固体中半整数四极核的自旋扩散

首先介绍固态中自旋扩散的一般理论，包括半经典描述和建立在投影算子理论上的密度矩阵描述. 接着以丰核环境中相互偶合的自旋-1/2系统以及自旋-3/2系统为典型列举了自旋扩散速率的计算. 最近藉助多量子魔角旋转(MQMAS)方法实现半整数四极核的多量子谱自旋扩散实验，可以测量固体粉末中半整数四极核体系四极张量相对方向. 结合作者最近的计算机模拟和实验测量结果对这一新兴方向作了重点介绍，尤其指出了射频
脉冲强度、宽度及样品旋转速度对交叉峰线型的影响.     

当能级间隔较小时三能级核四极共振自旋系统对脉冲的响应

用虚拟自旋-1/2算符理论考察了I=1的核四极共振自旋系统在其能级间隔较小时对1-2个脉冲的响应.由于核四极相互作用表象中的射频场与核自旋的相互作用(H_rf)包含时间,因而用Dyson时序算符来计算密度算符在H_rf作用下的演化.     

14N核四极共振中自旋锁定的偏共振效应

用虚拟自旋-1/2算符理论计算了核四极共振自旋系统在自旋锁定脉冲序列作用下的时间演化,获得了自旋锁定信号随锁定脉冲长度和射频频率偏置的变化关系。如果不考虑准备脉冲期间射频频率偏置的影响,那么可简单地用核磁共振中的矢量模型来解释自旋锁定这一现象。 关键词：     

14N核四极共振自旋系统自旋-晶格弛豫时间的测量

¹⁴N核四极共振自旋系统的自旋-晶格弛豫是一种双指数弛豫。本文介绍了¹⁴N核四极共振自旋系统的自旋-晶格弛豫时间的3种测量方法,利用可变多面体方法对实验数据进行拟合,获得了¹⁴N核四极共振自旋系统的自旋-晶格弛豫时间T_1s和T₁₁,对有关文献中关于核四极共振弛豫时间的测量的3个观点提出了质疑。     

自旋置换对称体系多脉冲及二维核磁共振实验的密度算符描述(Ⅱ)——多量子积算符方法

在对称化乘积算符(简称SAPO)方法基础上提出了多量子积算符(简称MQCPO)方法。改进的密度算符理论对I_nS(I=1/2,S=1/2;n为任意正整数)自旋体系多脉冲及二维核磁共振实验的描述普遍适用。MQCPO与SAPO从不同角度反映了自旋体系的对称性,故它们之间存在简单线性关系。文中给出I_n(I=1/2,n=2,3)自旋体系MQCPO的SAPO表示。MQCPO有利于自由演化过程的描述,而脉冲作用的描述则是SAPO为佳;利用MQCPO与SAPO的线性关系及SAPO笛卡儿分量的坐标轮换性质,“z”表象下脉冲作用的描述变得简单而直观。对异核谱剪辑及自旋拓扑滤波(spin topology filtration)等实验脉冲序列的分析,该方法是方便的。 关键词：     

Y123体系化学压强效应的63,65Cu核四极共振研究

我们研究了室温下系列Sr掺杂的Y(Ba1-xSrx)2Cu3O7-δ陶瓷样品的63,65Cu核四极共振谱.在YBa2Cu3O7-δ(Y123)中Sr2+的替代会在体系中产生化学压强效应,这种化学压强导致了CuO2平面的Cu(2)核四极共振信号向高频移动,而CuOx链层的Cu(1)核四极共振信号向低频移动.随着Sr2+掺杂的增加,Cu(2)和Cu(1)的核四极共振峰的峰宽都明显地变宽,同时还观察到一个新的Cu核四极共振峰.最后,我们给出了化学压强对超导转变温度的抑制的一些讨论,认为它与CuOx链层氧原子的部分无序导致的载流子非均匀分布或局域化有关.     

