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1.
Radiative decays π 0(π 0′) → γ + γ, π 0′ρ 0(ω) + γ, ρ 0′(ω′) → π 0 + γ, ρ 0′(ω′) → π 0′ + γ, and some processes of π 0′ production at lepton colliders are considered in the framework of the nonlocal SU(2) × SU(2) Nambu-Jona-Lasinio model. Mixing of the radially excited and the ground meson states is taken into account. Numerical results for the decay and production processes are presented.  相似文献   

2.
A multispectrum nonlinear least-squares fitting technique was applied to measure accurate zero-pressure line center positions, Lorentz self- and nitrogen (N2)-broadened half-width coefficients, and self- and N2-pressure-induced shift coefficients for over 700 transitions in the parallel ν4 band of CH3CN near 920 cm−1. Fifteen high-resolution (0.0016 cm−1) laboratory absorption spectra of pure and N2-broadened CH3CN recorded at room temperature using the Bruker IFS 125HR Fourier transform spectrometer located at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington, USA, were analyzed simultaneously assuming standard Voigt line shapes. Short spectral intervals containing manifolds of transitions from the same value of J were fitted together. In all, high-precision line parameters were obtained for P(44)-P(3) and R(0)-R(46) manifolds. As part of the analysis, quantum assignments were extended, and the total internal partition function sum was calculated for four isotopologs: 12CH312CN, 13CH312CN, 12CH313CN, and 13CH313CN. Measurements of N2 broadening, self-broadening, N2-shift, and self-shift coefficients for transitions with J up to 48 and K up to 12 were measured for the first time in the mid-infrared. Self-broadened half-width coefficients were found to be very large (up to ∼2 cm−1 atm−1 at 296 K). Ratios of self-broadened half-width coefficients to N2-broadened half-width coefficients show a compact distribution with rotational quantum number in both the P and R branches that range from ∼4.5 to 14 with maxima near ∣m∣=24, where m=−J″, J″, and J″+1 for P, Q, and R lines, respectively. Pressure-induced shifts for N2 are small (few exceed ±0.006 cm−1 atm−1 at 294 K) and are both positive and negative. In contrast, self-shift coefficients are large (maxima of about ±0.08 cm−1 atm−1 at 294 K) and are both positive and negative as a function of rotational quantum numbers. The present measured half-widths and pressure shifts in ν4 were compared with corresponding measurements of rotational transitions.  相似文献   

3.
The excitation of transitions from the 2 S , 2 P , and 2 D levels of the cobalt atom is studied by the method of extended crossing beams. Seventy-six excitation cross sections are measured at an exciting electron energy of 50 eV. Nine optical excitation functions are recorded in the electron energy region of 0–200 eV. Possible channels of excitation of levels under study are discussed.  相似文献   

4.
The Fourier transform gas-phase IR spectrum of 1,2,3-thiadiazole, C2H2N2S, has been recorded with a resolution of ca. 0.003 cm−1 in the 700-1100 cm−1 spectral region. Four fundamental bands ν6(A/; 1101.8 cm−1), ν7(A/; 1038.8 cm−1), ν9(A/, 858.9 cm−1), and ν13(A//; 746.2 cm−1) have been analyzed using the Watson model in A-reduction. Two additional bands, ν8 (A/; 894.6 cm−1) and ν12(A//; 881.2 cm−1) were assigned by their weak Q-branches. Ground state rotational and quartic centrifugal distortion constants as well as upper state spectroscopic constants have been obtained from fits. A number of weak global and local interactions are present in the bands. The resonances identified were qualitatively explained by Coriolis type perturbations with neighboring levels. Ground state rotational and quartic centrifugal distortion constants, anharmonic frequencies, and vibration-rotational α-constants predicted by quantum chemical calculations using a cc-pVTZ basis and B3LYP methodology, have been compared with the present experimental data, where there is generally good agreement.  相似文献   

