Viscometric properties of viscous theta solutions of monodisperse polystyrene

Theta solvents for polystyrene are prepared from high-viscosity blends of styrene and low-molecular-weight polystyrene, and then used to make dilute solutions with monodisperse polystyrene solutes of high-M = 2.3, 6.0, 9.0, 18.0 · 10⁵. A Weissenberg rheogoniometer is used to measure the non-Newtonian viscosity as a function of shear stress, for low values, and also the complex viscosity components and as functions of frequency. A capillary viscometer is used for high- measurements of(). Viscometric properties, at room temperature, are analyzed as functions of high-molecular-weight solute concentrationc with parameters of constant or to obtain [()], [ ()], and [ ()]. Such a collection of data has apparently not previously been available for polymers in theta solvents (in which Gaussian chain statistics prevail). Also unique is the achievement of high stress ( = 2 10⁴ Pa) at low shear rate, by virtue of high solvent viscosity which is not characteristic of other known theta solvents.     

Flow in porous media I: A theoretical derivation of Darcy's law

Stokes flow through a rigid porous medium is analyzed in terms of the method of volume averaging. The traditional averaging procedure leads to an equation of motion and a continuity equation expressed in terms of the volume-averaged pressure and velocity. The equation of motion contains integrals involving spatial deviations of the pressure and velocity, the Brinkman correction, and other lower-order terms. The analysis clearly indicates why the Brinkman correction should not be used to accommodate ano slip condition at an interface between a porous medium and a bounding solid surface.The presence of spatial deviations of the pressure and velocity in the volume-averaged equations of motion gives rise to aclosure problem, and representations for the spatial deviations are derived that lead to Darcy's law. The theoretical development is not restricted to either homogeneous or spatially periodic porous media; however, the problem ofabrupt changes in the structure of a porous medium is not considered.Roman Letters A interfacial area of the - interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the - interface contained within the averaging volume, m² - A ^* interfacial area of the - interface contained within a unit cell, m² - Ae area of entrances and exits for the -phase contained within a unit cell, m² - B second order tensor used to represent the velocity deviation (see Equation (3.30)) - b vector used to represent the pressure deviation (see Equation (3.31)), m^–1 - d distance between two points at which the pressure is measured, m - g gravity vector, m/s² - K Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the -phase (see Figure 2), m - characteristic length scale for the -phase (see Figure 2), m - n unit normal vector pointing from the -phase toward the -phase (n =–n ) - n _e unit normal vector for the entrances and exits of the -phase contained within a unit cell - p pressure in the -phase, N/m² - p intrinsic phase average pressure for the -phase, N/m² - p –p , spatial deviation of the pressure in the -phase, N/m² - r ₀ radius of the averaging volume and radius of a capillary tube, m - v velocity vector for the -phase, m/s - v phase average velocity vector for the -phase, m/s - v intrinsic phase average velocity vector for the -phase, m/s - v –v , spatial deviation of the velocity vector for the -phase, m/s - V averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ Greek Letters V/V, volume fraction of the -phase - mass density of the -phase, kg/m³ - viscosity of the -phase, Nt/m² - arbitrary function used in the representation of the velocity deviation (see Equations (3.11) and (B1)), m/s - arbitrary function used in the representation of the pressure deviation (see Equations (3.12) and (B2)), s^–1     

Transport in ordered and disordered porous media V: Geometrical results for two-dimensional systems

In this paper we continue the geometrical studies of computer generated two-phase systems that were presented in Part IV. In order to reduce the computational time associated with the previous three-dimensional studies, the calculations presented in this work are restricted to two dimensions. This allows us to explore more thoroughly the influence of the size of the averaging volume and to learn something about the use of anon-representative region in the determination of averaged quantities.

