共查询到19条相似文献,搜索用时 125 毫秒
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本文研究了1,10-双(1'-苯基-3'-甲基-5'-氧代吡唑-4'-基)癸二酮-[1,10](H2A)与1,10-菲罗啉(phen)或2,2'-联吡啶(dipy)对Co(Ⅱ)的协同萃取行为。确定了协萃配合物的组成为CoA.B(B分别为phen和dipy),求得萃取平衡常数logKex分别是4.78(H2A+phen)和1.61(H2A+dipy),并对协萃配合物的IR谱进行了讨论。 相似文献
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伯胺N1923萃取醋酸的研究 总被引:4,自引:1,他引:3
研究了伯胺N1923萃取醋酸(HAc)的机理.利用对应溶液法确定了萃取平衡,求得平衡常数;辅以饱和法、红外光谱法确认萃合物的组成为N1923·HAc,N1923·2HAc和N1923·3HAc.初步探讨了温度对萃取平衡的影响和进行反萃的条件. 相似文献
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本文研究了1,10-双(1'-苯基-3'-甲基-5'-氧代吡唑-4'-基)癸二酮-[1,10](H2A)与1,10-菲罗啉(phen)或2,2'-联吡啶(dipy)对Co(Ⅱ)的协同萃取行为.确定了协萃配合物的组成为CoA·B(B分别为Phen和dipy),求得萃取平衡常数logKex分别是4.78(H2A+phen)和1.61(H2A+dipy),并对协萃配合物的IR谱进行了讨论. 相似文献
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三正辛基氧化膦萃取钯的研究 总被引:6,自引:0,他引:6
本文研究了用三正辛基氧化膦(TOPO)煤油溶液从盐酸介质中萃取钯及用硫脲反萃钯的条件。用等摩尔系列法、饱和法、化学分析法和斜率法确定了萃合物的组成。用紫外-可见光谱法探讨了TOPO萃取钯的机理。 相似文献
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苯基硫脲—磷酸三丁酯二元中性体系对钯的协同萃取研究 总被引:1,自引:1,他引:1
本文研究了苯基硫脲-磷酸三丁酯组成的二元中性体系在HCl介质中Pd(II)的萃取行为,发现该体系有明显的协同萃取效应。实验证明:在0.5-6mol/L HCl介质中,该体系能定量萃取Pd(II)。文中研究了萃取的最佳条件,试验了反萃取条件及共存离子对Pd(II)萃取的影响。用斜率法测得萃合物的组成为Pd:PTU:PTB=1:2:2,采用电子吸收光谱及红外光谱对协萃机理及萃合物的结构作了探讨。 相似文献
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双(十二烷基亚磺酰)乙烷溶剂萃取钯及其机理的研究 总被引:2,自引:0,他引:2
本文研究用双(十二烷基亚磺酰)乙烷萃取钯的性能,在KI存在下从7mol/L盐酸介质中用含有BDSE的氯仿能定量萃取钯,有机的钯可被硫脲或氨溶液反萃继之用TMK-TritonX-100光度法测定,研究了萃取的最佳条件及干扰情况,斜率法测得萃合物组成为Pd:I:BDSE=1:2:1,红外光谱证实萃合物中BDSE的二个亚砜以硫原子与钯配位,萃合物为异位体络合物,提出了选择性萃取分离钯的新方法。 相似文献
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研究了二(2,4,4-三甲基戊基)膦酸(BTMPPA,HA)的正辛烷溶液从盐酸介质中萃取钍(Ⅳ)的机理。在未控制离子强度下,萃取平衡反应为:,在控制离子强度为1.0mol/L时,萃取反应为用饱和法确定的萃合物组成为ThCIA_3.计算了萃取反应的平衡常数及热力学函数。研究了饱和萃合物的IR和NMR谱。 相似文献
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《Journal of Coordination Chemistry》2012,65(1):47-56
Abstract Theoretical studies were carried out on a series of bis(phosphine) palladium ketene complexes (PR3)2Pd(CH2=C=O), and on the related CH2=C=O and Pd(PR3)2 molecular fragments in order to investigate the electronic structure and the bonding of the ketene ligand to the metal fragment in these complexes. An analysis of the frontier MOs has been performed in order to understand the interactions between the ketene and the metal fragments. The calculated results have shown that the η2-(C,C) mode is preferred over the η2-(C,O) mode by 10–15 kcal/mol in bis(phosphine) palladium ketene complexes. The basicity and bulkiness of the phosphine ligands PR3 have little effect on the bonding mode in (PR3)2Pd(CH2=C=O) complexes. The most stable structure was calculated to be the η2-(C,C) square planar geometry with the CH2 group of ketene out of the molecular plane. Comparison and discussion between the two bonding modes were also presented in this paper. 相似文献
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A natural polymer catalyst, sillca-supported chitosan palladium complex (abbr. asSiO_2-CS-Pd) was found to catalyze the hydrogenation of phenol and cresols to correspond-ing cyclohexanones in high yield and 100% selectivity at 70℃ and 1.01325×10~5 Pa mildconditions. N/Pd molar ratio in the complex, temperature and solvents have much infiuenceon the reaction. The reactivity order of reactants was found to be: phenol >m->p->o-cresol. The catalyst is stable during the reaction and could be repeatedly used for severaltimes without much decrease in its catalytic activity. 相似文献
