S0-S1 two photon absorption dynamics of organic dye solutions

The two-photon absorption cross-sections and excited-state absorption cross-sections of the dyes rhodamine 6G, methylene blue and fuchsin dissolved in methanol, and of the dyes safranine T, 1,3,3,1,3,3-hexamethylindocarbocyanine iodide (HMICI) and 1,3,1,3-tetramethyl-2,2-dioxopyrimidi-6,6-carbocyanine hydrogen sulphate (PYC) dissolved in hexafluoroisopropanol (HFIP) are determined. The excitation is achieved with picosecond light pulses of a passively mode-locked Nd-glass laser (_L = 1.054m). The influence of amplified spontaneous emission on the two-photon absorption dynamics is analysed.     

The effect of preliminary aging at various temperatures on the mechanism of the subsequent aging of EI702 steel

It is shown that the preliminary continuous precipitation of the -phase inhibits the subsequent discontinuous precipitation of this phase even after heavy cold working. The rate of discontinuous decomposition is found to increase with a small reduction of the quenching temperature into the two-phase region.     

Energy relations in sound propagation in porous materials with rigid skeleton

The paper deals with the determination of the frequency dependence of the acoustic resistance, of the structure factor, the porosity factor and the constant giving whether the process in the propagation of sound in porous materials with a rigid skeleton is isothermal, adiabatic or polytropic. The latter dependence enables a conclusion to be reached on the energy relations during sound propagation in porous materials.The derivation of the wave resistance and of the constant of wave propagation in a porous material with a rigid skeleton is given and a method described for calculating the constants characterizing the material on the basis of measurements of the wave resistance and the acoustic impedance of the material. The calculation was carried out for felt and it was found that the acoustic resistance and structure factor depends on the frequency and that the process at low frequencies approaches the isothermal and at high frequency the adiabatic. It is shown that the structure factor is not equal to unity even in order of magnitude, as is often assumed in the literature. It is shown that for a complete knowledge of the acoustic resistance necessary for the calculations it is not enough to determine it by the static method.

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The work was carried on through the cooperation of the Research Institute of Sound, Image and Reproduction Technique and the department of physics at the Electrotechnical Faculty of the Czech Technical University in Prague. The authors would like to thank Prof. J. B. Slavík, head of the department of physics, and M. Jahoda, director of the Research Institute of Sound, Image and Reproduction Technique, for the attention they paid to this work.     

Characteristics analysis of metal-clad and absorptive dielectric waveguides by a simple and accurate perturbation method

We present a simple and accurate method for characteristic analysis of metal-clad dielectric waveguides and absorptive waveguides. The real partN of the complex modal indexN=N + iN is obtained by solving the corresponding real eigenvalue equation, and the imaginary partN is given by (n/), where= + i is the complex dielectric constant of the absorptive layer, and N/ is obtained by numerical differentiation. The method is straightforward, and the cumbersome solution of complex transcendental equations is completely eliminated. Results for simple structures are in good agreement with those obtained by exact analysis.     

ИЗЛУЧЕНИЕ ЭЛЕКТРИЧЕ СКОГО ДИПОЛЯ НАД ГРАН ИЦЕЙ ДВУХ СРЕД

, , . , - - . - . -, - , . , - ; , , .     

ЧАстИЧНО пОгРУжЕННы И БлОк В кВАДРАтНОИ РЕ шЕткЕ

( ) , . , . [1] , , .

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Partially inserted block in square lattice

The paper gives a theory of the partially inserted block (control rod) in a reactor of finite height, consisting of a square lattice of fuel blocks and a moderator. The partially inserted block replaces the block of the original lattice which was located in the axis of cylindrical symmetry of the reactor. The results obtained agree with the relations for a homogeneous medium in paper [1] and are thereby justified for homogeneized reactors.

     

A solution spectrum of the nonlinear Schrödinger equation. II

It was shown in a previous communication that the nonlinear Schrödinger equation exhibits a spectrum of eigenfunctions of the form = _k,A _k (coshkx) ^–k and = _k B _k (coshkx) ^–k–1sinhkx, and the corresponding eigenvalues of the energy are related to a band structure with a characteristic energy gap as a significant feature. In the present paper, it is shown that a further spectrum exists exhibiting the general structure = _k=0 A _k(cosh kx)^–k–1/2and = _k=0 B_k(cosh kx)^–k–3/2sinhkx and yielding also a band structure. An extension of the solution spectrum to a nonlinear Klein-Gordon equation and a nonlinear Dirac equation does not imply essential difficulties, and the corresponding characteristic band structure has to be related to a mass spectrum.     

