Gold(I) Formamidinate Clusters: The Structure, Luminescence, and Electrochemistry of the Tetranuclear, Base-Free [Au4(ArNC(H)NAr)4]

The structures of the tetragold(I) formamidinate cluster complexes, [Au₄(ArNC(H)NAr)₄], Ar=C₆H₄-4-OMe (1), C₆H₃-3,5-Cl (2), C₆H₄-4-Me (3), have been characterized by x-ray crystallography. The range of AuAu distances is 2.8–3.0 Å. The angles at AuAuAu are acute and obtuse 70 and 109°, 88 and 91°, and 63 and 116° in 1, 2, and 3, respectively. The four gold atoms are located at the corner of a rhomboid with the formamidinate ligands bridged above and below the near plane of the four Au(I) atoms. The tetranuclear gold(I) complexes show a bright blue-green luminescence under UV light, with an emission at 490 nm and a weak emission at 530 nm in the solid state, at room temp and 77 K. The oxidation of the formamidinate cluster, 1, has been studied electrochemically in 0.1 M Bu₄NPF₆/CH₂Cl₂ at a Pt working electrode with different scan rates. Three waves were obtained, 0.75, 0.95, and 1.09V vs. Ag/AgCl at a scan rate of 500 mV/s, the three waves are reversible. The potentials are independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two.     

Synthesis, Characterization, Luminescence, and Electrochemistry of New Tetranuclear Gold(I) Amidinate Clusters: Au4[PhNC(Ph)NPh]4, Au4[PhNC(CH3)NPh]4, and Au4[ArNC(H)NAr]4

The syntheses and the X-ray structures of the tetranuclear gold(I) benzamidinate, Au₄[PhNC(Ph)NPh]₄, and the tetranuclear gold(I) acetamidinate, Au₄[PhNC(CH₃)NPh]₄, clusters are reported. The clusters are produced by the reaction of the sodium salt of an amidine ligand with the gold precursor Au(THT)Cl in a (1:1) stoichiometry. The average Au...Au distance between adjacent Au(I) atoms is ∼2.9 ?, typical of compounds having an aurophilic interaction. The four gold atoms are arranged in a square (Au...Au...Au... = 88–91°) in the acetamidinate and in a distorted square (Au...Au...Au... = 82–97°) in the benzamidinate derivative. Electrochemical oxidation of the tetranuclear complex Au₄[PhNC(Ph)NPh]₄ show three reversible waves at 0.87, 1.19, 1.42 V vs. Ag/AgCl at a scan rate of 100 mV/s in CH₂Cl₂ similar to the three reversible waves seen before from the tetranuclear complexes Au₄[ArNC(H)NAr]₄, Ar = C₆H₄-4-OMe, Ar = C₆H₄-4-Me, and Ar = C₆H₃-3,5-Cl. A summary of the chemistry of the tetranuclear Au(I) amidinate complexes Au₄[ArNC(H)NAr]₄, Ar = C₆H₄-4-OMe, C₆H₃-3,5-Cl, C₆H₄-4-Me, C₆H₄-3-CF₃, C₆F₅, C₁₀H₇ also is presented. The tetranuclear clusters Au₄[ArNC(H)NAr]₄, Ar = C₆H₄-4-OMe, Ar = C₆H₄-3-CF₃, Ar = C₆H₄-4-Me and Ar = C₆H₄-3,5-Cl are the first tetranuclear gold(I) cluster species from group 11 elements to show fluorescence at room temperature. The lifetimes of the naphthyl and trifluoromethylphenyl complexes are in the millisecond range indicating phosphorescent processes. Recently it has been shown that Au₄[ArNC(H)NAr]₄ are very effective catalysts upon calcination for room temperature CO oxidation. Congratulations to Dieter Fenske, a superb synthetic chemist with exceptional talents in cluster chemistry, on the occasion of his 65th birthday.     

