共查询到19条相似文献,搜索用时 78 毫秒
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本文总结了将乙炔基、乙烯基、丙烯基、氨基、马来酰亚胺基、氰酸酯基、环氧基等活性基团引入聚芳醚砜链端的方法。引用参考文献27篇。 相似文献
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含甲巯咪唑杂环为端基的非环冠醚的合成 总被引:2,自引:0,他引:2
本文以甲巯咪唑杂环为新的端基,在相转移催化条件合成了五个开链冠醚,这些化合物均通过元素分析、UV、IR 、^1H和^13CNMR波谱鉴定. 相似文献
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本文总结了将乙炔基、乙烯基、丙烯基、氨基、马来欧亚胺基、氰酸酯基、环氧基等活性基团引入聚芳醚砜链端的方法。引用参考文献27篇。 相似文献
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利用一维NMR方法研究了新型聚芳醚酮大环化合物的影响,用二维同核^1H-^1H COSY和^13C-^1H COSY实验方法以及类似物质标准谱图的比较,对一维NMR谱峰进行了归属。 相似文献
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含环氧端基酚酞聚芳醚腈的合成及表征 总被引:1,自引:0,他引:1
环氧树脂(ER)的冲击韧性和耐开裂性较差,因此,提高其抗冲强度而不显著影响力学性能和耐热性能是重要的研究课题.对于ER的增韧,以前主要采用液态橡胶.近年来,人们开始研究使用高性能热塑性树脂增韧ER[1~3].聚醚腈(PCE)是目前机械强度最高的热塑性... 相似文献
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5-甲基-1,3,4-噻二唑-2-硫为端基的非环冠醚的合成 总被引:6,自引:0,他引:6
本文用2-巯基-5-甲基-1,3,4-噻二唑与二溴乙烷或低聚乙二醇溴化物合成了四种新的非环冠醚. 通过元素分析,UV,IR和^1H NMR波谱鉴定. 相似文献
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Noncyclicpolyethershaveattractedmoreandmoreattentionfortheirnonexpensive,lesstoxicityandsoon.Theyhavesomepromisingapplicationsinsolventextractionandenrichmentofmetalionsaswellasintheionselectiveelectrode,etc.[1].NoncyclicpolyetherSchiffbaseisoneofpolyden… 相似文献
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A novel Schiff base (TAMET) was synthesized by the condensation of tetraglycol aldehyde with methionine and a mild oxidant CrO3· (C5H5N)2 was selected for the reaction. Seven new rare earth complexes with this Schiff base have been synthesized and characterized by elemental analysis, TG-DTA, molar conductivity, magnetic susceptibility and IR, especially 1H NMR spectra. Information was obtained from reflectance spectra and the coordination of sulfur atom to rare earths was discussed. The experimental results show that thesecompounds have some biological activity and could dispose of O2. 相似文献
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Ke Cao Zhen Xu Dong Guo Guoliang Liu 《Journal of polymer science. Part A, Polymer chemistry》2021,59(21):2365-2377
Poly(ether imide) (PEI) from polycondensation of 2,2-bis[4-(3,4-dicarboxyphenoxy) phenyl] propane dianhydride (BPADA) and m-phenylenediamine (mPD) is a type of high-temperature engineering thermoplastics that have high glass transition temperature and outstanding mechanical properties. Owing to its wide use in many fields including automotive, aircraft, and electronics, the research of PEI has surged in the last few decades. As science and technology continue to progress rapidly, there is a growing demand for PEIs with better properties. Although a few approaches have successfully improved the properties of PEI, it is recognized that these approaches require complex procedures and are uneconomical. Contrastingly, end-group modification of PEI is highly effective, simple, and economical. Over the last few years, our group has extensively studied the methods for improving the properties of PEI through end-group modification. The end-group moieties and polymer blocks introduce multiple hydrogen bonding, electrostatics, and microphase separation to PEI. In this article, we first classify the end groups based on their characteristics. Then, we compare their effects on the properties of PEIs, including thermal, rheological, mechanical, optical, flame-retardant, and morphological, and discuss the roots of these effects. The in-depth comparisons and discussion generate principles to guide the synthesis of PEIs with tailored properties by modifying the end groups. This timely article will provide insights into the synthesis of other novel high-temperature polymers and entice endeavors to develop novel end groups. 相似文献
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Tadayuki Kunisaki Kimiko Kawai Keiko Hirohata Kazuhiro Minami Koichi Kondo 《Journal of polymer science. Part A, Polymer chemistry》2001,39(6):927-933
The dichlorodihydropyrazines derived from 2,5‐diketopiperazine were treated with diols in a basic condition to afford polyethers containing cyclodipeptide moiety in the main chain, which were found to be degraded into amino acid components in an acidic condition. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 927–933, 2001 相似文献
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Jie Xue Liang Chen Li Zhou Zhifeng Jia Yanping Wang Xinyuan Zhu Deyue Yan 《Journal of Polymer Science.Polymer Physics》2006,44(15):2050-2057
α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006 相似文献
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I. G. Popović M. Tarabić B. šobić L. Katsikas 《Journal of Thermal Analysis and Calorimetry》1997,49(1):169-175
Polymethacrylonitrile (PMAN) was prepared by bulk, solution and precipitation polymerization. The thermal stability of the polymer, which is affected by the structure of the chain end groups, was studied by non-isothermal thermogravimetry (TG). On the basis of the differential TG curves of samples prepared by polymerization in the presence of chlorinated solvents, it may be concluded that, in addition to end-chain and random main chain scission initiated depolymerization, hydrogen chloride evolution also occurs during the thermal degradation of PMAN. 相似文献
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EPR characters of three new gadolinium complexes with noncydic polyether Schiff bases in powder or organic solvents, including various oxyethylene chain lengths and different substituting groups in ligands, are investigated respectively. Some regularities are summed up. The difference of EPR character in various solvents, particularly at different temperatures, has been examined. The 'single peak effect' due to THF solvent at low temperature is observed for the first time. This phenomenon is explicated. 相似文献
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M. Gali V. Cdiz A. Mantecn A. Serra 《Journal of polymer science. Part A, Polymer chemistry》1992,30(11):2379-2387
Polyethers with nadimide derivatives pendent groups have been prepared by ring-opening polymerization of nadimide glycidyl derivatives. The structure of the linear polymers has been confirmed by spectroscopic methods. Properties such glass transition temperatures and thermal resistance have been measured and related to their chemical structure. Crosslinking studies have been carried out by DSC and TGA. Kinetic parameters could be obtained by dynamic method. The crosslinking causes an increase in Tg of the system and it has been possible to relate this increase to the chemical structure of the network. © 1992 John Wiley & Sons, Inc. 相似文献