Synthesis of novel 7-aryl and 7-spiropyrazolo[4′,3′:5,6]pyrido[2,3-<Emphasis Type="BoldItalic">d</Emphasis>]pyrimidine derivatives and their study as AChE inhibitors

An efficient route for the synthesis of novel 7-aryl and 7-spiropyrazolo[4\(^{\prime }\),3\(^{\prime }\):5,6]pyrido[2,3-d]pyrimidine derivatives is described. These compounds were obtained by a cyclocondensation reaction between pyrazolopyridinediamines 4 and aldehydes 5 or cyclic ketones 6 in the presence of acetic acid as catalyst. This procedure provides the desired compounds in good yields under a simple two-step methodology. The obtained compounds were evaluated as AChE inhibitors and showed weak AChe inhibition with \(\hbox {IC}_{50} = 115{-}470 \, \upmu \hbox {M}\).     

Phenomenological study of $$Z'$$ in the minimal $$B-L$$B-L model at LHC

The phenomenological study of neutral heavy gauge boson (\(Z^{\prime }_{B-L}\)) of the minimal \(B-L\) extension was done in the context of the LHC, on the dimuon production channel. The study begins with the LEP-II constraints on \(Z'\) searches, and the dimuon events are simulated at the parton level at CM energies of 7 TeV and 8 TeV and studied with an integrated luminosity of 1.21 fb\(^{-1}\) and 20.5 fb\(^{-1}\) respectively. Later, the ATLAS detector-specific cuts unique to the muon pairs are imposed followed by the signal selection cuts on the invariant mass of the dimuon which restrict the events that are to be passed for signal-background analysis, that are finally compared with the ATLAS data, and accounted for no experimental detection of \(Z^{\prime }_{B-L}\) boson. It has been simulated further at 14 TeV CM energy with an integrated luminosity of 300 fb\(^{-1}\) to predict a possible discovery of this \(B-L\) neutral-heavy gauge boson with a mass corresponding to 1.5 TeV and a \(Z'\) coupling strength of 0.2 based on the signal-background analysis.     

Exact solutions to $$$$-dimensional Chaffee–Infante equation

A \(\gamma \)-ray spectroscopy system based on a 1\(^{\prime \prime }\times 1^{\prime \prime }\) NaI(Tl) detector and 1.5\(^{\prime \prime }\) photomultiplier tube has been developed at IUAC for teaching laboratory applications involving radioactive sources. Following along the lines of the Phoenix and Expeyes hardware developed in the laboratory earlier, a low-cost, light weight multichannel analyser also has been developed. Here the details about the same are presented. The detector–analyser system has been used as a part of the postgraduate curriculum for measuring \(^{40}\)K content in some potassium salts and common building materials like brick, cement, concrete and sand.     

Search of the neutrino-less double beta decay of $$^{}$$Se into the excited states of $$^{}$$Kr with CUPID-0

The CUPID-0 experiment searches for double beta decay using cryogenic calorimeters with double (heat and light) read-out. The detector, consisting of 24 ZnSe crystals 95\(\%\) enriched in \(^{82}\)Se and two natural ZnSe crystals, started data-taking in 2017 at Laboratori Nazionali del Gran Sasso. We present the search for the neutrino-less double beta decay of \(^{82}\)Se into the 0\(_1^+\), 2\(_1^+\) and 2\(_2^+\) excited states of \(^{82}\)Kr with an exposure of 5.74 kg\(\cdot \)yr (2.24\(\times \)10\(^{25}\) emitters\(\cdot \)yr). We found no evidence of the decays and set the most stringent limits on the widths of these processes: \(\varGamma \)(\(^{82}\)Se \(\rightarrow ^{82}\)Kr\(_{0_1^+}\))8.55\(\times \)10\(^{-24}\) yr\(^{-1}\), \(\varGamma \) (\(^{82}\) Se \(\rightarrow ^{82}\) Kr \(_{2_1^+}\))\(\,{<}\,6.25 \,{\times }\,10^{-24}\) yr\(^{-1}\), \(\varGamma \)(\(^{82}\)Se \(\rightarrow ^{82}\)Kr\(_{2_2^+}\))8.25\(\times \)10\(^{-24}\) yr\(^{-1}\) (90\(\%\) credible interval).     

