碱类型对地聚合物混凝土应变率效应影响的对比研究

采用经波形整形技术改进后的?100 mm SHPB实验装置开展了强度等级均为C30的NS激发矿渣粉煤灰基地聚合物混凝土(NaOH and sodium silicate-activated slag and fly ash based geopolymer concrete,NSSFGC)和NN激发矿渣粉煤灰基地聚合物混凝土(NaOH and Na₂CO₃-activated slag and fly ash based geopolymer concrete,NNSFGC)的动态压缩实验,并对比分析了在冲击荷载作用下的应变率效应。结果表明:NSSFGC和NNSFGC的峰值应力均随应变率的增加而越大。这表明,GC为应变率敏感材料;在动态压缩状态下,NSSFGC和NNSFGC的应变率敏感阈值分别为51.82、28.89 s-1;GC的应变率敏感性强于普通混凝土;NN型激发剂更有利于发挥GC的整体强度特性。由此可知,NNSFGC的应变率敏感性明显强于NSSFGC。     

高流态地质聚合物混凝土的高应变率动态压缩变形特性

以矿渣、粉煤灰为原材料,以NaOH、Na2CO3为碱激发剂,制备了强度等级为C30的高流态地质聚合物混凝土（highly-fluidized geopolymer concrete,HFGC）,运用波形整形技术改进了Ø100mm SHPB实验装置,通过参数控制保证应力均匀和恒应变率加载,对HFGC开展了动态压缩实验,分析了HFGC在冲击压缩荷载下的变形特性。HFGC属于应变率敏感材料和脆性材料,高应变率作用下,HFGC的典型应力应变曲线包括压实挤密阶段、弹性阶段和软化、屈服阶段。在10~100s-1的应变率范围内,HFGC的峰值应变εc随应变率的变化表现出明显的冲击韧化效应,εc随应变率的升高先增大后减小,满足二次函数关系εc＝-1.2×10-6+1.6×10-4+0.001 7,变形特性变化的临界应变率为66.7s-1。HFGC的动态弹性模量均低于其在准静态下的弹性模量。     

聚酯纤维对透水沥青混凝土冲击压缩性能的影响

为研究聚酯纤维对透水沥青混凝土冲击压缩性能的影响,采用?74 mm钢质分离式霍普金森压杆装置对掺杂不同质量分数的聚酯纤维透水沥青混凝土进行冲击压缩实验。在静态和4个应变率下的实验结果表明,透水聚酯纤维沥青混凝土是应变率敏感性材料,具有较强应变率效应。透水聚酯纤维沥青混凝土具有较好的延展性,动态应力应变曲线分为3个阶段:弹性变形阶段、塑性变形阶段和破坏阶段。当应变率相同时,随着掺杂聚酯纤维质量分数的增大,透水沥青混凝土的冲击抗压强度呈现出先升高后降低的变化规律,掺杂聚酯纤维的质量分数为0.40%时,冲击抗压强度达到最大。冲击抗压强度约为静态抗压强度的8~13倍。     

变形模式对多孔金属材料SHPB实验结果的影响

利用两种改进后的Hopkinson杆实验分别测得多孔金属材料冲击端和支撑端的应力.实验结果及高速摄影表明,随着撞击速度的增加,试件两端的应力均匀性变差,分别对应着泡沫材料的3种变形模式:准静态模式、过渡模式、冲击模式.实验得出在冲击模式下,冲击端与支撑端的应力与试件的厚度无关,但是与试件的密度有关.在多孔金属的高应变率实验中,变形模式对SHPB实验有很大的影响,轴向惯性(波动)效应会导致试件两端的应力不均匀,此时利用SHPB得出的实验结果将会是应变率效应和惯性效应的耦合,不能真实反映材料的动态力学性能(应变率效应).      

不同应变率下冰破坏特性的试验研究

为研究寒区流冰对水工/船舶结构的影响,需要获得不同流速冰载荷的特征,准静态下不同应变率条件下冰材料变形至破坏的特征就成为一项重要的基础性问题。为此,开展了低温环境应变率10-2s-1至10-4s-1下淡水冰的单轴压缩试验。试验发现:随着应变率减小,极限应力由18.51MPa降低至8.44MPa,达到极限应力后,试件承载能力由瞬间消失变为逐渐降低至稳态,试件破坏形貌由劈裂转变为周向膨胀,即由脆性转变为韧性破坏,转变应变率约为10-3s-1;在双对数坐标系中,单轴压缩强度随应变率的增加近似呈线性增大。通过对应力-应变曲线进行积分,给出了不同破坏形式下冰变形至破坏的临界应变能密度,发现脆/韧转变状态下加载至破坏所需能量最大,该能量特征主要由冰中微裂纹的萌生、断面摩擦、再结晶引起。     

