Analysis of elastomeric composites based on fiber-reinforced systems. 2. Unidirectional composites

The elastic properties of unidirectionally reinforced composite materials under large deformations are studied. The applied model for deformation of materials is based on the structural macroscopic theory of stiff and soft composites, including micro- and macromechanical levels of analysis of composite media. The properties of unidirectional elastomeric composites are studied in tension and shear in the plane of reinforcement. The microscopic fields in the structural components of composites having poorly compressible and compressible matrices are also analyzed. Changes in the parameters of macroscopic deformation of the composites are examined as functions of the loading parameters and initial conditions of the structure. The evolution of the structural changes in deformed composite materials is described.State Metallurgical Academy of Ukraine, Dnepropetrovsk, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 1, pp. 29–50, January–February, 1999.     

Analysis of elastomeric composites based on fiber-reinforced systems 3. Two-directional composites

Results of investigation of deformation of elastomeric composite materials with a two-directional reinforcement scheme are presented. The study is performed on the basis of a structural macroscopic theory. The matrix of the composites analyzed is of a poorly compressible material. The fibers of both reinforcing systems are simulated as compressible bodies. Dependences of the parameters of tensile and shear strains on the strain values for different geometries of fiber arrangement are obtained.State Metallurgical Academy of Ukraine, Dnepropetrovsk, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 4, pp. 479–492, May–June, 1999.     

Dependence of elastic and strength characteristics of high-modulus composites on schemes of reinforcement

The elastic and strength characteristics of high-modulus composites with 12 different reinforcement schemes have been studied thoroughly. The effect of reinforcement schemes on change in elastic and strength characteristics of composites has been evaluated. A calculation of the elastic characteristics of high-modulus composites has been performed from the properties of the reinforcement and binder, and a comparison of the results with experimental data is given. Diagrams of deformation upon extension of the composites studied are given.All-Union Scientific-Research Institute of Aviation Materials, Moscow. Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 6, pp. 1019–1027, November–December, 1974.     

Singular approximation of the method of periodic components in statistical mechanics of composite materials

A quasi-periodic model is developed for random structures of composites, when the locations of inclusions are given in terms of random deviations from nodes of an ideal periodic lattice. Solution of the stochastic boundary problem of the theory of elasticity is examined for a quasi-periodic component by the method of periodic components, which is reduced to determination of the field of deviations from the known solution for a corresponding periodic composite. The solution is presented for the tensor of effective elastic properties of a quasi-periodic composite in singular approximation of the method of periodic components in terms of familiar solutions for tensors of the effective elastic properties of composites with periodic and chaotic structures and the parameters of the quasi-periodic structure: the coefficient of periodicity and the tensor of the anisotropy of inclusion disorder. A numerical calculation is performed for the effective transversally isotropic elastic properties of unidirectional fibrous composites with different degrees of fiber disorder.Perm' State Technical University, Russia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 33, No. 4, pp. 460–473, July–August, 1997.     

Theory of spherofibrous composites. 1. Input relationships: Hypotheses and models

A theory is proposed for fibrous composites with a matrix reinforced with spherical hollow and solid inclusions based on an internal stress field and structural models. The problem solutions are obtained for the fiber-averaged matrix level. The matrix properties are determined assuming a regular distribution of the matrix inclusions. The problem of accounting for the scatter of inclusion properties on the effective composite parameters is examined.Presented at the Ninth International Conference on the Mechanics of Composite Materials, Riga, Latvia (October, 1995).A. A. Blagonravov Mechanical Engineering Institute. Russian Academy of Sciences. Moscow, Russia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 32, No. 3, pp. 291–305. May–June, 1996.     

Generalized self-consistent method: Modeling and computation of effective elastic properties of composites with composite or hollow inclusions

A new approach to the generalized self-consistent method [1,2] has been developed for problems of the statistical mechanics of composites with composite or hollow inclusions. The approach can reduce the problem of predicting the effective elastic properties of composites to a simpler averaged problem of a single, composite, or hollow inclusion with inhomogeneous elastic surrounding in a homogeneous effective elastic medium. The problem of predicting the effective elastic properties of composites with unidirectional hollow fibers or hollow spherical inclusions are studied by using the new approach.Submitted to the 10th International Conference on Mechanics of Composite Materials, April 20–23, 1998, Riga, Latvia.Perm' State Technical University, Russia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 2, pp. 173–183, March–April, 1998.     