Nomenclature

Roman Letters A interfacial area of the– interface associated with the local closure problem, m² - a _i i=1, 2, gaussian probability distribution used to locate the position of particles - l unit tensor - characteristic length for the-phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1,2,3 lattice vectors, m - m convolution product weighting function - m _V special convolution product weighting function associated with a unit cell - n _i i=1, 2 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume,V, m³ - x position of the centroid of an averaging area, m - x ₀ reference position of the centroid of an averaging area, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters V /V, volume average porosity - _{a i} standard deviation ofa _i - _r standard deviation ofr - intrinsic phase average of      

The effect of surface mass transfer on buoyancy induced flow in a variable porosity medium adjacent to a vertical heated plate

The effect of surface mass transfer on buoyancy induced flow in a variable porosity medium adjacent to a heated vertical plate is studied for high Rayleigh numbers. Similarity solutions are obtained within the frame work of boundary layer theory for a power law variation in surface temperature,T _Wx and surface injectionv _Wx(–1/2). The analysis incorporates the expression connecting porosity and permeability and also the expression connecting porosity and effective thermal diffusivity. The influence of thermal dispersion on the flow and heat transfer characteristics are also analysed in detail. The results of the present analysis document the fact that variable porosity enhances heat transfer rate and the magnitude of velocity near the wall. The governing equations are solved using an implicit finite difference scheme for both the Darcy flow model and Forchheimer flow model, the latter analysis being confined to an isothermal surface and an impermeable vertical plate. The influence of the intertial terms in the Forchheimer model is to decrease the heat transfer and flow rates and the influence of thermal dispersion is to increase the heat transfer rate.

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Der Effekt des Oberflächenstoffaustausches bei auftriebsinduzierter Strömung in einem variablen porösen Medium, das an eine vertikale, beheizte Platte angrenzt

Zusammenfassung Es wird der Effekt des Oberflächenstoffaustausches in auftriebsinduzierter Strömung in einem variablen porösen Medium, das an eine vertikale, beheizte Platte angrenzt, für große Reynoldszahlen untersucht. Ähnliche Lösungen werden im Rahmen der Grenzschicht-Theorie, durch Variation des Potenzansatzes der Oberflächentemperatur,T _Wx , und der Oberflächengeschwindigkeit,v _Wx(–1/2), erreicht. Die Analyse vereinigt sowohl den Ausdruck, der Porösität und Permeabilität verbindet, als auch den Ausdruck, der Porösität und Wärmeleitfähigkeit miteinander verbindet. Der Einfluß der Temperaturverteilung auf Strömung und Wärmeübergangskennzahlen wird ebenfalls im Detail analysiert. Als Ergebnis der vorliegenden Untersuchung ergibt sich die Tatsache, daß variable Porösität Wärmeübertragungsrate und Betrag der Geschwindigkeit in Wandnähe steigert. Die bestimmenden Gleichungen, sowohl für das Darcysche Strömungsmodell als auch für das Forchheimersche Strömungsmodell, werden mit Hilfe eines implizierten Differenzenschemas gelöst. Die Berechnung wird für die beiden Fälle, isotherme Oberfläche und undurchlässige vertikale Platte, angewandt. Der Einfluß der Terme für die Trägheitskräfte im Forchheimerschen Modell senkt Wärmeübergangs- und Durchgangsrate, wogegen die Wärmeübergangsrate durch den Einfluß der Temperaturverteilung erhöht wird.

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Nomenclature a constant defined by Eq. (12) - A constant defined by Eq. (12) - B constant defined by Eq. (3) - b _s/_f ratio of thermal conductivities - C constant defined by Eq. (1) - C _P specific heat of the convective fluid - d particle diameter - f dimensionless function defined by Eq. (14) - f _w lateral mass flux parameter - g acceleration due to gravity - k ₀ mean permeability of the mediumk ₀= ₀ ³ d ²/150 (1– ₀)² k ₀=1.75d/(1– ₀) 150 (Inertia parameter) - L length of the source or sink - m mass transfer - n constant defined in Eq. (12) - k (y) permeability of the porous medium - k (y) interial coefficient in the Ergun expression - Gr modified Grashof numberGr=(g k ₀ k ₀ (T _w–))/ ² - R _a Rayleigh number (g k ₀ x T _w–)/ - R _ad modified Rayleigh number (g k ₀ d|T _w–|)/ - N _u Nusselt number - s x/d - Q overall heat transfer rate - T temperature - T _w surface temperature - T ambient fluid temperature - u velocity in vertical direction - v velocity in horizontal direction - x vertical coordinate - y horizontal coordinate Greek symbols ₀ mean thermal diffusivity _f/ C_p - coefficient of thermal expansion - constant defined in Eq. (4) - ratio of particle to bed diameter - _e effective thermal conductivity - f thermal conductivity of fluid - _s thermal conductivity of solid - dimensionless similarity variable in Eq. (13) - value of at the edge of the boundary layer - constant defined in Eq. (1) - _e effective molecular thermal diffusivity - (y) porosity of the medium - ₀ mean porosity of the medium - viscosity of the fluid - ₀ density of the convective fluid - stream function - w condition at the wall - condition at infinity     

