共查询到19条相似文献,搜索用时 156 毫秒
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HFC混合物表面张力的预估方程 总被引:1,自引:1,他引:0
表面张力是有沸腾和凝结换热计算必不可少的物性参数,目前国际上已商业化使用或提出的潜在的环保工质,大多数为氢氟烃(HFC)混合物,尤其是R22和R502的替代物、本文应用对比态原理和重正化群理论,提出了一种新的HFC类物质混合物表面张力的预估方程,并与国际上现有的预估式进行了比较分析。新预估式可以在广阔的温度范围内较高精度地再现实验数据,计算精度可以满足工程应用的需要. 相似文献
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新型环保制冷剂氟化醚类物质的热力学分析 总被引:7,自引:1,他引:6
本文筛选了可能作为替代制冷剂的氟化醚类(HFEs)纯物质和混合物,然后对这些工质的制冷循环性能进行了热力学分析。分析结果表明:在醚类纯质及混合物中 c-HFE216、 HFE143a、 c-E2-216、 c-HFE216/HFE143a和c-HFE216/c-E2-216适合替代 CFC12和 HFC134a ; HFE125适合替代 CFC115; HFE134、 HFE245cb β和 HFE143/HFE31-10适合替代 CFC114 ; HFE338mf、 HFE245fa、 HFE143、 HPE263fb、 HFE236ea/HPE245fa和 HFE236ea/HFE143有望成为CFC11的替代物。 相似文献
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使用abinitio计算HF/LANL2DZ方法优化出了基态KrHF为C∞v结构,而基态KrFH为Cs结构,同时,计算了平衡几何和离解能,并用abinitio计算MP2/LANL2DZ方法计算了谐性力常数。应用多体项展式法导出了KrFH(X1A′)体系的分析势能函数,研究了势能面上的主要特征 相似文献
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范德瓦尔斯分子p—C6H4FCH3...Ar外部振动的共振双光子电离光谱 总被引:1,自引:0,他引:1
利用单色共振双光子电离光谱技术研究了p-C6H4FCH3与Ar形成的范德瓦尔斯分子p-C6H4FCh3...Ar电子太跃迁O带附近的光谱,观察到了许多谱带。分析表明,这些谱带,除来自于甲基CH3内转动跃迁外,都可以归属为Ar相对于p-C6H4FCH3的振动跃迁。在用三维谐湃郛波函数一组合作为基和内德-琼斯作用的基础上,借助量子力学方法计算了p-C6H4FCH3...Ar分子中范德瓦斯振动的能级,计 相似文献
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电子被HF和HCl分子散射总截面的计算 总被引:1,自引:1,他引:0
利用光学势方法计算了能量在10eV—1000eV范围内电子被H、F和Cl原子散射的总截面,并与已有的实验结果和理论计算进行了比较;又利用可加性规则(additivityrule)计算得到了电子被HF和HCl分子散射的总截面,计算结果也与已有的实验结果和理论计算进行了比较 相似文献
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KrFH体系的势能函数与反应动力学研究:(Ⅰ)基态KrFH的分析… 总被引:2,自引:1,他引:2
使用abinitioHEF/LANL2DZ方法优化出了基态KrHF为C∞v,基态KrFH为Cs结构,同时,计算了平衡几何和离解能,并用abinitio计算MP2/LANL2DZ方法计算了谐性力学常数。应用多体项展式法导出了KrFH体系的分析势能函数,研究了势能面上的主要特征。 相似文献
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CH2体系激发态的量子化学研究 总被引:1,自引:0,他引:1
本文使用SCF,MCSCF,SOCI方法计算了CH2的基态和三个激发态。讨论了总量,稳定性,平衡几何构型和振动频率等性质。所得结果与实验和理论计算的文献值相吻合,并且预言了一个新激发态c^1∑^+g的性质。 相似文献
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《Heat Recovery Systems and CHP》1993,13(4):373-381
Chlorofluorocarbons (CFCs) are major contributors to the depletion of the ozone layer and additionally they contribute to the greenhouse effect. A review is given of their regulations and current applications as well as their possible environmentally acceptable replacements. A set of statistics is presented of publications on thermophysical properties of hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs). The transport properties of HFC-134a are presented in the form of correlation equations and tables, based on a recent evaluation and correlation of the viscosity and thermal conductivity for a wide range of pressure and temperature. 相似文献
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K. Vokurka 《Czechoslovak Journal of Physics》1985,35(2):121-132
In the paper the range of bubble sizes for which the effects of gravity, surface tension, viscosity, and heat conduction can be neglected is determined. The equations of motion for macrobubbles and microbubbles are also presented. 相似文献
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We developed a new radiation parameterization of hydrofluorocarbons (HFCs), using the correlated k-distribution method and the high-resolution transmission molecular absorption (HITRAN) 2004 database. We examined the instantaneous and stratospheric adjusted radiative efficiencies of HFCs for clear-sky and all-sky conditions. We also calculated the radiative forcing of HFCs from preindustrial times to the present and for future scenarios given by the Intergovernmental Panel on Climate Change Special Report on Emission Scenarios (SRES, in short). Global warming potential and global temperature potential were then examined and compared on the basis of the calculated radiative efficiencies. Finally, we discuss surface temperature changes due to various HFC emissions. 相似文献