A generalized self-consistent method for composites with random elastic properties of inclusions

The generalized self-consistent method is extended to the problems of statistical mechanics of composites with random elastic properties of inclusions. This approach makes it possible to reduce the problem of predicting the effective elastic properties of composites with random structures to a sequence of simpler homogenized boundary-value problems for solitary inclusions with inhomogeneous elastic transition layers in a homogeneous effective elastic medium and with the corresponding boundary conditions. The elastic properties of a solitary inclusion for the gth homogenized problem are found from the solutions of the gth and (g+1)th homogenized problems. The elastic properties and sizes of the transition layers account for the random distribution, random sizes, and random elastic properties of inclusions in the composite. A test problem of predicting the effective elastic properties of a transversely isotropic layer composite with random elastic properties of some layers is solved by using the method proposed. The solution obtained coincides with the known exact solution [1].Perm State Technical University, Perm, Russia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 6, pp. 785–796, November–December, 1999.     

Structural approach to calculation of the effect of moisture on elastic characteristics of organoplastics

Data have been obtained for the structural calculation of the effect of moisture on the elastic characteristics of organoplastics from the properties of components. The distribution of moisture between the fiber and matrix — the components of a unidirectional composite — is considered. The elastic properties of the fiber are determined by an inverse calculation using the experimental dependences of the composite and matrix on moisture. The moisture effect on the properties of the materials is taken into account with influence functions, which differ by more than 25% for various characteristics. The results can be used for calculating the elastic properties of composites with various reinforcement schemes and at the nonequilibrium distribution of the moisture concentration in an actual environment.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Institute of Polymer Mechanics, Riga, LV-1006, Latvia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 4, pp. 525–530, July–August, 1998.     

Structural theory of elastomeric composites based on fiber systems — Invariant description

A three-dimensional theory of elastomeric composites with elastomeric matrices reinforced by systems of fibers is presented. The theory is based on a structural approach in which the matrix and the reinforcement of the composite are considered separately without reduction to a medium having continuously changing characteristics. The approach is based on the idea of a vector field of macroscopic displacements given by the positions of the axial lines of the fibers in the curret (deformed) configuration of the composite. The vector field determines the current macroscopic configuration, the tensor fields of the measures of macroscopic strain, and the field of the macroscopic stress tensor in the composite. The displacement, strain, and stress fields in the elastomeric matrix and the fibers of the reinforcing systems are regarded as derivatives of the field of macroscopic displacements of the medium. Relations are presented to describe the kinematics of the fibers in the current configuration of the composite, including the evolution of their orientation and the frequency of their planar and spatial distribution. Equations are obtained for the macroscopic motion of the fiber-reinforced matrix, and the dynamic variational principle that governs this motion is established. The elastic macroscopic potential of the matrix is found and related to the components of the macroscopic stress tensor. The procedure to be followed in constructing the constitutive equations of the composite is described. The proposed system of equations, relations, and algorithms is closed and can be used to solve problems involving the deformation of products made of fiber-reinforced elastomers and the creation of elastomeric composite products, based on fiber systems, that possess the requisite properties.     

Composites reinforced with a system of three straight mutually orthogonal fibers

The effectiveness of reinforcement in direction 3 has been estimated by investigating the mechanical characteristics of two types of three-dimensionally reinforced materials differing with respect to the arrangement of the reinforcement and the fiber content in each direction. The superior transverse stiffness, shear strength, and transverse tensile strength of three-dimensionally reinforced composites based on a system of three mutually orthogonal fibers, as compared with laminated materials, is demonstrated. The theoretical values of the elastic constants, calculated from the relations of [5], are compared with the experimental data.For communication 1 see [5].Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 6, pp. 1011–1018, November–December, 1973.     

Determination of rational structure for spherofibrous plastics

A complete set of elastic constants for various structures of triorthogonally reinforced plastics with a matrix dispersely reinforced by spherical particles has been determined on the basis of the proposed algorithm. Approximate equations are obtained for determination of all integral parameters from data on the components and structure geometry. It is established that for the reinforcement schemes investigated, the shear moduli of the composites have the lowest possible values and are calculated with a higher accuracy than the other elastic constants.A. A. Blagonravov Institute of Machine Science, Russian Academy of Sciences. Moscow, Russian. Translated from Mekhanika Kompozitnykh Materialov, Vol. 33, No. 2, pp. 155–160, March–April, 1997.     

Averaging the physical properties of fibrous piezocomposites

Elastic, piezoelectric, and dielectric properties of fibrous composites with piezoelectric components are averaged for antiplane strains. Methods for determining coupled electroelastic fields in piezocomposites are proposed. Calculation results of the effective physical characteristics of some composites are given.Sumskii State University, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 1, pp. 116–123, January–February, 1998.     