On the theory of ferromagnetic thin films

As is known, the second approximation in the calculation of the partition function by the traces method of ferromagnetic thin films gives wrong results for the coordination number equal to eight. In order to obtain correct results even for this case, the third order approximation of the partition function is developed and thus the magnetic properties of body-centred cubic iron thin films are studied. The dependence of the Curie temperature on the thickness, for different values of the ratio between the anisotropy constant and the exchange energy between two neighbours, is discussed. A value can be chosen for this ratio such that the thin film becomes ferromagnetic only for a thickness greater than a definite value.

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More inequalities for critical exponents

A variety of rigorous inequalities for critical exponents is proved. Most notable is the low-temperature Josephson inequalitydv +2 2–. Others are 1 1 +v, 1 1 , 1,d 1 + 1/ (for d),dv, ₃ + (for d), ₄ , and _{2m 2m+2} (form 2). The hypotheses vary; all inequalities are true for the spin-1/2 Ising model with nearest-neighbor ferromagnetic pair interactions.NSF Predoctoral Fellow (1976–1979). Research supported in part by NSF Grant PHY 78-23952.     

Honeycomb domain structure

A theory is given of a new structure produced when demagnetizing uniaxial single crystals (e.g. magnetoplumbite) in a field normal to thec axis. The experimental results fully support the theory on the assumption that domain structures produced under normal conditions are metastable. Methods are given by which stable structures can be prepared from such metastable ones. On the basis of these results opinions are expressed as to the nucleation of plate and honeycomb structures, produced either by reducing the field from saturation or by cooling below the Curie point.

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, (, ) , c. , , , , , . , . , .

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In conclusion the authors would like to thank C. Novák from the Institute of Technical Physics, Czechoslovak Academy of Sciences, for checking the calculation of the harmonic analysis and Z. Málek and J. Eousek for carefully reading the paper and for valuable remarks.     

Photo-luminescence and growth defects in ZnS: Cu monocrystals

The paper describes microscopic investigation into the spectral distribution of photo-luminescence and its polarization on hexagonal ZnS monocrystals in relation to the structural defects of such crystals. These observations, as well as birefringent observations, show that the values of the birefringence and the degree of polarization in different stripes of the same crystal are the same within the limits of observational errors.

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ZnS: Cu

ZnS . , , , .

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In conclusion the author would like to thank K. Pátek, L. Souková and M. Mokonová for providing the monocrystals and for fruitful discussions.     

Excition dynamics in the J-aggregates of a carbocyanine dye

We report on the exciton dynamics in the J-aggregating dye 5,5, 6,6-tetrachloro-1,1-diethyl-3,3-di(4-sulfobutyl)-benzimidazolocarbocyanine which is known readily to form J-aggregates, even at room temperature and at a low concentration. We performed a series of time-correlated singlephoton-counting experiments at different emission wavelengths and at different temperatures in the range between 1.5 and 125 K. Additionally, the temperature dependence of the relative fluorescence quantum yield was determined.     

МОДЕЛИРОВАНИЕ ЭЛЕКТ РОННО-ОПТИЧЕСКИХ СИС ТЕМ С ОСЕВОЙ СИММЕТРИЕЙ П РИ ПОМОЩИ СЕТИ СОПРОТИВЛЕНИЙ

The paper explains the theory of modelling electrostatic fields by a resistance network. The conditions, which the resistance network must satisfy, are derived and the question of modelling electrodes of different shapes is solved. The finished network and the results obtained on it when modelling a jet for a linear h-f accelerator of electrons are described. Particular attention is paid to the influence of a space charge, the modelling of which is an advantage of this method.

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Mixed-valence states in TCNQ salts of monoalkylbiferrocenes and their mixed crystals with dialkyl derivative

TCNQ salts of 1-monoalkylbiferrocenes showed a temperature-independent trapped-valence state as expected for the unsymmetrical structure of cations. On the other hand, mixed crystals of 1-monobutyl- and 1.1-dibutylbiferrocenium⁺(TCNQ) ₃ ^– showed a temperature dependence of the mixed-valence states, showing that the lattice affects the mixed-valence states.     

