Correlation between the mechanical properties and the amount of desorbed water for composites based on a recycled low-density polyethylene and linen yarn production waste

The effect of the amount of sorbed water on the mechanical properties (tensile modulus, tensile strength, unit work of fracture, and characteristic strains) of composites based on a recycled low-density polyethylene, both unmodified and modified with diphenylmethane diisocyanate (DIC), is an a lyzed by statistical methods. The results of tensile tests are found to depend on the amount of sorbed water considerably. The elastic modulus, the unit work of fracture, and the characteristic strains correlate linearly with the amount of water. It is found that the elastic modulus drops after the sorption of water, but then, during the desorption process, it is restored gradually and reaches its initial value after a 30-day drying. This is explained by the plasticizing effect of water on composite materials containing hydrophilic natural fibers. DIC improves the interfacial interaction of the fiber-matrix interface and slows down the desorption of water. The investigations of the main deformational and strength characteristics of the unmodified and modified systems showed that the ad verse effect of water completely disappeared after a 30-day drying. The same conclusion, with a 95% probability, can be drawn from the results of an analysis of variance (ANOVA). __________ Translated from Mekhanika Kompozitnykh Materialov, Vol. 43, No. 5, pp. 626–638, September–October, 2007.     

Water Resistance of Polyester Polymer Concrete

The results of experimental investigation of polyester resin and polymer concrete at a long-term (four-year) exposure to water and air with 98% RH are presented. The polymer concrete was composed of a polyester resin as a binder, lime flour, quartz sand, and granite chips. The resin content in concrete was 20 wt.%. The features of sorption properties of the materials investigated are discussed. Data on the water effect on the compressive strength in short-term loading are reported. The creep tests of virgin polymer-concrete specimens were carried out for five years at different stress levels from 0.11 to 0.44 of the short-term prismatic strength. The effect of moisture on the creep behavior was also studied.     

Effect of Water on the Physicomechanical Properties of Composites Containing Low-Density Polyethylene and Linen Yarn Production Waste

The effect of the amount of absorbed water on the physicomechanical indices (tensile modulus and tensile strength) of composites based on low-density polyethylene (LDPE) and linen yarn production waste (LW), both with and without coupling agents (stearic acid - SA and diphenylmetane diisocyanate - DIC), is studied. It is shown that the strength properties depend considerably on the time of water sorption and on the blend composition. The tensile strength decreases with increased amount of absorbed water (with increased time of exposure to distilled water) and with increased content of LW in the composite. Somewhat different results are obtained for systems containing SA and DIC modifiers. The modifiers, intensifying the interfacial interaction, retard the process of water sorption, therefore the drop in the strength indices is not so significant. Of special interest is the behavior of systems with DIC. In some cases, a slight increase in strength (after a two to five day exposure to water) is observed, which is probably caused by cross-linking of the free diisocyanate in the system under the action of moisture.     

Mathematical modelling of the stochastic mechanical properties of wood and its extensibility at small scales

This paper investigates the relation between the uncertain mechanical properties of wood and its extensibility at the ultrastructural scale. A statistical approximation to the output of a multi-scale constitutive model is adopted to predict the extensibility of wood in the presence of parametric uncertainty. By means of this procedure, a very large number of computationally intensive fully-coupled multi-scale simulations are avoided. Following this approach, four different micromechanical parameters are chosen to assess their influence on the extensibility of the material under tensile loading conditions. These are the degree of cellulose crystallinity, the ultimate strain and Young’s modulus of the hemicellulose–lignin matrix, and the thickness of the amorphous cellulose layer which covers the periodic crystalline portions of cellulose. We believe that a better understanding of the mechanisms of deformation and extensibility in wood and in natural materials can pave the way for the development of new strategies to design more advanced materials in engineering structures.     