高应变率下纯水冰和杂质冰的动态力学行为

通过采用大热惯性试件快速加载技术和波形整形技术,对3种冰材料在-18℃下的动态压缩性能进行测试,实验中试件达到了应力均衡和近似恒应变率加载等条件。通过实验波形对比分析,解释了反射波和透射波中的“双峰现象”。在700~2 700 s^-1的应变率范围内,纯冰试件的压缩强度为14.5~49.3 MPa,相比于准静态结果表现出明显的动态增强效应。含有杂质的冰试件总体峰值应力相比于纯水冰试件有较大提升,而峰值应力对应的平均应变在减小,这表明添加了杂质的冰试件动态模量增大,冰材料变得更硬,其抵抗变形的能力更强。b型试件所表现出的强度(41.3~51.6 MPa)较a、c型试件均有提高并且分散性较小,说明该试件中杂质与冰晶体之间的结合力较强,抑制了微裂纹的萌生、扩展、成核等过程。     

粗骨料粒径对混凝土动态压缩行为的影响研究

粗骨料作为混凝土材料组成最主要的部分,对混凝土力学性能和破坏模式有着很重要的影响。为了研究粗骨料平均粒径对混凝土动态力学性能的影响规律,针对不同平均粗骨料平均粒径（6、12、24 mm）的混凝土和砂浆材料进行了一系列SHPB试验,得到了不同应变率下各试件的应力-应变曲线,并对每种材料的动态增长因子（dynamic increase factor,DIF）与应变率的对数进行了线性拟合。结果表明:砂浆和混凝土材料的抗压强度具有明显的应变率效应,其动态抗压强度随着应变率的增加而逐渐增大,应力-应变曲线呈现相似的变化趋势;在相同的动态应变率条件下,平均粗骨料粒径为12 mm的混凝土的动态抗压强度最大,这与准静态条件下砂浆抗压强度最大截然不同;不同粗骨料粒径混凝土材料的应变率强化系数均大于砂浆材料,且随着粗骨料无量纲尺寸的增大,混凝土材料的应变率强化因子呈现先增大后减小的趋势。     

新型混凝土桥面铺装材料的冲击力学性能

利用大尺寸Hopkinson压杆对新型混凝土桥面铺装材料钢纤维增强聚合物改性混凝土（steel fiber reinforced and polymer modified concrete,SFRPMC）进行了冲击实验,并且在相同基准配合比下,与普通混凝土、钢纤维混凝土的冲击性能进行了对比。观察了不同打击速度下三种材料的破坏形态,得到了在不同应变率下的应力应变关系,比较了三种材料的应变率敏感性,最后从机理上分析了掺加钢纤维和聚合物对混凝土材料冲击力学性能的影响。结果表明,钢纤维增强聚合物改性混凝土材料具有良好的冲击韧性,是一种理想的混凝土桥面铺装材料。     

钢纤维高强混凝土冲击压缩的试验研究

介绍了利用100 mm SHPB装置获得钢纤维高强混凝土冲击压缩应力-应变曲线的试验研究。同一类试样在静态和动态共4个不同应变率下的试验结果揭示混凝土是应变率敏感材料,其破坏应变、峰值应变和弹性模量表现出显著的应变率强化效应。从静态和动态压缩下混凝土损伤演化的不同形式对这种应变率强化效应进行了详细讨论。从相近应变率下不同钢纤维含量试样的试验结果中,发现冲击压缩下钢纤维对混凝土的增强效应随应变率的增大而减弱。从钢纤维对混凝土静态和动态压缩下损伤演化形式的影响,讨论了钢纤维对混凝土的这种增强效应。     

盐腐蚀后混凝土的动态本构模型

为探究混凝土受盐腐蚀后的动态力学响应,配置了粉煤灰质量分数为15%的普通硅酸盐水泥混凝土,将其置于质量分数均为15%的NaCl和Na₂SO₄溶液中浸泡腐蚀60 d后,利用?100 mm分离式霍普金森压杆实验装置,测试其受腐蚀后的动态力学性能,并结合宏观唯象损伤统计理论和Weibull分布思想,建立了混凝土受盐腐蚀后的动态统计损伤本构模型。结果表明:受盐腐蚀后,混凝土试件的动态抗压强度均有不同程度的下降,且NaCl溶液腐蚀试件的降幅大于Na₂SO₄溶液腐蚀试件;模型曲线与实验曲线的拟合度较高,能够较准确地描述混凝土在冲击荷载作用下的动态力学响应规律。     