Asymptotic behavior of the Schrödinger–Debye system with refractive index of quadratic wave amplitude

We obtain local well-posedness for the one-dimensional Schrödinger–Debye interactions in nonlinear optics in the spaces \(L^2\times L^p,\; 1\le p < \infty \). When \(p=1\) we show that the local solutions extend globally. In the focusing regime, we consider a family of solutions \(\{(u_{\tau }, v_{\tau })\}_{\tau >0}\) in \( H^1\times H^1\) associated to an initial data family \(\{(u_{\tau _0},v_{\tau _0})\}_{\tau >0}\) uniformly bounded in \(H^1\times L^2\), where \(\tau \) is a small response time parameter. We prove that \(\left( u_{\tau }, v_{\tau }\right) \) converges to \(\left( u, -|u|^2\right) \) in the space \(L^{\infty }_{[0, T]}L^2_x\times L^1_{[0, T]}L^2_x\) whenever \(u_{\tau _0}\) converges to \(u_0\) in \(H^1\) as long as \(\tau \) tends to 0, where u is the solution of the one-dimensional cubic nonlinear Schrödinger equation with the initial data \(u_0\). The convergence of \(v_{\tau }\) for \(-|u|^2\) in the space \(L^{\infty }_{[0, T]}L^2_x\) is shown under compatibility conditions of the initial data. For non-compatible data, we prove convergence except for a corrector term which looks like an initial layer phenomenon.     

Likelihood analysis of the pMSSM11 in light of LHC 13-TeV data

We use MasterCode to perform a frequentist analysis of the constraints on a phenomenological MSSM model with 11 parameters, the pMSSM11, including constraints from \(\sim 36\)/fb of LHC data at 13 TeV and PICO, XENON1T and PandaX-II searches for dark matter scattering, as well as previous accelerator and astrophysical measurements, presenting fits both with and without the \((g-2)_\mu \) constraint. The pMSSM11 is specified by the following parameters: 3 gaugino masses \(M_{1,2,3}\), a common mass for the first-and second-generation squarks \(m_{\tilde{q}}\) and a distinct third-generation squark mass \(m_{\tilde{q}_3}\), a common mass for the first-and second-generation sleptons \(m_{\tilde{\ell }}\) and a distinct third-generation slepton mass \(m_{\tilde{\tau }}\), a common trilinear mixing parameter A, the Higgs mixing parameter \(\mu \), the pseudoscalar Higgs mass \(M_A\) and \(\tan \beta \). In the fit including \((g-2)_\mu \), a Bino-like \(\tilde{\chi }^0_{1}\) is preferred, whereas a Higgsino-like \(\tilde{\chi }^0_{1}\) is mildly favoured when the \((g-2)_\mu \) constraint is dropped. We identify the mechanisms that operate in different regions of the pMSSM11 parameter space to bring the relic density of the lightest neutralino, \(\tilde{\chi }^0_{1}\), into the range indicated by cosmological data. In the fit including \((g-2)_\mu \), coannihilations with \(\tilde{\chi }^0_{2}\) and the Wino-like \(\tilde{\chi }^\pm _{1}\) or with nearly-degenerate first- and second-generation sleptons are active, whereas coannihilations with the \(\tilde{\chi }^0_{2}\) and the Higgsino-like \(\tilde{\chi }^\pm _{1}\) or with first- and second-generation squarks may be important when the \((g-2)_\mu \) constraint is dropped. In the two cases, we present \(\chi ^2\) functions in two-dimensional mass planes as well as their one-dimensional profile projections and best-fit spectra. Prospects remain for discovering strongly-interacting sparticles at the LHC, in both the scenarios with and without the \((g-2)_\mu \) constraint, as well as for discovering electroweakly-interacting sparticles at a future linear \(e^+ e^-\) collider such as the ILC or CLIC.     