Tetranuclear Gold(I) Clusters with Nitrogen Donor Ligands: Luminescence and X-Ray Structure of Gold(I) Naphthyl Amidinate Complex

The syntheses and characterization of gold(I) naphthyl, pentafluorophenyl, and trifluoromethylphenyl amidinate complexes are reported. The tetranuclear clusters are obtained from the reaction of Au(tetrahydrothiophene)Cl with the potassium salt of the corresponding amidinate in a THF solvent. The crystal structures of the gold(I) naphthyl, 2, and pentafluorophenyl, 3, amidinates show a short Au···Au distance of ~3. 0 Å typical of compounds having an aurophilic interaction. The gold atoms are arranged in a square (Au···Au···Au = 87°–92°) in the pentafluorophenyl derivative and in a parallelogram (Au···Au···Au = 68°–110°) in the naphthyl amidinate complexes. The naphthyl and trifluoromethylphenyl complexes are visibly luminescent in the solid state at liquid nitrogen temperature displaying asymmetric emission bands at 538 and 473 nm, respectively. The luminescent lifetimes of these species are in the millisecond range indicating phosphorescent processes.     

Characterization of a New Tetranuclear Cluster of Palladium, [Pd4(dppm)4(H)]—

The recently discovered and characterized [Pd₄(dppm)₄(H)]²⁺ cluster catalyst ( 1 ; dppm = Ph₂PCH₂PPh₂), slowly evolves in the presence of the reducing tetraphenylborate anion, to generate a new diamagnetic cluster [Pd₄(dppm)₄(H)]⁺ ( 2 ). The evolution of this starting material 1 , has been monitored using NMR (¹H and ³¹P), UV‐vis and ESR spectroscopy. This new 56‐electron Pd cluster has been characterized from X‐ray crystallography, and consists of a cyclic species exhibiting an approximate puckered square structure. The Pd₂ bond distances are 2.7367(10) and 2.7495(11)Å and indicate the presence of weak bonding. The diagonal Pd···Pd separations are 3.646(10) and 3.590(10)Å indicating that the square is relatively symmetric. Such a structure is unprecedented for “Pd_x(dppm)_x” species. Although not formally observed from the X‐ray data, the hydride is assumed to be fluxional as found in 1 . The cyclic voltammogram for 2 exhibits an irreversible reduction wave at —1.65V vs SCE which is greater than that found for 1 , and corroborates the lower oxidation state for Pd (+1/2). The Pd‐H bonding scheme and MO symmetry for a model cluster where the hydride has been placed at the center of the Pd₄ frame, have been addressed qualitatively using the EHMO model. These calculations demonstrate clearly that the Pd‐H bonding is strong.     

精确控制合成Au36(SR)24金原子簇(SR = SPh,SC6H4CH3, SCH(CH3)Ph,SC10H7)

近十几年来,具有原子精确的金原子簇(Au_nL_m)逐渐发展成一种新型可靠的金纳米材料。在本研究中,报道一种简单实用合成脂肪或者芳香巯基保护Au₃₆(SR)₂₄金原子簇的方法。通过“尺寸聚焦”方法,成功地获得Au₃₆(SCH(CH₃)Ph)₂₄,Au₃₆(SC₆H₄CH₃)₂₄,Au₃₆(SPh)₂₄及Au₃₆(SC₁₀H₇)₂₄等金原子簇。这些原子簇通过UV-Vis光谱,电喷雾(ESI)和基质辅助激光解析飞行时间(MALDI)质谱以及TGA等表征进行了进一步的确定。同时发现在UV-Vis光谱中,芳香巯基保护Au₃₆(SR)₂₄金原子簇发生了明显的红移现象;例如与Au₃₆(SCH(CH₃)Ph)₂₄原子簇相比,萘巯基保护的Au₃₆(SC₁₀H₇)₂₄原子簇在570 nm左右的吸收峰发生了13 nm的位移。     

Synthesis,Structural Characterization and Luminescence Studies of Di‐ and Trinuclear Gold(I) Alkynyl‐phosphine Complexes