自旋I=3/2核四极共振体系对梳状脉冲的响应

用密度矩阵理论和计算机模拟较详细地讨论了自旋I=3/2核四极共振(NQR)粉末体系对梳状脉冲的响应以及偏共振效应的影响.在偏共振强度(包括谱线的非均匀增宽)较小的条件下.由它获得的谱与二维章动谱是相似的.但是实验所需时间能够减少近两个数量级. 关键词：     

粉末样品中半整数四极核中心线的自旋锁定现象

本文研究了半整数四极体系中心跃迁的自旋锁定,认为占据|-1/2>与|1/2>态的粒子可构成一个孤立的子体系,用密度算符理论证明了旋转坐标系自旋温度理论在这子体系中仍适用。在实验上用NaNO₂和NaOH粉末样品验证了上述结论。     

液体多脉冲及二维FT-NMR实验的乘积算符描述的计算机模拟

本文报道了利用乘积算符方法分析多脉冲及二维FT-NMR实验的模拟程序PROPER-MT.该程序对分析弱耦合I_mS_n(I=1/2;S=(1)/2;1 ≤ m十n<4)自旋体系实验脉冲序列是普遍适用的;它可给出实验过程中体系任何时刻算符的解析表达式.用PROPER-MT程序对一些典型的多脉冲及二维FT-NMR实验进行了模拟,特别对多量子滤波及多自旋滤波脉冲序列进行了分析计算,得到了预期的结果.     

具有面内四极磁场的旋转玻色-爱因斯坦凝聚体的基态结构研究

通过虚时演化方法研究了具有面内四极磁场的旋转玻色-爱因斯坦凝聚体的基态结构.结果发现:面内四极磁场和旋转双重作用可导致中央Mermin-Ho涡旋的产生;随着磁场梯度增强,Mermin-Ho涡旋周围环绕的涡旋趋向对称化排布;在四极磁场下,密度相互作用和自旋交换相互作用作为体系的调控参数,可以控制Mermin-Ho涡旋周围的涡旋数目;该体系自旋结构中存在双曲型meron和half-skyrmion两种拓扑结构.     

The HeI photoelectron spectra of methyl-substituted 1,2,4-pentatrienes (vinylallene)

The HeI photoelectron spectra of trans-1,2,4-hexatriene(1), 4-methyl-1,2,4-pentatriene(2), 3-methyl-1,2,4-pentatriene(3), 1,3,4-hexatriene(4) and 3,4-dimethyl-1,2,4-pentatriene(5) have been obtained and interpreted. LCBO and CNDO/S calculations indicate for the highest energy orbitals a π,π,π,σ sequence as in 1,2,4-pentatriene. The effect of methyl substitution on the three π orbitals is analyzed.     

Study of charmonium(-like) states via ISR at Belle

The cross sections for e+e-→π+π-J/ψ, π+π-ψ(2S), K+K-J/ψ, DD, D0D-π++c.c., D*D+c.c., and D*D-* are measured using data sample collected on or near the T(4S) resonance with the Belle detector at KEKB. A peak near 4.25 GeV/c2, corresponding to the so called Y(4260), is observed in π+π-J/ψ final state. In addition, there is another cluster of events at around 4.05 GeV/c2. Two resonant structures are observed in the π+π-J/ψ(2S) invariant mass distribution, one at 4361±9±9 MeV/c2 with a width of 74±15±10 MeV/c2, and another at 4664±11±5 MeV/c2 with a width of 48±15±3 MeV/c2. The rich structures observed in all these final states indicate that our understanding of the vector charmonium states above the open charm threshold is still poor, let alone the other possible dynamics such as charmonium hybrids or final state re-scattering and so on.     

Comparative analysis of the energy levels of planar and core-twisted perylene bisimides in solution and solid state by UV/VIS, CV, and UPS/IPES

The frontier orbital energies of four different functionalized perylene bisimide derivatives, PBI-Ph(iPr)₂, PBI-H₄, PBI-F₂ and PBI-Cl₄, were directly determined by UV-photo electron spectroscopy (UPS) and inverse photo electron spectroscopy (IPES) and are compared to the results from cyclic voltammetry (CV) and optical absorption spectroscopy (UV/VIS). The optical spectra reveal significant differences between monomeric species in solution and assembled molecules in the condensed state for the nearly planar PBI-H₄ and PBI-F₂, which are attributed to significant π–π stacking interactions in the condensed phase. In contrast, for PBIs with bulky substituents or twisted core, i.e. 2,6-isopropylphenyl substituents at the imide positions (PBI-Ph(iPr)₂) or four chlorine substituents at perylene bay positions (PBI-Cl₄), similar spectra are observed in solution and in the condensed state, which suggests the absence of strong intermolecular π–π stacking interactions. An entirely different result is obtained for the HOMO/LUMO energy values obtained from UPS/IPES and CV measurements which do not reveal a significant impact of intermolecular π–π stacking interactions. When comparing CV and UPS/IPES results, an accentuated deviation was observed for the perylene bisimide derivatives as compared to correlations found in the literature.     