$$\varvec{B^0\rightarrow K^{*0}\mu ^+\mu ^-}$$ decay in the aligned two-Higgs-doublet model

In the aligned two-Higgs-doublet model, we perform a complete one-loop computation of the short-distance Wilson coefficients \(C_{7,9,10}^{(\prime )}\), which are the most relevant ones for \(b\rightarrow s\ell ^+\ell ^-\) transitions. It is found that, when the model parameter \(\left| \varsigma _{u}\right| \) is much smaller than \(\left| \varsigma _{d}\right| \), the charged scalar contributes mainly to chirality-flipped \(C_{9,10}^\prime \), with the corresponding effects being proportional to \(\left| \varsigma _{d}\right| ^2\). Numerically, the charged-scalar effects fit into two categories: (A) \(C_{7,9,10}^\mathrm {H^\pm }\) are sizable, but \(C_{9,10}^{\prime \mathrm {H^\pm }}\simeq 0\), corresponding to the (large \(\left| \varsigma _{u}\right| \), small \(\left| \varsigma _{d}\right| \)) region; (B) \(C_7^\mathrm {H^\pm }\) and \(C_{9,10}^{\prime \mathrm {H^\pm }}\) are sizable, but \(C_{9,10}^\mathrm {H^\pm }\simeq 0\), corresponding to the (small \(\left| \varsigma _{u}\right| \), large \(\left| \varsigma _{d}\right| \)) region. Taking into account phenomenological constraints from the inclusive radiative decay \(B\rightarrow X_{s}{\gamma }\), as well as the latest model-independent global analysis of \(b\rightarrow s\ell ^+\ell ^-\) data, we obtain the much restricted parameter space of the model. We then study the impact of the allowed model parameters on the angular observables \(P_2\) and \(P_5'\) of \(B^0\rightarrow K^{*0}\mu ^+\mu ^-\) decay, and we find that \(P_5'\) could be increased significantly to be consistent with the experimental data in case B.     

Recent results on kaon decays by the NA48/2 experiment at CERN

The NA48/2 experiment reports the first observation of the rare decay K^± → π^±π⁰e⁺e^?, based on about 2000 candidates from 2003 data. The preliminary branching ratio in the full kinematic region is \(\mathcal {B}(K^{\pm } \to \pi ^{\pm }\pi ^{0}e^{+}e^{-})=(4.06\pm 0.17)\cdot 10^{-6}\). A sample of 4.687 × 10⁶\(K^{\pm }\to \pi ^{\pm }{\pi ^{0}_{D}}\) events collected in 2003/4 is analyzed to search for the dark photon (\(A^{\prime }\)) via the decay chain K^± → π^±π⁰, \(\pi ^{0}\to \gamma A^{\prime }\), \(A^{\prime }\to e^{+}e^{-}\). No signal is observed, limits in the plane mixing parameter ε² versus its mass \(m_{A^{\prime }}\) are reported.     

