共查询到12条相似文献,搜索用时 0 毫秒
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Shunqiang Chen JiaJia Fan Zhuangzhuang Cui Lijiang Tan Digen Ruan Xin Zhao Jinyu Jiang Prof. Shuhong Jiao Prof. Xiaodi Ren 《Angewandte Chemie (International ed. in English)》2023,62(23):e202219310
Albeit ethers are favorable electrolyte solvents for lithium (Li) metal anode, their inferior oxidation stability (<4.0 V vs. Li/Li+) is problematic for high-voltage cathodes. Studies of ether electrolytes have been focusing on the archetype glyme structure with ethylene oxide moieties. Herein, we unveil the crucial effect of ion coordination configuration on oxidation stability by varying the ether backbone structure. The designed 1,3-dimethoxypropane (DMP, C3) forms a unique six-membered chelating complex with Li+, whose stronger solvating ability suppresses oxidation side reactions. In addition, the favored hydrogen transfer reaction between C3 and anion induces a dramatic enrichment of LiF (a total atomic ratio of 76.7 %) on the cathode surface. As a result, the C3-based electrolyte enables greatly improved cycling of nickel-rich cathodes under 4.7 V. This study offers fundamental insights into rational electrolyte design for developing high-energy-density batteries. 相似文献
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Chao Wang Xiaoxue Zhao Dabing Li Dr. Chong Yan Qiang Zhang Li-Zhen Fan 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(19):e202317856
In solid-state lithium metal batteries (SSLMBs), the inhomogeneous electrolyte-electrode interphase layer aggravates the interfacial stability, leading to discontinuous interfacial ion/charge transport and continuous degradation of the electrolyte. Herein, we constructed an anion-modulated ionic conductor (AMIC) that enables in situ construction of electrolyte/electrode interphases for high-voltage SSLMBs by exploiting conformational transitions under multiple interactions between polymer and lithium salt anions. Anions modulate the decomposition behavior of supramolecular poly (vinylene carbonate) (PVC) at the electrode interface by changing the spatial conformation of the polymer chains, which further enhances ion transport and stabilizes the interfacial morphology. In addition, the AMIC weakens the “Li+-solvation” and increases Li+ vehicle sites, thereby enhancing the lithium-ion transport number (tLi+=~0.67). Consequently, Li || LiNi0.8Co0.1Mn0.1O2 cell maintains about 85 % capacity retention and Coulombic efficiency >99.8 % in 200 cycles at a charge cut-off voltage of 4.5 V. This study provides a new understanding of lithium salt anions regulating polymer chain segment behavior in the solid-state polymer electrolyte (SPE) and highlights the importance of the ion environment in the construction of interfacial phases and ionic conduction. 相似文献
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Hong-Jun Liu Cheng-Ye Yang Mei-Chen Han Chun-Yu Yu Prof. Xiaofeng Li Prof. Zhong-Zhen Yu Prof. Jin Qu 《Angewandte Chemie (International ed. in English)》2023,62(11):e202217458
Constructing efficient artificial solid electrolyte interface (SEI) film is extremely vital for the practical application of lithium metal batteries. Herein, a dense artificial SEI film, in which lithiophilic Zn/LixZny are uniformly but nonconsecutively dispersed in the consecutive Li+-conductors of LixSiOy, Li2O and LiOH, is constructed via the in situ reaction of layered zinc silicate nanosheets and Li. The consecutive Li+-conductors can promote the desolvation process of solvated-Li+ and regulate the transfer of lithium ions. The nonconsecutive lithiophilic metals are polarized by the internal electric field to boost the transfer of lithium ions, and lower the nucleation barrier. Therefore, a low polarization of ≈50 mV for 750 h at 2.0 mA cm−2 in symmetric cells, and a high capacity retention of 99.2 % in full cells with a high lithium iron phosphate areal loading of ≈13 mg cm−2 are achieved. This work offers new sights to develop advanced alkali metal anodes for efficient energy storage. 相似文献
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Jing Chen Xuetian Deng Yiyang Gao Yuanjun Zhao Xiangpeng Kong Qiang Rong Junqiao Xiong Demei Yu Shujiang Ding 《Angewandte Chemie (International ed. in English)》2023,62(35):e202307255
All-solid-state lithium metal batteries (LMBs) are considered as the promising higher-energy and improved-safety energy-storage systems. Nevertheless, the electrolyte-electrodes interfacial issues due to the limited solid physical contact lead to discontinuous interfacial charge transport and large interfacial resistance, thereby suffering from unsatisfactory electrochemical performance. Herein, we construct an integrated cathode/polymer electrolyte for all-solid-state LMBs under the action of polymer chains exchange and recombination originating from multiple dynamic bonds in our well-designed dynamic supramolecular ionic conductive elastomers (DSICE) molecular structure. The DSICE acts as polymer electrolytes with excellent electrochemical performance and mechanical properties, achieving the ultrathin pure polymer electrolyte thickness (12 μm). Notably, the DSICE also functions as lithium iron phosphate (LiFePO4, LFP) cathode binders with enhanced adhesive capability. Such well-constructed Li|DSICE|LFP-DSICE cells generate delicate electrolyte-electrodes interfacial contact at the molecular level, providing continuous Li+ transport pathways and promoting uniform Li+ deposition, further delivering superior long-term charge/discharge stability (>600 cycles, Coulombic efficiency, >99.8 %) and high capacity retention (80 % after 400 cycles). More practically, the Li|DSICE|LFP-DSICE pouch cells show stable electrochemical performance, excellent flexibility and safety under abusive tests. 相似文献
