µCF experiments in thin deuterium films and progress towards slow µ− production

Muon-catalyzed fusion was investigated in thin solid deuterium films to determine the experimental feasibility of slow µ^– production by detection of dd fusion protons as well as slow µ^– collection utilizing a large-acceptance magnetic spectrometer. The spatial distribution of the fusion reaction in the film was extracted, and an optimum thickness for slow µ^– emission was deduced. Collected 10 keV µ^– were also successfully detected. However, the dd fusion yield being insufficient, we were not able to distinguish slow µ^– via µCF from degraded µ^–.     

MISTRAL: A new program for precise atomic mass determinations of nuclides far from stability

The MISTRAL project (Mass measurements at ISolde using a Transmission RAdiofrequency spectrometer on-Line) is scheduled to begin experiments towards the end of 1996. With high resolution (10⁵), potentially high accuracy (5×10^–7) and excellent sensitivity (10 s^–1), the MISTRAL spectrometer promises to provide needed mass measurements in regions of very-short lived nuclei. The spectrometer operation principles are described and a discussion concerning the interest in using highly charged ions is presented.CSNSM, Orsay; IAP, Bucharest; PPE Division, CERN; GSI, Darmstadt; University of Mainz; McGill University, Montreal; IPN, Orsay; Chalmers University, Göteborg; University of Giessen and the ISOLDE Collaboration.     

Dissociative electron attachment to CF2Cl2

Using a recently constructed high resolution crossed electron/molecular beam apparatus consisting of a hemispherical electron monochromator and a quadrupole mass spectrometer we have measured the relative production cross sections for CI^– and F^– via electron attachment to CF₂Cl₂. The relative Cl^– cross section is placed on an absolute scale by reference to an absolute rate coefficient using a calibration method involving integration of the measured anion signal. The most efficient Cl^– production process is at about zero energy and its magnitude is resolution limited. The present high resolution value of 6 × 10^–16 cm² compares well with an earlier value reported by Chen and Chantry. A second peak is detected at around 0.8 eV in accordance with some of the earlier beam and swarm measurements. The observed production of F^– has an appearance energy of 1.9 eV and the energy of maximum cross section is 3.36 eV, the latter value comparing well with several previous studies.     

Far infrared spectrum of methylamine

The far-infrared (FIR) spectrum of CH₃NH₂ has been studied in the 25–125 cm^–1 region at a resolution of 0.005 cm^–1 with a BOMEM Fourier transform spectrometer. All of the^rR branches with K rotational quantum number from 5 to 13 have been identified for A-a and E-a torsion-inversion symmetries in the ground torsional state, as well as some branches of A-s and E-s symmetries and some in excited torsional states. The observed branches have been fitted to series expansions in order to determine the branch origins.     

Second-order doppler-free spectroscopy

The observation of second-order Doppler-free optical resonances with a width of 50 Hz are reported for the first time. It was achieved due to the use of optical selection of cold particles from an absorbing gas. The experiments have been carried out by using a new laser spectrometer, supposed to obtain the saturated absorption resonances with a relative width 10^–13–10^–14. The results of experimental and theoretical studies of second-order Doppler-free effect influence on the shape of nonlinear optical resonances in transit-time conditions are considered.     

Diode laser measurements of line strengths and collisional half-widths in thev2band of14NH3 and15NH3

A tunable diode laser spectrometer was used to perform measurements of half-widths and intensities of several rotational lines in v₂-band of ammonia. The intensity measurements of 16 lines of¹⁵NH₃ allowed us to estimate v₂-band strength of this molecule at 298 K to be S_v ⁰=(550±10) cm^–2-atm^–1.     

Fourier Transform Emission Spectroscopy of theAΔ–XΠ Transition of SiH and SiD

The emission spectra of theA²Δ–X²Π transition of SiH and SiD have been observed at high resolution using a Fourier transform spectrometer. The molecules were excited in a Si hollow cathode lamp by passing a discharge through a mixture of Ne and a trace of H₂or D₂. The present data, combined with the previous infrared vibration–rotation measurements, have been used to determine improved molecular constants for the ground and excited states of SiH and SiD.     