5.
Line positions, intensities, Lorentz self- and N2-broadened half-width coefficients have been measured for PQ3, PQ2, PQ1, RQ0, RQ1, RQ2, and RQ3 sub-band transitions in the ν9 fundamental band of 12C2H6. A multispectrum nonlinear least-squares fitting technique was used to fit up to 17 high-resolution (∼0.00156 cm−1), room temperature absorption spectra of pure (99.99% chemical purity) natural sample of ethane and lean mixtures of the high-purity ethane diluted with N2. A Bruker IFS 120HR Fourier transform spectrometer located at the Pacific Northwest National Laboratory (PNNL), in Richland, Washington was used to record the data. A standard Voigt line shape was assumed to fit all the data since no line mixing or other non Voigt line shapes were required to fit any of the spectra used in the analysis. Short spectral intervals (∼2-2.5 cm−1) of all 17 spectra covering a specific PQ or RQ sub-band were fit simultaneously. For the first time in an ethane band, pressure-broadened half-width coefficients were determined for the torsional-split components. However, for better reliability of the retrieved coefficients for the weaker components (transitions with large intensity ratios of 4:1 or 3:1 for most K levels between the strong and weak components), constraints were used such that the half-width coefficients of both torsional-split components for a given J were identical for a specific broadening gas. No pressure-induced shift coefficients were necessary to fit the spectra to their noise level. The present study revealed for the first time the dependence of self- and N2-broadened half-width coefficients upon the J, K quantum numbers of the transitions in ethane. A number of transitions belonging to the ν9+ν4ν4 and the ν9+2ν4−2ν4 hot bands were also observed in the fitted regions and measurements were made when possible.  相似文献   

6.
Previous studies of the parallel bands 2ν2 and 50 of CH3Br by the two first authors have been completed by the analysis of the weaker perpendicular band ν2 + ν5, centered near 2745 cm?1. It is well known that the v2 = 1 and v5 = 1 states of methylbromide are linked by an x-y-type Coriolis interaction. Therefore, in the 2500–2900-cm?1 range, the levels
(v2=2), (v52, l5=0), (v5=2, l5±2), (v5=v2=1, l=5±1)
are linked by a similar interaction. Least-squares and prediction programs have been written to treat this kind of problems and they have been satisfactorily applied to both isotopic species, CH379Br and CH381Br. A localized resonance in the K = 0 subband of ν2 + ν5 has been shown to be due to the 3ν3 + ν6 band. No evidence for a strong Fermi resonance between ν1 and 50 has been found.  相似文献   

7.
The extended stretch-bender Hamiltonian, incorporating spin-orbit coupling and overall rotation, has been used to calculate the spin-vibronic structure of the rovibronic energies in the region where the vibronic states of the excited Ã2A1 electronic state of NH2 interact with near-resonant high-lying levels of the X?2B1 state of NH2. A detailed comparison has been made with the experimental measurements which were made of these rovibronic states, the majority of which are due to Ramsay, Vervloet, and their collaborators. We have shown that, as in our study of the vibronic levels of the X?2B1 state below the barrier to linearity, in order to fit the variation of the effective vibronic spin-orbit coupling constant over the whole of this energy regime, the effective linear molecule spin-orbit coupling constant, ASO must be increased from the earlier value of 50 cm−1 of Ch. Jungen, K.-E. J. Hallin, and A. Merer (Mol. Phys.40, 65-94 (1980)) to 61.6 cm−1. The impact of Fermi resonance, in both the Ã2A1 and X?2B1 states, on the observed rovibronic structure has been assessed. The pattern of calculated spin-rovibronic levels, including the effects of spin uncoupling, is in good agreement with that measured experimentally.  相似文献   