Cryogenic mechanical response of multilayer satin weave CFRP composites with cracks

We deal with the thermomechanical response of multilayer satin weave carbon-fiber-reinforced polymer (CFRP) laminates with internal and/or edge cracks and temperature-dependent material properties subjected to tensile loading at cryogenic temperatures. The composite material is assumed to be under the generalized plane strain. Cracks are located in the transverse fiber bundles and extend to the interfaces between two fiber bundles. A finite-element model is employed to study the influence of residual thermal stresses on the mechanical behavior of multilayer CFRP woven laminates with cracks. Numerical calculations are carried out, and Young’s modulus and stress distributions near the crack tip are shown graphically. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 44, No. 4, pp. 479–492, July–August, 2008.     

The influence of water sorption-desorption cycles on the mechanical properties of composites based on recycled polyolefine and linen yarn production waste

The effect of water on the mechanical properties (tensile modulus, ultimate tensile strength, tensile strain, and specific work at break) of both chemically treated and untreated composites based on a recycled low-density polyethylene and linen yarn production waste is analyzed. It is found that three water sorption-desorption cycles change the tensile properties of both the materials irreversibly. This effect is considered as the result of partial fracture of the fiber-matrix interface. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 43, No. 6, pp. 839–848, November–December, 2007.     

Influence of fiber structure modification on the mechanical properties of flax fiber-epoxy composites

The mechanical characteristics of flax fibers were optimized by using the NaOH treatment process to improve the properties of composite materials. Shrinkage of the fibers during this treatment had a significant effect on the structure and, as a result, on the mechanical properties of the fibers and the composites based on them. Due to the higher mechanical strength and stiffness of flax fibers after NaOH treatment under isometric conditions, the strength and stiffness of composites in general increase. Further, NaOH treatment leads to a rougher surface morphology, as shown, e.g., for jute fibers, compared with the surface of untreated fibers without improved fiber/matrix adhesion.     

Sorption Characteristics of Polymer Concrete during Long-Term Exposure to Water

The moisture sorption characteristics of polymer concrete and its components (polyester resin, unfilled and filled with diabase flour) on long-term (up to 15-year) exposure to water at different temperatures are studied. It is established that, during the long-term sorption and subsequent desorption at 20°C, the ratio of diffusion coefficients of the polymer concrete and the corresponding resin is equal to the value of time-moisture reduction function, which characterizes changes in the creep compliance of the materials. The evaluation of the diffusion coefficient of the composite from the properties of its components, by using various known heat-and-mass-transfer models, shows that most acceptable is the Kerner model. With account of volume content of pores, an estimate for the limiting moisture content in the composite is proposed. An analysis of sorption curves of the composite and the corresponding resin reveals that Fick's law does not describe the experimental results in the range of large times and/or elevated temperatures. In the case of polyester resin filled with diabase flour, the composite effect is expressed in a linear increase in the specimen mass (the rate of the increase is temperature-dependent. In the case of polymer concrete, the composite effect is expressed in mass losses, which can be described by Fick's law with a diffusion coefficient and a limiting moisture content both depending on temperature.     

Effect of Water on the Physicomechanical Properties of Composites Containing Secondary Polyethylene and Linen Yarn Production Waste

The effect of the amount of absorbed water on the physicomechanical indices (tensile modulus, tensile strength, and ultimate strain) of composites based on secondary polyethylene (SPE) of two trademarks and linen yarn production waste (LW), both with and without a coupling agent (diphenylmetane diisocyanate - DIC), is evaluated. It is shown that the strength properties considerably depend on the time of water sorption and on the blend composition. The tensile strength decreases with increased amount of absorbed water (with increased time of exposure to distilled water) and with increased content of LW in the composites. This can be explained by the plasticizing effect of water molecules, which is confirmed by the increase in the ultimate strain of specimens after their exposure to water. The slight increase in the strength observed for the systems modified with DIC is probably caused by cross-linking of the free diisocyanate in the system under the action of moisture. The diisocyanate intensifies the interfacial interaction and retards the water-sorption process. Therefore, the resulting strength indices of these systems are higher than those of the unmodified compositions.     