Einige Beziehungen zwischen Transportkoeffizienten und thermodynamischen Zustandsgrö\en

Zusammenfassung Eine früher mitgeteilte Beziehung [1] zwischen der ViskositÄt und dem isenthalpen Joule-Thomson-Koeffizienten _h wird für kleine Drücke theoretisch begründet und an sieben Stoffen nachgeprüft. Die WärmeleitfÄhigkeit wird als Funktion von c_v für drei Stoffe dargestellt.

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Some relations between transport coefficients and thermodynamical properties

A formerly given relation [1] between viscosity and isenthalpic Joule-Thomson-coefficient _h is proved theoretically for small pressures and checked with seven substances. The heat conductivity is presented as a function ofc_v for three substances.

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Bezeichnungen B ^* dimensionsloser zweiter Virialkoeffizient - B ₁ ^* Ableitung vonB ^* nachT ^*.B ₁ ^*=T ^* dB ^*/dT ^* - c _v isochore spezifische WärmekapazitÄt - C _p ^o isobare molare WärmekapazitÄt fürp 0 - h spezifische Enthalpie - k Boltzmann-Konstante.k=R/N _A - M molare Masse - N _A Avogadro-Konstante - p Druck - R molare Gaskonstante - R _i spezifische Gaskonstante des Stoffesi - it Celsius-Temperatur - T Kelvin-Temperatur - T ^* dimensionslose Temperatur.T ^*=kT/ - _h isenthalper Joule-Thomson-Koeffizient. _h=(T/p)_h - , Konstanten der Potentialfunktion - ViskositÄt - WärmeleitfÄhigkeit - (^2,2)^* dimensionsloses Sto\integral     

Effect of measuring volume length on two-component laser velocimeter measurements in a turbulent boundary layer

The effects of finite measuring volume length on laser velocimetry measurements of turbulent boundary layers were studied. Four different effective measuring volume lengths, ranging in spanwise extent from 7 to 44 viscous units, were used in a low Reynolds number (Re=1440) turbulent boundary layer with high data density. Reynolds shear stress profiles in the near-wall region show that u v strongly depends on the measuring volume length; at a given y-position, u v decreases with increasing measuring volume length. This dependence was attributed to simultaneous validations on the U and V channels of Doppler bursts coming from different particles within the measuring volume. Moments of the streamwise velocity showed a slight dependence on measuring volume length, indicating that spatial averaging effects well known for hot-films and hot-wires can occur in laser velocimetry measurements when the data density is high.List of symbols time-averaged quantity - u wall friction velocity, ( _w /)^1/2 - v kinematic viscosity - d _p pinhole diameter - l _eff spanwise extent of LDV measuring volume viewed by photomultiplier - l ⁺ non-dimensional length of measuring volume, l _eff u /v - y ⁺ non-dimensional coordinate in spanwise direction, y u /v - z ⁺ non-dimensional coordinate in spanwise direction, z u /v - U ⁺ non-dimensional mean velocity, /u - u instantaneous streamwise velocity fluctuation, U &#x2329;U - v instantaneous normal velocity fluctuation, V–V - u RMS streamwise velocity fluctuation, u ^21/2 - v RMS normal velocity fluctuation, v ^21/2 - Re Reynolds number based on momentum thickness, U 0/v - R _uv cross-correlation coefficient, u v/u v - R₁₂(0, 0, z) two point correlation between u and v with z-separation, <u(0, 0, 0) v (0, 0, z)>/<u(0, 0, 0) v (0, 0, 0)> - N rate at which bursts are validated by counter processor - T Taylor time microscale, u (dv/dt²)^–1/2     

LDA measurements in low Reynolds number turbulent boundary layer

LDA measurements of the mean velocity in a low Reynolds number turbulent boundary layer allow a direct estimate of the friction velocity U from the value of /y at the wall. The trend of the Reynolds number dependence of / is similar to the direct numerical simulations of Spalart (1988).     