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This research is concerned with the problem of heat transfer in a thin liquid layer on a horizontal surface, which evaporates at reduced pressure, when structures shaped as “funnels” and “craters” appear on its surface under the action of vapor recoil force. An approximate model that takes into account the surface tension force, gravity force, vapor recoil force, and disjoining pressure is developed. For the experimentally realized shape of curved surface, in the frames of the model, the distribution of vapor recoil force, temperature, pressure, shear stresses, and local heat fluxes along the interface is found. The density of the heat flux corresponding to appearance of a crater at the place of an array of funnels is estimated. The results are in good agreement with the experimental measurements and the estimates by the Kutateladze formula for the first critical heat flux density. 相似文献
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喷雾冷却具有散热能力强、冷却工质需求量小等优点,在解决电子器件散热方面具有广阔的应用前景。纯水中添加醇类可以有效提升喷雾冷却性能。为进一步探索醇类添加剂强化喷雾冷却性能的机理,本文开展醇水混合溶液表面张力和接触角的实验测定研究。分别在水中加入不同浓度的乙醇、正丙醇、正丁醇、正戊醇、正己醇、正庚醇和正辛醇等醇类,利用悬滴法探究醇类浓度对溶液的表面张力的影响规律;利用Young-Laplace坐滴法探究醇类浓度对接触角的影响规律。结果表明,水中添加醇类后表面张力降低,且其随醇类溶质浓度的增加而变小,且其下降速率均随浓度的增加越来越慢;添加低醇类添加剂均可降低溶液的接触角,而高醇类接触角随浓度变化没有明显的变化规律。 相似文献
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Flow characteristics of a liquid film flowing over a smooth surface and structured surface with the Reynolds number range from 10 to 1121 are studied. The mixture of R21 and R114 refrigerants is used as the test liquid. The 3D transient simulations are taken to capture the liquid film’s dynamic characteristics and spatial distribution. Effects of the inlet dimension, inlet flow rates, surface tension, and surface structuring on the wettability, average velocity, and film thickness are studied systematically. The obtained results show that surface tension is essential for an accurate simulation, while inlet width has no effect on the liquid film parameters in the steady-state flow regime. For low flow rates, wetting area and film thickness both are small, and a suggested range of Reynolds number is chosen to simulate further heat transfer in order to balance the film thickness and dry spots generation. It is shown that a ripple surface structure hinders the liquid film movement, reflected in a lower velocity and a larger film thickness compared to the smooth surface. Lateral movement of a liquid film can also be observed at the structured surface. 相似文献
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Using the method of the parameter expansion up to the third order, explicitly investigates surface tension effect on harmonics at weakly nonlinear stage in Rayleigh-Taylor instability (RTI) for arbitrary Atwood numbers and compares the results with those of classical RTI within the framework of the third-order weakly nonlinear theory. It is found that surface tension strongly reduces the linear growth rate of time, resulting in mild growth of the amplitude of the fundamental mode, and changes amplitudes of the second and third harmonics, as is expressed as a tension factor coupling in amplitudes of the harmonics. On the one hand, surface tension can either decrease or increase the space amplitude; on the other hand, surface tension can also change their phases for some conditions which are explicitly determined. 相似文献