Microstress fields and the mechanical properties of disordered fiber composites

Conclusion The effective elastic moduli and Poisson's ratios and the mean characteristics of the stress fields in the components of unidirectional fiber composites with a stochastic structure are nearly the same as the corresponding values calculated for a regular model of the composite. Relatively small increase (up to 6%) is seen in the transverse shear moduli with the transition from a regular structure to a stochastic structure. In the latter, there is a substantial increase in the stress concentration factor. Here, the difference between the stochastic structure and the regular structure increases with an increase in fiber stiffness and is particularly great (with a difference of two to three orders of magnitude) in the case of shear loading. The probability of the occurrence of microscopic fracture in the binder of the investigated materials is higher in transverse tension, but the difference from the results obtained for the regular models is more significant in the case of shear loading. Microscopic fracture nuclei will be formed in the matrix of the composite with the stochastic structure at considerably lower macroscopic stresses than are required for the regular structure.Translated from Mekhanika Kompozitnykh Materialov, No. 5, pp. 860–865, September–October, 1990.     

天然水驱油藏边底水能量计算

塔南油田19-14断块为低渗透油藏,在其开采过程中要考虑开采方式,为确定是否应采用天然能量开采,能否达到预期的效果,需要确定断块的天然能量,其中边底水能量不容忽视,即水体倍数的大小.以塔19-14断块的边底水能量为研究对象,根据非稳定状态法,计算塔南油田19-14断块的边底水能量,为不活跃型,不适合采用边底水能量开采.     

Strength and fracture properties of advanced SiC-based fibers

The tensile strength and the fracture properties of advanced SiC-based fibers were characterized, and an extensive fractographic analysis was conducted to correlate their mechanical behavior and microstructure. Tensile tests re vealed that the strength of Hi-Nicalon™ and Hi-Nicalon™ Type S fibers was sensitive to a critical flaw. The inspection of fracture surfaces revealed that the fracture of these fibers originated mainly at the critical flaw, which was surrounded by an obvious mirror zone. The Tyranno™-SA fiber showed a transcrystalline fracture behavior. The different fracture behavior observed in this work could be related to different fabrication processes and compositions at the grain boundary. For the Hi-Nicalon™ and Hi-Nicalon™ Type S fibers, the critical flaw size was linearly related to the mirror size. By using the linear fracture mechanics, the fracture toughness and the critical fracture energy of the fibers were estimated. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 6, pp. 759–770, November–December, 2006.     

Opportunities and challenges for textile reinforced composites

For several decades researchers have been interested in textile processes for the production of composite reinforcement. These technologies have offered several promises: reduced fabrication costs, 3-D multiaxial reinforcement, and damage tolerance. Despite these advantages, textile composites have not reached the level of implementation of laminated composites. In this paper, the opportunities provided by textile reinforced composites and the challenges that limit their implementation will be discussed in detail. Textile composites refer to a family of processes: weaving, braiding, knitting, and hybrids thereof. The various families of textiles will be defined and the basics of fabric formation for each family will be detailed. In particular, the strengths and weaknesses of each manufacturing technique will be addressed to provide a view of the applicability of each technology. This will include some guidance on shape formation capability, property ranges, size limitations, and estimates of cost to produce. Potential applications for these materials will be presented. Among the limitations on the application of textile reinforced composites is the lack of adequate modeling capabilities for these materials. Textile composites have rather large unit cell structures and are highly inhomogeneous throughout their volumes. These features provide benefits in manufacturing, but require novel modeling techniques to correctly understand the mechanical behavior. A review of analytical techniques applied to textile composites will be presented along with a discussion of the benefits and weaknesses of each of these methods. The enabling technologies needed to further the implementation of textile composites in structural applications will be discussed. Submitted to the 11th International Conference on Mechanics of Composite Materials (Riga, June 11–15, 2000). Published in Mekhanika Kompozitnykh Materialov, Vol. 36, No. 2, pp. 165–194, March–April, 2000.     

