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1.
The main objective of this study was to evaluate the feasibility of pistachio shell as a biomass feedstock for the production of fungicidal oil and a precursor for the production of activated carbon by physical activation. For this purpose, pistachio shell was pyrolyzed in a fixed bed reactor at the different temperatures (300-600 °C). The pyrolysis products were identified as gas, bio-oil, aqueous solution and char. The product distribution from pyrolysis process did not significantly change when the pyrolysis temperature was above 300 °C. The pyrolysis gas product had low calorific value since it contained the high proportion of carbon oxides. Because of their high oxygen content, the bio-oils were found not to be used as a fuel. Thus, the bio-oil was tested again four different types of fungi (pathogenetic, wood decaying and saprophyting). It was shown fungicidal activity again all tested fungi at the concentration of 10-50 mg ml −1. The pyrolysis char was evaluated as a precursor for the production of activated carbon. The surface area and micropore volume of the activated carbon produced from the char by CO 2 activation at 900 °C were found to be 708 m 2 g −1 and 0.280 cm 3 g −1, respectively. 相似文献
2.
Fast pyrolysis of biomass materials impregnated with ZnCl 2 offered a promising way to obtain a liquid product rich in furfural (FF) and acetic acid (AA), and the pyrolytic solids could be used as the precursors to prepare activated carbons (ACs). In this study, a lab-scale fast pyrolysis set was designed and used for the quantitative production of the three chemicals. The maximum FF was produced from the corncob impregnated with at least 15 wt% ZnCl 2 and at the pyrolysis temperature around 340 °C, with the yield of more than 8 wt% compared with only 0.49 wt% from the raw corncob. Meanwhile, AA of around 4 wt% could be obtained. The content of the FF and AA was over 50 wt% and 25 wt% on the water-free basis of the pyrolytic liquids. In addition, ACs were prepared from the pyrolytic solids, and they exhibited similar properties as those prepared from direct activation of ZnCl 2-impregnated biomass materials. 相似文献
3.
Activated carbons from bagasse fly ash (BFA) were prepared by one step chemical activation using ZnCl 2 as activating agent, or combination method of chemical with CO 2 physical activation (physicochemical activation). The development of porosity was studied in correlation with the method of activation, activation temperature, and also the chemical weight ratio. A typical sample by the combination method at 600 °C and weight ratio of ZnCl 2:BFA = 2 exhibited micropore volume of 0.528 cc/g, mesopore volume of 0.106 cc/g and surface area of 1200 m 2/g. For determining the adsorption capacity of the carbon samples in solutions, phenol and methylene blue equilibrium adsorption experiments were conducted. The properties and adsorption capacity of the synthesized activated carbons has been compared to commercial activated carbon (Norit ® SX Plus). 相似文献
4.
A new and simple method, based entirely on a physical approach, was proposed to produce activated carbon from longan fruit seed with controlled mesoporosity. This method, referred to as the OTA, consisted of three consecutive steps of (1) air oxidation of initial microporous activated carbon of about 30% char burn-off to introduce oxygen surface functional groups, (2) the thermal destruction of the functional groups by heating the oxidized carbon in a nitrogen atmosphere at a high temperature to increase the surface reactivity due to increased surface defects by bond disruption, and (3) the final reactivation of the resulting carbon in carbon dioxide. The formation of mesopores was achieved through the enlargement of the original micropores after heat treatment via the CO 2 gasification, and at the same time new micropores were also produced, resulting in a larger increase in the percentage of mesopore volume and the total specific surface area, in comparison with the production of activated carbon by the conventional two-step activation method using the same activation time and temperature. For the activation temperatures of 850 and 900 °C and the activation time of up to 240 min, it was found that the porous properties of activated carbon increased with the increase in activation time and temperature for both preparation methods. A maximum volume of mesopores of 0.474 cm 3/g, which accounts for 44.1% of the total pore volume, and a maximum BET surface area of 1773 m 2/g was achieved using three cycles of the OTA method at the activation temperature of 850 °C and 60 min activation time for each preparation cycle. The two-step activation method yielded activated carbon with a maximum mesopore volume of 0.270 cm 3/g (33.0% of total pore volume) and surface area of 1499 m 2/g when the activation temperature of 900 °C and a comparable activation time of 240 min were employed. Production of activated carbon by the OTA method is superior to the two-step activation method for better and more precise control of mesopore development. 相似文献
5.