Control of the elastic properties of a shell working at stability

This examines a shell with elastic properties varying across the coordinates, which are prescribed by means of scalar functions of the invariants of the elasticity tensor. The basis of the arrangement of the tensor for the elasticity consists of q linear-independent tensors of the fourth range (q is the number of linear-independent components of the elasticity tensor) which are obtained by multiplying and turning the first tensor of the surface and the tensor characterizing the class of symmetry of the medium. The invariants of the elasticity tensor present in the stability equation and their derivatives are taken to be the equations and parameters for the state of the system (shell), and the problem is thus reduced to a problem of optimum equations. As an example we shall examine an orthotropic cylindrical shell with a model varying over the length under the action of external pressure.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 1, pp. 93–100, January–February, 1974.     

Multi-objective optimization of composite structures. A review

Studies performed on the optimization of composite structures by coworkers of the Institute of Polymers Mechanics of the Latvian Academy of Sciences in recent years are reviewed. The possibility of controlling the geometry and anisotropy of laminar composite structures will make it possible to design articles that best satisfy the requirements established for them. Conflicting requirements such as maximum bearing capacity, minimum weight and/or cost, prescribed thermal conductivity and thermal expansion, etc. usually exist for optimal design. This results in the multi-objective compromise optimization of structures. Numerical methods have been developed for solution of problems of multi-objective optimization of composite structures; parameters of the structure of the reinforcement and the geometry of the design are assigned as controlling parameters. Programs designed to run on personal computers have been compiled for multi-objective optimization of the properties of composite materials, plates, and shells. Solutions are obtained for both linear and nonlinear models. The programs make it possible to establish the Pareto compromise region and special multicriterial solutions. The problem of the multi-objective optimization of the elastic moduli of a spatially reinforced fiberglass with stochastic stiffness parameters has been solved.The region of permissible solutions and the Pareto region have been found for the elastic moduli. The dimensions of the scatter ellipse have been determined for a multidimensional Gaussian probability distribution where correlation between the composite's properties being optimized are accounted for. Two types of problems involving the optimization of a laminar rectangular composite plate are considered: the plate is considered elastic and anisotropic in the first case, and viscoelastic properties are accounted for in the second. The angle of reinforcement and the relative amount of fibers in the longitudinal direction are controlling parameters. The optimized properties are the critical stresses, thermal conductivity, and thermal expansion. The properties of a plate are determined by the properties of the components in the composite, eight of which are stochastic. The region of multi-objective compromise solutions is presented, and the parameters of the scatter ellipses of the properties are given.Translated from Mekhanika Kompozitnykh Materialov, Vol. 32, No. 3, pp. 363–376, May–June, 1996. Institute of Polymer Mechanics, Latvian Academy of Sciences, Riga.     

Viscoelasticity of liquid-crystalline copolymer/poly(methyl methacrylate) blends. Effect of reinforcement by aluminum borate whiskers

The elastic moduli and mechanical losses for blends of liquid-crystalline copolyester (LCP) and PMMA have been determined at various temperatures. The specimens were produced by the extrusion of preliminary mixed components. In the course of extrusion, a system is formed where the LCP forms thin fibers imbedded into a PMMA matrix. The greatest effect of the reinforcement of the thermoplastic matrix with LCP was found for a 7/3 ratio of components. The effect of fillers (whiskers) was also investigated. It is shown that the reinforcing action of the filler is much higher for the 7/3 blends as compared with the reinforced pure components. The effects observed are explained by features of the interphase formation in the reinforced systems and the surface segregation of an LCP-component.Institute of Macromolecular Chemistry, Kiev, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 33, No. 5, pp. 681–689, September–October, 1997.     

Anisotropy of torsional rigidity of sheet polymer composite materials

Wide application of polymer composite materials (PCM) in modern technology calls for detailed evaluation of their stress-strain properties in a broad temperature range. To obtain such information, we use the dynamic mechanical analysis and with the help of a reverse torsion pendulum measure the dynamic torsional rigidity of PCM bars of rectangular cross section in the temperature range up to 600 K. It is found that the temperature dependences of the dynamic rigidity of the calculated values of dynamic shear moduli are governed by the percentage and properties of the binder and fibers, the layout of fibers, the phase interaction along interfaces, etc. The principles of dynamic mechanical spectrometry are used to substantiate and analyze the parameters of anisotropy by which the behavior of a composite can be described in the temperature range including the transition of the binder from the glassy into a highly elastic state. For this purpose, the values of dynamic rigidity are measured under low-amplitude vibrations of the PCM specimens with a fiber orientation angle from 0 to 90°. It is shown that for unidirectional composites the dependence between the dynamic rigidity and the fiber orientation angle is of extreme character. The value and position of the peak depend on the type of the binder and fibers and change with temperature. It is found that the anisotropy degree of PCM is dictated by the molecular mobility and significantly changes in the temperature range of transition of the binder and reinforcement from the glassy into a highly elastic state (in the case of SVM fibers). The possibility of evaluating the anisotropy of composites with other reinforcement schemes, in particular, of orthogonally reinforced PCMs, is shown.Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 3, pp. 291–308, May–June, 1999.     