Likelihood analysis of the minimal AMSB model

We perform a likelihood analysis of the minimal anomaly-mediated supersymmetry-breaking (mAMSB) model using constraints from cosmology and accelerator experiments. We find that either a wino-like or a Higgsino-like neutralino LSP, \(\tilde{\chi }^0_{1}\), may provide the cold dark matter (DM), both with similar likelihoods. The upper limit on the DM density from Planck and other experiments enforces \(m_{\tilde{\chi }^0_{1}} \lesssim 3 \,\, \mathrm {TeV}\) after the inclusion of Sommerfeld enhancement in its annihilations. If most of the cold DM density is provided by the \(\tilde{\chi }^0_{1}\), the measured value of the Higgs mass favours a limited range of \(\tan \beta \sim 5\) (and also for \(\tan \beta \sim 45\) if \(\mu > 0\)) but the scalar mass \(m_0\) is poorly constrained. In the wino-LSP case, \(m_{3/2}\) is constrained to about \(900\,\, \mathrm {TeV}\) and \(m_{\tilde{\chi }^0_{1}}\) to \(2.9\pm 0.1\,\, \mathrm {TeV}\), whereas in the Higgsino-LSP case \(m_{3/2}\) has just a lower limit \(\gtrsim 650\,\, \mathrm {TeV}\) (\(\gtrsim 480\,\, \mathrm {TeV}\)) and \(m_{\tilde{\chi }^0_{1}}\) is constrained to \(1.12 ~(1.13) \pm 0.02\,\, \mathrm {TeV}\) in the \(\mu >0\) (\(\mu <0\)) scenario. In neither case can the anomalous magnetic moment of the muon, \((g-2)_\mu \), be improved significantly relative to its Standard Model (SM) value, nor do flavour measurements constrain the model significantly, and there are poor prospects for discovering supersymmetric particles at the LHC, though there are some prospects for direct DM detection. On the other hand, if the \(\tilde{\chi }^0_{1}\) contributes only a fraction of the cold DM density, future LHC Open image in new window -based searches for gluinos, squarks and heavier chargino and neutralino states as well as disappearing track searches in the wino-like LSP region will be relevant, and interference effects enable \(\mathrm{BR}(B_{s, d} \rightarrow \mu ^+\mu ^-)\) to agree with the data better than in the SM in the case of wino-like DM with \(\mu > 0\).     

Spin-label Order Parameter Calibrations for Slow Motion

Calibrations are given to extract orientation order parameters from pseudo-powder electron paramagnetic resonance line shapes of ¹⁴N-nitroxide spin labels undergoing slow rotational diffusion. The nitroxide z-axis is assumed parallel to the long molecular axis. Stochastic-Liouville simulations of slow-motion 9.4-GHz spectra for molecular ordering with a Maier–Saupe orientation potential reveal a linear dependence of the splittings, \(2A_{\hbox{max} }\) and \(2A_{\hbox{min} }\), of the outer and inner peaks on order parameter \(S_{zz}\) that depends on the diffusion coefficient \(D_{{{\text{R}} \bot }}\) which characterizes fluctuations of the long molecular axis. This results in empirical expressions for order parameter and isotropic hyperfine coupling: \(S_{zz} = s_{1} \times \left( {A_{\hbox{max} } - A_{\hbox{min} } } \right) - s_{o}\) and \(a_{o}^{{}} = \tfrac{1}{3}\left( {f_{\hbox{max} } A_{\hbox{max} } + f_{\hbox{min} } A_{\hbox{min} } } \right) + \delta a_{o}\), respectively. Values of the calibration constants \(s_{1}\), \(s_{\text{o}}\), \(f_{\hbox{max} }\), \(f_{\hbox{min} }\) and \(\delta a_{o}\) are given for different values of \(D_{{{\text{R}} \bot }}\) in fast and slow motional regimes. The calibrations are relatively insensitive to anisotropy of rotational diffusion \((D_{{{\text{R}}//}} \ge D_{{{\text{R}} \bot }} )\), and corrections are less significant for the isotropic hyperfine coupling than for the order parameter.     

Uncertainties of the $$B\rightarrow D$$B→ D transition form factor from the D-meson leading-twist distribution amplitude

