Dynamic properties of blue-phase mixtures

The dynamics of electric-field-induced lattice distortions and phase transitions in the BPI, BPII and BPIII (fog) phases of blue-phase mixtures, which include low-molar-mass and/or polymeric components, have been studied. Several electric-field-induced effects have been observed in the blue phases, and the electro-optic characteristics of the driven and non-driven responses of each are considered. Anomalous behaviour in BPIII, where driven response times were measured to be slower than the relaxation responses, is described and considered with respect to relaxation processes previously observed in BPII. Finally, we present data for a mixture containing 40 per cent by weight of a side-chain-polymer liquid crystal. In this case only BPI was observed, and it appears that the increased viscosity had little effect on the response times of the system. These data are discussed.     

Enlargement of blue-phase stability for rod-like low-molecular-weight chiral nematic liquid crystal mixtures

In this study, we investigated the enlargement of liquid crystal (LC) blue-phase (BP) temperature range using the rod-like low-molecular-weight cyano phenyl-type chiral nematic LC with various core group and chiral dopant concentrations. Also, the electro-optic response time was investigated for them. We found that the BP temperature range was strongly dependent upon the core structure and the chiral dopant concentration for the chiral nematic LC mixtures having the same terminal group. Also, we found a stable BP with a wide temperature range (more than 6 K), including a BP-isotropic coexistence state over 13.5 K upon heating and cooling processes and very fast response time (less than 1 ms), by using the cyano phenyl-type chiral nematic LC mixture with a high molecular aspect ratio and a high chiral dopant concentration.     

Dynamic mechanical properties of epoxy‐phenolic mixtures

The dynamic‐mechanical properties of different mixtures formed by an epoxy resin (DGEBA type) and a phenolic resin (resole type) cured by trietylenetetramine and/or p‐toluensulphonic acid at different concentrations have been studied by means of dynamic mechanical thermal analysis (DMTA). All samples were cured by pressing at 90 °C during 6 h. The mechanical studies were performed between ?100 to 300 °C at a heating rate of 2 °C/min. This study was also carried out for the epoxy‐TETA and phenolic‐p‐toluensulphonic acid systems. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 1548–1555, 2005     

Dynamic scattering properties of mixtures of cyclic and linear homopolymers and copolymers

The dynamic scattering properties of mixtures of cyclic copolymers and homopolymers are discussed. These properties are compared with those characterizing linear chain mixtures in similar conditions. The differences between cyclic and linear chains are introduced through the form factors only. The interaction parameter between different monomer species are assumed to be the same whether they belong to cyclic or linear chains. The dynamical model is based upon a generalization of the random phase approximation neglecting hydrodynamic interaction and mode coupling effects. Despite these simplifications, substantial differences are found in the dynamics of mixtures containing cyclic copolymers and homopolymers when compared to those of linear chain systems in similar conditions of temperature, concentration, and molecular weight. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35 : 1191–1200, 1997     

Dynamic properties of bicellar lipid mixtures observed by rheometry and quadrupole echo decay

In bicellar dispersions of 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and 1,2-dihexanoyl-sn-glycero-3-phosphocholine (DHPC), the transition from isotropic reorientation to partial orientational order, on warming, is known to coincide with a sharp increase in viscosity. In this work, cone-and-plate rheometry, (2)H NMR spectroscopy, and quadrupole echo decay observations have been used to obtain new insights into the dynamics of phases observed in bicellar DMPC/DHPC mixtures. Samples with 25% of the DMPC component deuterated were used to correlate rheological measurements with phase behavior observed by (2)H NMR spectroscopy. Mixtures containing only normal DMPC (DMPC/DHPC) or only chain perdeuterated DMPC (DMPC-d(54)/DHPC) were used to refine rheology and quadrupole echo decay measurements respectively. The viscosity peaked at 4-9 Pa·s, just above the isotropic-to-nematic transition, and then dropped as samples were warmed through the nematic-to-lamellar transition. Quadrupole echo decay times above the nematic-to-lamellar transition were significantly longer than typically observed in the liquid crystalline phase of saturated lipid multilamellar vesicles. This may indicate a damping of slow bilayer undulations resulting from the coupling of opposite bilayer surfaces by DHPC-lined pores.     

Interfacial properties of colloid-polymer mixtures

Density functional theory and a virial approach are used to calculate the surface tension and bending rigidity of the interface between demixed fluid phases for a colloid-polymer mixture. The calculated surface tension compares well with results from computers simulations and experiments. The bending rigidity obtained from both theoretical approaches is negative (approximately equal to -0.1k(B)T), its magnitude increases away from the critical point and it is in reasonable agreement with computer simulations.     

