关于顺式聚乙炔共振喇曼谱的理论解释

本文建议以双极化子微观模型,根据多声子晶格弛豫理论解释顺式聚乙炔的喇曼谱。在准一维哈密顿量中考虑了电子与不同声子模的耦合,其耦合常数由红外及喇曼实验数据确定。理论计算结果与实验数据进行了比较和讨论。文中采用的方法可以推广到类似的系统 关键词：     

ZnSe—ZnTe应变层超晶格的纵光学声子模

本文首次利用室温非共振喇曼后向散射测得具有7.3％晶格失配的ZnSe-ZnTe应变层超晶格限制在ZnSe层中的纵光学声子模。计算了限制效应引起的声子模频率的红移,以及弹性应变引起的声子模的移动,它比前者大得多。ZnSe层所受拉伸应变引起声子频率红移,ZnTe层所受压缩应变引起声子频率蓝移。同时在喇曼光谱中观察到由于这种效应导致出现的纵光学声子折叠模。     

近周期超晶格中的声学声子及其光散射特性

利用转移矩阵方法计算了近周期超晶格体系（包括有限周期数的超晶格、耦合超晶格、层厚起伏和层厚渐变的超晶格）中声学声子的喇曼散射谱．结果表明上述近周期超晶格的光散射特性与理想严格周期的体系和完全无序的体系都不相同，呈现出许多独特的性质．对有限周期数的超晶格，由于边界的存在，喇曼谱中除了理想超晶格中存在的折叠声学声子峰（主峰）外，还会出现一系列等间距分布的卫星峰．对耦合超晶格体系，理想超晶格中存在的主峰将出现分裂．对层厚起伏变化的超晶格，主峰呈现非对称展宽，展宽主要出现在高波数端．计算结果和实验测得的谱线作了比 关键词：     

固体的光散射讲座第三讲 晶格振动的喇曼散射

晶体的喇曼散射是研究晶体内部结构的一种简单而有效的成熟方法.它对研究材料的结构和结构相变以及各种特殊条件下的晶体状态有着重要的作用.本文先从晶体的对称性出发,讨论晶格振动的分类,并以k=0处的晶格振动为例,介绍晶格振动模的对称类的分类.然后简述晶体喇曼散射的机理以及对晶体喇曼谱的实验研究. 一、晶体的对称性 我们知道,分子具有一定的点对称性,即保持体系中一点位置不变,对体系施以转动、反射或反演等(点)对称操作,体系仍处于与操作前等效的状态.晶体不仅也具有这种点对称性,而且由于其中原子排列的周期性,晶体还具有平移对称…     

ZnS-ZnSe应变层超晶格的纵声学声子折叠模

本文报道室温下ZnS-ZnSe应变层超晶格的纵声学声子折叠模的喇曼光谱测量,在10～90cm~(-1)范围内得到三级双峰结构。     

BaTiO3和Ce:BaTiO3晶体极性声子和电磁激元的喇曼散射研究

从声子-电磁激元频率色散关系的普遍公式出发,推导出了单轴晶体的Merten方程和电磁激元的频率色散关系。测量了BaTiO₃和Ce:BaTiO₃晶体的简正模和斜声子的喇曼散射谱,并根据Merten方程,拟合出了斜声子的方向色散曲线;记录了A₁类电磁激元在不同波矢值下的喇曼谱,观察到其频率色散现象.根据以上结果,对A₁(TO)模喇曼谱中两个宽的非对称峰的归属和BaTiO₃晶体的结构相变机制进行了讨论;计算出了这两种晶体的受夹介电常数;分析了掺Ce对BaTiO₃晶体结构的影响。 关键词：     

极性倍频晶体中的相干喇曼混频

本文建立了极性倍频晶体中极化声子相干喇曼混频的耦合波方程,其中考虑了超喇曼极化率β_R.该方程在小信号、声子近似以及喇曼驱动的参量近似下求解.结果表明:在高强度泵浦光受激喇曼散射的相干驱动下,极性倍频晶体可以在泵浦光倍频附近产生极化声子的相干喇曼光束.这种光束可以通过不同的相干喇曼混频过程,由倍频光直接转换,或由基波光直接转换,还可以由倍频光与基波光共同转换而成.这三种转换过程具有各自不同的相位失配因子.在一定条件下,后两种过程可以同时进行.在LiIO_3晶体中证实了上述的结论.实验中泵浦光强度约3.0×10~9W/cm~2.     