Activated carbons are produced from wastes of Algerian date stones by pyrolysis and physical activation in the presence of water vapor into a heated fixed-bed reactor. The effect of pyrolysis temperature and activation hold time on textural and chemical surface properties of raw date stones and carbon materials produced are studied. As expected, the percentage yield decreases with increase of activation temperature and hold time. The characterization of carbon materials is performed by scanning electron microscopy (SEM). X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption (BET). Results show the presence of cellulose and hemicellulose in the raw material, and the predominance of carbon and graphite after pyrolysis. Different oxygen-containing functional groups are found in the raw material while aromatic structures are developed after pyrolysis and activation. The best specific surface area (635 m 2 g −1) and microporous volume (0.716 cm 3 g −1) are obtained when the date stones are grinded, pyrolysed at 700 °C under a 100 cm 3 min −1 nitrogen flow and then activated under water vapor at 700 °C for 6 h. 相似文献
6.
Oil-palm shells, a biomass by-product from palm-oil mills, were converted into activated carbons by vacuum or nitrogen pyrolysis, followed by steam activation. The effects of pyrolysis environment, temperature and hold time on the physical characteristics of the activated carbons were studied. The optimum pyrolysis conditions for preparing activated carbons for obtaining high pore surface area are vacuum pyrolysis at a pyrolysis temperature of 675 °C and 2 h hold time. The activation conditions were fixed at a temperature of 900 °C and 1 h hold time. The activated carbons thus obtained possessed well-developed porosities, predominantly microporosities. For the pyrolysis atmosphere, it was found that significant improvement in the surface characteristics of the activated carbons was obtained for those pyrolysed under vacuum. Adsorption capacities of activated carbons were determined using phenol solution. For the activated carbons pyrolysed under optimum vacuum conditions, a maximum phenol adsorption capacity of 166 mg/g of carbon was obtained. A linear relationship between the BET surface area and the adsorptive capacity was shown. 相似文献
7.
Poly( p-phenylene benzobisoxazole) (PBO) was impregnated with small amounts of H 3PO 4, and the effects of this additive on the porosity and other characteristics of chars and activated carbon fibers (ACFs) derived from this polymer were investigated. To this end, PBO-AS impregnated with 5, 10 or 15 wt.% H 3PO 4 was pyrolyzed at 850 °C, and the resulting chars were physically activated with carbon dioxide at 800 °C to different burn-off (BO) degrees. Thermal analysis techniques only detected minor effects of H 3PO 4 on PBO pyrolysis. The char yield and char reactivity towards CO 2 increased following PBO-AS impregnation with H 3PO 4. Structural (X-ray diffraction), porous textural (CO 2 adsorption) and surface chemical (temperature-programmed desorption, X-ray photoelectron spectroscopy) characterizations of the pyrolysis chars indicated that the increase in char reactivity is probably associated with a higher content of oxygenated functionalities. Following CO 2 activation, the surface area and pore volume of the obtained ACFs chiefly depended on the BO degree, but impregnation with H 3PO 4 restricted the pore size to the micropore and narrow mesopore range, thus producing adsorbents with a slightly narrower pore size distribution than in the absence of H 3PO 4. The results are compared with those previously obtained under equivalent conditions with other high-crystallinity polymers as precursors for ACFs. 相似文献
8.
Char and tar derived from pyrolysis of Uruguayan Eucalyptus wood has been evaluated as raw materials for the preparation of
high mechanical resistance activated carbon pellets. Thermogravimetric analysis was used as the main technique for studying
tar and char pyrolysis in N2 and CO 2 atmospheres, and to determine the best conditions for CO 2 activation of the carbon pellets. Results indicated that activated carbon pellets with high surface area and good mechanical
resistance were obtained by CO 2 gasification at 1098 K. Pellets properties can be explained as due to the independent contribution of each component. 相似文献
9.