The room-temperature decomposition of metastable phases precipitated in the Al-Zn alloys at 200 °C

The room-temperature decomposition of metastable phases in the Al-Zn alloys (from 25 to 50 wt. % Zn) was studied by the transmission electron microscopy and X-ray diffraction. Metastable phases, i.e. G.-P. zones, _R-and -phases, were grown at 200 °C and their decomposition into equilibrium -phase at 20 °C was investigated. Ageing times comprised 1 to 999 days.Both the decomposition mechanism and the rate of decomposition of coherent phases were found to be dependent on the particle sizes and their density reached at 200 °C. The local vacancy supersaturation around the -nucleus in a dense system of G.-P. zones leads to an enhanced growth rate of such nucleus and thus to the formation of one large -precipitate at the expense of several neighbouring G.-P. zones. The elastic stress field around this -particle promotes the further nucleation and growth of -precipitates and leads to their gradual spread throughout the matrix. The decomposition of intermediately sized _Rprecipitates results in the development of -precipitates of comparable sizes nucleated on the array of misfit dislocations at the periphery of _R-precipitates. The cooperative effect between neighbouring particles does not influence the decomposition of large _R-precipitated which split then into several smaller -particles. The rate of G.-P. zones or _R to -decomposition increases with the increasing sizes of transition precipitates and with the zinc content of the alloy. The kinetics of to -decomposition was found to be independent both on the annealing time at 200 °C and on the investigated alloy composition. This can be attributed to the constant density of misfit dislocations as nucleation sites for -precipitates along the -matrix interface and to the large mutual separation of -precipitates in all these alloys.In conclusion we would like to express our thanks to Doc. Dr. V.Syneek, CSc. for his valuable discussions and to Ing. V.íma for the preparation of Al-Zn alloys. Our thanks are also due to Mr. Z.iký for his help in the X-ray diffraction measurement and to P.Vyhlídka for the careful chemical analyses of the investigated alloys.     

Natural boundaries for area-preserving twist maps

We consider KAM invariant curves for generalizations of the standard map of the form (x, y)=(x+y, y+f(x)), wheref(x) is an odd trigonometric polynomial. We study numerically their analytic properties by a Padé approximant method applied to the function which conjugates the dynamics to a rotation +. In the complex plane, natural boundaries of different shapes are found. In the complex plane the analyticity region appears to be a strip bounded by a natural boundary, whose width tends linearly to 0 as tends to the critical value.     

A contribution to the semi-focusing method with a flat polycrystalline sample

Condition are derived for the approximate focusing of diffraction lines in the chosen, relatively wide angular region, using the semi-focusing method with a flat sample, if a bent crystal monochromator is employed. The form of the absorption factor for a flat polycrystalline sample is derived for the case of uniform oscillation of the sample in the angular region ± around the axis of the camera.

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Weakly Bound States in Light Hypernuclei

From the viewpoint of critical stability, we discuss the three- and four-body structure of ⁶He, ⁷He, ⁴He, and ⁴H. With the + + N three-body model, ⁶He is found to have a three-layer structure of the matter distribution: core, a skin and neutron halo. Also the level structure of ⁷He with the three-body model of ⁵He + n + n is predicted. This stimulates a new study of neutron-rich and proton-rich hypernuclei. By performing a four-body calculation with both NNN and NNN channels and with both NN and NNN channels, we show that the N-N and -N couplings are very important in critical stability of few-body hypernuclear systems.     

Small perturbations ofC*-dynamical systems

It is shown that if is the generator of a strongly continuous oneparameter group of *-automorphisms of aC*-algebraA and is an unbounded *-derivation ofA with the same domain as , then + is also a generator for all sufficiently small real numbers .     

Kinetic theory of adsorption and desorption

In this paper we use stochastic methods to discuss adsorption and desorption. The paper derives generalized coefficients of sticking and accomodation depending on surface temperatureT _s and gas temperatureT _g and shows, that for additive Markov processes, these kinetic coefficients are identical. Furthermore, exact solutions of the kinetic equations for certain simple transition probabilitiesP(, ) are found and an approximation method for more complicatedP(, ) is given. The comparison of the theory with experimental results for noble gas-metal systems indicate a quadratic relationship between the first moment of the transition probabilityP(, ) and the well depth of the physisorption system.