Characteristics analysis of metal-clad and absorptive dielectric waveguides by a simple and accurate perturbation method

We present a simple and accurate method for characteristic analysis of metal-clad dielectric waveguides and absorptive waveguides. The real partN of the complex modal indexN=N + iN is obtained by solving the corresponding real eigenvalue equation, and the imaginary partN is given by (n/), where= + i is the complex dielectric constant of the absorptive layer, and N/ is obtained by numerical differentiation. The method is straightforward, and the cumbersome solution of complex transcendental equations is completely eliminated. Results for simple structures are in good agreement with those obtained by exact analysis.     

The thickness dependence of the permittivity of barium titanate single crystals

A thickness dependence of the permittivity ofc-domain barium titanate single crystals was found. The experimental results were explained by means of a model of a dielectric with surface layers. The thickness of the layer and the permittivity of the surface layer and bulk of the crystal were determined.

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iO₃

iO₃, -. . , .

     

Kinetic theory of adsorption and desorption

In this paper we use stochastic methods to discuss adsorption and desorption. The paper derives generalized coefficients of sticking and accomodation depending on surface temperatureT _s and gas temperatureT _g and shows, that for additive Markov processes, these kinetic coefficients are identical. Furthermore, exact solutions of the kinetic equations for certain simple transition probabilitiesP(, ) are found and an approximation method for more complicatedP(, ) is given. The comparison of the theory with experimental results for noble gas-metal systems indicate a quadratic relationship between the first moment of the transition probabilityP(, ) and the well depth of the physisorption system.     

Mixed-valence states in TCNQ salts of monoalkylbiferrocenes and their mixed crystals with dialkyl derivative

TCNQ salts of 1-monoalkylbiferrocenes showed a temperature-independent trapped-valence state as expected for the unsymmetrical structure of cations. On the other hand, mixed crystals of 1-monobutyl- and 1.1-dibutylbiferrocenium⁺(TCNQ) ₃ ^– showed a temperature dependence of the mixed-valence states, showing that the lattice affects the mixed-valence states.     

Temperature Dependence of the Gibbs State in the Random Energy Model

We consider the problem of temperature dependence of the Gibbs states in two spin-glass models: Derrida's Random Energy Model and its analogue, where the random variables in the Hamiltonian are replaced by independent standard Brownian motions. For both of them we compute in the thermodynamic limit the overlap distribution ^N _{i=1 i i} /N[–1,1] of two spin configurations , under the product of two Gibbs measures, which are taken at temperatures T,T respectively. If TT are fixed, then at low temperature phase the results are different for these models: for the first one this distribution is D _{0 0}+D _{1 1}, with random weights D ₀, D ₁, while for the second one it is ₀. We compute consequently the overlap distribution for the second model whenever T–T0 at different speeds as N.     

Small perturbations ofC*-dynamical systems

It is shown that if is the generator of a strongly continuous oneparameter group of *-automorphisms of aC*-algebraA and is an unbounded *-derivation ofA with the same domain as , then + is also a generator for all sufficiently small real numbers .     

S0-S1 two photon absorption dynamics of organic dye solutions

The two-photon absorption cross-sections and excited-state absorption cross-sections of the dyes rhodamine 6G, methylene blue and fuchsin dissolved in methanol, and of the dyes safranine T, 1,3,3,1,3,3-hexamethylindocarbocyanine iodide (HMICI) and 1,3,1,3-tetramethyl-2,2-dioxopyrimidi-6,6-carbocyanine hydrogen sulphate (PYC) dissolved in hexafluoroisopropanol (HFIP) are determined. The excitation is achieved with picosecond light pulses of a passively mode-locked Nd-glass laser (_L = 1.054m). The influence of amplified spontaneous emission on the two-photon absorption dynamics is analysed.     

Chelate complexes of gold(III)

New gold(III) complexes involving substituted picolinic acids acting as bidentate ligands have been characterised: [AuCl₂(LL), and [Au(LL)₂]⁺ (H-LL=hydroxy- or carboxy-substituted picolinic acid). The latter readily undergo deprotonation of the substituent on one ligand, to yield novel uncharged complexes which appear to be polymeric via hydrogen bonds between protonated and depronated substituents. A completely depronated anionic complex has also been obtained. The characterisation of these materials was considerably aided by¹⁹⁷Au Mussbauer spectroscopy.     