Reactions of the polymer {Au^IC₂Ph}_n with polyphosphine ligands [1,4‐bis(2‐diphenylphosphino‐1H‐imidazol‐1‐yl)‐benzene (dpib), 1,3,5‐tris(4‐diphenylphosphinophenyl)benzene (tppb), 2,2′‐bis(diphenylphosphanyl)‐4,4′‐bipyridine (dpbp), and 3,6‐bis(diphenylphosphanyl)pyridazine (dppz)] afforded four gold(I) alkynyl‐polyphosphine complexes [{AuC₂Ph}₂(μ‐dpib)] ( 1 ), [{AuC₂Ph}₃(μ₃‐tppb)] ( 2 ), [{AuC₂Ph}₂(μ‐dpbp)] ( 3 ), and [{AuC₂Ph}₂(μ‐dppz)] ( 4 ) in nearly quantitative yield. The compounds obtained were characterized using elemental analysis, ESI‐MS, X‐ray crystallography, and polynuclear NMR spectroscopy. Intermolecular aurophilic interaction together with π–π and σ–π stacking build up the supramolecular 3D network of complex 3 , whereas none of these intermolecular bondings were found in the crystal structures of compounds 1 , 2 , and 4 . Complexes 1 – 4 are luminescent both in solution (CH₂Cl₂) and in solid state under laser irradiation (λ_ex = 308 nm). In solution, the diphosphine complexes 1 – 4 display dual emission corresponding to ligand centered transitions (λ_em = 360–375 nm) along with weaker contribution from MLCT excited states at ca. 490 nm. The long wavelength component of the emission plays a dominant role in the solid state luminescence spectra of complexes 1 , 3 , and 4 (460, 544, 520 nm, respectively) whereas the triphosphine complex 2 shows dual luminescence (372 and 520 nm) with considerable contribution from ligand centered excited state.     

The [Au(CH3SO3)4]– Anion in the Crystal Structures of M[Au(CH3SO3)4] (M = Li,Na, Rb)

The reactions of Au(OH)₃, M₂CO₃ (M = Li, Na, Rb), and methanesulfonic acid at elevated temperatures in sealed glass ampoules lead to single crystals of M[Au(CH₃SO₃)₄] (M = Li, Na, Rb). In the crystal structures of Li[Au(CH₃SO₃)₄] (tetragonal, I$\bar{4}$ , Z = 2,a = 938.64(2) pm, c = 917.01(3) pm, V = 807.93(4) ų) and Rb[Au(CH₃SO₃)₄] (tetragonal, P$\bar{4}$ 2₁c, Z = 2, a = 946.7(1) pm,c = 889.9(1) pm, V = 797.6(2) ų) the complex aurate anions are linked by the M⁺ ions in three dimensions. Contrastingly, in the structure of Na[Au(CH₃SO₃)₄] (triclinic, P$\bar{4}$ , Z = 1, a = 540.04(2) pm,b = 863.75(2) pm, c = 973.29(3) pm, α = 72.694(2)°, β = 75.605(2)°, γ = 77.687(2)°, V = 415.05(2) ų) the complex anions are connected into layers that are further connected by weak hydrogen bonds. The thermal decomposition of Li[Au(CH₃SO₃)₄] was monitored up to 500 °C and leads in a multi‐step process to elemental gold and Li₂SO₄.     

Neue Gold‐Selen‐Komplexverbindungen: Synthesen und Strukturen von [Au10Se4(dpppe)4]Br2, [Au2Se(dppbe)]∞, [(Au3Se)2(dppbp)3]Cl2 und [Au34Se14(tpep)6(tpepSe)2]Cl6

Novel Gold Selenium Complexes: Syntheses and Structures of [Au₁₀Se₄(dpppe)₄]Br₂, [Au₂Se(dppbe)]_∞, [(Au₃Se)₂(dppbp)₃]Cl₂, and [Au₃₄Se₁₄(tpep)₆(tpep^Se)₂]Cl₆ The reaction of gold phosphine complexes [(AuX)(PR₃)] (X= halogen; R = org. group) with Se(SiMe₃)₂ yield to new chalcogeno bridged gold complexes. Especially within the use of polydentate phosphine ligands cluster complexes like [Au₁₀Se₄(dpppe)₄]Br₂ ( 1 ) (dpppe = 1, 5‐Bis(diphenylphosphino)pentane), [Au₂Se(dppbe)]_∞ ( 2 ) (1, 4‐Bis(diphenylphosphino)benzene), [(Au₃Se)₂(dppbp)₃]Cl₂ ( 3 ) (dppbp = 4, 4′‐Bis‐diphenylphosphino)biphenyl) und [Au₃₄Se₁₄(tpep)₆(tpep^Se)₂]Cl₆ ( 4 ) (tpep = 1, 1, 1‐Tris(diphenylphosphinoethyl)phosphine, tpep^Se = 1, 1‐Bis(diphenylphosphinoethyl)‐1‐(diphenylselenophosphinoethylphosphine) could be isolated and their structures could be determined by X‐ray diffraction. ( 1: Space group P1 (No. 2), Z = 2, a = 1642.1(11), b = 1713.0(9), c = 2554.0(16) pm, α = 80.41(3)°, β = 76.80(4)°, γ = 80.92(4)°; 2: Space group P2₁/n (No. 14), Z = 4, a = 947.3(2), b = 1494.9(3), c = 2179.6(7) pm, β = 99.99(3)°; 3: Space group P2₁/c (No. 14), Z = 8, a = 2939.9(6), b = 3068.4(6), c = 3114.5(6) pm, β = 109.64(3)°; 4: Space group P1 (No. 2), Z = 1, a = 2013.7(4), b = 2420.6(5), c = 2462.5(5) pm, α = 77.20(3), β = 74.92(3), γ = 87.80(3)°).     