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A new type of palladium chelate of β-diketone-based side chain liquid crystal polysiloxane (Pd-DKLCP) has been synthesized by chelation reaction of palladium dichloride with polymeric ligand, β-diketone polysiloxane (DKLCP), using THF as solvent at R.T.. The Pd-chelation results in greatly increasing the phase transition temperature T_K and the enthalpy change △H_K from crystal to liquid crystal state and making the temperature range of LC state △T(△T=T_(Cl)-T_K) widened. All these chelates Pd-DKLCP's do not show T_(Cl) until decomposition at 205℃. It is noteworthy that the Pd-chelation can exert more positive effect on the mesomorphic behaviour of the polymer ligand than the counterpart Cu-DKLCP does. It is probable due to the bigger size of disc-like mesogen formed from β-diketone and Pd~(+2) ion with 4d orbital. 相似文献
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《Journal of Coordination Chemistry》2012,65(3-4):209-216
Abstract By reaction of palladium halides with D,L-ethionine (D,L-EthH; molar ratio 1:1) in dichloromethane solutions containing an excess of 2,6-dimethyl-4H-pyran-4-one (DMP) [Pd(D,L-EthH)X2] (X?Cl, Br or I) complexes have been isolated. When the solvent was benzene [Pd(D,L-EthH)X2].DMP adducts were obtained in which the DMP molecule does not bind to the metal. The complexes have been characterized by infrared and nmr (1H and 13C) spectroscopy and by thermogravimetric measurements (TG, DTG and DTA). The importance of DMP in determining the reaction course is discussed. 相似文献
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S. J. Sabounchei V. Jodaien S. Samiee 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):473-481
Complexes of the type NBu 4 MCl 3 PR 3 R=P.Tolyl,Ph,Bu) (M = Pt, Pd) are prepared by the reaction of MCl 2 or K 2 [MCl 4 ] by phosphine ligands. Addition of NBu 4 Br or NBu 4 I to these compounds, in dichloromethane results in a redistribution of halogens and formation of all six isomers of the type MBr 3 ?XClXPR 3 X= 0, 1, 2, and 3 which have been identified by 31 P- 1 H NMR spectroscopy. The intensities show that the products are proportional to the statistical distribution. 相似文献
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N,N(二甲庚基)乙酰胺萃钯机理研究 总被引:2,自引:0,他引:2
本文研究了N,N二甲庚基乙酰胺(N_(s03))从氯化物体系中萃取钯的机理。应用等摩尔系列法和斜率法确定萃合物组成为:(CH_3CONR_2H)_2PdCl_4。通过紫外-可见光谱法研究,证实N_(503)萃取钯的机理属阴离子交换反应,其萃取方程式为: 2CH_3CONR_2HCl_((o)) PdCl_4~(2-)(a)?(CH_3CONR_2H)_2PdCl_4(o) 2Cl~-(a) 相似文献
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β羟肟、硫醚等在盐酸介质中萃取钯(Ⅱ)的配位取代反应具有较高的选择性,有实用意义[1-5]。Cleare等[1]曾提出加入胺类化合物以加快β羟肟萃钯的速度。本文在研究β羟肟萃钯(Ⅱ)机理[2,3]的基础上考察了加入伯胺后2-羟基-4-(1-甲基庚氧基)二苯甲酮肟(HL)萃取钯(Ⅱ)的热力学和动力学行为以及界面特性,试图阐明伯胺对该取代反应的加速机理。试验所用伯胺N1923(Am)为混合支链伯胺,上海有机所实验厂生产。水相中伯胺含量用溴酚兰分光光度法测定[6],其它实验方法参见[3]。 相似文献
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《Journal of Coordination Chemistry》2012,65(3-4):281-288
Abstract Reactions of a series of binuclear, phosphine bridged late transition metal complexes, Pd2Cl2(dppm)2, Pd2Cl2(dmpm)2, Pd2Cl2(Ph2Ppy)2, Pt2Cl2(dppm)2, and Ag2Br2(dppm)2, with Me3SiX (X = Br, I), Me3GeBr and Me3SnBr were examined by 31P NMR spectroscopy. Rapid exchange of Pd-Cl, Pt-Cl and Ag-Br bonds for Pd-X, Pt-X (X = Br, I) and Ag-I bonds was observed to be independent of the nature of the phosphine ligand, the nature of the metal center or the group IV element. Differences in Lewis acidity of the transition metal center as a function of the ligands and the identity of the transition metal and differences in the basicity of the Me3EBr ligands are proposed to account for the failure to detect intermediates in these reactions similar to those reported for reactions between Pd2Cl2(dppm)2 and Me3SiX. 相似文献