Kaon interferometry in heavy-ion collisions at the CERN SPS

K⁺K⁺ and K^–K^– correlations from S+Pb collisions at 200 GeV/c per nucleon and K⁺K⁺ correlations from p+Pb collisions at 450 GeV/c per nucleon, are presented as measured by the focusing spectrometer of the NA44 experiment at CERN. Multidimensional fits are performed in order to characterize the kaon-emission volume, which is found to be smaller than the pion-emission volume.     

Submillimeter-Wave Spectroscopy of CO in the aΠ State

Submillimeter-wave absorption spectrum of CO in electronically excited a³Π state was observed in the 540–830 GHz region by using a phase-locked BWO spectrometer. New rotational transitions up to J = 9–8 in the vibrational excited states up to v = 5 were analyzed accompanied with previous observations in the RF and millimeter-wave regions. A multivibrational states fit among a′ ³Σ⁺ (v = 0–3) and a³Π (v = 0–7) states was performed in order to analyze overall perturbation between the a³Π and a′ ³Σ⁺ states. As a result, the deperturbed rotational parameters were derived precisely to improve the RKR potential.     

Absolute intensities for the Q-branch of the 3ν2-ν1 (465.161 cm) band of nitrous oxide

The absolute intensities of four lines, Q15–Q18 in the 03¹0–10⁰0 band, of N₂O have been measured using a tunable diode laser spectrometer at temperatures between 380 and 420 K and pressures between 4 and 15 torr. Even though these transitions are weak and produced only about 2% of absorption at the line center for a pathlength of 52m, they were measured with a signal to noise ratio of about 20 due to the high sensitivity of the instrument. The band strength derived is 1.03 × 10^-24cm molec^-1 at 296 K.     

The hyperfine field on carbon in iron

Integral perturbed angular correlation experiments have been carried out on recoilimplanted¹⁵C nuclei in iron. The 739 keV5/2⁺ level of¹⁵C was populated via the¹⁴C(d, p)¹⁵C^* reaction. Using the known g-factor and lifetime of the state, effective internal fields of –12.4±1.1 kG and –10.9±1.5 kG were determined at room temperature and 77 K, respectively. A conduction electron polarization hyperfine field of about –20 kG was deduced from the data.Work supported in part by the National Science Foundation.     

Fourier transform emission spectroscopy of the TiF radical in the 407 nm region

Ultraviolet emission spectra of the TiF radical in the 407 nm region have been observed at a resolution of 0.04 cm⁻¹ using a Fourier transform spectrometer. A new electronic assignment of ⁴Γ–X⁴Φ has been proposed. Rotational analysis has been obtained for the 0–0 and 1–1 vibrational bands of the ⁴Γ_5/2–X⁴Φ_3/2, ⁴Γ_9/2–X⁴Φ_7/2, and ⁴Γ_11/2–X⁴Φ_9/2 subbands and the 0–0 band of ⁴Γ_7/2–X⁴Φ_5/2. The lower state rotational and centrifugal distortion constants are consistent with the previous results [J. Mol. Spectrosc. 184 (1997) 186; J. Chem. Phys. 119 (2003) 9496], to the conformation that the lower state of the 407 nm band is the ⁴Φ ground electronic state. Rough estimates of the vibrational interval ΔG(1/2) and the spin–orbit coupling constant A in the ⁴Γ state were also obtained.     

Investigation of a heterodyne receiver with open structure mixer at 324 GHz and 693 GHz

The performance of a submillimeter heterodyne receiver using an HCOOH laser local oscillator and an open structure mixer with a Schottky barrier diode has been optimized for 693 GHz. Working at room temperature a single sideband (SSB) system noise temperature of 7,300 K, a mixer noise temperature of 6,100 K and a conversion loss of 12 dB has been achieved. The same receiver system has been investigated at 324 GHz using an HCOOD laser local oscillator yielding a noise temperature of 3,100 K (SSB), a mixer noise temperature of 2,400 K (SSB) and a conversion loss of 10 dB (SSB). An acousto-optical spectrometer has also been constructed, with 1024 channels and a channel-bandwidth of 250 kHz. The system NEP per channel was 2.5×10^–17 W/Hz^1/2 at 324 GHz and 5.0×10^–17 W/Hz^1/2 at 693 GHz.     

