Near-field photocurrent spectroscopy: A novel technique for studying defects and aging in high-power semiconductor lasers

Received: 28 October 1996/Accepted: 5 November 1996     

Identification of single fluorescently labelled mononucleotide molecules in solution by spectrally resolved time-correlated single-photon counting

We describe a method to identify single dye-labelled mononucleotide molecules in solution with high classification probability based on confocal microscopy in combination with spectrally and time-resolved fluorescence detection with two detectors. For efficient excitation of the labelled mononucleotide molecules JA133-dUTP, JA169-dUTP, Cy5-dCTP, and JA242-dUTP a short-pulse diode laser emitting at 634 nm with a repetition rate of 64 MHz was applied. The time-resolved fluorescence signals of individual molecules were analyzed and identified by a maximum likelihood estimator (MLE). Scatter plots of spectrally and time-resolved fluorescence data demonstrated the existence of four distinct populations with symmetrical shape. The distributions of each of the mononucleotide conjugates were determined by fitting a superposition of two independent Gaussians. Taking only those single-molecule bursts which contain more than 50 photon counts, three labelled mononucleotide molecules were identified in solution by spectrally and time-resolved fluorescence spectroscopy with a probability of correct classification of ≈99%. Received: 31 March 2000 / Revised version: 31 May 2000 / Published online: 13 September 2000     

Compact mid-infrared trace gas sensor based on difference-frequency generation of two diode lasers in periodically poled LiNbO3

3 (PPLN) crystal pumped by two single-frequency diode lasers. A maximum DFG power of 1.6 μW at 3.6 μm was generated with a pump power of 61.4 mW at 832 nm and a signal power of 41.5 mW at 1083 nm incident on a 19-mm-long PPLN crystal, which corresponds to a conversion efficiency of 335 μW W^-2 cm^-1. Received: 16 June 1998     

Detection of aromatic pollutants in the environment by using UV-laser-induced fluorescence

Fluorescence spectra, decay times, and detection limits of the 16 US-EPA polycyclic aromatic hydrocarbons (PAH) have been measured and the results are discussed in terms of separability of single PAHs in a multicomponent mixture. The results of a mathematical analysis of a 16-component mixture is presented. Spectra from natural water samples contaminated with gasoline and tar are also presented and the potential and limits of the LIF technique are discussed. Received: 19 March 1998/Revised version: 2 June 1998     

Accurate spectroscopic wavelength determination of pulsed lasers

We present a simple, easy, and straightforward spectroscopic approach for the determination of the wavelength of pulsed laser systems with an accuracy of ≤0.006 cm^-1 (180 MHz). This is better than currently realised by the best commercially available wavemeters for pulsed laser systems. As an example, the temperature dependence of the emitted wavelength of a pulsed Nd:YAG laser has been studied in detail. Our measurements indicate that the passively Q-switched monolithic nonplanar ring-oscillator Nd:YAG laser with a free spectral range of the resonator of about 5.8 GHz can be tuned without mode hops over a range of 3.8 GHz. The concept is generally applicable to any other wavelength regions of interest. Received: 9 April 2001 / Revised version: 9 July 2001 / Published online: 19 September 2001     

Quantum dot lasers: recent progress in theoretical understanding and demonstration of high-output-power operation

The field of semiconductor quantum dot (QD) diode lasers is rapidly developing. Important milestones, such as low-threshold operation and room-temperature cw operation, have been achieved in the last years. We review the progress in theoretical understanding and present recent results on high-power QD laser operation (>3 W@1100 nm). Received: 24 June 1999 / Revised version: 23 August 1999 / Published online: 20 October 1999     

Effect of intrinsic-gain fluctuations on quantum noise of phosphor materials used in medical X-ray imaging

The quality of a medical image depends, among other parameters, on quantum noise. Quantum noise is affected by the fluctuations in the number of optical quanta produced within the phosphor, per absorbed X-ray (i.e. phosphor intrinsic-gain fluctuations). This effect is considered by means of a factor, called in this study intrinsic-gain noise factor, IGNF(E). In existing theoretical models of quantum noise, the corresponding factor is taken to be equal to one. In this paper, an expression that accounts for the coefficient of variation of the phosphor intrinsic gain is introduced. This expression takes into account the process of electron–hole pair conversion to optical photons and the frequency distribution function of the emitted optical photon energy. Subsequently IGNF(E) is expressed in terms of this coefficient of variation. IGNF(E) has been calculated for several phosphors and for various energies. For all medical X-ray energies studied, phosphors that exhibit a high relative fluctuation of emitted optical photon energy, IGNF(E) exceeds by 2% to over 17% the corresponding factor of the existing theoretical models of quantum noise. Received: 25 March 1999 / Accepted: 29 March 1999 / Published online: 14 July 1999     