Strength of biodegradable polypropylene tapes filled with a modified starch

The possibility of creating composite materials with high deformation and strength characteristics based on polypropylene (PP) and a natural polysaccharide in the form of a modified starch (MS) has been studied. The modified starch is shown to interact chemically with functional groups of PP, thereby positively affecting the physicomechanical properties, structure, and water absorption properties of films and oriented flat fibers based on starch-filled PP. The strength characteristics of both oriented and unoriented composites are 1.5–2.0 times as high as those of the initial PP. The water absorption ability of the materials varies symbatically with content of MS, which points to the dominant contribution of interactions at the PP-MS interface. The introduction of MS into synthetic polymers offers a possibility of producing new ecologically safe materials with high strength characteristics. __________ Translated from Mekhanika Kompozitnykh Materialov, Vol. 42, No. 3, pp. 389–400, May–June, 2006.     

Measuring and modeling the thermal conductivities of three-dimensionally woven fabric composites

The effect of a three-dimensional fiber reinforcement on the out-of-plane thermal conductivity of composite materials is investigated. Composite preforms with different fibers in the thickness direction were fabricated. After in fusion by using a vacuum-assisted resin transfer molding process, their through-thickness thermal conductivities were evaluated. The measured thermal conductivities showed a significant increase compared with those of a typical laminated composite. Although the through-thickness thermal conductivity of the samples increased with through-thickness fiber volume fraction, its values did not match those predicted by the simple rule of mixtures. By using finite-element models to better under stand the behavior of the composite material, improvements in an existing analytical model were performed to predict the effective thermal conductivity as a function of material properties and in-contact thermal properties of the composite. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 45, No. 2, pp. 241–254, March–April, 2009.     

Bounds and estimates on the effective properties for nonlinear composites

In this paper we derive lower bounds and upper bounds on the effective properties for nonlinear heterogeneous systems. The key result to obtain these bounds is to derive a variational principle, which generalizes the variational principle by P. Ponte Castaneda from 1992. In general, when the Ponte Castaneda variational principle is used one only gets either a lower or an upper bound depending on the growth conditions. In this paper we overcome this problem by using our new variational principle together with the bounds presented by Lukkassen, Persson and Wall in 1995. Moreover, we also present some examples where the bounds are so tight that they may be used as a good estimate of the effective behavior.     

A review of the mechanical properties of isolated carbon nanotubes and carbon nanotube composites

A literature review on the prediction of Young’s modulus for carbon nanotubes, from both theoretical and experimental aspects, is presented. The discrepancies between the values of Young’s modulus reported in the literature are analyzed, and different trends of the results are discussed. The available analytical and numerical simulations for predicting the mechanical properties of carbon nanotube composites are also reviewed. A gap analysis is performed to highlight the obstacles and drawbacks of the modeling techniques and fundamental assumptions employed which should be overcome in further studies. The aspects which should be studied more accurately in modeling carbon nanotube composites are identified.     

Correlation between the Mechanical Properties and the Amount of Desorbed Water for Composites Based on Low-Density Polyethylene and Linen Yarn Production Waste

The effect of the amount of desorbed water on the mechanical properties of composites based on low-density polyethylene and linen yarn production waste (LW) is analyzed by statistical methods. It is shown that the amount of absorbed water decreases during the desorption process at room temperature both for specimens modified and unmodified with diphenylmethane diisocyanate (DIC.) The most sensitive to the action of water is the elastic modulus, which decreases considerably under the effect of water and is fully restored in the desorption process. The tensile strain also increases with the amount of absorbed water. It is found that the elastic modulus of the unmodified composite correlates linearly with the amount of desorbed water. Between the amount of desorbed water and the tensile strain, as well the specific work of deformation, a negative linear correlation is revealed. After water desorption, all strength and deformation characteristics of both the modified and unmodified composites are fully recovered.__________Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 4, pp. 515–524, July–August, 2005.