The \(B\rightarrow D\) transition form factor (TFF) \(f^{B\rightarrow D}_+(q^2)\) is determined mainly by the D-meson leading-twist distribution amplitude (DA) , \(\phi _{2;D}\), if the proper chiral current correlation function is adopted within the light-cone QCD sum rules. It is therefore significant to make a comprehensive study of DA \(\phi _{2;D}\) and its impact on \(f^{B\rightarrow D}_+(q^2)\). In this paper, we calculate the moments of \(\phi _{2;D}\) with the QCD sum rules under the framework of the background field theory. New sum rules for the leading-twist DA moments \(\left\langle \xi ^n\right\rangle _D\) up to fourth order and up to dimension-six condensates are presented. At the scale \(\mu = 2 \,\mathrm{GeV}\), the values of the first four moments are: \(\left\langle \xi ^1\right\rangle _D = -0.418^{+0.021}_{-0.022}\), \(\left\langle \xi ^2\right\rangle _D = 0.289^{+0.023}_{-0.022}\), \(\left\langle \xi ^3\right\rangle _D = -0.178 \pm 0.010\) and \(\left\langle \xi ^4\right\rangle _D = 0.142^{+0.013}_{-0.012}\). Basing on the values of \(\left\langle \xi ^n\right\rangle _D(n=1,2,3,4)\), a better model of \(\phi _{2;D}\) is constructed. Applying this model for the TFF \(f^{B\rightarrow D}_+(q^2)\) under the light cone sum rules, we obtain \(f^{B\rightarrow D}_+(0) = 0.673^{+0.038}_{-0.041}\) and \(f^{B\rightarrow D}_+(q^2_{\mathrm{max}}) = 1.117^{+0.051}_{-0.054}\). The uncertainty of \(f^{B\rightarrow D}_+(q^2)\) from \(\phi _{2;D}\) is estimated and we find its impact should be taken into account, especially in low and central energy region. The branching ratio \(\mathcal {B}(B\rightarrow Dl\bar{\nu }_l)\) is calculated, which is consistent with experimental data.     

Rapid communication: $$K_{S}^{0}$$ Production from beryllium target using 120 $$\hbox {GeV}/\hbox {c}$$GeV/c protons beam interactions at the MIPP experiment

We have measured the cross-section for the \(K_{S}^{0}\) production from beryllium target using 120 \(\hbox {GeV}/\hbox {c}\) protons beam interactions at the main injector particle production (MIPP) experiment at Fermilab. The data were collected with target having a thickness of 0.94% of the nuclear interaction length. The \(K_{S}^{0}\) inclusive differential cross-section in bins of momenta is presented covering momentum range from \(0.4\,\hbox {GeV}/\hbox {c}\) to \(30\,\hbox {GeV}/\hbox {c}\). The measured inclusive \(K_{S}^{0}\) production cross-section amounts to \(39.54\pm 1.46\delta _{\mathrm {stat}}\pm 6.97\delta _{\mathrm {syst}}\) mb and the value is compared with the prediction of FLUKA hadron production model.     

Test the mergers of the primordial black holes by high frequency gravitational-wave detector

The black hole could have a primordial origin if its mass is less than \(1M_\odot \). The mergers of these black hole binaries generate stochastic gravitational-wave background (SGWB). We investigate the SGWB in high frequency band \(10^{8}\)–\(10^{10}\,\mathrm {Hz}\). It can be detected by high frequency gravitational-wave detector. Energy density spectrum and amplitude of the SGWB are derived. The upper limit of the energy density spectrum is around \(10^{-7}\). Also, the upper limit of the amplitude ranges from \(10^{-31.5}\) to \(10^{-29.5}\). The fluctuation of spacetime origin from gravitational wave could give a fluctuation of the background electromagnetic field in a high frequency gravitational-wave detector. The signal photon flux generated by the SGWB in the high frequency band \(10^{8}\)–\(10^{10}\,\mathrm {Hz}\) is derived, which ranges from 1 to \(10^2\,\mathrm {s^{-1}}\). The comparison between the signal photon flux generated by relic gravitational waves (RGWs) and the SGWB is also discussed in this paper. It is shown that the signal photon flux generated by the RGW, which is predicted by the canonical single-field slow-roll inflation models, is sufficiently lower than the one generated by the SGWB in the high frequency band \(10^{8}\)–\(10^{10}\,\mathrm {Hz}\). Our results indicate that the SGWB in the high frequency band \(10^{8}\)–\(10^{10}\,\mathrm {Hz}\) is more likely to be detected by the high frequency gravitational-wave detector.     

