Cluster centers in forsterite laser crystals Mg2SiO4 : Cr and Mg2SiO4 : Cr : Li

The structures of chromium-containing cluster centers in forsterite laser crystals Mg₂SiO₄ : Cr and Mg₂SiO₄ : Cr : Li have been simulated using the interatomic potential method. A system of position-dependent parameters of interatomic interaction potentials in forsterite has been developed. In the ionic approximation, this system adequately describes the structure, properties, and defects of the crystal with correct representation of the preferred positional arrangement of chromium ions. The preferred mechanisms of chromium dissolution in forsterite crystals have been evaluated from a comparison of the energies of formation of chromium-containing clusters with different configurations. It has been demonstrated that the results of the simulation of interatomic interaction potentials are consistent with the experimental data obtained from electron paramagnetic resonance and optical spectroscopy studies.     

Tunable single-mode pulsed Ti3+:Sapphire laser injection-seeded by a continuous-wave Cr3+:LiSrAlF6 laser

Spectrally pure high-power tunable single-mode operation of a pulsed Ti³⁺:sapphire laser by a tunable injection-seeding is reported. The injection laser was a cw diode laser pumped, spectrally narrowed tunable Cr³⁺:LiSrAlF₆ (Cr³⁺:LiSAF) laser with a grating in the auxiliary cavity. Single-mode tunable operation of a pulsed Ti³⁺: sapphire ring oscillator was obtained at different wavelengths in the range between 818 nm and 848 nm with a typical linewidth of 0.006 cm^-1. To extend the applicability of this operation to a differential absorption lidar system, the single-mode Ti³⁺:sapphire oscillator output was amplified and a high energy output of 38 mJ was obtained with the same linewidth.     

Efficient laser operation of diode-pumped Pr3+,Mg2+:SrAl12O19

We report on diode-pumped laser operation of Pr³⁺,Mg²⁺:SrAl₁₂O₁₉ at lasing wavelengths of λ _L = 724.4 nm, λ _L = 643.5 nm, and λ _L = 622.8 nm. Furthermore, the laser threshold could be reached in the green spectral range. By pumping the crystal longitudinally from each side with two polarization beam combined InGaN laser diodes, a total pump power of ≈4 W was available. In the deep red spectral range, a maximum output power of 564 mW was achieved with a maximum slope efficiency of 50 % with respect to the absorbed pump power. The maximum possible internal losses were estimated to ≈1 %. Beam quality factors M ² were in the range of 1.2–1.5.     

Broadly tunable continuous-wave diode-pumped Cr4+:YAG laser

We describe a widely tunable, continuous-wave, room temperature Cr⁴⁺:YAG laser with direct pumping by two high brightness 4 W InGaAs laser diodes. In a tunable configuration, the output wavelength covered a span of 197 nm (1356–1553 nm) and provided a maximum power of 195 mW. A maximum non-tunable output power of 260 mW was obtained with a 0.6% transmission output coupler (OC) and 6.6 W of incident pump power. Pumping at two different wavelengths, 911 and 968 nm, was investigated.     

Efficient laser operation and continuous-wave diode pumping of Cr2+:ZnSe single crystals

Efficient continuous-wave laser operation of Cr²⁺:ZnSe was demonstrated with an output power of 1400 mW at an absorbed pump power of 1900 mW from a Tm:YAG laser. Under continuous-wave diode pumping at 1.54 μm an output power of 15 mW was obtained from a Cr⁺²:ZnSe laser. Excited state absorption is shown to be negligible in the pump and laser spectral region. Received: 12 October 2000 / Published online: 30 November 2000     

Directly diode-pumped tunable continuous-wave room-temperature Cr4+:YAG laser

We report what is to our knowledge the first directly diode-pumped tunable (over 120 nm) continuous-wave Cr(4+): YAG laser, operating near 1.5 mum . At room temperature the laser delivered as much as 200 mW of power at 4 W of absorbed pump power. We also report observation of slow laser output degradation and bleaching in highly concentrated cyrstals, which we suggest is due to a photorefractive phenomenon.     

红色长余辉材料Mg2SiO4：Dy3+,Mn2+的制备及发光特性

用高温固相法制备了长余辉发光材料Mg₂SiO₄:Dy³⁺,Mn²⁺,对这种材料的红色长余辉性质进行了研究.对以不同掺杂浓度单掺杂Mn²⁺、单掺杂Dy³⁺以及双掺杂Dy³⁺,Mn²⁺的Mg₂SiO₄体系,通过在紫外激发下的发射光谱及其激发光谱的研究,确认了在双掺杂体系中,峰值为660nm的发光带对应着Mn²⁺的⁴T₁(⁴G)→⁶A₁(⁶S)跃迁,Mn²⁺为主要发光中心.Mn²⁺的660nm发射的激发谱分布很宽,样品在近紫外和可见光区都有良好的吸收,长波边可达600nm,是这种材料的一个显著优点.还研究了双掺杂体系中Dy³⁺对Mn²⁺的660nm发光带的敏化作用.另外,通过对单掺杂、双掺杂体系热释光曲线的比较,揭示了双掺杂体系中Dy³⁺的陷阱作用.     

