纳米复合永磁Pr9Fe74Co12B5Snx(x=0, 0.5)的磁化行为与磁黏滞性

用熔体快淬法制备了纳米复合永磁样品Pr₉Fe₇₄Co₁₂B₅ 与Pr₉Fe₇₄Co₁₂B₅Sn_0.5，分析了样品的起始磁化、反磁化过程，测得样品的总磁化率、可逆磁化率以及样品的磁黏滞性.结果表明，两样品在室温下均表现为单一硬磁相磁化行为，在低温下表现为双相行为，且由于添加Sn后使晶粒均匀化从而导致样品低温下的双相行为更加明显.添加Sn后引起样品中软磁相含量和软磁相晶粒尺寸的增加，使磁化反转中可逆磁化部分增多，且使反磁化形核场降低.磁黏滞性研究表明，热激活体积与软磁相晶粒的大小有关. 关键词： 纳米复合永磁 磁化反转 磁粘滞     

不同快淬速度对Nd8Fe85Mo1B6磁性的影响

通过直接快淬制备了不同淬速的Nd₈Fe₈₅Mo₁B₆样品.由振动样品磁强计测量的结果发现,快淬速度对样品的磁性有很大的影响.对样品进行X射线衍射和热磁分析发现,随着淬速的增加样品中的TbCu₇相增多,同时软磁相的晶粒尺寸降低,认为样品的相组成和晶粒尺寸的变化是其磁性存在差异的原因. 关键词：     

Nd28Fe66B6/Fe50Co50双层纳米复合膜的结构和磁性

利用磁控溅射法制备了Nd₂₈Fe₆₆B₆/Fe_{50Co50 双层纳米复合磁性薄膜，研究了其结构和磁性.经873K退火处理15min 后，利用x射线衍射仪测定薄膜晶体结构，采用俄歇电子能谱仪估算薄膜厚度和超导量子干 涉仪测量其磁性.磁性测量表明，1)该系列薄膜具有垂直于膜面的磁各向异性.从起始磁化曲 线和小回线的形状特征可知，矫顽力机制主要是由畴壁钉扎控制.2)对于固定厚度（10nm） 层的硬磁相Nd-Fe-B和不同厚度（dFeCo=1—100nm）层软磁相FeCo双层纳米复合 膜,剩磁随软磁相FeCo 厚度的增加快速增加，而矫顽力则减少.当dFeCo=5nm 时 ，最大磁能积达到160×１０^３A/m.磁滞回线的单一硬磁相特征说明，硬磁相Nd -Fe-B层和软磁相FeCo层之间的相互作用使两相很好地耦合在一起.剩磁和磁能积的提高是由 于两相磁性交换耦合所致. 关键词： Nd-Fe-B/FeCo双层纳米复合膜 交换耦合 磁性增强}     

复相Nd4.5Fe76.3Ga0.3Co1.0B18合金的结构与磁性

利用快淬法制备了Nd_4.5Fe_76.3Ga_0.3Co_1.0B₁₈非晶合金,晶化处理后获得主相为Fe₃B与Nd₂Fe₁₄B的纳米晶永磁材料.采用X射线衍射、透射电子显微镜及磁测量手段分析研究了材料的微观结构与磁性能,并通过测量磁体的δM曲线,研究了晶粒间的交换耦合作用及其与微观结构、磁性能的关系. 关键词：     

Nd2Fe14B/α-Fe双泪永磁合金快淬带的织构与形貌

利用X射线衍射仪和扫描探针显微镜研究了NeFeB系双相永磁合金快淬带的织构与形貌.结果表明,合金快淬带自由面存在择优取向.与三元NdFeB合金相比,复合添加Dy和Ga具有增加合金快淬带织构和细化组织形貌的作用. 关键词：     

压力下Nd60Al10Fe20Co10块体金属玻璃的弹性行为

室温下在等静压最高达～0.5GPa的条件下，利用超声回波技术测量了超声波横波和纵波在Nd₆₀Al₁₀Fe₂₀Co₁₀块体金属玻璃中的传播时间来确定横波和纵波速度.测量时所采用的超声波频率为10MHz.利用所测量的数据，建立了超声波波速、样品的密度、弹性模量以及Debye温度等与所施加的压力之间的相互关系.并且推导出Murnaghan状态方程.另外，基于非晶态与晶态物理性能的相似性，对此块体非晶的压缩曲线、弹性常数和Debye温度等进行了理论计算，结果表明Nd₆₀Al₁₀Fe₂₀Co₁₀块体金属玻璃的弹性性能与其组成的元素有着密切的关系. 关键词： 块体金属玻璃 弹性性能 等静压     