Alkali activated fly ash: effect of admixtures on paste rheology

In this paper, an investigation related to the rheological behaviour of alkali-activated fly-ash pastes (AAFA) is described. Those pastes were prepared by mixing the fly ash with an alkaline dissolution containing 85% of a 12.5 M NaOH solution and 15% of waterglass and adding some commercial chemical admixtures usually used in the Portland cement concrete fabrication, like lignosulphonates, melamines (first and second generation products) and polycarboxylates (latest generation). The fly ash rheological data were determined by rotational viscometry measurements as well as by the use of the flow table test. Results indicate that chemicals admixtures used do not work the same in the Portland cement systems than in alkali-activated fly ash systems. As a general rule, it seems that the most efficient admixtures for these new cementitious pastes (AAFA) are those based in polycarboxylates.     

水泥粉煤灰加固有机质土的试验研究

对于高有机质含量的泻湖相软土,单纯采用水泥不能有效提高该软土的力学性能,因此提出了采用水泥和粉煤灰作为固化剂的加固方法。通过不同水泥掺入量、粉煤灰掺入量和龄期下水泥土的无侧限抗压强度试验,分析了水泥粉煤灰固化土的强度规律和变形规律,探讨了水泥和粉煤灰加固高有机质含量软土的机理。结果表明,粉煤灰对于水泥试块的早期强度影响较小,对后期强度影响较大;粉煤灰最佳掺入量为12％,超过此掺入量水泥土强度反而会降低,粉煤灰水泥土的破坏应变、E50也在粉煤灰掺量为12％时分别达到最低值和最大值。水泥掺加粉煤灰可有效地提高高有机质含量软土的强度。     

混凝土多尺度应力响应方程及其数值模拟

针对混凝土的多相多尺度材料组成特征及其复杂力学响应问题, 首先, 根据混凝土中各组成材料的几何特征, 将C-S-H凝胶、硬化水泥浆体、砂浆及混凝土细观组成分别视为纳观、微观、亚细观和细观尺度上的复合材料, 并利用颗粒空间堆积方法, 重构了混凝土各尺度复合材料的简化几何模型; 其次, 基于重构的几何模型和等效夹杂理论, 通过等效刚度的升阶计算和应力响应的降阶计算, 建立各尺度复合材料应力响应之间的过渡关系, 推导混凝土多尺度应力响应方程, 并编制相应的计算程序; 最后, 以单轴压缩载荷作用为例, 数值计算载荷作用下混凝土各尺度复合材料中的应力响应, 分析骨料空间位置和相互作用以及水化产物刚度、几何形状和空间取向对其应力响应的影响规律. 结果表明, 单轴压缩载荷作用下, 混凝土细观组成中的应力分布并不均匀; 骨料颗粒之间的距离影响到混凝土中的应力分布, 其有效影响范围约为骨料粒径的6倍; 水泥水化产物的刚度、几何形状和空间取向是影响其应力分布的重要因素, 刚度越大, 所受应力越大, 与载荷作用方向的夹角越小, 长椭球形水化产物沿载荷作用方向的应力越大, 扁椭球形水化产物与之相反.      

Fracture analyses of different pre-holed concrete specimens under compression

Crack propagation processes in specially prepared concrete discs and rectangular specimens containing a single cylindrical hole or multiple holes of varying diameters have been studied both experimentally and numerically.In this research, the cracks coalescence paths in Brazilian disc and rectangular specimens made from rock-like material containing multi-holes are investigated. These concrete specimens are specially prepared from an appropriate mixture of Portland Pozzolana Cement(PPC), fine sands, and water.The pre-holed Brazilian discs and rectangular specimens are experimentally tested under compression. The breakage load in the ring type disc specimens containing an axial hole with varying diameters is measured and the distribution of the induced lateral stress is obtained. The mechanism of cracks propagation in the wall of the ring type specimens is also studied. In the case of multi-hole Brazilian disc and rectangular specimens, the cracks propagation and cracks coalescence are also investigated. These experiments are numerically modeled by a modified higher order displacement discontinuity method. It has been shown that the corresponding experimental and numerical results are in good agreement with each other. The results presented in this research validate the accuracy and applicability of these crack analyses procedures.     