A non-dualistic unified field theory of gravitation,electromagnetism and spin

The wisdom of classicalunified field theories in the conceptual framework of Weyl, Eddington, Einstein and Schrödinger has often been doubted and in particular there does not appear to be any empirical reason why the Einstein-Maxwell (E-M) theory needs to be geometrized. The crux of the matter is, however not whether the E-M theory is aesthetically satisfactory but whether it answers all the modern questions within the classical context. In particular, the E-M theory does not provide a classical platform from which the Dirac equation can be derived in the way Schrödinger's equation is derived from classical mechanics via the energy equation and the Correspondence Principle. The present paper presents a non-dualistic unified field theory (UFT) in the said conceptual framework as propounded by M. A. Tonnelat. By allowing the metric formds ²=g dx ^v x ^v and the non-degenerate two-formF=(1/2> _l) dx ^vdx ^vto enter symmetrically into the theory we obtain a UFT which contains Einstein's General Relativity and the Born-Infeld electrodynamics as special cases. Above all, it is shown that the Dirac equation describing the electron in an external gravito-electromagnetic field can be derived from the non-dualistic Einstein equation by a simple factorization if the Correspondence Principle is assumed.     

Transport in ordered and disordered porous media III: Closure and comparison between theory and experiment

In this paper we examine the closure problem associated with the volume averaged form of the Stokes equations presented in Part II. For both ordered and disordered porous media, we make use of a spatially periodic model of a porous medium. Under these circumstances the closure problem, in terms of theclosure variables, is independent of the weighting functions used in the spatial smoothing process. Comparison between theory and experiment suggests that the geometrical characteristics of the unit cell dominate the calculated value of the Darcy's law permeability tensor, whereas the periodic conditions required for thelocal form of the closure problem play only a minor role.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A interfacial area of the- interface associated with the local closure problem, m² - A _p surface area of a particle, m² - b vector used to represent the pressure deviation, m^–1 - B ⁰ B+I, a second order tensor that maps v _m ontov - B second-order tensor used to represent the velocity deviation - d _p 6V _p/A_p, effective particle diameter, m - d a vector related to the pressure, m - D a second-order tensor related to the velocity, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor calculated on the basis of a spatially periodic model, m² - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p characteristic length for the volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - characteristic length (pore scale) for the-phase - _i i=1, 2, 3 lattice vectors, m - weighting function - m(-y) , convolution product weighting function - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - n unit normal vector pointing from the-phase toward the -phase - p pressure in the-phase, N/m² - p _m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p – p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function - r position vector, m - r position vector locating points in the-phase, m. - V averaging volume, m³ - B volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v _m superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - v traditional superficial volume averaged velocity, m/s - v – v _m , spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the -phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * , weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

On natural convection from a vertical plate with a prescribed surface heat flux in porous media

This paper presents a theoretical and numerical investigation of the natural convection boundary-layer along a vertical surface, which is embedded in a porous medium, when the surface heat flux varies as (1 +x ²)), where is a constant andx is the distance along the surface. It is shown that for > -1/2 the solution develops from a similarity solution which is valid for small values ofx to one which is valid for large values ofx. However, when -1/2 no similarity solutions exist for large values ofx and it is found that there are two cases to consider, namely < -1/2 and = -1/2. The wall temperature and the velocity at large distances along the plate are determined for a range of values of .Notation g Gravitational acceleration - k Thermal conductivity of the saturated porous medium - K Permeability of the porous medium - l Typical streamwise length - q _w Uniform heat flux on the wall - Ra Rayleigh number, =gK(q _w /k)l/(v) - T Temperature - Too Temperature far from the plate - u, v Components of seepage velocity in the x and y directions - x, y Cartesian coordinates - Thermal diffusivity of the fluid saturated porous medium - The coefficient of thermal expansion - An undetermined constant - Porosity of the porous medium - Similarity variable, =y(1+x ) ^/3/x ^1/3 - A preassigned constant - Kinematic viscosity - Nondimensional temperature, =(T – T )Ra^1/3 k/qw - Similarity variable, = =y(log_e x)^1/3/x ^2/3 - Similarity variable, =y/x ^2/3 - Stream function     

