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Erdman A. A. Zubreichuk Z. P. Knizhnikov V. A. Maier A. A. Aleksandrov G. G. Nefedov S. E. Eremenko I. L. 《Russian Chemical Bulletin》2001,50(11):2248-2250
The reaction of bis(o-dicarbollyl)nickel(iv) with PPh3 in EtOH gave rise to the complex 3,3-(PPh3)2-3,1,2-NiC2B9H11 (2) whose structure was established by X-ray diffraction analysis. 相似文献
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A. P. Tyurin A. F. Smol’yakov F. M. Dolgushin I. A. Godovikov I. T. Chizhevsky 《Russian Chemical Bulletin》2013,62(8):1938-1940
A reaction of complexes CoCl2(dppe) (dppe is the 1,2-bis(diphenylphosphino)ethane) or CoCl2(dppp) (dppp is the 1,3-bis(diphenylphosphino)propane) with [K][7,8-nido-C2B9H12] upon reflux in benzene led to the mixed ligand closo-cobaltacarboranes [3,3-(Ph2P(CH2) n PPh2)-3-Cl-closo-3,1,2-CoIIIC2B9H11] (n = 2 and 3, respectively) in moderate yields (34 and 16%). The structure of the 18-electron complexes in solution and the solid state was studied by NMR and IR spectroscopy, the structure in the case of the closo-complex with dppe-ligand was confirmed by X-ray crystallography. 相似文献
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Conclusions The electronic effects of the 1-[closo-3,3,3-(CO)3-3,1,2-ReC2B9H10]– (I=-0.066; r
o=0.101) and 1-[closo-3,3,3-(CO)3-3,1,2-MnC2B9H10]–(I=0.090; r
o=0.165) groups were determined by the Taft method.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2296–2298, October, 1987. 相似文献
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《Journal of Coordination Chemistry》2012,65(18):1949-1958
The reaction of [RuCl2(PPh3)3] complex with 1-isoquinolyl phenyl ketone has been examined. A new ruthenium(II) complexes–[RuCl2(PPh3)2(C16H11NO)] has been obtained and characterised by IR and UV-VIS measurements. Crystal structure of the complex has been determined. The electronic spectrum of the complex has been calculated by TDDFT method. 相似文献
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