非晶Nd3Fe81B16合金的晶化及其对磁性和M?ssbauer谱的影响

本文报道利用单辊方法制备的非晶Nd₃Fe₈₁B₁₆合金的晶化及其对磁性和M?ssbauer谱的影响。发现在非晶Fe₈₁B₁₉合金中用3at％Nd取代B,使非晶Fe₈₁B₁₉合金的晶化温度提高88℃。在适当的退火条件下晶化后样品在室温下的磁性是:σ_s=189emu/g,σ_r/σ_s=0.7,_iH_c=2.15kOe,B_r≈12kG,_bH_c=2kOe,(BH)_max≈8MGOe。与目前广泛使用的六角铁氧体相比,_bH_c相近,但B_r和(BH)_max远比六角铁氧体高。这种材料仅含有少量的Nd,因此可能开发为一种新的廉价永磁材料。本文对少量Nd的添加对非晶FeB合金的晶化温度,磁性和M?ssbauer谱的影响进行了讨论。初步探讨了高矫顽力的来源,认为它的磁化和反磁化过程可以用畴壁钉扎理论解释。 关键词：     

烧结Nd25.5Dy6.5Co13FebalM1.05B0.98磁体温度稳定性和力学性能研究

本文采用速凝甩带-氢破-气流磨-取向成型-烧结回火等工序,同时添加Dy和Co元素,制备了烧结Nd_25.5Dy_6.5Co₁₃Fe_balM_1.05B_0.98磁体(Co13磁体),室温下磁能积(BH)_max=30.88 MGOe,矫顽力H_cj=19.01 kOe.与Nd₃₀Dy_1.5Co_0.5Fe_balM_1.05B_0.98(35SH)磁体相比, Co13磁体的室温磁性能略低,但温度稳定性显著提升,剩磁温度系数α从–0.136%/℃提升至–0.065%/℃(室温—180℃);居里温度T_C从310℃升高至约454℃;最高使用温度T_W从165℃提升到约200℃.力学性能测试和断口分析表明, Co13磁体中由于Co含量较高,主相晶粒发生解理断裂的比例提高...     

相分离体系Nd1-xSrxCoO3的亚铁磁行为

研究了Nd1-xSrxCoO3(0.1≤x≤0.5)系列多晶样品在低温时的亚铁磁行为.通过传统的固相反应法合成了Nd1-xSrxCoO3多晶样品,应用物理性质测试系统对样品进行了直流磁化强度、磁滞回线的测试.磁化强度的研究表明,随掺杂量增加,团簇的数目和尺寸都在增加,铁磁性增强.同时,多晶样品在低温时形成亚铁磁序.磁滞回线的研究表明,Nd离子与Co离子之间存在磁性耦合.由于Co与Nd的反平行排列,Nd1-xSrxCoO3体系低温时出现亚铁磁序.     

Y3Fe5-xMnxO12的磁结构和磁性能

对多晶Y₃Fe₃Fe_5-xMn_xO₁₂(x=0.05和0.09),得到300K下的中子衍射曲线。发现当x=0.05时,Mn³⁺离子占据16a和24d位置的几率分别为0.72和0.28;当x=0.09时,Mn³⁺离子全部占据16a位置;还得到两种组分16a和24d位置各自的磁矩值。在外磁场(800—10KOe)下测量Y₃Fe_5-xMn_xO₁₂(x=0—0.11)的磁化曲线,温度范围是1.5—300K。得到饱和磁矩值;并利用趋近饱和定律确定1.5K下的磁晶各向异性常数k₁值,发现|k₁|值随含锰量增加而减小。 关键词：     

Nd5Fe18B18 (Nd1.11Fe4B4), a new nowotny-like phase. structural and magnetic properties

The crystal structure of a ternary compound, whose chemical composition is Nd₅Fe₁₈B₁₈, has been determined. Nd atoms on the one hand, Fe and B atoms on the other hand, form 2 different substructures, both of tetragonal symmetry. In a previous investigation¹ only incommensurate or very long period ordering along the $\overrightarrow{c}$ directions between the 2 substructures was proposed, with non-definite composition. The whole structure is now described in the Pccn orthorhombic space group (a=b=7.117Å ; c = 35.07Å). This compound appears then as a new Nowotny-like phase. Fe atoms are essentially non magnetic. Ferromagnetic order between Nd atoms occurs only below 14 K. 2^nd order Crystalline Electric Fiel (CEF) terms are deduced from the anisotropy of the paramagnetic susceptibility. Higher order CEF terms must also be considered.     

