共查询到17条相似文献,搜索用时 78 毫秒
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运用金属有机物化学气相沉积法(MOCVD),在LaAlO3(LAO)单晶上沉积YBa2Cu3O7-x(YBCO)超导薄膜。通过使用优化的进液装置,使金属有机源连续、稳定地输送至蒸发皿进行闪蒸。通过优化总气压、氧分压等生长条件,获得高质量的YBCO薄膜。在固定的温度条件下,调节反应总气压和氧分压,在总压为380Pa,氧分压为180Pa获得YBCO薄膜临界电流密度Jc=0.6MA/cm2。随着氧分压增大,YBCO薄膜产生a轴取向,(005)峰向左偏移,且薄膜中的Cu/Ba由1.0变化至1.63。在Cu/Ba=1.48时,YBCO薄膜结构与性能较优。 相似文献
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传统全三氟乙酸前驱液对涂敷环境湿度、低温预分解过程中的升温速率和水汽分压等因素具有敏感性,采用改进型前驱液可以降低其敏感性,从而有利于涂层导体的连续制备.我们提出的改进型前驱液中,三氟乙酸钇、三氟乙酸钡和苯甲酸铜是前驱体,甲醇和丙酸的为溶剂.采用化学溶液法在铝酸镧单晶衬底上制备YBCO,低温分解阶段以1~5℃/min快速升温,可以获得低温后的前驱膜光滑完整,无裂纹.通过X衍射分析和扫描电镜分析了薄膜的织构和表面微结构,四引线法测试薄膜超导电性.采用改进型前驱液制备的薄膜超导转变温度(Tc)为90K,在77K、自场下临界电流密度(Jc)为1MA/cm2. 相似文献
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以铋、钆的硝酸盐等制备前驱溶胶体系,用CSD法在SrTiO3(100)基底上制备出c轴织构良好的可作为涂层导体缓冲层的GdBiO3(GBO)薄膜。首先利用差热分析的结果对GBO薄膜分解过程的吸、放热情况进行了研究,确定了较为适当的有机物分解工艺。在此基础上研究了不同外延成相热处理温度对GBO薄膜生长的影响,并对较高温度处理后样品产生裂纹的原因进行了初步分析。GBO薄膜的相组成和微结构利用XRD和SEM进行分析。研究结果表明,在Ar气氛中适宜于GBO薄膜生长的最佳温度在770℃度附近,在此条件下可以制备出表面平整致密的GBO薄膜。 相似文献
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化学修饰的Sol-Gel法因无需光刻胶、腐蚀液被用于YBCO薄膜图形的制备。以丙烯酸(AA)、苯酰丙酮(BzAcH)作为化学修饰剂制备YBCO薄膜图形,研究了化学修饰剂、光源、前烘温度和时间、溶洗剂对薄膜图形的最小线宽和质量的影响。 相似文献
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激光沉积法制备(Y1—xHox)Ba2Cu3O7—δ薄膜 总被引:1,自引:1,他引:0
本文报道了用激光沉积法在(100)LaAlO3衬底上制备(Y1-xHox)Ba2Cu3O7-δ(x=0,0.2,0.4)超导薄膜.结果表明,新超导薄膜表面光滑,具有很强的c轴织构,零电阻温度Tc0约91K,最佳临界电流密度Jc为4.7×106A/cm2(77K). 相似文献
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介绍了电泳技术制备YBCO高温超导厚膜的实验方法和YBCO高温超导厚膜的电学性质测量 ,讨论了在学生小型科研实验或设计实验中开展此实验的学时安排、注意事项和实验内容的扩展 . 相似文献
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W.T. Wang M.H. Pu Y. Yang H. Zhang C.H. Cheng Y. Zhao 《Physica C: Superconductivity and its Applications》2010,470(20):1261-1265
YBCO films without and with dilute cobalt and zinc doping were prepared on (0 0 l) LaAlO3 substrate by non-fluorine metal organic deposition method. Effects of dilute cobalt and zinc doping on biaxial texture, microstructure and flux-pinning properties of YBCO films were investigated. The surface density and smoothness of the doped YBCO films have been distinctly improved compared with that of the pure film. Dilute cobalt- and zinc-doped YBCO films exhibit significantly enhanced Jc values in the magnetic field. The best result is achieved in the cobalt-doped YBCO film. At 77 K, Jc values of cobalt-doped film are 1.7 and 5.4 times higher than that of pure film in 0.5 T and 1.5 T, respectively. These results strongly suggest that dilute cobalt and zinc doping is a promising way to increase the current carrying capability of YBCO films. 相似文献
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L.H. Jin Y. Zhang Z.M. Yu G. Yan C.S. Li Y.F. Lu 《Physica C: Superconductivity and its Applications》2010,470(20):1257-1260
YBa2Cu3O7−x (YBCO) films have been prepared on LaAlO3 (1 0 0) substrates by chemical solution deposition using metal trifluoroacetates. The influence of relative humidity in coating circumstance on the morphology of YBCO films was examined by optical microscopy and atomic force microscopy. The crack-free YBCO film was obtained if the relative humidity in coating circumstance was lower than 30%. During the decomposition step, the influences of the water vapor partial pressure and the heating rate within the temperature range from 200 °C to 320 °C were discussed. A smooth YBCO pyrolzed film could be obtained if the suitable water vapor partial pressure and the suitable heating rate within the temperature range from 200 °C to 320 °C were chosen. Furthermore, the smooth crystallized films show a high critical current density of 3 MA/cm2 at 77 K. 相似文献
