共查询到20条相似文献,搜索用时 31 毫秒
1.
《Journal of organometallic chemistry》1996,526(1):145-147
The reaction of [Os3(CO)10(μ-dppm)] (1) with tBu2PH in refluxing diglyme results in the electron-deficient metal cluster complex [Os3(CO)5(μ3-H)(μ-PtBu2)2(μ-dppm)] (2) (dppm = Ph2PCH2PPh2) in good yields. The molecular structure of 2 has been established by a single crystal X-ray structure analysis. In contrast to the known homologue [Ru3(μ-CO)(CO)4(μ3-H)(μ-H)(μ-PtBu2)2(μ-dppm)] (3), no bridging carbonyl ligand was found in 2. The electronically unsaturated cluster 2 does not react with carbon monoxide under elevated pressure, therefore 2 seems to be coordinatively saturated by reason of the high steric demands of the phosphido ligands. 相似文献
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V. V. Strelets V. I. Zdanovich V. Yu. Lagunova A. M. Sheloumov A. A. Koridze 《Russian Chemical Bulletin》1997,46(10):1721-1725
The redox properties of the clusters Ru3(CO)12(1), Ru3(μ-H)(μ3-μ1:μ2:μ2-C2Fe)(CO)9 (2), OS3(μ-H)(μ3-μ1:μ2:μ2-C2Fe)(CO)9 (3), Ru4(μ-H)(μ4-μ1:μ1:μ1:μ2-C2Fe)(CO)12 (4), and RuOS3(μ-H)(μ4-μ1:μ1:μ1:μ2-C2Fe)(CO)12 (5) in THF have been studied by cyclic voltammetry in the temperature range from ?60 to +20°C. It was demonstrated that reversible one-electron oxidation of the ferrocenyl fragment in clusters 2–5 occurs at more positive potentials (δE 0=0.15–0.26 V) than that of free ferrocene. This is indicative of the electron-withdrawing character of the cluster core with respect to the ferrocenylacetylide ligand. The electron-withdrawing effect of the metal core is more pronounced in tetranuclear clusters4 and 5 than in trinuclear clusters2 and3. Unlike complexes1–3, which undergo irreversible reduction, complexes4 and5 undergo reversible one-electron reduction to form the corresponding radical anions4 ? and5 ?. 相似文献
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μ3-O-{[μ-(n-Bu)2Sn(μ-FcCO2)(n-Bu)2Sn]FcCO2}二聚物的晶体结构和分子结构 总被引:1,自引:0,他引:1
标题配合物Mr=933.84,属单斜晶系,空间群P2_1/n,晶胞参数a=15.244(4)A,b=20.895(7)A,c=12. 375(4)A,β=97.39(3)°,Z=4,V=3909(2)A~3,Dc=1.5879·cm~(-3),F(000)=1872,最终偏差因子R=0.0684。该配合物分子呈中心对称,是具有Sn_2O_2中心内环的二聚体,Sn_2O_2中的每个桥氧原子又各连接一个外环锡而形成了四核分子。分子中四个羧酸酯基有桥联双齿(μ-COO)和单齿两种不同的配位模式;在内环锡和外环锡的配位单元中,锡均形成具有五配位的畸变三角双锥配位构型,同时另有一氧原子与中心锡原子之间有弱相互作用。它与类似物[FcCO_2Sn(n-BU)_2]O}_2·4C_6H_6的晶体结构完全不同,却又存在着内在的联系。 相似文献
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《Polyhedron》1999,18(8-9):1131-1134
The action of [(μ2-η2-CHCHPh)(μ-CO)Fe2(CO)6]− with (μ-S)2Fe2(CO)6 gives the anionic complex [(μ2-η2-CHCHPh)(μ-S){Fe2(CO)6}2(μ4-S)]− (1). The anion 1 reacts with alkyl halides, acid chlorides and Cp(CO)2FeI to yield neutral products (μ2-η2-CHCHPh)(μ-RS)[Fe2(CO)6]2(μ4-S) (R=Me, 2a; Et, 2b; PhCH2, 2c; PhC(O), 3a; PhCHCHC(O), 3b and Cp(CO)2Fe, 4). 相似文献
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V. V. Volkov K. G. Myakishev E. A. Il'inchik 《Russian Journal of Coordination Chemistry》2001,27(6):398-400
The mechanoactivated solid-state reaction of [Et4N]2[Mo3S7Br6] with Na(Et2NCS2) in a vacuum vibration ball mill yields the [Mo3S7(Et2NCS2)3]+[Et2NCS2]–complex. The product was studied by IR and Raman spectroscopy and differential thermal analysis. 相似文献
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《Journal of Coordination Chemistry》2012,65(18):2905-2915
3D LaIII and 2D CuII coordination polymers with 5-nitroisophthalate anions, [La2(μ-Nip)(μ-SO4)2(H2O)5] n (1) and {[Cu3(μ-OH)2(μ-Nip)2(μ-H2O)2] ·?2H2O} n (2), have been synthesized, characterized and studied by X-ray crystallography. The La atoms have eight–coordinate geometries in distorted square antiprism environments and the Cu atoms have five- and six–coordinate geometries with distorted square pyramidal and octahedral environments. Self-assembly of these compounds in the solid state occurs through coordination and hydrogen bonding. 相似文献
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Michael I. Bruce Michael Schulz Brian W. Skelton Allan H. White 《Journal of Cluster Science》2000,11(1):79-86
Addition of aqueous HCl to Ru5(
3-C=CH2)(-SMe)2(-PPh2)2(CO)10 afforded the structurally characterized carbyne complex Ru5(
3-SMe)(
3-CMe)(-Cl)(-SMe)(-PPh2)2(CO)9, formed by addition of H to the vinylidene ligand; a Cl atom bridges an Ru–Ru bond. 相似文献
14.
