,49(9):1629-1633
A new alkaloid, anhydrolycaconitine (C36H46N2O9), was isolated from roots ofAconitum septentrionale K. Based on the results of1H and13C NMR and IR spectroscopy and mass spectrometry of the alkaloid and the product of its alkaline hydrolysis and on the data
of X-ray diffraction analysis of the hydrolysis product, the structure of 1α, 6β, 14α, 16β-tetramethoxy-7-oxo-18-succinylanthranoyloxy-17-(7→8)abeo-aconane was assigned to anhydrolycaconitine.
Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1640–1644, September, 2000. 相似文献
19.
The succinic acid 12α-deoxoartemisinyl ester 4′-O-demethyl-4-β-(4″-nitroanilino)-4-desoxypodophyllotoxin was synthesized for the first time.
Published in Khimiya Prirodnykh Soedinenii, No. 5, pp. 442–443, September–October, 2007. 相似文献
20.
I. V. Nechepurenko M. P. Polovinka N. I. Komarova D. V. Korchagina N. F. Salakhutdinov S. B. Nechepurenko 《Chemistry of Natural Compounds》2008,44(1):31-34
Isoflavonoids (−)-medicarpin, (−)-vestitol, formononetin, 8-hydroxydaidzein, and 6″-O-acetylononin were isolated for the first time in addition to (−)-catechin, (−)-epicatechin, protocatechoic acid, raspberry
ketone, and rhododendrol from the alcohol extract of Hedysarum theinum roots.
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Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 26–28, January–February, 2008. 相似文献