Heuristic Relative Entropy Principles with Complex Measures: Large-Degree Asymptotics of a Family of Multi-variate Normal Random Polynomials

Let \(z\in \mathbb {C}\), let \(\sigma ^2>0\) be a variance, and for \(N\in \mathbb {N}\) define the integrals

$$\begin{aligned} E_N^{}(z;\sigma ) := \left\{ \begin{array}{ll} {\frac{1}{\sigma }} \!\!\!\displaystyle \int _{\mathbb {R}}\! (x^2+z^2) \frac{e^{-\frac{1}{2\sigma ^2} x^2}}{\sqrt{2\pi }}dx&{}\quad \text{ if }\, N=1,\\ {\frac{1}{\sigma }} \!\!\!\displaystyle \int _{\mathbb {R}^N}\! \prod \prod \limits _{1\le k<l\le N}\!\! e^{-\frac{1}{2N}(1-\sigma ^{-2}) (x_k-x_l)^2} \prod _{1\le n\le N}\!\!\!\!(x_n^2+z^2) \frac{e^{-\frac{1}{2\sigma ^2} x_n^2}}{\sqrt{2\pi }}dx_n &{}\quad \text{ if }\, N>1. \end{array}\right. \!\!\! \end{aligned}$$

These are expected values of the polynomials \(P_N^{}(z)=\prod _{1\le n\le N}(X_n^2+z^2)\) whose 2N zeros \(\{\pm i X_k\}^{}_{k=1,\ldots ,N}\) are generated by N identically distributed multi-variate mean-zero normal random variables \(\{X_k\}^{N}_{k=1}\) with co-variance \(\mathrm{{Cov}}_N^{}(X_k,X_l)=(1+\frac{\sigma ^2-1}{N})\delta _{k,l}+\frac{\sigma ^2-1}{N}(1-\delta _{k,l})\). The \(E_N^{}(z;\sigma )\) are polynomials in \(z^2\), explicitly computable for arbitrary N, yet a list of the first three \(E_N^{}(z;\sigma )\) shows that the expressions become unwieldy already for moderate N—unless \(\sigma = 1\), in which case \(E_N^{}(z;1) = (1+z^2)^N\) for all \(z\in \mathbb {C}\) and \(N\in \mathbb {N}\). (Incidentally, commonly available computer algebra evaluates the integrals \(E_N^{}(z;\sigma )\) only for N up to a dozen, due to memory constraints). Asymptotic evaluations are needed for the large-N regime. For general complex z these have traditionally been limited to analytic expansion techniques; several rigorous results are proved for complex z near 0. Yet if \(z\in \mathbb {R}\) one can also compute this “infinite-degree” limit with the help of the familiar relative entropy principle for probability measures; a rigorous proof of this fact is supplied. Computer algebra-generated evidence is presented in support of a conjecture that a generalization of the relative entropy principle to signed or complex measures governs the \(N\rightarrow \infty \) asymptotics of the regime \(iz\in \mathbb {R}\). Potential generalizations, in particular to point vortex ensembles and the prescribed Gauss curvature problem, and to random matrix ensembles, are emphasized.

     

Decay widths of the spin-2 partners of the <Emphasis Type="Italic">X</Emphasis>(3872)

We consider the X(3872) resonance as a \(J^\mathrm{{PC}}=1^{++}\) \(D\bar{D}^*\) hadronic molecule. According to heavy quark spin symmetry, there will exist a partner with quantum numbers \(2^{++}\), \(X_{2}\), which would be a \(D^*\bar{D}^*\) loosely bound state. The \(X_{2}\) is expected to decay dominantly into \(D\bar{D}\), \(D\bar{D}^*\) and \(\bar{D} D^*\) in d-wave. In this work, we calculate the decay widths of the \(X_{2}\) resonance into the above channels, as well as those of its bottom partner, \(X_{b2}\), the mass of which comes from assuming heavy flavor symmetry for the contact terms. We find partial widths of the \(X_{2}\) and \(X_{b2}\) of the order of a few MeV. Finally, we also study the radiative \(X_2\rightarrow D\bar{D}^{*}\gamma \) and \(X_{b2} \rightarrow \bar{B} B^{*}\gamma \) decays. These decay modes are more sensitive to the long-distance structure of the resonances and to the \(D\bar{D}^{*}\) or \(B\bar{B}^{*}\) final state interaction.     