合成了新型具有Pd—W键的双核化合物PdW(μ-Ph_2Ppy)_2(μ-CO)(CO)_2Cl_2·0.7CH_2Cl_2(Ph_2Ppy为2-二苯基膦基吡啶)。首次测定了具有Pd—W键化合物的晶体及分子结构,该晶体空间群为P2_1/C,晶胞参数:a=14.616(3),b=15.289(1),c=17.676(1),β=97.29(1)°和Z=4。最终R值为0.081。 钯原子为d~9五配位构型,钨原子为d~5七配位构型,两者形式氧化数均为+1。Pd—W键距为2。819(5)。该分子为手性分子,属C_1点群。 相似文献
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《结构化学》1987,(3)
<正> The crystal and molecular structure of (μ-SPh)(μ-SCH2CH2CN)Fe2-(CO)5 has been determined by X-ray diffraction method. The crystals of this complex are triclinic, space group P1,with a=ll.175(1), b=ll.877(2), c= 15.640(2)1,α=106.20(1),β=103.15(1),γ=98.46(1)°; Z=4; Dc=1.67g/cm3. The final structure refinement converged with unweighted and weighted R factors of 0.028 and 0.034 for 2853 observed unique reflections. 相似文献
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在无机化学、络合物化学、结构化学教学中常涉及磁矩问题,对此问题常有如下或近似如下的一段叙述:“设原子、离子和分子的未成对电子数为 n,则它们的磁矩μ=n(n 2)~(1/2)μ_(?)式中μ_B 为磁矩单位,称为玻尔磁子”。初学者对此结论甚为满意,因为此公式极其简单,物理意义一目了然,以为由此公式一下子把物质顺磁性的有无及大小问题全部解决。事实上在应用此公式时存在着适用范围的问题。例如我们 相似文献
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The title compound,[Cu2(CH3COO)4(C8H10N2)]n·nCH3CN1 (C8H10N2,4,4'-bipy = 4,4'-bipyridine),has been solvothermally synthesized in CH3CN and characterized by X-ray diffraction.The crystal is of monoclinic,space group Cc with a = 22.626(6),b = 14.012(4),c =15.106(4) (A),β = 107.610(3)°,V = 4565(2) (A)3,C20H23Cu2N3O8,Mr = 560.49,Z = 8,Dc = 1.631 g/cm3,μ = 1.914 mm-1,Flack parameter = 0.48(1),F(000) = 2288,R = 0.042 and wR = 0.)98 for 8887 observed reflections (I > 2σ(I)).It consists of nearly linear one-dimensional chains [Cu2(CH3COO)4(C8H10N2)]n derived from paddle-wheel [Cu2(CH3COO)4] unit linked by 4,4'-bipy,and CH3CN as guest molecule regularly decorates between the chains. 相似文献
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Di-μ-hydroxo bridge-cleavage reactions between [Co(nta)(μ-OH)]2 2− and different monodentate ligands
The cleavage of the di--hydroxo bridges of [Co(nta)(-OH)]2
2– by dimethylaminopyridine (dmap) and pyridine (py) has been investigated. [Co(nta)(-OH)]2
2– equilibrates rapidly in aqueous basic solutions with a mono--hydroxo bridged CoIII species [pK
OH = 3.26(2)] and both these species react with the incoming ligand to form different ion associated species which react in the subsequent rate-determining steps (k
1 and k
2) to form presumably a ligand-substituted, mono-bridged species, [(nta)(OH)Co--OH-Co(nta)(L)]2–. Values for k
2, the preferred mono--hydroxo bridged substitution pathway for these reactions, vary between 6.8(2) × 10–4 s–1 (py) and 8.5(4) × 10–2 s–1 (dmap). 相似文献
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本文合成了新的异双核化合物PdMo(μ-Ph_2Ppy)_2(μ-CO)(CO)_2I_2·0.5CH_2Cl_2,对它进行了表征,并测定其晶体和分子结构。该化合物属PI空间群,d=0.9500(2),b=1.1302(2),c=1.993(1)nm,α=102.82(3),β=101.21(3),‘γ=94.57(2)°,D_x=1.82g/cm~3,Z=2,R=0.064。晶体结构测定表明,该化合物具有Pd—Mo键,键长为0.28596(9)nm。如将Pd—Mo键考虑在内,Pd原子为d~9五配位构型,Mo原子为d~5七配位构型。两者的形式氧化态均为+1。 相似文献