陶瓷再生粗骨料混凝土力学性能研究

采用硅烷偶联剂KH-550溶液浸泡陶瓷再生粗骨料,改变其表面性能,从而增强陶瓷骨料-水泥石界面的粘结性能。使用处理后的陶瓷骨料制备陶瓷再生混凝土,并对其进行了立方体抗压强度试验和弹性模量测试。结果表明:随着陶瓷粗骨料掺量的增加,再生混凝土的强度降低;当掺量为60%时,再生混凝土的弹性模量较原碎石混凝土提高了3.2%;当掺量为100%时,再生混凝土抗压强度仍然满足要求。     

Experimental and numerical studies of thermo-hydrous transfers in concrete exposed to high temperature

The compressive strength of concrete can be as high as 80 MPa at 28 days. High strength concrete (HSC) can be obtained by decreasing porosity and lowering permeability. Concrete, especially HSC, performs poorly when subjected to fire. This is attributed to high thermal stresses and water vapour pressure. High thermal gradient induces high thermo-mechanical stresses in the concrete system. Low permeability prevents water from escaping and induces high water vapour pressure causing cracking and spalling. The aim of this study is both experimentally and numerically study the coupled heat and mass transfers in concrete exposed to elevated temperature. Five concrete mixtures with various cement contents and water cement ratios of a constant aggregate content were studied before and after heating–cooling cycles. The concrete cylindrical specimens were subjected to several tests: compression and splitting tensile tests, measurement of modulus of elasticity, heating–cooling cycles, thermal field and mass loss during the heating–cooling cycles, and permeability tests. Comparisons between the numerical and experimental results on the thermo-hydrous behaviour were reported. Parametric analyses were carried out in order to underline main parameters involved in concrete behaviour at high temperature. The numerical and experimental results included thermal gradient, water vapour pressure, relative humidity, concrete mass losses due to dehydration, and water content for concrete elements heated from 20 to 600°C. The results show the degrees of damage due to the concrete chemical transformations at high temperature.     

玄武岩纤维高延性水泥基复合材料的动态力学性能

利用玄武岩纤维和水泥基材料,通过一定配比融合制成了在静态拉伸试验中呈现多缝开裂、应变硬化、极限拉伸应变0.5%以上的玄武岩纤维高延性水泥基复合材料(basalt fiber engineered cementitious composites, BF-ECCs)。用分离式霍普金森压杆(split Hopkinson pressure bar, SHPB)装置对不同玄武岩纤维掺量的水泥基复合材料进行动态压缩和动态劈裂试验。结果表明:(1)在压、拉两种应力状态下,玄武岩纤维对水泥基复合材料的静态强度、动态强度均有增强,且高应变率下玄武岩纤维对抗压强度动态增幅较小,对劈裂强度动态增幅较大;(2) BF-ECC的抗压强度和劈裂强度均随应变率升高而显著提高,两者均可以采用动态增强因子(dynamic increase factor, DIF)反映动态强度的增幅,但劈裂强度的应变率敏感性强于抗压强度;(3)依据试验得到的普通水泥混凝土速率敏感性的CEB-FIP方程(2010)不适用于BF-ECCs。     

爆破冲击对早龄期混凝土强度影响的实验研究

以某大型全碎石填方机场工程为背景,针对早龄期混凝土受爆破振动损伤开展了实验研究。通过室内实验模拟场地爆破振动作用于早龄期混凝土试块,测量了不同龄期混凝土受振损伤后的强度。并将实验结果与有限元数值计算和现场爆破场地测试数据相结合,分析了早龄期混凝土损伤后的强度增长规律,建立了场地爆破与混凝土结构浇筑平行施工的安全技术指标。     

The analysis of thermoplastic characteristics of special polymer sulfur composite

Specific chemical environments step out in the industry objects. Portland cement composites (concrete and mortar) were impregnated by using the special polymerized sulfur and technical soot as a filler (polymer sulfur composite). Sulfur and technical soot was applied as the industrial waste. Portland cement composites were made of the same aggregate, cement and water. The process of special polymer sulfur composite applied as the industrial waste is a thermal treatment process in the temperature of about 150–155 \(^{\circ }\hbox {C}\). The result of such treatment is special polymer sulfur composite in a liquid state. This paper presents the plastic constants and coefficients of thermal expansion of special polymer sulfur composites, with isotropic porous matrix, reinforced by disoriented ellipsoidal inclusions with orthotropic symmetry of the thermoplastic properties. The investigations are based on the stochastic differential equations of solid mechanics. A model and algorithm for calculating the effective characteristics of special polymer sulfur composites are suggested. The effective thermoplastic characteristics of special polymer sulfur composites, with disoriented ellipsoidal inclusions, are calculated in two stages: First, the properties of materials with oriented inclusions are determined, and then effective constants of a composite with disoriented inclusions are determined on the basis of the Voigt or Rice scheme. A brief summary of new products related to special polymer sulfur composites is given as follows: Impregnation, repair, overlays and precast polymer concrete will be presented. Special polymer sulfur as polymer coating impregnation, which has received little attention in recent years, currently has some very interesting applications.