Experimental investigation of a hybrid wind tunnel model

New developments in power electronics (such as the linear motor) may be of great advantage for future economic aerodynamic testing. After a comprehensive review of economical aspects of present wind tunnel technologies, the experimental verification of the hybrid wind tunnel concept will be presented. A scale law is derived to extrapolate the experimental results of the model-HWT to a facility size for simulating full scale Re-numbers. Finally, methods will be discussed by which the flow constancy during the running time may be improved.List of symbols A area - a velocity of sound - d diameter - i influence region - l length - Ma Mach number - m facility mass - n exponent in power law of boundary layer profile u/u ₂ = (y/)^1/n - P power - p pressure - q kinetic pressure (=(/2)u ²) - Re Reynolds number - r radius - t time - u, w velocity - V volume - x, y coordinates - boundary layer thickness - ^* boundary layer displacement thickness - velocity deficit at boundary layer edge (usually defined as = 0.01) - windtunnel efficiency factor - efficiency - ratio of specific heats - test facility mass ratio - kinematic viscosity - normalized coordinate - mass density - stress - ( )_1,2,3 flow region (Fig. 1) presuffix 0 signifies - ( )_2,2,2 flow state (Figs. 7; 11) stagnation condition - ( ) test section values - ( ) _c cryo-windtunnel - ( ) _d diffusor - ( ) _D model drag - ( ) _el electric - ( ) _ew1 head of expansion wave - ( ) _ew2 tail of expansion wave - ( ) _f fan - ( ) _fs fan shaft - ( ) _mt model tunnel - ( ) _N normal temperature windtunnel - ( ) _or original tunnel - ( ) _r,l right, leftrunning waves - ( ) _rp wind tunnel return pipe - ( ) _s suction tube - ( ) _sl test sled - ( ) _sw shock wave - ~ relative system - - values normalized with a ₁ or p ₁ - ETW European Transonic Windtunnel (early, noncryogenic concepts. A = 21 m₂) - HWT Hybrid-Wind-Tunnel - LIM Linear Induction Motor - LN₂ Liquid Nitrogen - LT Ludwieg-tube     

The mirror relations and nonlinear viscoelasticity of polymer melts

An attempt is made to incorporate into a quasilinear viscoelastic constitutive equation of the Boltzmann superposition type the two mirror relations of Gleissle, as well as his relation between the steady-state first normal-stress difference and the shear viscosity curve. It is shown that the three relations can hold separately within this constitutive model, but not simultaneously, because they require a different nonlinear strain measure, namelyS ₁₂ () = – a ( – 1) (a = 0 for 1,a = 1 for 1) for the mirroring of the viscosities,S ₁₂ () = – a (–k ²/) (a = 0 for k, a = 1 for k) for the mirroring of the first normal-stress coefficients, and for the third relation. Here denotes the shear strain and erf the error function. Experimental data on melts of a low-density polyethylene, a high-density polyethylene and a polypropylene show that the mirror relations are passable approximations, but that the third relation meets reality surprisingly close if the right value ofk is used.     

The chaotic response of a fluttering panel: The influence of maneuvering

The influence of maneuvering on the chaotic response of a fluttering buckled plate on an aircraft has been studied. The governing equations, derived using Lagrangian mechanics, include geometric non-linearities associated with the occurrence of tensile stresses, as well as coupling between the angular velocity of the maneuver and the elastic degrees of freedom. Numerical simulation for periodic and chaotic responses are conducted in order to analyze the influence of the pull-up maneuver on the dynamic behavior of the panel. Long-time histories phase-plane plots, and power spectra of the responses are presented. As the maneuver (load factor) increases, the system exhibits complicated dynamic behavior including a direct and inverse cascade of subharmonic bifurcations, intermittency, and chaos. Beside these classical routes of transition from a periodic state to chaos, our calculations suggest amplitude modulation as a possible new mode of transition to chaos. Consequently this research contributes to the understanding of the mechanisms through which the transition between periodic and strange attractors occurs in, dissipative mechanical systems. In the case of a prescribed time dependent maneuver, a remarkable transition between the different types of limit cycles is presented.Nomenclature a plate length - a _r u _r /h - D plate bending stiffness - E modulus of elasticity - g acceleration due to gravity - h plate thickness - j₁,j₂,j₃ base vectors of the body frame of reference - K spring constant - M Mach number - n 1 + ₀/g - N ₁ applied in-plane force - p–p aerodynamic pressure - P pa ⁴/Dh - q ₀/2 - Q _r generalized Lagrangian forces - R rotation matrix - R ₄ N, a ²/D - t time - kinetic energy - u plate deflection - u displacement of the structure - u _r modal amplitude - v₀ velocity - x coordinates in the inertial frame of reference - z coordinates in the body frame of reference - Ka/(Ka+Eh) - - elastic energy - 2qa ³/D - a/_mh - Poisson's ratio - material coordinates - air density - _m plate density - - _r prescribed functions - _r sin(r z/a) - angular velocity - a/v₀ - skew-symmetric matrix form of the angular velocity     