8.
The infrared spectrum of propynal, C2HCHO, is studied at high resolution (0.003 cm−1) in the range 570-640 cm−1. The relatively intense ν11 (CC-H out-of-plane bend, 693 cm−1) and ν7 (CC-H in-plane bend, 651 cm−1) fundamental bands are linked by a strong a-type Coriolis interaction. The somewhat weaker ν8 (CCO in-plane bend, 614 cm−1) fundamental has a significant Fermi-type interaction with the “dark” background state 3ν9 (∼618 cm−1). About 1400 lines are assigned and analyzed in terms of a four-state fit in order to obtain accurate band origins, rotational and centrifugal distortion parameters, and Fermi and Coriolis interaction parameters. This represents the first systematic high-resolution infrared study of propynal.  相似文献   

9.
In this paper, double Λ binding energies BΛΛ s of ΛΛ5He(ΛΛ5H), AA4He and ΛΛ4H are calculated with the help of few-body models. The results show that stable binding state for ΛΛ5H or ΛΛ5He exists definitely with BΛΛ(ΛΛ5H)=6.75MeV and BΛΛ(ΛΛ5He)=7.67MeV,respectively. As to ΛΛ4He and ΛΛ4H, preliminary results indicate that ΛΛ4H is unstable against decaying into Λ+Λ3H, and ΛΛ4He has no binding state.  相似文献   

10.
The magnetoelectric composites xNi0.4Zn0.6Fe2O4-(1 − x)Pb0.95Sr0.05Zr0.53Ti0.47O3 (x = 0, 0.2, 0.4, 0.6, 0.8, 1.0) were prepared by ceramic technology. It is established that these composites have a two-phase structure. The magnetic and ferroelectric properties of the composites were studied by measuring the hysteresis loops and the temperature dependences of corresponding quantities on the composite composition. It is revealed that the phase content in the composite strongly affects the properties studied. Original Russian Text ? S.A. Gridnev, A.G. Gorshkov, O.N. Korolevskaya, 2009, published in Fizika Tverdogo Tela, 2009, Vol. 51, No. 8, pp. 1464–1467.  相似文献   

11.
Among all the 4478 classical isomers of C66, C66(C s :0060) with the lowest number of pentagon–pentagon fusions was predicted to be the most stable isomer, followed by isomers C66(C 2v :0011) and C66(C 2:0083). The infrared spectra and aromaticity of the most stable isomers were predicted. The relative stabilities of C66 isomers change with charges or doping of metals. The structures and relative stabilities of the most stable metallofullerenes were delineated and compared with experiment. Sc2@C66(C 2:0083) was predicted to be the most stable metallofullerene, although Sc2@C66(C 2v :0011) was observed. Charge-transfer from Sc2 to the fused pentagons and the bonding between these two moieties significantly decrease the strain energies caused by the pair of fused pentagons thereby stabilizing the fullerene cage.  相似文献   

12.
The ν6, ν17, and ν21 fundamental bands of dimethyl ether have been assigned and rotationally analyzed. The spectra used were recorded at 0.005 cm−1 spectral resolution with a Fourier-transform spectrometer coupled to a supersonic molecular beam leading to a rotational temperature of about 70 K. The ν6 and ν21 bands do not seem to be perturbed and the analysis of the rotational structure leads to band centers located at 933.906 6(9) and 1 103.951(1) cm−1, respectively, and to accurate rotational and centrifugal distortion constants. For the ν17 band at 2817.385(2) cm−1, only the P and R branches could be assigned.  相似文献   

13.
14.
We present a set of formulas using the solution of the QCD Dokshitzer-Gribov-Lipatov-Altarelli-Parisi (DGLAP) evolution equation to extract of the exponents of the gluon distribution, λ g , and structure function, λ S , from the Regge-like behavior at low x. The exponents are found to be independent of x and to increase linearly with lnQ 2 and are compared with the most data from the H1 Collaboration. We also calculated the structure function F 2(x,Q 2) and the gluon distribution G(x,Q 2) at low x assuming the Regge-like behavior of the gluon distribution function at this limit and compared them with an NLO-QCD fit to theH1 data, two-Pomeron fit, multipole Pomeron exchange fit, and MRST (A.D. Martin, R.G. Roberts, W.J. Stirling, and R.S. Thorne), DL (A. Donnachie and P.V. Landshoff), and NLO GRV (M. Glük, E. Reya, and A. Vogt) fit results. The text was submitted by the authors in English.  相似文献   