Determination of dispersion characteristics in anisotropic materials using ultrashort pulses

2 crystal. This method, based on group velocity measurement, allows the determination of the principal axes, the indices, the group velocities and the group velocity dispersion (GVD). Received: 11 February 1997/Revised version: 23 May 1997     

A study of some optical properties of hafnium dioxide (HfO2) thin films and their applications

2 ), a series of films ranging in thickness from 50 to 10000 nm was prepared by using an electron beam gun inside an evacuated coating chamber of pressure 1×10^-5 mbar. The films were obtained on optical glass substrate by using oxygen with a backfill pressure of 2.4×10^-4 mbar during the deposition processes. The optical constants of the films were computed in the spectral wavelength region (350–2000 nm) from the transmission, reflection and thickness measurements. A computer program was created to determine two optical parameters n and k of the films, and this was achieved by entering the practical results into the computer program, which solved a series of equations for each wavelength. The effects created by changing various evaporation conditions (thickness, substrate temperature and evaporation rate) were studied in the spectral wavelength range, and the optimum values of the various conditions were obtained while achieving the best optical performance. According to the investigations of the HfO₂ material, two applications of the anti-reflection (AR) multi-layer coatings were achieved in two different spectral wavelength ranges. The first application was measured in the visible and near infra-red (VIS/NIR) range from 500 nm to 850 nm deposited on the glass substrate. The second application was measured in the infrared (IR) range from 7500 nm to 11500 nm deposited on germanium substrate. Computer modelling for designing the optical multi-layer system has been presented. The theoretical formulation and experimental results with the same specification were achieved. The correlation between the theoretical and the experimental results reveals a close agreement that offers a convenient method for predicting and controlling the multi-layer coating. By continuous measurement of the optical and mechanical (durability) performances of the coating process, high-quality films were produced in the manufacture of various optical devices. Received: 16 April 1997/Accepted: 5 August 1997     

Chemical sensing with pulsed QC-DFB lasers operating at 15.6 micrometers

Pulsed thermoelectrically cooled QC-DFB lasers operating at 15.6 μm were characterized for spectroscopic gas sensing applications. A new method for wavelength scanning based on repetition rate modulation was developed. A non-wavelength-selective pyroelectric detector was incorporated in the sensor configuration giving the advantage of room-temperature operation and low cost. Absorption lines of CO₂ and H₂O were observed in ambient air, providing information about the concentration of these species. Received: 29 April 2002 / Published online: 21 August 2002 RID="*" ID="*"Corresponding author. Fax: +1-713/348-5686, E-mail: akoster@rice.edu     

Detection of formaldehyde using mid-infrared difference-frequency generation

3 (PPLN) is reported. Minimum detectable concentration of 30 ppb was achieved with a compact, portable room-temperature gas sensor configured for formaldehyde (H₂CO) detection. This sensitivity, coupled with high selectivity and long term stability, is sufficient for various environmental applications. Received: 29 September 1997     

Soliton-like pulse-shaping mechanism in passively mode-locked surface-emitting semiconductor lasers

We discuss a mechanism that allows the formation of nearly transform-limited soliton-like pulses in passively mode-locked optically pumped external-cavity surface-emitting semiconductor lasers. It involves the interplay of positive dispersion and the nonlinear index changes in gain medium and saturable absorber, while ordinary solitons are based on dispersion and the Kerr effect. The obtained quasi-soliton pulses share some of the properties of ordinary solitons (in particular, their stability and near bandwidth-limited nature), while other properties are different. In particular, the pulse duration scales with the square root of the cavity dispersion, and an excessive drift of the laser wavelength must be avoided by proper design. Received: 23 April 2002 / Published online: 25 September 2002 RID="*" ID="*"Corresponding author. Fax: +41-1/633-1059, E-mail: Paschotta@iqe.phys.ethz.ch     

Measurement and analysis of the electric field in semiconductor lasers by continuous-wave electro-optic probing

The electric field distribution in semiconductor lasers are detected experimentally by using CWEOP (Continuous-Wave Electro-Optic Probing). The paper briefly describes the experimental results. The obtained results reflect several characteristics of the lasers such as injection current, carrier confinement, and the variation of the distribution of the electric field corresponding to different bias conditions.     