Zur solvensfreien Darstellung von Tetramethylammoniumsalzen: Synthese und Charakterisierung von [N(CH3)4]2[C2O4], [N(CH3)4][CO3(CH3)], [N(CH3)4][NO2], [N(CH3)4][CO2H] und [N(CH3)4][O2C(CH2)2CO2(CH3)]

Solvent-free Synthesis of Tetramethylammonium Salts: Synthesis and Characterization of [N(CH₃)₄]₂[C₂O₄], [N(CH₃)₄][CO₃CH₃], [N(CH₃)₄][NO₂], [N(CH₃)₄][CO₂H], and [N(CH₃)₄][O₂C(CH₂)₂CO₂CH₃] A general procedure to synthesize tetramethylammonium salts is presented. Several tetramethylammonium salts were prepared in a crystalline state by solvent-free reaction of trimethylamine and different methyl compounds at mild conditions: [N(CH₃)₄]₂[C₂O₄] (cubic; a = 1 114.8(3) pm), [N(CH₃)₄][CO₃CH₃] (P2₁/n; a = 813.64(3), b = 953.36(3), c = 1 131.3(4) pm, β = 90.03(1)°), [N(CH₃)₄][NO₂] (Pmmn; a = 821.2(4), b = 746.5(3), c = 551.5(2) pm), [N(CH₃)₄][CO₂H] (Pmmn; a = 792.8(7), b = 791.7(3), c = 563.3(4) pm) and [N(CH₃)₄][O₂C(CH₂)₂CO₂CH₃] (P2₁; a = 731.1(2), b = 826.4(3), c = 1 025.2(3) pm, β = 110.1(1)°). The tetramethylammonium salts were characterized by IR-spectroscopy and X-ray diffraction. The crystal structures of the methylcarbonate and the nitrite are described.     

Organic‐Inorganic Hybrids: Preparation and Structural Characterization of (Bu4N)2[Mo6O17(NAr)2] and (Bu4N)2[Mo6O18(NAr)] (Ar = o‐CH3C6H4)

In the presence of N, N′‐dicyclohexylcarbodiimide (DCC), (Bu₄N)₂[Mo₆O₁₈(NAr)] ( 1 ) and (Bu₄N)₂[Mo₆O₁₇(NAr)₂] ( 2 ), Ar = o‐CH₃C₆H₄, have been synthesized via the reaction of [α‐Mo₈O₂₆]^4— with o‐toluidine. If the hydrochloride salt of o‐toluidine was added into the reactive mixture, only the monofunctionalized imido derivative of [Mo₆O₁₉]^2— was obtained; the bifunctionalized derivative of [Mo₆O₁₉]^2— was exclusively synthesized in the presence of non‐protonated o‐toluidine. The molecular and crystal structures of the hybrid compounds 1 and 2 were determined by X‐ray single crystal diffraction, and their UV, IR and NMR spectra were compared. Additionally, a possible reaction mechanism was proposed.     

Synthesis of bridged and linked ruthenium and osmium carbonyl clusters containing a [Au2(Ph2PCH2CH2PPh2)]2+ unit. The crystal and molecular structures of Ru5C(CO)14Au2(Ph2PCH2CH2PPh2) and {Os4H3(CO)12}2Au2(Ph2PCH2CH2PPh2)