15.
xCeO2–30Bi2O3–(70−x) B2O3 glasses are synthesized by using the melt quench technique. A number of studies such as XRD, density, molar volume, optical band gap, refractive index and FTIR spectroscopy are employed to characterize the glasses. The band gap decreases from 2.15 to 1.61 eV, refractive index increases from 2.67 to 2.93 and density increases from 4.151 to 4.633 g/cm3. The decrease in band gap with CeO2 doping approaches the semiconductor behavior. FTIR spectroscopy reveals that incorporation of CeO2 into glass network helps to convert the structural units of [BO3] into [BO4] and results in Bi–O bond vibration of [BiO6].  相似文献   

16.
This paper reports on a study of the effect of oxygen deficiency on the magnetic and electrical properties of the La1 − x Sr x MnO3 − δ manganites (x = 0, 0.2, 0.4; δ = 0, 0.13, 0.2). In compositions with x = 0 and δ = 0.13 and 0.2, the temperature dependence of the magnetization M (T) can be approximated by the Langevin function with the moment of superparamagnetic clusters μ = 77μB (δ = 0.13) and 86μB (δ = 0.2) at temperatures of 25 K ≤ T ≤ 250 K, with the exception of a small temperature range near 132 K in which a maximum characteristic of the LaMnO3 antiferromagnet is seen. These compositions, as well as Sr-doped compositions with δ ≠ 0, reveal a difference between the magnetizations of the sample cooled in a weak magnetic field and in zero field. At T = 6 K in a magnetic field of 16 kOe, the compositions with x = 0.2 and 0.4, δ = 0.13 possess a magnetic moment per formula unit lower than that with δ = 0, as well as reveal an anomalous relation between the Curie temperature T C and the Curie paramagnetic point gJ, namely, T C > gJ. The magnetization of compositions with x = 0.2 and 0.4, δ = 0.2 follows the Langevin function with μ = 40μB and 130μB, respectively. The electrical resistivity of samples with x = 0.4 and δ = 0.13 and 0.2 is one to two orders of magnitude larger than that of the composition with x = 0.4, δ = 0, which evidences partial or complete compensation of acceptor defects (Sr2+ ions) by donor defects (doubly charged O2− vacancies). The above properties of oxygen-deficient compositions suggest that they contain an insulating ferro-antiferromagnetic magnetically double-phase state. The magnetoresistance and volume magnetostriction in samples with x = 0.4 and δ = 0, 0.13, and 0.2 are small; indeed, in a magnetic field of 8 kOe, they do not exceed 1.4% and 6 × 10−6, respectively. On this basis, it is concluded that the unbalanced doubly charged donors (O vacancies) are in the state with antiparallel spins and, thus, do not initiate the formation of ferron-type ferromagnetic clusters. The significance of both compensated and unbalanced doubly charged donors consists in that they give rise to the formation of fractured Mn-O-Mn bonds, which bring about lowering of the magnetic moment per formula unit in compositions with x = 0.2 and 0.4 and δ = 0.13 and the transition to superparamagnetism in compositions with x = 0.2 and 0.4, δ = 0.2. Original Russian Text ? L.I. Koroleva, D.M. Zashchirinskiĭ, T.M. Khapaeva, L.I. Gurskiĭ, N.A. Kalanda, V.M. Trukhan, R. Szymczak, B. Krzumanska, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50, No. 12, pp. 2201–2205.  相似文献   