Entropy as a measure of the performance of phosphor materials used in medical imaging radiation detectors

In information theory, entropy expresses the information gain obtained after detection of a signal concerning the state of a parameter of interest. In this study, entropy has been expressed in terms of physical quantities (emitted optical fluence and MTF) related to the imaging performance of phosphor materials, which are employed in medical imaging radiation detectors. Four phosphor materials, used in the form of laboratory-prepared fluorescent layers (screens), were compared on the basis of their entropy performance. Measurements were performed using 30- and 80-kVp X-ray beams often employed in X-ray imaging. Results showed that phosphor materials with high density and effective atomic number exhibit high entropy performance, especially at the higher X-ray tube voltage of 80 kVp. Entropy values are also affected by the type of activator, which determines the intrinsic X-ray-to-light conversion efficiency, and the spectrum of emitted light. The proximity of the incident X-ray quanta energy to the energy of the K-shell threshold for photoelectric absorption is an additional important factor which increases entropy. This effect was more apparent in the performance of yttrium-based phosphors at the lower voltage of 30 kVp. Received: 7 January 2000 / Accepted: 28 March 2000 / Published online: 23 August 2000     

Optical fiber tip in front of a phase conjugator: focused light spot with inclusion of evanescent field contribution

 Within the framework of electric dipole approximation, the focused light spot produced by a tiny optical fiber tip in front of a phase conjugate mirror is investigated numerically. The fiber tip is the probe of a reflection scanning near field optical microscope and the incident light is guided through the fiber. Intensity distribution of local field is calculated in the half space where the fiber tip locates. Both homogeneous (q _‖≤ω/c ₀) and part of inhomogeneous (ω/c ₀<q _‖≤ωn/c ₀) fields are included in establishing a field propagator (Green’s function) which is employed to calculate the local field distribution. The local field forms at the tip position a diffraction light spot with a finite central value and a finite size, and when the tip-surface distance is sufficient small, the strength and the shape of the light spot become a function of the distance, which is due to the contribution of evanescent field. Fairly good agreements are found with the existing experimental reports. Received: 30 April 1996/Accepted: 19 August 1996     

Simultaneous CH planar laser-induced fluorescence and particle imaging velocimetry in turbulent nonpremixed flames

jet =18600). Here, PLIF images reveal a CH layer of thickness typically <1 mm from flame base to tip. Furthermore, in these permanently blue flames, we observe instantaneous flamefront strain rates – derived from the PIV data – in excess of ±10⁴ s^-1 without flame extinction. Received: 16 October 1997/Revised version: 30 October 1997     

Photorefractive properties of ion-implanted waveguides in strontium barium niobate crystals

0.61 Ba_0.39Nb₂O₆, SBN61), either by proton or helium ion implantation. Proton-implanted samples show a large increase of dark conductivity that reduces or even prevents the recording of refractive index gratings. For waveguides formed by helium implantation this effect is absent, and they can be used for efficient holographic recording. Photorefractive properties of the waveguides are investigated by two-beam coupling. After implantation with 2.0 MeV He⁺ and doses of (0.5-5)×10¹⁵ cm^-2, the samples have to be polarized again, because heating or charge effects at the crystals surface during the implantation process decreases or even reverses the effective electrooptic coefficients in the waveguiding layer. For repoled samples, we find logarithmic gain coefficients of up to 45 cm^-1 with time constants for the build-up of the purely π/2-shifted refractive index grating of the order of 1 ms for the blue lines of an Ar⁺ laser. Photoconductivity depends nonlinearly on light intensity with an exponent x≈0.55. With increasing implanted helium dose, both electronic and nuclear damage of the waveguiding layer grows, and the photorefractive properties of the waveguides are considerably degraded. Received: 20 February 1997/Revised version: 1 May 1997     

Characterization of p-n junctions and surface-states on silicon devices by photoemission electron microscopy

Received: 22 November 1996/Accepted: 17 December 1996     

Experimental investigation of the optical signal, gain, signal-to-noise ratio and information content characteristics of X-ray phosphor screens

In this study, the quality of medical images produced by X-ray phosphor screens is described by a model based on the light generation and emission properties of the phosphor material. Combined detector gain (CDG), modulation transfer function (MTF), detective quantum efficiency (DQE) and information capacity (IC) of the screens were expressed and evaluated as functions of emitted optical fluence, incident X-ray fluence and emitted optical spectrum. Phosphor screens with coating thickness ranging from 21 mg/cm² to 137 mg/cm² were prepared in the laboratory and were irradiated by X-rays with X-ray voltages from 50 to 140 kVp. Experimental data were obtained in both transmission and reflection modes of measurement (light emission from both screen sides). Results showed that most image quality parameters (CDG, MTF, DQE) depend strongly on phosphor screen thickness. CDG and DQE also depend on X-ray tube voltage. However, the total quantity of information (IC), which depends on both the incident X-ray fluence and phosphor material type, was not found to be significantly affected by phosphor thickness. Received: 7 September 2000 / Revised version: 8 January 2001 / Published online: 27 April 2001