Enhancement of up-conversion luminescence in Zn2SiO4:Yb3+, Er3+ by co-doping with Li+ or Bi3+

Yb³⁺/Er³⁺ co-doped Zn₂SiO₄ ceramics are rapidly synthesized by the microwave radiation method. Green and red up-conversion emissions are observed in Zn₂SiO₄: Yb³⁺, Er³⁺ ceramics under 980 nm excitation. The influence of co-doped Li⁺ or Bi³⁺ ion on luminescence intensity for the phosphors has been investigated. At Li⁺ or Bi³⁺ doping concentration of 1 mol%, up-converted green emission can be increased by 6 times and 20 times, respectively. It is believed that co-doped Li⁺ or Bi³⁺ ion results in the local distortion of Er³⁺ in Zn₂SiO₄, increasing the intra-4f transitions of Er³⁺ ions. The local distortion is proved by spectral probing method with Eu³⁺.     

EPR study of the effect of ionizing radiation on chromium centers in Mg2SiO4: Cr,Li laser crystals

Forsterite single crystals doped with chromium and lithium and exposed to ionizing radiation have been studied using multifrequency electron paramagnetic resonance (EPR) spectroscopy. It has been found that ionizing irradiation up to a dose of 10⁸ rad does not lead to a significant change in the concentration of single chromium impurity centers. At the same time, γ-ray irradiation of the crystal leads to a decrease in the concentration of active laser centers, which form an associate of trivalent chromium and monovalent lithium in the crystallographic positions M2 and M1, respectively, and to the formation of new centers of divalent chromium. The structure and magnetic properties of the new centers have been discussed.     

Tunable room-temperature cw laser action in Cr3+: GdScGa-Garnet

We report for the first time on tunable room temperature cw laser action of a transition metal laser material. In Cr³⁺:GdScGa-garnet crystals almost the total fluorescence is channelled into the broad band⁴ T ₂→⁴ A ₂ transition. The fluorescence lifetime is τ=120 μs. Laser pumping in the blue-green and yellow-red spectral range yields pump thresholds around 250 mW and slope efficiencies up to 11%. The wavelength of the free running Cr³⁺ laser is centered at 777 nm.     

Femtosecond and continuous-wave laser performance of a diode-pumped Yb3+:CaYAlO4 laser

The cw and femtosecond laser operations of Yb(3+):CaYAlO(4) (Yb:CYA) are demonstrated. The laser emitted a maximum cw power of 1.94 W with a slope efficiency (η(slope)) of 71% and an optical-to-optical efficiency (η(opt)) of 51%. Under mode-locking operation, the laser emitted near transform-limited pulses with 156 fs pulse width, 8.1 nJ pulse energy and 0.74 W average power. The η(slope) and η(opt) of the mode-locked laser were 37% and 20%, respectively.     

二极管泵浦双掺杂YAG微片自调Q激光器

 利用激光二极管泵浦双掺杂YAG微片晶体，在连续泵浦时获得了重复频率为2.78kHz，脉冲宽度为6ns的自调Q激光输出。并通过预泵浦加脉冲调制电流的方法，实现可控重复率的自调Q脉冲输出。与外腔式自调Q微片激光器相比，这种一体化微片激光器具有更高的转换效率、更窄的输出脉冲宽度和更高的重复频率，同时结构更为简单紧凑，易于调整。     

Yellow persistent luminescence of Sr2SiO4:Eu2+,Dy3+

This paper reports the photoluminescence and afterglow of Sr₂SiO₄ doped with Eu²⁺ and Dy³⁺. Factors governing the formation of the monoclinic or orthorhombic phase of this ortho-silicate are described and the impact of the crystallographic modification on the luminescence and afterglow under UV and VUV excitation are discussed and insight in factors limiting the efficiency of this yellow afterglow material is given.     

Ca8Mg(SiO4)4Cl2:Ce3+, Tb3+: A potential single-phased phosphor for white-light-emitting diodes

A single-phased white-light-emitting phosphor Ca₈Mg(SiO₄)₄Cl₂:Ce³⁺, Tb³⁺ (CMSC:Ce³⁺, Tb³⁺) is synthesized by a high temperature solid-state reaction method, and its photoluminescence properties are investigated. The obtained phosphor exhibits a strong excitation band between 250 and 410 nm, matching well with the dominant emission band of a UV light-emitting-diode (LED) chip. Energy transfer from Ce³⁺ to Tb³⁺ ions has been investigated and demonstrated to be a resonant type via a dipole–dipole mechanism. The energy transfer efficiency as well as the critical distance is also estimated. Furthermore, the phosphors can generate light from yellow-green through white and eventually to blue by properly tuning the relative ratio of Ce³⁺ to Tb³⁺ ions grounded on the principle of energy transfer. The results show that this phosphor has potential applications as a single-phased phosphor for UV white-light LEDs.     