A new interpretation of viscosity and yield stress in dense slurries: Coal and other irregular particles

Illinois coal was ground and wet-sieved to prepare three powder stocks whose particle-size distributions were characterized. Three suspending fluids were used (glycerin, bromonaphthalene, Aroclor), with viscosities _s that differed by a factor of 100 and with very different chemistries, but whose densities matched that of the coal. Suspensions were prepared under vacuum, with coal volume fractions that ranged up to 0.46. Viscosities were measured in a cone-and-plate over a shear rate range 10^–3–10² s^–1. Reduced viscosity _r = /_s is correlated in the high-shear limit ( ) with/ _M, where _M is the maximum packing fraction for the high-shear microstructure, to reveal the roles of size distribution and suspending fluid character. A new model that invokes the stress-dependence of _M is found to correlate _r well under non-Newtonian conditions with simultaneous prediction of yield stress at sufficiently high; a critical result is that stress and not governs the microstructure and rheology. Numerous experimental anomalies provide insight into suspension behavior.     

Rheology of molten polymers

Summary TheCross equation describes the flow of pseudoplastic liquids in terms of an upper and a lower Newtonian viscosity corresponding to infinite and zero shear, and ₀, and of a third material constant related to the mechanism of rupture of linkages between particles in the intermediate, non-Newtonian flow regime, Calculation of of bulk polymers is important, since it cannot be determined experimentally. The equation was applied to the melt flow data of two low density polyethylenes at three temperatures.Using data in the non-Newtonian region covering 3 decades of shear rate to extrapolate to the zero-shear viscosity resulted in errors amounting to about onethird of the measured ₀ values. The extrapolated upper Newtonian viscosity was found to be independent of temperature within the precision of the data, indicating that it has a small activation energy.The ₀ values were from 100 to 1,400 times larger than the values at the corresponding temperatures.The values of were large compared to the values found for colloidal dispersions and polymer solutions, but decreased with increasing temperature. This shows that shear is the main factor in reducing chain entanglements, but that the contribution of Brownian motion becomes greater at higher temperatures.

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Zusammenfassung Die Gleichung vonCross beschreibt das Fließverhalten von pseudoplastischen Flüssigkeiten durch drei Konstante: Die obereNewtonsche Viskosität (bei sehr hohen Schergeschwindigkeiten), die untereNewtonsche Viskosität ₀ (bei Scherspannung Null), und eine Materialkonstante, die vom Brechen der Bindungen zwischen Partikeln im nicht-Newtonschen Fließbereich abhängt. Die Berechnung von ist wichtig für unverdünnte Polymere, wo man sie nicht messen kann.Die Gleichung wurde auf das Fließverhalten der Schmelzen von zwei handelsüblichen Hochdruckpolyäthylenen bei drei Temperaturen angewandt. Die Werte von ₀, durch Extrapolation von gemessenen scheinbaren Viskositäten im Schergeschwindigkeitsbereich von 10 bis 4000 sec^–1 errechnet, wichen bis 30% von den gemessenen ₀-Werten ab. Die Aktivierungsenergie der war so klein, daß die-Werte bei den drei Temperaturen innerhalb der Genauigkeit der Extrapolation anscheinend gleich waren. Die ₀-Werte waren 100 bis 1400 mal größer als die-Werte.Im Verhältnis zu kolloidalen Dispersionen und verdünnten Polymerlösungen war das der Schmelzen groß, nahm aber mit steigender Temperatur ab. Deshalb wird die Verhakung der Molekülketten hauptsächlich durch Scherbeanspruchung vermindert, aber der Beitrag derBrownschen Bewegung nimmt mit steigender Temperatur zu.