Fourier transform emission spectroscopy of some new bands of ReN

The emission spectrum of ReN has been reinvestigated in the visible region using a Fourier transform spectrometer. Two new bands have been identified with band origins near 22 110 and 22 224 cm⁻¹. These bands have a common lower state and have been assigned as the 0⁺–A1 and 0⁻–A1 transitions. After rotational analysis it was noted that the new 0⁺–A1 transition also has its upper state in common with the upper state of the [24.7]0⁺–X0⁺ transition reported previously [W.J. Balfour, J. Cao, C.X.W. Qian, S.J. Rixon, J. Mol. Spectrosc. 183 (1997) 113–118.]. This observation provides T₀₀ = 2616.26 cm⁻¹ for the A1 state. It is likely that the A1 and X0⁺ states are two spin components of the ³Σ⁻ ground state.     

Argon and nitrogen broadening in the pure rotational spectrum of HCl

The Ar- and N₂-broadened linewidths have been measured for the first four pure rotational transitions of HCl. The spectra were taken by means of a Fourier transform spectrometer working in the range 10–100 cm⁻¹ with an apodized resolution of 0.05 cm⁻¹. The results obtained generally agree with those of other authors. Comparison is also made with the most recent results of various theoretical calculations.     

The Rotational Spectrum of H2Te

In the present work, we study the spectrum of the H₂Te molecule in the submillimeter-wave and far infrared region. An important aim of this investigation is the further experimental characterization of the anomalous “four-fold cluster effect” exhibited by the rotational energy levels in the vibrational ground state of H₂Te. The spectrum in the region 90–472 GHz was measured with a source-modulated millimeter-wave spectrometer and that between 600 and 1600 GHz with a far-infrared sideband spectrometer. The far infrared spectrum from 30 to 360 cm⁻¹was measured with a Bruker IFS 120 HR interferometer attached to a 3 m long cell. We have assigned 224 submillimeter-wave lines and 1695 FIR lines. These observed data were supplemented by a large number of ground state combination differences derived from rotation–vibration bands of H₂Te, and the resulting large data set was analyzed by means of a modified Watson Hamiltonian. Accurate sets of rotational and centrifugal distortion constants for all eight tellurium isotopomers were obtained.     

Magneto-optical measurements with a hybrid magnet

An FFT spectrometer has been constructed to measure magneto-optical spectra in the far-infrared region (3 to 40 cm^–1) with a hybrid magnet system. The magneto-absorption was studied in the spin-Peierls cuprate CuGeO₃ at various magnetic fields. Coil constants of superconducting magnet and resistive one, of which a hybrid magnet consists, were calibrated by ESR spectra at the constant field.     

Reaction of the muonium substituted cyclohexadienyl radical with 2,3-dimethyl-1,3,-butadiene

The rate constant for the title reaction is represented by log (k _M/M^–1s^–1)=6.9(4)–700(350)K/T between 279 and 343K, whereas the H analogous radical, C₆H₇, reacts at room temperature withk _H 12 M^–1s^–1 with dimethylbutadiene. The title reaction is proposed to be transfer of the light hydrogen isotope, Mu, and the large kinetic isotope effect is discussed.Support by the Swiss National Foundation for Scientific Research and by the Swiss Institute for Nuclear Research (SIN) are gratefully acknowledged.     

Millimeter-wave spectrum of Ne–CO: new measurements

The b-type rotational transitions of the van der Waals complex, Ne–CO have been measured using the intracavity OROTRON jet spectrometer in the frequency range of 80–115 GHz. The high sensitivity of this technique enabled us to detect all three Ne isotopic modifications of the complex, ²⁰Ne–CO, ²²Ne–CO, and ²¹Ne–CO in natural abundance. The observed and assigned transitions belong to the Q-branch of the K = 1–0 subband and include also R (0) and P (2) lines. The newly obtained data were analysed together with previously observed millimeter-wave b-type and microwave a-type rotational transitions.     

A circular reflector interferometer for the far infrared

The construction of a Fourier transform spectrometer to study magnetic resonances in solids is described. The spectrometer operates in the Far Infrared (maximum frequency of 500 cm^–1) and is based on a wavefront dividing interferometer with circular geometry. To illustrate the performance, a water vapour spectrum is given.