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Belén F. Alfonso Camino Trobajo Miguel A. Salvadó Pilar Pertierra Santiago García-Granda Jesús Rodríguez-Fernández Jesús A. Blanco José R. García 《无机化学与普通化学杂志》2005,631(11):2174-2180
Polycrystalline intercalated TiMxH2−nx(PO4)2· yC3H7NH2·wH2O compounds with transition metal (TM) ions (Mn+ = Co2+, Ni2+, Fe3+ or Cr3+) have been prepared by means of an indirect route and characterised using X-ray diffraction, scanning electron microscopy, chemical and thermal analysis, X-ray absorption and magnetic measurements. These novel pillared layered materials, which were obtained from the monoclinic (P21/c space group) α-Ti(HPO4)2·H2O phase, lose its crystallinity after intercalation. However all the TM ions are octahedrally surrounded by 6 oxygen atoms, although the X-ray absorption spectra evidence a clear dependence on the temperature. Surprisingly, all the materials behave as paramagnetic down to 1.5 K, but they exhibit different colours, what means that they are optically active (Co2+: violet; Ni2+: pale green; Fe3+: yellow; Cr3+: dark green). 相似文献
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Shantao Han Baifei Wu Huaijiao Wang Peng Wen Lu Zhang Prof. Dr. Xinrong Lin Prof. Dr. Mao Chen 《Angewandte Chemie (International ed. in English)》2023,62(37):e202308724
Dendrite growth on electrode-electrolyte interphase has severely limited applications of lithium metal batteries (LMBs). Here, we developed an ionic alternating polymer with fluorocarbons and phosphonium cations in repeating units to regulate Li deposition for the first time. The combined functionalities in the F/P hybrid polymer exhibit remarkable characteristics as a protective layer on top of Li anode, demonstrating outstanding electrochemical stability, ion flux redistributing capability and adaptive chain mobility. Based on characterizations and simulations, this cationic interlayer could effectively furnish long-standing electrostatic shielding for anodes, allowing restrained coating decomposition and homogenized electric field distribution to induce dendrite-free Li deposition, and enabling full cells with enhanced rate and long-term cycling performance. Given the importance of LMBs, this work will promote polymer design to stabilize anodes with superior electrochemical behavior. 相似文献
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Linhui Chen Rong-Ao Tong Jingxi Zhang Hailong Wang Gang Shao Yanhao Dong Chang-An Wang 《Angewandte Chemie (International ed. in English)》2023,62(27):e202305099
Garnet oxides such as Li6.4La3Zr1.4Ta0.6O12 (LLZTO) are promising solid electrolyte materials for all-solid-state lithium-metal batteries because of high ionic conductivity, low electronic leakage, and wide electrochemical stability window. While LLZTO has been frequently discussed to be stable against lithium metal anode, it is challenging to achieve and maintain good solid-on-solid wetting at the metal/ceramic interface in both processing and extended electrochemical cycling. Here we address the challenge by a powder-form magnesium nitride additive, which reacts with the lithium metal anode to produce well-dispersed lithium nitride. The in situ formed lithium nitride promotes reactive wetting at the Li/LLZTO interface, which lowers interfacial resistance, increases critical current density (CCD), and improves cycling stability of the electrochemical cells. The additive recipe has been diversified to titanium nitride, zirconium nitride, tantalum nitride, and niobium nitride, thus supporting the general concept of reactive dispersion-plus-wetting. Such a design can be extended to other solid-state devices for better functioning and extended cycle life. 相似文献
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商业化锂离子电池石墨负极和锂盐过渡金属氧化物正极材料的储锂容量都已接近各自的理论值,探索下一代高能量密度电极材料是解决现阶段锂离子电池容量限制的关键。近年来,新型金属草酸基负极材料,借助其在金属离子电池中多元化储能机制诱发的较高储能效应在碱金属离子电池绿色储能材料领域备受关注。本文就金属草酸基材料在锂、钠、钾金属离子电池方面的最新研究进行了综述,着重介绍了材料的晶型结构、多元化储能机制及储能过程中的动力学特征,简单阐述了材料在电化学储能中存在的问题,分析了金属草酸基负极材料在形貌晶型控制、界面碳复合改性和金属元素掺杂方面的改性策略。最后,预测了金属草酸基负极材料在碱金属离子电池体系的发展方向。 相似文献
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《Analytical letters》2012,45(12):943-951
Abstract An initial investigation of ion-exchange membranes as trace metal concentrating devices in natural water systems and their suitability as targets for proton-excited x-ray flurorescence (PEXF) is reported. Element maps (Z=19 to Z=85) for various locations along a river were obtained with acceptable sensitivity in an irradiation period of 300 sec. The membrane used is mechanically stable in situ and is not destroyed by the 3 Mev (50 na) proton beam used in the study. 相似文献
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Cover Feature: Alloying in an Intercalation Host: Metal Titanium Niobates as Anodes for Rechargeable Alkali‐Ion Batteries (Chem. Asian J. 3/2018)
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Suman Das Dr. Diptikanta Swain Dr. Rafael B. Araujo Dr. Songxin Shi Prof. Rajeev Ahuja Prof. Tayur N. Guru Row Prof. Aninda J. Bhattacharyya 《化学:亚洲杂志》2018,13(3):219-219
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Cover Picture: Green Template‐Free Synthesis of Hierarchical Shuttle‐Shaped Mesoporous ZnFe2O4 Microrods with Enhanced Lithium Storage for Advanced Li‐Ion Batteries (Chem. Eur. J. 37/2015)
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Prof. Linrui Hou Hui Hua Lin Lian Hui Cao Siqi Zhu Prof. Changzhou Yuan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(37):12813-12813