Treatment of Au₂(Ph₂PCH₂CH₂PPh₂)Cl₂ with one equivalent of the [Ru₅C(CO)₁₄]²⁻ dianion in the presence of TlPF₆ gives Ru₅C(CO)₁₄Au₂(Ph₂PCH₂CH₂PPh₂) (1) in good yield and the [{Ru₅C(CO)₁₄}₂Au₂(Ph₂PCH₂CH₂PPh₂)]²⁻ (2) anion in low yield. Complex 2 becomes the major product if 2 equivalents of [Ru₅C(CO)₁₄]²⁻ are used. Reaction of [Au₂(Ph₂PCH₂CH₂PPh₂)Cl₂] with 3 equivalents of [H₃Os₄(CO)₁₂]⁻ anion in the presence of TlPF₆ affords {H₃Os₄(CO)₁₂}₂Au₂(Ph₂PCH₂CH₂PPh₂) (3) in reasonable yield. X-ray diffraction studies of 1 and 3 show that they contain the [Au₂(Ph₂PCH₂CH₂PPh₂)]²⁺ fragment in different coordination modes.     

Synthese,Kristallstruktur und spektroskopische Charakterisierung von [Au12(PPh)2(P2Ph2)2(dppm)4Cl2]Cl2

Synthesis, Crystal Structure and Spectroscopic Characterization of [Au₁₂(PPh)₂(P₂Ph₂)₂(dppm)₄Cl₂]Cl₂ The reaction of [(AuCl)₂dppm] (dppm = Ph₂PCH₂PPh₂) with P(Ph)(SiMe₃)₂ in CHCl₃ results in the formation of [Au₁₂(PPh)₂(P₂Ph₂)₂(dppm)₄Cl₂]Cl₂ ( 1 ), the crystal structure of which was determined by single crystal X‐ray analysis (space group P2₁/c, a = 1425.3(3) pm, b = 2803.7(6) pm, c = 2255.0(5) pm, β = 95.00(3)°, V = 8977(3)·10⁶ pm³, Z = 2). The dication in 1 consists of two Au₆P₃ units built by highly distorted Au₃P and Au₂P₂ heterotetrahedra, connected via four bidentate phosphine ligands. Additionally, the compound was characterized by IR‐, UV‐ and NMR spectroscopy. The ³¹P{¹H} NMR spectrum is discussed in detail.     

配合物[Eu(4-MOBA)3(terpy)(H2O)]2的合成、表征、热分解机理及性质

合成了一个新的配合物[Eu(4-MOBA)₃(terpy)(H₂O)]₂ (4-MOBA:4-甲氧基苯甲酸根, terpy:2, 2':6', 2"-三联吡啶)。采用傅里叶变换红外(FTIR)光谱、元素分析和X射线粉末衍射(XRD)技术对标题配合物进行了表征,用X射线单晶衍射仪测定了配合物的晶体结构,在配合物中每个Eu³⁺离子与一个三联吡啶分子、一个水分子和三个羧酸分子结合,配位数为9,羧酸基团的配位模式包含三种:双齿螯合,桥连双齿,单齿。根据热重-差示扫描量热/傅里叶变换红外(TG-DSC/FTIR)联用技术,研究了配合物的热分解机理。配合物的发射光谱显示出Eu³⁺离子的特征荧光发射,表明三联吡啶和4-甲氧基苯甲酸在该体系中可作为敏化集团。另外,文中还讨论了配合物对白色念珠菌和大肠杆菌的抑菌活性。     

Synthesis and Characterization of Sn-W Complexes and Crystal Structure of Ph_3SnW(CO)_3C_5H_4CH_3

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Copper(I) Clusters with Trifunctional Silyl Amide Ligands. Synthesis and Crystal Structures of [Li(THF)4]2[Cu10{RSi(NPh)3}4] (R = Me,Ph, Vin)

Treatment of CuCl with the lithiated silyl amides RSi(NLiPh)₃ (R = Me, Ph, Vin) in THF as solvent led to the formation of the novel Cu^I cluster compounds [Li(THF)₄]₂[Cu₁₀{RSi(NPh)₃}₄]. For each of the three compounds the X‐ray crystal structure analysis revealed similar Si₄N₁₂Cu₁₀ cores which are based on cubane like Cu₈ cores bearing two additional peripheral copper atoms. The copper atoms are coordinated nearly linearly by the μ₅‐bridging silyl amide ligands with Cu–N distances in the range of 187.1(3) to 194.5(4) pm and N–Cu–N angles of 171.6(1) to 178.7(1)°. For each of the compounds the structural parameters are very similar which indicates that the structures are barely influenced by the different steric requirements of the organic groups bound to silicon.     