Novel perturbation expansion for the Langevin equation

We discuss the randomly driven systemdx/dt= -W(x) +f(t), wheref(t) is a Gaussian random function or stirring force withf(t)f(t)=2(t–t), andW(x) is of the formgx ¹⁺². The parameter is a measure of the nonlinearity of the equation. We show how to obtain the correlation functionsx(t)f(t)···x(t( n)) _f as a power series in. We obtain three terms in the expansion and show how to use Padé approximants to analytically continue the answer in the variable. By using scaling relations, we show how to get a uniform approximation to the equal-time correlation functions valid for allg and.     

The effect of preliminary aging at various temperatures on the mechanism of the subsequent aging of EI702 steel

It is shown that the preliminary continuous precipitation of the -phase inhibits the subsequent discontinuous precipitation of this phase even after heavy cold working. The rate of discontinuous decomposition is found to increase with a small reduction of the quenching temperature into the two-phase region.     

Correlations of Spin States for Icosahedral Double Group

The irreducible bases of the icosahedral double groups I and I_h are explicitly presented in their respective group spaces. Applying these bases to the spin states |j, , we obtain a simple formula for combining the spin states into the symmetry-adapted bases which belong to a given row of given irreducible representations of I and I_h.     

The quantum theory of multipole radiation in a dielectric

The potentials of an electromagnetic field of multipoles in a dielectric, which is realized by a dielectric sphere having a perfectly conducting surface, are derived. The diagonal values of the energy for thez component of the angular momentum and the square of the angular momentum of the field are determined and also the ratio between thez component of the angular momentum and the energy and the ratio between the square of the angular momentum and the square of the energy. It is shown that the total angular momentum can be divided in the usual way into orbital and spin parts but that these parts cannot be interpreted as the orbital and spin angular momentum because their eigenvalues cannot be the eigenvalues of any operator of infinitesimal rotation. In the commutation rules of a multipole field the vector character of the field is to a certain extent suppressed and the spin of the photon in a state with a certain value of the energy, parityz component of the angular momentum and the square of the angular momentum is not defined.

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, . ,z— , , z— . , , , , , - . , ,z— .

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In conclusion the author thanks Dr. . Muziká for directing the work, F. Samek for valuable remarks and discussion and J. Kvasnica for help in preparing the paper for publication and for adding a number of remarks.     

Spectroscopic properties of the photoproducts of pyridoxal-5′-P irradiation: Catalytic site recognition of ribonuclease A

Photoproducts of pyridoxal-5-P, i.e., 4-pyridoxic-5-P and bis-pyridoxal-5-P, have been studied by spectroscopic methods. The spectroscopic properties of bis-pyridoxal-5-P (bis-PLP) resemble those of pyridoxal-5-P (PLP) under similar experimental conditions. The coupling of methylen hydrogens to the phosphorus atom has been shown by NMR spectroscopy. The singlet in the³¹P-NMR spectra and the triplet in¹H-undecoupled experiments confirm the presence of the phosphate group in the 5 position of the structure of the vitamin. The effect of pH and solvent composition on the relative distribution of species of bis-pyridoxine-5-P (bis-PNP) has been investigated by absorption and fluorescence spectroscopy. The acid-base dissociation of the phosphate group is easily detected by emission spectroscopy. Bis-PNP and bis-PLP bind to the enzyme RNase A and they behave as competitive inhibitors with respect to the substrate cytidine-2-3-cyclic phosphate. The natural forms of vitamin B₆, pyridoxine, and pyridoxine-5-P have no effect on the catalytic activity of the protein. Experimental evidence derived from fluorescence and inhibition experiments is consistent with the hypothesis that bis-PNP recognizes the catalytic site of RNase A.     