Branching Ratios of J/ψ→π03(π+π－)

The decay mode of J/ψ→π⁰3(π⁺π^－) was studied very little before. There are no informations except branching ratios for this channel in PDG book which based on less than 0.2×10⁶J/ψ events of MARKⅠ. Now, BESⅠ has a data sample of 7.8×10⁶J/ψ events, we can make more accurate results than MARKⅠ. Total of 3290±43 J/ψ→π⁰3(π⁺π^－) events including 1275±86 J/ψ→ω²(π⁺π^－) events are selected. J/ψ→π⁰3(π⁺π^－) and J/ψ→ω²(π⁺π^－) events have been generated with MC simulition for calculating events selection efficiency. BESⅠ result is: Br(J/ψ→π⁰3(π⁺π^－))=(2.52±0.06±0.43)% and Br(J/ψ→π⁰3(π⁺π^－))=(1.31±0.09±0.21)%. Meanwhile, we studied the invariant mass of 4π and ωππ to find interesting signals. It seems that there is a peak at about 1.74GeV in the invarianat mass spectrum of 4π, and a enhancement was also found at about 1.9GeV in the invariant mass spectrum of ωππ. It is not clear whether they are from resonances or background. Therefore, more work in detail is still going on.     

Angular Distributions for φ＇ Sequential Decays into 2（π^＋π^-）pp^-γ via XCJ

Amplitudes for φ（2S） sequential decays into 2（π^＋π^-）pp^-γ via XCJ are constructed in effective coupling scheme. A Mote-Carlo simulation is carried out to study angular distributions of the decayed particles in laboratory system. The results can be taken as a reference for measuring the decay of XCJ into at BESⅡ/BEPC in the near future.     

基本粒子的质量关系和层子相互作用

本文利用重子和介子的SU(6)波函数,讨论强子内部的层子作用,分析各个质量关系的动力学根源,建立重子和介子质量的联系,并求得了几个联系二者的新关系:(ρ-π)/(K^*-K)=(△-N)/(Σ^*-Σ), 4(∧-N)=3(K^*-ρ)+(K-π), (ρ-π)/(△-N)=((φ-ρ)-2(K-π))/(2(Ω-△)-3/2(K-π)-9/4(φ-ρ)).研究了它们的成立与层子-层子力和层子-反层子力的对称性的联系。     

波荡器入口区绝热压缩磁场分布对自由电子激光输出功率和效率的影响

本文对波荡器(Wiggler)入口区绝热压缩磁场分布对自由电子激光输出功率、增益、效率的影响,进行了非线性计算机模拟.结果表明:磁场幅值沿轴向接立方函数分布,比通常采用的正弦平方函数和平方函数这两种分布更好,更接近实验值.     

Photoelectron spectroscopic assignment of symmetry to the ground state and first excited state of the 1,4-cyclohexadiene radical cation

The empirical correlation of the photoelectron spectra of 1,4-cyclohexadiene (molecule 4), 1, 4, 5, 8-tetrahydronaphthalene (molecule 5), 1, 4, 5, 6, 9, 1 0-hexahydroanthracene (molecule 6), and 1, 4, 5, 6, 7, 10, 11, 12-octahydronaphthacene (molecules 6) proves that the electronic ground state of these molecules is ²B_1u, assuming that they have D_2h symmetry. In particular this confirms previous predictions for 1,4-cyclohexadiene (molecule 4), for which the “inverted” orbital sequence 2b_1u(π) above lb_3g(π) had been proposed under the assumption that hyperconjugative “through-bond” interaction dominates the “through-space” interaction of the two semi-localized π-orbitals.     

二维旋转边带分解实验

描述了一类新的二维旋转边带分解实验,准备期包括交叉极化、若干个以TOSS序列的延迟加上的π脉冲和一个π/2脉冲,混合期包括一个π/2脉冲和一个TOSS序列,在演化期内,磁化矢量位于z方向。本实验能给出完全分解的各向同性化学位移与各向异性化学位移,它与Kolbert等人^[5]的实验方法相互补充。     

Study of ππ final state interactions in ψ(2S)→π+π-J/ψ

The π+π- transition of heavy quarkonia in decay ψ(2S) ψ(2S)→π+π-J/ψ is studied. With the BESII data on the decay ψ(2S)→π+π-J/ψ, we update the values of coupling constants (gi) and chromopolarizability (аψ(2S)J/ψ) in this process.