Contributions to the Chemistry of Silicon-Sulfur Compounds. 65 synthesis,crystal and molecular structure of cyclo-tetrakis[tri-tert-butoxysilanethiolatogold(I)], [(t-C4H9O)3SiSAu]4, the first example of an Au4S4 ring System

The preparation of the first silanethiolate complex of gold, cyclo-tetrakis[tri-tert-butoxysilanethiolatogold(I)] from tri-tert-butoxysilanethiol and tetrachloroauric acid is described. The compound forms colorless orthorhombic crystals, and the molecular structure was determined at 200 K by single crystal X-ray diffraction. At 187 K, a possible, reversible phase transition is observed. The center of the molecule is a distinctly folded eight-membered Au₄S₄ ring of alternating three-fold coordinated sulfur and two-fold coordinated gold atoms. The relevant bond lengths and angles are: Au? S 228.4 and 229.6 pm, Si? S 216.9 pm, S? Au? S 178.8° and 178.3°, Au? S? Au 90.3°, Si? S? Au 103.7° and 101.9°. The gold atoms are separated by 324.8 pm.     

Übergangsmetallsubstituierte Gallane: Synthese,Struktur und Bindungsverhältnisse von [(CO)4CoGaEt2(NC7H13)], [(PMe3)(CO)3CoGaCl2(NMe3)], [(CO)4CoGaCl3]K und [(CO)5MnGaEt2(NC7H13)]

Transition Metal substituted Gallanes: Synthesis and X-Ray Structures of [(CO)₄CoGaEt₂(NC₇H₁₃)], [(PMe₃)(CO)₃CoGaCl₂(NMe₃)], [(CO)₄CoGaCl₃]K, and [(CO)₅MnGaEt₂(NC₇H₁₃)] The transition metal substituted gallanes [(CO)₅MnGaEt₂(NC₇H₁₃)] ( 1 ), [(PMe₃)(CO)₃CoGaCl₂ · (NMe₃)] ( 2 ), [(CO)₄CoGaEt₂(NC₇H₁₃)] ( 3 ), and [(CO)₄CoGaCl₃]K ( 4 ) were obtained by the reaction of the potassium/sodium salts of the manganese- and cobaltcarbonylmetallates with the chlorogallium species ClGaEt₂(NC₇H₁₃), Cl₃Ga(NMe₃), and GaCl₃. The structures were established by single crystal X-ray analysis 1 : space group P2₁/c (I.T.-No.: 14); Z = 4; a = 1425.4(2) pm, b = 1007.4(1) pm, c = 1429.9(3) pm; β = 113.92(1)°; 2 : space group P2₁/m (I.T.-No.: 11); Z = 2; a = 746.1(1) pm, b = 1131.2(1) pm, c = 1061.5(1) pm; β = 101.87(1)°; 3 : space group P2₁/c (I.T.-No.: 14); Z = 8; a = 1405.9(2) pm, b = 1786.2(2) pm, c = 1430.9(2) pm; β = 91.47(1)°; 4 : space group P2₁/c; Z = 4; a = 1185.7(1) pm, b = 895.4(1) pm, c = 1144.7(3) pm; β = 106.47(2)°. The model compounds [{L′(CO)₃Co}GaX₂L] (L′ = CO, PH₃; L = NH₃, X = H, Cl) with polar σ(Co–Ga) bonds and the effect of the substituent on the bond length are characterized with DFT-calculations.     

夹心三明治结构的二十五核银硫簇合物[Ag25(SC6H4Pri)18 (dppp)6](CF3SO3)7·CH3CN：结构表征及光学性能

在本研究中,使用(ⁱPrC₆H₄SAg)_n作为合成银硫纳米簇合物的前驱体。当存在辅助的双膦配体1, 3-双(二苯基膦)丙烷(dppp)及可溶性银盐(CF₃SO₃Ag),在超声合成条件下,获得了一例二十五核银硫簇合物Ag₂₅,并借助X射线单晶衍射技术确定相应的分子结构。该银硫簇合物具有夹心三明治的骨架结构：分别由两个结构相似的圆柱体共享一个七核纯银簇所构成的金属簇平面。固态紫外可见漫反射光谱测试表明该簇合物的能级带隙为2.5 eV,属于半导体材料的范畴。固态发光测试显示,该簇合物在室温下发射绿光。