Second-order Zeeman effect of theX−B transition in molecular iodine

Saturated absorption spectroscopy was applied to study the line shape of the molecular iodineX( = 0,J = 13,15) B( = 43,J = 12, 16) transition ( = 514.5 nm) in a transversal magnetic field as high as 0.51 T. The Zeeman structure of several hyperfine structure (hfs) components was completely resolved and a detailed study of the second-order Zeeman shift and splitting was made. The anisotropic Magnetic Susceptibility (MS) of the molecular iodine both in theB(43) (X = 7.3 ± 1 × 10^–34 J/Oe²) and theX(0) [ = (0.6 ± 1) × 10^–34 J/Oe²] states as well as the isotropic MS difference [0 –o = (2 ± 0.2) × 10^–34 J/Oe²] was measured.     

Kinetics of nonresonant vibrational energy exchange in binary mixtures of molecular gases

The variation of the temperature of a gas during vibrational relaxation is a unique source of information on the kinetics of vibrational-vibrational (VV) and vibrational-translational (VT) energy exchange, and the characteristic parameters of the temperature curve are related to the characteristic times of the VV and VT processes. The effect of kinetic cooling, in which VV exchange leads to a temperature drop, has been studied quite extensively [1]. It was shown in [2] that the characteristic parameters of the cooling curve are uniquely related to the VV and VT relaxation times.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 15–18, October, 1988.     

Bounded perturbations of dynamics

If and are one-parameter automorphism groups of a von Neumann algebraM is said to be a bounded perturbation of if _t – _t 0 ast0. We give a complete characterization of the bounded perturbations of . In particular, we show that if can be implemented by a strongly continuous one-parameter group with self-adjoint generator (Hamiltonian)H, then can be implemented in the same way and the corresponding HamiltonianH can be chosen to be of the formH=VHV ^–1+h, whereV is a unitary ofM andh=h*M.On leave of absence from II. Institut für Theoretische Physik, Universität Hamburg, D-2000 Hamburg 50, Federal Republic of Germany     

Electrodynamics Under a Possible Alternative to the Lorentz Transformation

A generalization of the classical electrodynamics for systems in absolute motion in presented using a possible alternative to the Lorentz transformation. The main hypothesis assumed in this work are: a) The inertial transformations relate two inertial frames: the privileged frame S and the moving frame S with velocity v with respect to S. b) The transformation of the fields from S to the moving frame S is given by H = a(H – v × D) and E = a(E + v × B), where a is a matrix whose elements depend of the absolute velocity of the system. c) The constitutive relations in the moving frame S are given by D = E, B = H and J = E. It is found that Maxwell's equations, which are transformed to the moving frame, take a new form depending on the absolute velocity of the system. Moreover, differing from classical electrodynamics, it is proven that the electrodynamics proposed explains satisfactorily the Wilson effect.     

Analytical Electron Microscopy Examination of the γ′/γ Interfaces in a Ni-Based Superalloy

The investigation of microstructure and chemical composition of the and phases were performed in a Ni-base superalloy by means of analytical electron microscopy. The distribution of particular elements in the alloy was revealed using X-ray mapping in a transmission electron microscope. The detected concentration profiles of alloying elements at the / interface were relatively sharp in the case of cuboidal shape of the phase while they resembled the classical diffusion profile for the oval phase. The quantitative analysis of the phase revealed much higher content of Al and lower of Ti, W, Co and Mo in the oval precipitates compared to cuboidal ones. This result is attributed to the different solidification paths, which is eutectic for the cuboidal precipitates and peritectic for the oval precipitates.     

The diffusion and non-radiative transfer of excitation energy in molecular crystals containing foreign molecules

A study is made of the non-radiative transfer and diffusion of excitation energy in molecular crystals containing foreign molecules and its influence on the luminescent properties of these crystals.

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, .

     

Uniqueness of gibbs fields via cluster expansions

For the unbounded spin systems one cannot get cluster expansion if there exist large enough boundary values. A simple idea to avoid these difficulties is to prove that with probabilityp 1 when ^v there is a large subvolume of such that on all spin values do not exceed some fixed number. This gives a new method to prove uniqueness results for the unbounded spin systems generalizing some results of Refs. 1 and 2. The formulations of these results are in Section 1; the proofs are in Section 2.