近年国内非弹性光散射研究的一些进展

本文介绍了近二年来我国在用喇曼散射和布里渊散射研究半导体、金属及半导体超晶格,高温超导体、磁性物质和介电晶体等方面的进展,以及表面增强喇曼和受激光散射研究的进展情况。     

LiZnTa_3O_9晶体的喇曼光谱及其对称性

本文首次获得了LiZnTa_3O_9晶体的喇曼光谱,并与LiTaO_3的喇曼光谱进行了比较.前向喇曼散射表明此晶体不存在极化声子色散,从而断定其对称性是D_(3d)点群,然后对LiZnTa_3O_9的喇曼光谱进行了识别和讨论.     

掺镁铌酸锂晶体结构的研究

通过LiNbO₃：MgO(6.7 mol/kg)晶体在常温和低温下的喇曼光谱分析,研究了掺Mg²⁺后晶体结构的变化情况．研究结果表明,常温下晶格略有畸变,个别的散射峰有耦合现象存在,随温度降低,耦合逐渐减少,但掺Mg²⁺后晶格基本结构并无变化. 关键词：     

Magnetism and magnetic entropy change in LaFe11Al2Cx compounds around room temperature

Magnetism and magnetic entropy changes in LaFe11A12Cx(x=0.0, 0.2 and 0.5) compounds have been investigated.The Curie temperature TC is conveniently controlled from 200K to room temperature by varying the carbon concentration.Large magnetic entropy change is obtained over a wide temperature range due to the high magnetization and the drastic decrease in the magnetization around TC.The large magnetic entropy change in wide temperature range,low cost and the convenience of controlling TC suggest that the LaFe11Al2Cx compounds are promising candidates for magnetic refrigerants in the corresponding temperature range.     

Massless Leggett mode in three-band superconductors with time-reversal-symmetry breaking

The Leggett mode associated with out-of-phase oscillations of the superconducting phase in multiband superconductors usually is heavy due to interband coupling, which makes its excitation and detection difficult. We report on the existence of a massless Leggett mode in three-band superconductors with time-reversal-symmetry breaking. The mass of this Leggett mode is small close to the time-reversal-symmetry-breaking transition and vanishes at the transition point, and thus locates within the smallest superconducting energy gap, which makes it stable and detectable, e.g., by means of the Raman spectroscopy. The thermodynamic consequences of this massless mode and possible realization in iron-based superconductors are also discussed.     

厚度与应变效应对La0.67Ca0.33MnO3薄膜电输运与居里温度的影响

在厚度为25—400nm范围内，系统地研究了 (001)SrTiO_3(STO), (001)LaAlO_3(LAO)衬底上La_0.67Ca_0.33Mn_O.3 (LCMO)薄膜的电输运与居里温度T_C随薄膜厚度及衬底的变化. 结果表明，随薄膜变薄，电阻率ρ增加，T_C降低. 对于同一薄膜厚度，LCMO/STO薄膜的ρ大于LCMO/LAO基上的薄膜的ρ. T_C衬底的依赖关系则与ρ相反. 分析表明，LCMO薄膜的低温区电阻温度(ρ-T) 符合关系式ρ=ρ_0+Bω_s/sin h^2(ω_s/2/k_BT)+CT^n， 其中ρ_0为剩余电阻；等号右端第二项反映软光学模声子对电子散射的贡献；第三项包括其余可能散射机 理在电输运过程中所起的作用；B，ωs（软光学模声子的平均频率）与C都为拟合系数. 高温区的电输运则由小极化子跃迁模型ρ=DT×exp（E_a/k_BT）描述（E_a为极化子激 发能）. 根据ρ_0，ωs，E_a以及T_Ｃ变化，初步讨论了薄膜中的厚度与应变效应. 进一步 研究发现ωs，E_a的变化与T_C相关，从而说明极化子效应为影响T_C变化的主要因素. 关键词： 锰氧化物薄膜 电输运 居里温度 极化子     