Magnetic anisotropy induced in Nd16Fe76B8 by Hf additions

Remanence, coercivity and maximum energy product (BH)_max of Nd₁₆Fe_76−xHf_xB₈ (x=0, 0.1, 0.2) magnets processed under different hydrogenation-disproportionation-desorption-recombination (HDDR) conditions, were studied. Vibrating sample magnetometry results showed that Hf-doped materials develop an important degree of anisotropy, especially for the case of solid-HDDR treatments at 800°C and 850°C, with the largest effect at 850°C. Maximum values of remanence and coercivity were observed for Hf-added samples S-HD at 850°C, and 900°C, respectively. The highest (BH)_max value was also observed in S-HD 900°C Hf-added samples. These results are discussed in terms of the expected microstructure of the intermediate HD and final HDDR processed powders.     

Magnetization and demagnetization behaviours of melt-spun Pr12Fe82B6 and Pr8Fe87B5 ribbons

Nanocrystalline Pr_{12}Fe_{82}B_6 and nanocomposite Pr_8Fe_{87}B_5 ribbons have been prepared using a melt spinning technique. Recoil loops have been measured at 20, 200 and 300K. Demagnetization curves are analysed by dividing it into reversible and irreversible portions. High recoil loop susceptibility at low applied field and large reversible change in the demagnetization curve have been found in Pr_8Fe_{87}B_5 ribbons, showing that the reversible behaviours in nanocomposite permanent magnets originate primarily from the magnetically soft phase. The hysteresis in recoil loops found in Pr_8Fe_{87}B_5 ribbons originates from the soft phase α-Fe that suffers a stress.     

Die-upset Nd11.5Fe72.4Co9Nb1B6.1 magnets with additions of Zn, Al and Sn

The magnetic properties and microstructure were studied for bulk Nd_11.5Fe_72.4Co₉Nb₁B_6.1 magnets synthesized by hot-pressing and subsequent die-upsetting the melt-spun ribbons with additions of three kinds of low-melting-point metal (Zn, Al and Sn). Die-upset Nd_11.5Fe_72.4Co₉Nb₁B_6.1 magnets have low magnetic properties since they have an inhomogeneous microstructure with many coarse grains. The microstructure of die-upset magnets remains almost unchanged with Al and Sn additions, which only have negative effects on the magnetic properties. Different from Al and Sn additions, Zn addition changes the phase composition of the starting melt-spun powers due to the reaction of Zn and Nd₂Fe₁₄B during hot-pressing and hot-deforming and enhances the development of the desired [0 0 1] texture and improves the microstructure of die-upset magnets. As a result, an anisotropic magnet with good maximum energy product (221 kJ/m³) and high coercivity (670 kA/m) is obtained by adding 2 wt% Zn to the Nd_11.5Fe_72.4Co₉Nb₁B_6.1 alloy.     

Domain structures of Nd13Fe80B7 magnets during HDDR process

The domain structures of Nd13Fe80B7 alloy at different stages of the HDDR process have been revealed using a magnetic force microscope. In the as-cast samples, the columnar crystals with easy axis perpendicular to one another are clearly characterized by their different domain structures. For the insufficient and sufficient HD treatment, an obvious change of domain structure occurs, which is related to the variation of composition and crystalline microstructure during the HD process. And for the samples after sufficient DR processing, it is confirmed that the configuration of the columnar crystals is retained by the detected domain structures.     

Magnetic properties of Nd0.9Dy0.1Fe3(BO3)4

The magnetic properties of trigonal Nd_0.9Dy_0.1Fe₃(BO₃)₄ substituted compound with the competitive Nd-Fe and Dy-Fe exchange interactions have been investigated. It has been shown that in Nd_0.9Dy_0.1Fe₃(BO₃)₄ a spontaneous spin-reorientation transition from an ease-axis state to an easy-plane occurs near 8 K. Anomalies of the magnetization curves are observed in a spin-flop transition induced by the magnetic field B‖c. The calculations were performed using a molecular-field approximation and a crystal-field model for the rare-earth subsystem. Extensive experimental data on the magnetic properties of Nd_0.9Dy_0.1Fe₃(BO₃)₄ have been interpreted and good agreement between theory and experiment has been achieved using the obtained theoretical dependences.