17.
The Fourier transform gas-phase IR spectrum of 1,3,4-thiadiazole, C2H2N2S, has been recorded with a resolution of ca. 0.003 cm−1 in the 800-1500 cm−1 spectral region. Five fundamental bands ν2(A1; 1391.9 cm−1), ν4(A1; 964.4 cm−1), ν5(A1; 894.6 cm−1), ν9(B1; 821.5 cm−1), and ν14(B2; 898.4 cm−1) have been analysed using the Watson model. Ground state rotational and quartic centrifugal distortion constants as well as upper state spectroscopic constants have been obtained from fits. The ν4 and ν9 bands are unperturbed while a strong c-Coriolis resonance perturbs the close-lying ν5 and ν14 bands. This dyad system has been analysed by a model including first and second order c-Coriolis resonance using the theoretically predicted Coriolis coupling constant . The ν2 band is strongly perturbed by a local resonance, and we obtain a set of spectroscopic parameters using a model including second order a-Coriolis resonance with the inactive ν10 + ν14 band. Ground state rotational and quartic centrifugal distortion constants, anharmonic frequencies, and vibration-rotational α-constants predicted by quantum chemical calculations using a cc-pVTZ basis and B3LYP methodology, have been compared with the present experimental data, where there is generally good agreement.  相似文献   

18.
Spectra and angular distributions of the(α,d)reactions on 56Fe 57Fe and 59Co have been measured with the △E-E telescopic systems and Q3D magnetic spectrometer at a bombarding energy of 35MeV from the HI-13 Tandem,and analyzed with microscopic DWBA.Among the angular distributions of nine levels strongly populated by 56Fe(α,d)58Co reaction, the experimental data of 6.79MeV and 6.4MeV levels in 58Co were analyzed and discussed. The highest stretched configuration (1g9/2,1g9/2)9 was found and Jπ=1+ of 6.4MeV level was determined for the first time. No isolated stretched states were observed by 57Fe 59Co(α,d)reactions.This probably means that the strength of the stretched configuration spreads on a number of states.  相似文献   

19.
Total cross sections of electron scattering by several sulfur-containing molecules OCS, SO2, SF4, SF6, SF5CF3, SO2Cl2 and SO2ClF are calculated at the Hartree-Fork level employing the modified additivity rule approach. The modified additivity rule approach, which was proposed by Shi et al. [Eur. Phys. J. D 45, 253 (2007); Nucl. Instrum. Meth. B 254, 205 (2007)], takes into consideration that the contributions of the geometric shielding effect vary as the energy of incident electrons, the target’s molecular dimension and the atomic and electronic numbers in the molecule. The present investigations cover the impact energies ranging from 30 to 5000 eV. The quantitative total cross sections are compared with those obtained by experiments and other theories. Good agreement is observed even at energies of several tens of eV. It shows that the modified additivity rule approach is applicable to carry out the total cross section calculations of electron scattering by these sulfur-containing molecules at intermediate and high energies, especially over the energy range above 100 eV or so. In the present calculations, the atoms are still represented by the spherical complex optical potential, which is composed of static, exchange, polarization and absorption terms.  相似文献   

20.
Non magnetic material Ca2+ as a substitute in Cobalt ferrite (Co1?xCaxFe2O4x?=?0.00, 0.05, 0.10 & 0.15) is prepared by self auto combustion method. The synthesized samples were carried out for various characterizations such as X-ray diffraction, Field emission scanning electron microscope (FE-SEM), Dielectric measurement and Magnetic property. X-ray diffraction reveals the values of crystalline size, lattice parameter and x-ray density by using the standard formula. The saturation magnetization (Ms) decreases from 63.92 to 43.17 emu/g for x?=?0.00 to 0.15 and the coercivity (Hc) increases gradually from 819.85 to 1312.32?Oe with the increase in Ca2+ concentration. The dielectric properties of synthesized nano materials were carried out at room temperature. The dielectric parameters such as tangent loss, Cole–Cole plot (Impedance, Modulus), and AC Conductivity were determined for various Ca2+ concentration. The frequency dependent dielectric dispersion behaviour of all the samples can be explained by the Maxwell–Wagner two-layer model along with Koop's phenomenological theory. As a result, Ca2+ substituted Cobalt ferrite is enhanced with their dielectric and magnetic property which is suitable for a memory device, recording media application and high frequency device.  相似文献   

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