Electronic Raman spectra in iron-based superconductors with two-orbital model

Electronic Raman spectra in iron-based superconductors with two-orbital model is discussed. In the orbital space, some possible pairing symmetries of the gap are selected. To further discriminate them, electronic Raman spectra and spectra weight at Fermi surface (FS) which helps understand the Raman spectra are calculated in each case. From the low energy threshold, the number of Raman peaks, and the low frequency power law behavior, we can judge whether it is full gap or nodal gap, and even one gap or multi-gaps. The results provide useful predictions for comparison with experiments.     

Raman scattering under extreme conditions

Raman scattering is a versatile and powerful technique and has been widely used in modern scientific research and vast industrial applications. It is one of the fundamental experimental techniques in condensed matter physics, since it can sensitively probe the basic elementary excitations in solids like electron, phonon, magnon, etc. The application of extreme conditions(low temperature, high magnetic field, high pressure, etc.) to Raman scattering, will push its capability up to an unprecedented level, because this enables us to look into new quantum phases driven by extreme conditions, trace the evolution of the excitations and their coupling, and hence uncover the underlying physics. This review contains two topics.In the first part, we will introduce the Raman facility under extreme conditions, belonging to the optical spectroscopy station of Synergetic Extreme Condition User Facilities(SECUF), with emphasis on the system design and the capability the facility can provide. Then in the second part we will focus on the applications of Raman scattering under extreme conditions to a variety of condensed matter systems such as superconductors, correlated electron systems, charge density waves(CDW) materials, etc. Finally, as a rapidly developing technique, time-resolved Raman scattering will be highlighted here.     

Collective excitations in superconductors with structural transition

In this paper we have found new low-frequency collective excitations in superconductors with structural transformation. The connection between our results and the experiments on Raman scattering in 2H-NbSe₂ cDw- superconductor is discussed.     

Remarks on the order parameter of the cuprate high temperature superconductors

A large body of spectroscopic data on the cuprate high temperature superconductors (CHTSC) is reviewed in order to determine their order parameter. ASJ, INS, B_2g Raman spectra, optical data, NIS “dips”, ARPES “dips” and ARPES “kinks” all show the same excitation energy (40 meV for OP95 systems), proportional to the superconducting transition temperature, and it is therefore identified with the order parameter.     

铜氧化物超导体两能隙问题的电子拉曼散射理论研究

电子拉曼实验表明在空穴型掺杂的铜氧化物超导体中存在两能隙行为,即在欠掺杂区,随着掺杂浓度的降低,一个能隙逐渐增大而且在超导转变温度以上仍然存在,而另一个能隙逐渐减小且在DDW态依然存在.解释两能隙行为非常重要因为它与赝能隙的机理密切相关.本文计算了超导序和d-density-wave(DDW)序竞争机理下相图上不同区域的电子拉曼谱,发现欠掺杂区能隙表现出两能隙行为,与实验一致.特别地,本文发现B_1g峰对应能量由超导和DDW序共同决定,且随着掺杂浓度的降低而增大,在D 关键词： 两能隙 电子拉曼散射 竞争序     

Influence of collective effects and the d charge-density wave on electronic raman scattering in high-T(c) superconductors

Electronic Raman scattering in high-T(c) superconductors is studied within the t-J model. It is shown that the A(1g) and B(1g) spectra are dominated by amplitude fluctuations of the superconducting and the d charge-density-wave order parameters, respectively. The B(2g) spectrum contains no collective effects and its broad peak reflects vaguely the doping dependence of T(c), similarly to the pronounced peak in the A(1g) spectrum. The agreement of our theory with the experiment supports the picture of two different, competing order parameters in the underdoped regime of high-T(c) superconductors.