Analysis of Elastomeric Composites Based on Fiber Systems. 4. 3D Composites

The elastic properties of 3D elastomeric composite materials under large deformations are considered. The investigation is based on the structural macroscopic theory of stiff and soft composites. The results of micro- and macromechanical analyses of composite materials with compressible and poorly compressible matrices are presented. The character of interaction between the fibers of various reinforcing systems in these matrices is revealed. The deformation characteristics of the composites in tension and shear are presented as functions of their orientation and loading parameters. The evolution of the configuration of a composite material with a compressible matrix during loading is traced.     

Evaluating the effect of whiskerization of the fibers of composites on the fundamental frequency of a laminated cylindrical shell

Conclusion The calculations showed that whiskerization of the reinforcement of the structural material of multilaminate shells makes it possible in some cases to increase the fundamental vibration frequency of the structure up to 15–20%. In combination with the well-known [1] effect of improved strength characteristics for a whiskerized composite in the transverse and shear directions, this finding allows us to conclude that whiskerized structural materials are more efficient than ordinary laminated composites in shell-type load-bearing structures. Here, the greatest benefit can be expected in the case of whiskers which have higher elastic moduli than the main reinforcement. Since considerably higher reinforcement intensities can be achieved in whiskerized laminated composites than in composites with a reinforcement characterized by an arbitrary three-dimensional structure, it can be concluded on the basis of the results obtained here that, at least for shells of moderate thickness (10 < R/h 50), whiskerized composites are the optimum structural material for load-bearing shells.Translated from Mekhanika Kompozitnykh Materialov, No. 6, pp. 1022–1027, November–December, 1987.     

Modern trends in the development of fibrous composites

The two main trends in the development of high-modulus composites are considered. Improved methods of calculation sensitive to the effects associated with the weak shear and transverse characteristics are reviewed. It is shown that the disadvantages of composites with a traditional arrangement of the reinforcement can be overcome. The properties of boron- and carbon-reinforced plastics with a traditional reinforcement structure are described and compared with those of three-dimensionally structured materials with two- or three-strand reinforcing. Whiskerized fiber reinforcement is also considered. A program of further research on high-modulus composites is outlined.Presented at the 2nd All-Union Conference on Polymer Mechanics, Riga, November 10–12, 1971.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 3, pp. 541–552, May–June, 1972.     

Effect of combined extrusion parameters on mechanical properties of basalt fiber-reinforced plastics based on polypropylene

Basalt fibers are efficient reinforcing fillers for polypropylene because they increase both the mechanical and the tribotechnical properties of composites. Basalt fibers can compete with traditional fillers (glass and asbestos fibers) of polypropylene with respect to technological, economic, and toxic properties. The effect of technological parameters of producing polypropylene-based basalt fiber-reinforced plastics (BFRPs) by combined extrusion on their mechanical properties has been investigated. The extrusion temperature was found to be the main parameter determining the mechanical properties of the BFRPs. With temperature growth from 180 to 240°C, the residual length of the basalt fibers in the composite, as well as the adhesive strength of the polymer-fiber system, increased, while the composite defectiveness decreased. The tensile strength and elastic modulus increased from 35 to 42 MPa and 3.2 to 4.2 GPa, respectively. At the same time, the growth in composite solidity led to its higher brittleness. Thus, a higher temperature of extrusion allows us to produce materials which can be subjected to tensile and bending loads, while the materials produced at a lower temperature of extrusion are impact stable. The effect of the gap size between the extruder body and moving disks on the mechanical properties of the BFRPs is less significant than that of temperature. An increase of the gap size from 2 to 8 mm improves the impregnation quality of the fibers, but the extruder productivity diminishes. The possibility of controling the properties of reinforced polypropylene by varying the technological parameters of combined extrusion is shown. The polypropylene-based BFRPs produced by the proposed method surpass the properties of glass and asbestos fiber-reinforced plastics.Submitted to the 10th International Conference on Mechanics of Composite Materials (Riga, April 20–23, 1998).Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 33, No. 6, pp. 845–850, November–December, 1997.