     

Nonstationary vibration of a rotating shaft with nonlinear spring characteristics during acceleration through a critical speed (A critical speed of a summed-and-differential harmonic oscillation)

Nonstationary vibration of a flexible rotating shaft with nonlinear spring characteristics during acceleration through a critical speed of a summed-and-differential harmonic oscillation was investigated. In numerical simulations, we investigated the influence of the angular acceleration , the initial angular position of the unbalance _n and the initial rotating speed on the maximum amplitude. We also performed experiments with various angular accelerations. The following results were obtained: (1) the maximum amplitude depends not only on but also on _n and : (2) when the initial angular position _n changes. the maximum amplitude varies between two values. The upper and lower bounds of the maximum amplitude do not change monotonously for the angular acceleration: (3) In order to always pass the critical speed with finite amplitude during acceleration. the value of must exceed a certain critical value.Nomenclature O-xyz rectangular coordinate system - , ₁, ₁ inclination angle of rotor and its projections to thexy- andyz-planes - I _r polar moment of inertia of rotor - I diametral moment of inertia of rotor - i _r ratio ofI _r toI - dynamic unbalance of rotor - directional angle of fromx-axis - c damping coefficient - spring constant of shaft - N _nt ,N _nt nonlinear terms in restoring forees in ₁ and ₁ directions - ₄ representative angle - a small quantity - V. V _u .V _N potential energy and its components corresponding to linear and nonlinear terms in the restoring forees - directional angle - _n coefficients of asymmetrical nonlinear terms - _n coefficients of symmetrical nonlinear terms - coefficients of asymmetrical nonlinear terms experessed in polar coordinates - coefficients of symmetrical nonlinear terms expressed in polar coordinates - rotating speed of shaft - t time - _n initial angular position of att=0 - p natural frequency - p ₁.p _t natural frequencies of forward and backward precessions - , ₁, ₁ total phases of harmonic, forward precession and backward precession components in summed-and-differential harmonic oscillation - , ₁, ₁ phases of harmonic, forward precession and backward precession components in summed-and-differential harmonic oscillation - P, R _t ,R _b amplitudes of harmonic, forward precession and backward precession components in summed-and-differential harmonic oscillation - difference between phases ( = _f – _u) - acceleration of rotor - initial rotating speed - t _t ,r _b amplitudes of nonstationary oscillation during acceleration - (r _t )_max, (r _b )_max maximum amplitudes of nonstationary oscillation during acceleration - (r ₁ ¹ )_max, (r _b ¹ )_max maximum value of angular acceleration of non-passable case - ₀ critical value over which the rotor can always pass the critical speed - p ₁,p ₂,p ₃,p ₄ natural frequencies of experimental apparatus     

Experimentelle Bestimmung von Diffusionskoeffizienten in den gasförmigen Systemen He-CH4, He-N2 und CH4-N2

Zusammenfassung Mit einer Apparatur nach dem Meßprinzip von Loschmidt wurden für die Systeme He-CH₄, He-N₂ und CH₄-N₂ binäre Gasdiffusionskoeffizienten innerhalb des Temperaturbereiches 173 < T < 273 K und des Druckbereiches 1,5 < p < 6 bar bestimmt. Die Meßdaten können mit Hilfe einer einfachen halbempirischen Funktion korreliert werden. Ein Vergleich mit Literaturwerten ist durch Extrapolation möglich und zeigt sehr gute Übereinstimmung.

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Experimental determination of binary diffusion coefficients in the gaseous systems He-CH₄, He-N₂, CH₄-N₂

An apparatus based on Loschmidt's method was built operable in the temperature range 100 < T < 300 K and the pressure range 1 < p < 150 bar. A series of measurements was performed in order to determine the binary diffusion coefficients of He-CH₄, He-N₂ and CH₄-N₂ for the ranges 173 < t < 273 K and 1,5 < p < 6 bar. The results can be correlated with the semi-empirical equation D_ij(T, p)=D_oij (T₀, p₀)(t/t₀)^m(p₀/p)ⁿ. Extrapolations coincide with available data.