A hysteresis-free polymer-stabilised blue-phase liquid crystal

We report a polymer-stabilised blue-phase liquid crystal (BPLC) in an in-plane-switching (IPS) cell with negligible hysteresis and good stability. Long ultraviolet (UV) wavelength and top-side (no IPS electrode) exposure create uniform polymer network, which in turn helps to suppress hysteresis. The effect of photoinitiator is also investigated. Although a BPLC precursor without photoinitiator requires a higher UV dosage to stabilise the polymer network, it is favourable for keeping high resistivity and reducing image sticking.     

Optimisation of blue-phase liquid crystal with protrusion

The optimised structures of blue-phase liquid crystal display (BPLCD) with various protrusions were discussed in this article. The voltage-dependent transmittances for the cell with four protrusion shapes, wall-shaped electrode, trapezoid electrode, double penetration electrode and elliptical electrode, are simulated. The electrode gap and width and protrusion height’s effects on the optimised cell gap and the corresponding operating voltage are calculated. The optimised cell has the lowest operating voltage and relative high transmittance. The results are significant on design BPLCD with low operating voltage.     

Low-voltage blue-phase liquid crystal display with diamond-shape electrodes

We propose a new electrode configuration, called diamond-shape in-plane switching, to lower the operation voltage of polymer-stabilised blue-phase liquid crystal (BPLC) displays (BPLCDs). The electrode structure is modified from conventional protruded IPS, where the strip protrusion is changed to diamond shape. By optimising the electrode gap and diamond length, we are able to obtain peak transmittance over 75% at 15 V. It enables single thin-film transistor (TFT) driving, and more importantly, this is based on an industrially proven BPLC material. That means good long-term stability, adequate TFT charging time for high-resolution displays and sub-millisecond response time and acceptable voltage-holding ratio for field sequential displays can be achieved simultaneously. Our device design helps accelerate the emergence of the long-awaited BPLCDs.     

Low-gamma shift asymmetrical double-side blue-phase liquid crystal display

ABSTRACT

A single-domain blue-phase liquid crystal display (BPLCD), which has asymmetrical double-side electrode structure, is proposed to reduce gamma shift. Firstly, the electro-optical curve and gamma shift of the proposed BPLCD are discussed under the comparison with conventional in-plane switching (IPS) BPLCD. And then, its gamma shift is investigated under various conditions. Compared with the conventional IPS-BPLCD, the operating voltage can be reduced by ~31%, and the transmittance is increased by ~6%. The indistinguishable gamma shift can be obtained under various electrodes’ sizes, when the cell gap is appropriate. The results also indicate that if the electrodes’ height and Kerr constant of BPLC increase, the operating voltage can be further reduced (only 9.6 V in this work), and the gamma shift almost do not change. Moreover, a certain misalignment between the top and bottom glasses are permitted, which is good for reducing the fabrication difficulty. In terms of viewing angle, the proposed BPLCD has an average contrast ratio of ~5000:1, and the gamma shifts at full viewing angles are all indistinguishable.     

One-dimensional model for simulating blue-phase liquid crystal display

We proposed a one-dimensional model for simulating some performances of blue-phase liquid crystal (BPLC) and polymer-stabilised blue-phase liquid crystal (PSBPLCD). The one-dimensional model treats liquid crystal arrangement of BPLC as cholesteric liquid crystal with high and uniform tilt angle to simulate the Bragg reflection of BPLC. The simulated results agree quite well with the experimental results. The elastic and dynamical equations are formed to calculate the effective elastic parameters and the response times of PSBPLCD. The effective elastic parameter is a constant for low electric field and decreases with the increasing of electric field. The varied effective elastic parameter means the varied restoring force of liquid crystal under the electric field. The dynamical equations are proposed to calculate response times, and the response mechanism of BPLCD is discussed by researching the difference between the decay times from equation and experiment. The sub-millisecond response time results from the weak anchoring of polymer network or the increasing of rotational viscosity of PSBPLC with high-concentration monomer, and the reason of 10 µs response time is the strong anchoring and small amount of chiral dopant and monomer.     

The effects of silica nanoparticles on blue-phase liquid crystals

We investigate the effects of hydrophobic silica nanoparticles (SNs) on blue-phase liquid crystals (BPLCs). The optical microscope and reflection spectra observation reveal that a tiny hydrophobic SN dopant stabilises the BPLC phase, and widens the temperature range of the BP I phase. Furthermore, the doped dilute SNs can fine-tune their positions to relax the formation stress of the BPLC lattices, and slightly increase the platelet sizes of the BPLCs. The doped SNs also decrease the driving voltage and response time of the BPLC cell, because the added SNs decrease the elastic constant of the LC host and the relaxation time constant of the BPLC mixture.     