CP violations in predictive neutrino mass structures

We study the CP-violation effects from two types of neutrino mass matrices with (i) \((M_\nu )_{ee}=0\), and (ii) \((M_\nu )_{ee}=(M_\nu )_{e\mu }=0\), which can be realized by the high-dimensional lepton number violating operators \(\bar{\ell }_R^c\gamma ^\mu L_L (D_\mu \Phi )\Phi ^2\) and \(\bar{\ell }_R^c l_R (D_\mu {\Phi })^2\Phi ^2\), respectively. In (i), the neutrino mass spectrum is in the normal ordering with the lightest neutrino mass within the range \(0.002\,\mathrm{eV}\lesssim m_0\lesssim 0.007\,\mathrm{eV}\). Furthermore, for a given value of \(m_0\), there are two solutions for the two Majorana phases \(\alpha _{21}\) and \(\alpha _{31}\), whereas the Dirac phase \(\delta \) is arbitrary. For (ii), the parameters of \(m_0\), \(\delta \), \(\alpha _{21}\), and \(\alpha _{31}\) can be completely determined. We calculate the CP-violating asymmetries in neutrino–antineutrino oscillations for both mass textures of (i) and (ii), which are closely related to the CP-violating Majorana phases.     

A theoretical study on the B3 phases of ZnSe: Structural and electronic properties

We analysed the process of \(B_{c}^{+}{\to } D_{s}^{+}\overline {K}^{0^{\ast } }\) using QCD factorization (QCDF) and final-state interaction (FSI) effects. First, the \(B_{c}^{+}{\to } D_{s}^{+}\overline {K}^{0^{\ast } }\) decay is calculated using QCDF method. The value found by using the QCDF method is less than the experimental value. Then we considered FSI effect as a sizable correction where the intermediate state \(D^{+^{\ast } }\pi ^{0}\) mesons via the exchange of \(K^{0}(K^{0^{\ast } })\) are produced. To consider the amplitudes of this intermediate state, the QCDF approach was used. The experimental branching ratio of \(B_{c}^{+}{\to } D_{s}^{+}\overline {K}^{0^{\ast } }\) decay is less than 0.4×10^?6 and our results are (0.21±0.04)×10^?7 and (0.37±0.05)×10^?6 from QCDF and FSI, respectively.     

One-pot synthesis of $$\upgamma $$-spiroiminolactones and $$\upgamma $$-dispiroiminolactones using $$\textit{N}{,}{} \textit{N}^{\prime }$$N,N′-disubstituted parabanic acid and thioparabanic acid derivatives

A direct entry and simple process for the synthesis of \(\upgamma \)-spiroiminolactones present in a large number of natural products has been developed. In the first step, the synthesis of parabanic acid derivatives was commenced from the reaction of \(\textit{N}{,}{} \textit{N}^{\prime }\)-disubstituted urea and thiourea with oxalyl chloride, then a three-component reaction was carried out with isocyanides, acetylenic esters, and \(\textit{N}{,}{} \textit{N}^{\prime }\)-disubstituted parabanic acid derivatives. The method allows the construction of a variety of \(\upgamma \)-spiroiminolactone structures in good to high yields starting from readily available precursors. It was found that in the case of \(\textit{N}{,}{} \textit{N}^{\prime }\)-diphenyl thioparabanic acid, additional products of \(\upgamma \)-dispiroiminolactones have been formed due to the higher electrophilicity of \(\upalpha \)-dicarbonyl groups. The structures were fully established using spectroscopic analysis NMR, IR, and Mass spectrometry. The crystal structure of \(\upgamma \)-dispiroiminolactone was confirmed from single-crystal X-ray diffraction study.