共查询到20条相似文献,搜索用时 140 毫秒
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探讨了一类具有高位阻特征的烃基膦酸单十六烷基酯萃取剂R1(R2O)P(O)OH从氯化物介质中萃取Yb(Ⅲ)和Lu(Ⅲ)的结构与性能关系.其中,R1分别为CH2,C2H5,i-C3H7,cyclo-C3H11和C6H5,R2为C4H9CH(C2H5)C2H4CH(C6H13)或C6H13CH(CH3)CH2CH(C6H13).结果表明,这类萃取剂对于Yb,Lu的萃取和分离能力随着其分子中取代基空间位阻的增大而降低. 相似文献
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在研究O,O二烷基O芳基硫代磷酸酯(1)与三氯氧磷的异构化氯化反应机理时,发现1的异构化产物O,S二烷基硫代磷酸酯(4)能顺利地与三氯氧磷反应,4中的烷氧基被氯原子取代,得到的产物S烷基硫代磷酰氯酯(2)和O烷基磷酰二氯酯3.当4中的R为烷基或苯基,R'为烷氧基、芳氧基、烷硫基、芳硫基、二烷基氨基、氮杂环基、苯基和甲基,R"为C1-4烷基时,4的氯化反应也能顺利发生,并得到较高产率的预期产物. 相似文献
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O,O-二烷基硫代磷(膦)酸酯(1)与三氯氧磷作用得到S-烷基硫代磷酰氯(2)和O-烷基磷酰二氯(3),此反应包含异构化和氧化两个过程.实验结果表明,1的预期氯化产物O-烷基硫代磷(膦)酰氯酯(5)与三氯氧磷不发生反应,而1的预期异构化产物O,S-二烷基硫代磷(膦)酸酯(6)与三氯氧磷能顺利反应得到2.由此推测,在1的异构化/氯化反应中,异构化很可能发生在氯化之前.根据此结果和三角双锥中间体(TBP)概念,提出了该反应初步的可能机理. 相似文献
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用二甲基胺取代 烃基膦酸树脂对钆的吸附行为进行研究,试验结果表明,在pH4.90时,树脂对钆的静态饱和吸附容量为219mg·g-1(树脂);用2mol·L-1HCl可以定量洗脱;表观吸附速率常数k298=1.81×10-4s-1,测得吸附热力学参数分别为:ΔH=77.46kJ·mol-1,ΔG=-32.417kJ·mol-1,ΔS=368.69J·mol-1·K-1;等温吸附服从Frenndlich曲线;树脂功能基与Gd(Ⅲ)的配位比为2∶1;并用红外光谱探讨了树脂与钆的成键情况。 相似文献
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The chemical ionization (CI) mass spectrometry of fumaric and maleic acids and their esters with methylene chloride as reagent gas is described. The introduction of methylene chloride to the CI(CH4) plasma led to the formation of new characteristic ions in addition to the protonation and the subsequent fragmentation, revealing diagnostic information on the configuration of geometrical isomers. The new characteristic ions have been found to arise from the addition of the reactant ion of methylene chloride, [CH2Cl]+, to the substrates and, for higher dialkyl esters, from the further McLafferty rearrangement of the adduct ion [M + CH2Cl]+. 相似文献
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Adrián Schwarzenberg Farid Ichou Richard B. Cole Xavier Machuron‐Mandard Christophe Junot Denis Lesage Jean‐Claude Tabet 《Journal of mass spectrometry : JMS》2013,48(5):576-586
Organophosphorus compounds have played important roles as pesticides, chemical warfare agents and extractors of radioactive material. Structural elucidation of phosphonates poses a particular challenge because their initial forms can be hydrolyzed, thus, degradation products may predominate in samples acquired in the field. The analysis of non‐volatile organophosphorus compounds and their degradation products is possible using electrospray tandem mass spectrometry ESI‐MS/MS. Here, we present a generic strategy that allows the unambiguous identification of substituents for two families of organophosphorus compounds: the phosphonates and phosphates. General fragmentation rules were deduced based on the study of decomposition pathways of 55 organophosphorus esters, including examples found in the literature. Multistage MS (MSn) experiments at high resolution in a hybrid mass spectrometer provide accurate mass measurements, whereas collision‐induced dissociation experiments in a triple quadrupole give access to small fragment ions. The creation of a specific nomenclature for each possible structure of organophosphorus compound, depending on the alkyl side chain linked to the oxygen, was achieved by applying these fragmentation rules. This led to the creation of an ‘identification tree’ based upon the unique consecutive decomposition pathways uncovered for each individual compound. Hence, seven structural motifs were created that orient an unequivocal identification using the ‘identification tree’. Despite the similar structures of the ensemble of phosphate and phosphonate esters, distinct identifications based upon characteristic neutral losses and diagnostic fragment ions were possible in all cases. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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Polyhitroethylurethanes react smoothly with various nitroso compounds in the presence of dibromoisocyanurate to give polynitroalkyl esters of ONN-azoxycarboxylic acids in a yield of 55–95%.N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 7, pp. 1660–1663, July, 1992. 相似文献
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S. A. Matlin L. Chan M. A. Prazeres S. Mehani Q. B. Cass 《Journal of separation science》1987,10(4):186-190
Procedures are described for the normal phase and reverse phase HPLC analysis of testosterone esters having diverse side chains: examples are given of the gram-scale purification of these compounds using two commercial preparative liquid chromatography and an economical and efficient laboratory-assembled preparative liquid chromatograph. 相似文献
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The influence of substituents on the thermal decomposition of monomeric organic compounds was studied. For this purpose the
thermal destruction of dozen or so α-amino acids of the diversified chemical constitution, among others compounds containing
the second amine group, additional carboxyl group, amino acids containing hydroxyl or sulfhydryl groups and amino acids connected
with five-member heterocyclic ring or existing in the form of hydrates or hydrochlorides were investigated. The analyses were
performed using a derivatograph in an air atmosphere, sample sizes were from 50 to 200 mg and heating rate from 3 to 15 K
min-1. It has been established that the thermal decomposition of studied compounds occurs in three stages. The temperature ranges,
in which the analyzed compounds undergo thermal transformations were established. For evaluation of the thermoanalytical results
an advanced multivariate data processing method, principal component analysis (PCA), was used. By this method the influence
of the specific functional groups on the thermal decomposition of α-amino acids was determined. The stage of decomposition,
in which the thermoanalytic data are the best correlated to the chemical constitution of the compound, is the second stage.
It has also been recognized, that better discrimination among the analyzed compounds was obtained for the data set of the
DTA. 相似文献
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Conclusions The Arbuzov reaction and alkylation by -haloalkylphosphonic esters gave diesters of aminooxymethane-, -aminooxyethane-, and -aminooxybutanephosphonic acids; aminooxymethane- and -aminooxyethanephosphonic acids; and monoesters of -aminooxyethanephosphonic acid.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1202–1204, May, 1986. 相似文献