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Zinc sulphide thin films are deposited on SnO2/glass using the chemical bath deposition technique. X-ray diffraction and atomic force microscopy are used to characterize the structure of the films; the surface composition of the films is studied by Auger electrons spectroscopy, the work function and the photovoltage are investigated by the Kelvin method. Using these techniques, we specify the effect of pH solution and heat treatment in vacuum at 500 °C. The cubic structure corresponding to the (1 1 1) planes of β-ZnS is obtained for pH equal to 10. The work function (Φmaterial − Φprobe) for ZnS deposited at pH 10 is equal to −152 meV. Annealing at 500 °C increases Φm (by about 43 meV) and induces the formation of a negative surface barrier. In all cases, Auger spectra indicate that the surface composition of zinc sulphide thin films exhibits the presence of the constituent elements Zn and S as well as C and O as impurity elements. 相似文献
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ZHU Yabin ZHOU Yueliang LIU Zhen WANG Shufang CHEN Zhenghao U Huibin YANG Guozhen XlAO Ling Ren Hongtao JIAO Yulei Zheng Minghui 《中国科学G辑(英文版)》2004,47(2):165-172
The irreversibility field (Hirr) of Y-based superconductor is much higher than that of Bi-based superconductor. Y-based superconductor is capable of maintaining stable electrical currents in high magnetic field and electric field, so it is a better suited mate-rial for electric-current applications. Commonly, the Y-based tapes comprise a YBCO thick film deposited on a flexible substrate, typically with an intermediate buffer layer, and an overcoat of noble metal. In this process, the interm… 相似文献
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Optical and electrical characteristics of Al-doped ZnO thin films prepared by aqueous phase deposition 总被引:1,自引:0,他引:1
Transparent conducting Al-doped ZnO (AZO) thin films have been deposited by sol-gel route. Starting from an aqueous solution of zinc acetate by adding aluminum chloride as dopant, a c-axis oriented polycrystalline ZnO thin film 100 nm in thickness could be spin-coated on glass substrates via a two-step annealing process under reducing atmosphere. The effects of thermal annealing and dopant concentration on the structural, electrical and optical properties of AZO thin films were investigated. The post-treated AZO films exhibited a homogenous dense microstructure with grain sizes less than 10 nm as characterized by SEM photographs. The annealing atmosphere has prominent impact on the crystallinity of the films which will in turn influence the electrical conductivity. By varying the doping concentrations, the optical and electrical properties could be further adjusted. An optimal doping concentration of Al/Zn = 2.25 at.% was obtained with minimum resistivity of 9.90 × 10−3 Ω-cm whereas the carrier concentration and mobility was 1.25 × 1020 cm−3 and 5.04 cm2 V−1 s−1, respectively. In this case, the optical transmittance in the visible region is over 90%. 相似文献