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Formelzeichen D_ij binärer Gasdiffusionskoeffizient (cm²/s) - t₀ Versuchszeit (s) - l Rohrlänge (cm) - h Länge eines Rohrteiles (cm) - c_i Konzentration des Gases i (mol/cm³) - _i dimensionslose Konzentration c_i/c_i0 - dimensionslose Zeit t/t₀ - dimensionslose Länge x/1 - Fo Fourier-Zahl für den Stofftransport (D_ij t₀/l²) - erf z Fehlerfunktion - ¯_i über einen Bereich gemittelte dimensionslose Konzentration - ¯_io, ¯_iu mittlere Konzentration des Gases i im oberen bzw. unteren Rohrteil - q ¯_iu/¯_io - T Temperatur (K) - p Druck (bar) - m, n Exponenten in der Ausgleichsfunktion - F Peakfläche am Gaschromatographen - relativer Fehler der Ausgleichsfunktion (D_Afkt.-D_exptl.–100/D_exptl. (%) Herrn Professor Dr. Romano Gregorig gewidmet zum 65. Geburtstag.     

Impacts of local dispersion and first-order decay on solute transport in randomly heterogeneous porous media

Stochastic subsurface transport theories either disregard local dispersion or take it to be constant. We offer an alternative Eulerian-Lagrangian formalism to account for both local dispersion and first-order mass removal (due to radioactive decay or biodegradation). It rests on a decomposition of the velocityv into a field-scale componentv , which is defined on the scale of measurement support, and a zero mean sub-field-scale componentv _s , which fluctuates randomly on scales smaller than. Without loss of generality, we work formally with unconditional statistics ofv _s and conditional statistics ofv . We then require that, within this (or other selected) working framework,v _s andv be mutually uncorrelated. This holds whenever the correlation scale ofv is large in comparison to that ofv _s . The formalism leads to an integro-differential equation for the conditional mean total concentration c which includes two dispersion terms, one field-scale and one sub-field-scale. It also leads to explicit expressions for conditional second moments of concentration cc. We solve the former, and evaluate the latter, for mildly fluctuatingv by means of an analytical-numerical method developed earlier by Zhang and Neuman. We present results in two-dimensional flow fields of unconditional (prior) mean uniformv . These show that the relative effect of local dispersion on first and second moments of concentration dies out locally as the corresponding dispersion tensor tends to zero. The effect also diminishes with time and source size. Our results thus do not support claims in the literature that local dispersion must always be accounted for, no matter how small it is. First-order decay reduces dispersion. This effect increases with time. However, these concentration moments c and cc of total concentrationc, which are associated with the scale below, cannot be used to estimate the field-scale concentrationc directly. To do so, a spatial average over the field measurement scale is needed. Nevertheless, our numerical results show that differences between the ensemble moments ofc and those ofc are negligible, especially for nonpoint sources, because the ensemble moments ofc are already smooth enough.     

Transcendentally small transversality in the rapidly forced pendulum

The rapidly forced pendulum equation with forcing sin((t/), where =<₀^p,p = 5, for ₀, sufficiently small, is considered. We prove that stable and unstable manifolds split and that the splitting distanced(t) in the ( ,t) plane satisfiesd(t) = sin(t/) sech(/2) +O( ₀ exp(–/2)) (2.3a) and the angle of transversal intersection,, in thet = 0 section satisfies 2 tan/2 = 2S _s = (/2) sech(/2) +O(( ₀ /) exp(–/2)) (2.3b) It follows that the Melnikov term correctly predicts the exponentially small splitting and angle of transversality. Our method improves a previous result of Holmes, Marsden, and Scheuerle. Our proof is elementary and self-contained, includes a stable manifold theorem, and emphasizes the phase space geometry.     

Unsteady forced convection heat/mass transfer from a flat plate

Numerical methods are used to investigate the transient, forced convection heat/mass transfer from a finite flat plate to a steady stream of viscous, incompressible fluid. The temperature/concentration inside the plate is considered uniform. The heat/mass balance equations were solved in elliptic cylindrical coordinates by a finite difference implicit ADI method. These solutions span the parameter ranges 10 Re 400 and 0.1 Pr 10. The computations were focused on the influence of the product (aspect ratio) × (volume heat capacity ratio/Henry number) on the heat/mass transfer rate. The occurrence on the plates surface of heat/mass wake phenomena was also studied.