Polymer encapsulated and stabilised blue-phase liquid crystal droplets

Polymer-encapsulated–polymer-stabilised blue-phase liquid crystals (LCs) are investigated. Encapsulated droplets are formed in a polyvinyl alcohol solution by emulsification, and blue-phase (BP) LCs in the droplets are stabilised via the polymerisation of reactive monomers to extend the BP temperature range. Polymer stabilised droplets are found to cause the expansion of the BP temperature range from 53°C to below 0°C. The effects of composition on droplet formation and the electro-optical behaviour and morphological properties of these droplets are reported.     

Dielectric properties of binary mixtures of n-methylbenzenesulfonamide

The dielectric permittivities of binary mixtures of N-methylbenzenesul-fonamide (N-MBS) with benzyl alcohol, 1,2-dichloroethane, 1,4-dioxane and hexamethylphosphortriamide were measured as a function of mole fraction over the whole composition range at 30 and 50°C. The excess dielectric permittivities and the excess molar polarizations were also calculated. The excess dielectric permittivities ^E and excess molar polarizations P_E were found to be negative for N-methylbenzene-sulfonamide mixtures with benzyl alcohol and 1,4-dioxane, ^E values were positive and P^E values negative for mixtures with 1,2-dichloroethane, and ^E and P^E values were clearly positive for mixtures with hexamethylphosphortriamide. The results are discussed in terms of the strength of the dipolar and hydrogen-bonding interactions between the molecules in various binary mixtures.     

Physiochemical properties of condensed phosphoric acid mixtures

The condensational growth of phosphorus acid is measured as a function of relative humidity and aging time.     

Calorimetric and relaxation properties of xylitol-water mixtures

We present the first broadband dielectric spectroscopy (BDS) and differential scanning calorimetry study of supercooled xylitol-water mixtures in the whole concentration range and in wide frequency (10(-2)-10(6) Hz) and temperature (120-365 K) ranges. The calorimetric glass transition, T(g), decreases from 247 K for pure xylitol to about 181 K at a water concentration of approximately 37 wt. %. At water concentrations in the range 29-35 wt. % a plentiful calorimetric behaviour is observed. In addition to the glass transition, almost simultaneous crystallization and melting events occurring around 230-240 K. At higher water concentrations ice is formed during cooling and the glass transition temperature increases to a steady value of about 200 K for all higher water concentrations. This T(g) corresponds to an unfrozen xylitol-water solution containing 20 wt. % water. In addition to the true glass transition we also observed a glass transition-like feature at 220 K for all the ice containing samples. However, this feature is more likely due to ice dissolution [A. Inaba and O. Andersson, Thermochim. Acta, 461, 44 (2007)]. In the case of the BDS measurements the presence of water clearly has an effect on both the cooperative α-relaxation and the secondary β-relaxation. The α-relaxation shows a non-Arrhenius temperature dependence and becomes faster with increasing concentration of water. The fragility of the solutions, determined by the temperature dependence of the α-relaxation close to the dynamic glass transition, decreases with increasing water content up to about 26 wt. % water, where ice starts to form. This decrease in fragility with increasing water content is most likely caused by the increasing density of hydrogen bonds, forming a network-like structure in the deeply supercooled regime. The intensity of the secondary β-relaxation of xylitol decreases noticeably already at a water content of 2 wt. %, and at a water content above 5 wt. % it has been replaced by a considerably stronger water (w) relaxation at about the same frequency. However, the similarities in time scale and activation energy between the w-relaxation and the β-relaxation of xylitol at water contents below 13 wt. % suggest that the w-relaxation is governed, in some way, by the β-relaxation of xylitol, since clusters of water molecules are rare at these water concentrations. At higher water concentrations the intensity and relaxation rate of the w-relaxation increase rapidly with increasing water content (up to the concentration where ice starts to form), most likely due to a rapid increase of small water clusters where an increasing number of water molecules interacting with other water molecules.     

Thermodynamic properties of binary mixtures containing hydrofluoroether

Excess molar enthalpy and excess molar volume at T =  298.15 K are reported for binary mixtures of (nonafluorobutylmethylether  +  butylmethylether, or nonane, or heptane, or pentane, or 1-propanol, or 2-propoxyethanol). Excess molar enthalpies of the mixture of (nonafluorobutylmethylether  +  1-pentanol) also are reported at T =  298.15 K. The results of excess molar enthalpy are endothermic and the results of excess molar volume are positive in the whole concentration for all the mixtures. The phase separation is found in the range of 0.15  < x <  0.92 for the 1-pentanol system. The results are explained by means of the destruction of the dipolar interactions and hydrogen bonds in the component liquids, the difference of the dispersion interaction, and the formation of the intermolecular hydrogen bonds between unlike molecules.