Efficient diode-pumped Yb3+:Y2SiO5 and Yb3+:Lu2SiO5 high-power femtosecond laser operation

We report the mode-locked operation of two new Yb-doped oxyorthosilicates, Y2SiO5 (YSO) and Lu2SiO5 (LSO), that are longitudinally diode pumped. Yb:YSO supplied pulses as short as 122 fs with 410 mW of output power at 1041 nm. More than 2.6 W of average output power, for pulse durations of 198 fs at 1044 nm and 260 fs at 1059 nm for Yb:YSO and Yb:LSO, respectively, were provided. These are, to our best knowledge, the highest values ever obtained and the most efficient mode-locked laser in such a classic fiber-coupled diode-pumping configuration.     

LD预泵浦条件与Cr4+,Nd3+:YAG微片激光器的输出特性

建立了LD预泵浦的被动调Q平平腔Cr4+,Nd3+:YAG微片激光器模型,分析了预泵浦参数与激光脉冲时间特性的关系,设计了LD预泵浦的Cr4+,Nd3+:YAG微片激光器实验,测量了不同预泵浦参数下激光单脉冲以及脉冲序列的时间特性。实验结果与数值计算结果基本符合：调节预泵浦参数使每个泵浦脉冲刚好对应输出单个激光脉冲时,固定脉冲泵浦宽度,脉冲泵浦速率随连续泵浦速率的增加呈一次函数减小;固定连续泵浦速率,脉冲泵浦速率随脉冲泵浦宽度的增加呈非线性函数减小。结果还表明,激光脉冲半高全宽随整体泵浦速率的增加而减小,峰值功率随整体泵浦速率的增加而增加;当整体泵浦速率在阈值附近变动时,激光单脉冲时间特性的变化最为明显。     

LD预泵浦条件与Cr4+,Nd3+:YAG微片激光器的输出特性

 建立了LD预泵浦的被动调Q平平腔Cr⁴⁺,Nd³⁺:YAG微片激光器模型,分析了预泵浦参数与激光脉冲时间特性的关系,设计了LD预泵浦的Cr⁴⁺,Nd³⁺:YAG微片激光器实验,测量了不同预泵浦参数下激光单脉冲以及脉冲序列的时间特性。实验结果与数值计算结果基本符合：调节预泵浦参数使每个泵浦脉冲刚好对应输出单个激光脉冲时,固定脉冲泵浦宽度,脉冲泵浦速率随连续泵浦速率的增加呈一次函数减小;固定连续泵浦速率,脉冲泵浦速率随脉冲泵浦宽度的增加呈非线性函数减小。结果还表明,激光脉冲半高全宽随整体泵浦速率的增加而减小,峰值功率随整体泵浦速率的增加而增加;当整体泵浦速率在阈值附近变动时,激光单脉冲时间特性的变化最为明显。     

分光光度法研究Hg2+与Ag+、Bi3+、Pb2+、Mg2+和Cr3+的绿色析相萃取分离

研究了正丙醇-KBr-水体系析相萃取分离和富集Hg2+的行为及Hg2+与一些金属离子分离的条件.实验表明,在一定条件下,正丙醇-KBr-水体系能使Hg2+与Ag+、Bi3+、Pb2+、Mg2+和Cr3+析相分离.     

Efficient laser operation of heavily doped Cr4+:forsterite

Pulsed laser operation of a new high Cr4+ concentration forsterite crystal is reported. Slope efficiencies of 13% and 5% have been obtained for 1064 and 532nm pumping. Results are compared with the performance of three other forsterite crystals. A threefold enhancement in operating efficiency is obtained over standard low dopant-level material. Tuning ranges have also been investigated. This revised version was published online in November 2006 with corrections to the Cover Date.     

Diode pumping of a continuous-wave Pr3+-doped LiYF4 laser

We report, for the first time to our knowledge, diode-pumped cw laser oscillation of Pr3+:LiYF4 in the red spectral range. The pump power is provided by a GaN laser diode emitting a maximum output power of 25 mW at a wavelength of approximately 442 nm. The Pr3+ laser emits 1.8 mW of output power at a 639.7-nm wavelength. Threshold pump power and slope efficiency in a nonoptimized setup are determined to be 5.5 mW and 24%, respectively.