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神农架地区五味子科植物成分的研究 III: 五味子酯G,H和I的分离与结构研究 总被引:1,自引:0,他引:1
本文继续报道从湖北房县中坝采集的一种南五味子(Kadsura sp.种名待定)根中分得的另外三个木脂素类新化合物: 五味子酯(schisantherin)G, H, I和六个已知物:schizandronic acid, isoschizandrolie acid, kadsurarin, veraguensin, β-谷甾醇和硬脂酸的分离, 鉴定与结构研究. 同时报道在结构研究中获得的八个衍生物的理化数据以及kadsurarin(1a)的绝对构型. 相似文献
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Enantio-differentiating hydrogenation of methyl acetoacetate was performed over the supported nickel catalysts modified by the solution of (R,R)-tartaric acid or (S)-malic acid and NaBr. The reduction temperature of supported nickel was the most important factor determining the enantio-selectivity of catalysts. The reduction temperature changed the nickel dispersion, by which the quantity and coverage of modifier adsorption were varied. The enantio-selectivity of modifiers both (R,R)-tartaric acid and (S) -malic acid were compared at various reduction temperatures. (R,R)-tartaric acid with two hydroxyl groups in a molecule showed an optimum coverage on the nickel surface that gave the maximum ee value. The maximum ee value was 72% at the reduction temperature of 973 K. In contrast, (S)-malic acid with one hydroxyl group in a molecule showed a monotonous decrease in ee and decreasing amounts of adsorbed modifier with increasing reduction temperatures. 相似文献
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A new bicyclo[9.3.0]tetradecane diterpenoid (dolabellane) lactone named clavulactone (I) was isolated from soft coral qunzhuchong (Clavularia sp.). Its partial structure was determine by spectral anal. and hydrogenation reaction. X-ray anal. established the complete mol. structure of I and the relative configuration. Finally, according to the neg. Cotton effect of n畃* and CD band of a,b-unsatd. d-lactone at 252 nm, the absolute configuration was assigned. 相似文献
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(+)-莪术二酮系从中药温莪术中分到的抗癌活性成份. 本文研究了由(-)-香芹酮经12步反应合成(-)-莪术二酮的过程, 并以此结果证实了天然(+)-莪术二酮的绝对构型. 相似文献