Pyrolysis oils were produced from hardwood or softwood feedstocks in a vacuum batch reactor and trapped at 0 °C. The vacuum process was used to intentionally avoid the presence of entrained char particles. The hardwood feedstock was a pelletized mixture of various Eastern tree species. The softwood samples were de-barked Lodgepole pine ( Pinus contorta) and Douglas Fir ( Pseudotsuga menziesii) wood cut into the same dimensions as the pellets. The oils’ physical (viscosity) and chemical (speciation) properties were measured as-produced and after aging. The total liquid and char yields ranged from ∼50 to 55% and 25 to 27% respectively. Measured water contents were 30% or more, which are greater typically reported from fast pyrolysis oils produced in fluidized beds. Aging took place in covered glass containers at room temperature over a period of 5 months. Gas chromatography-mass spectrometry (GCMS) was used to characterize the oils’ volatile components. Since bio-oils are mixtures of hundreds of different compounds with wide-ranging molecular weights and polarities, the oils were extracted using benzene followed by methanol. Out of ca. 80 non-polar and 100+ polar compounds GCMS showed a few chemical species present in the freshly produced oils were absent in the aged oils. The oils’ viscosities at shear rates (measured between 1 and 1000 s −1) increased by approximately a factor of 2.5 during aging. To determine if this was due to polymerization reactions during aging or simply water and other volatile material losses, freshly made oils were aged at an accelerated rate by using elevated temperatures (65 °C and 85 °C) in a water-saturated environment between 1 and 7 days. The oils are fairly stable with respect to aging both over long periods of time (months) at room temperature and at elevated temperatures, 65 °C and 85 °C for shorter time periods (days). It is concluded that high water content and char-free characteristics act to slow polymerization reactions. 相似文献
10.
Saponified, palm, olive, rapeseed and castor oils were pyrolysed (at 750 °C for 20 s) by pyrolysis gas chromatography with mass selective and flame ionisation detection (Py-GC/MSD and FID) to clarify their thermochemical behaviours. The liquefiable compounds recovered from palm, olive and rapeseed oils mainly contained linear alkenes (up to C 19) and alkanes (up to C 17), both similar to those found in gasoline (C 4-C 10) and diesel fuel (C 11-C 22) boiling range fractions of petroleum, whereas in the case of castor oil a significant amount of undesired oxygen-containing products (e.g., ketones and phenols) were formed. The obtained data on reaction mechanisms can also be utilised in applications where various biofuels are produced, for example, from the extractive-derived by-product (tall oil) of kraft pulping. 相似文献
11.
In this work, we present a comprehensive and systematic study on the use of low-cost and highly abundant carbon precursors to obtain SiO2/C anodes with superior electrochemical performance towards Li-ions. Different SiO2/C composites are prepared by soaking silica nanoparticles in solutions containing 20 wt%, 40 wt%, or 60 wt% of glucose, sucrose, or cornstarch, followed by thermal decomposition of the carbohydrates at 850 °C or 1200 °C. Structural, microstructural, and textural differences on the composites derived from the different carbon coating treatments are related to the electrochemical performance of the anodes. Composites containing final carbon contents close to 15 wt% show a complete coverage of the SiO2 particles with a nanometric carbon layer and exhibit the best electrochemical results. The increase in the annealing temperature from 850 to 1200 °C reduces the porosity of the carbon layer and increases its level of ordering, both having positive effects on the overall electrochemical performance of the electrodes. SiO2/C composites coated with 40 wt% sucrose and heat treated at 1200 °C display the best electrochemical performance, delivering a reversible specific capacity of 723 mAhg−1 at 50 mAg−1 after 100 cycles, which is considerably higher than the reversible capacity of 233 mAhg−1 obtained with the uncoated material cycled under the same conditions. 相似文献
12.
High specific capacitance and low cost are the critical requirements for a practical supercapacitor. In this paper, a new activated carbon with high specific capacitance and low cost was prepared, employing cotton stalk as the raw material, by using the phosphoric acid (H 3PO 4) chemical activation method. The optimized conditions were as follows: the cotton stalk and activating agent with a mass ratio of 1:4 at an activation temperature of 800 °C for 2 h. The samples were characterized by nitrogen adsorption isotherms at 77 K. The specific surface area and pore volume of activated carbon were calculated by Brunauer–Emmett–Teller (BET) and t-plot methods. With these experimental conditions, an activated carbon with a BET surface area of 1,481 cm 2?g ?1 and micropore volume of 0.0377 cm 3?g ?1 was obtained. The capacitance of the prepared activated carbon was as high as 114 F?g ?1.The results indicate that cotton stalk can produce activated carbon electrode materials with low cost and high performance for electric double-layer capacitor. 相似文献
13.
Evolved gas analysis-mass spectrometry (EGA-MS), which has high sensitivity and is a simple experimental procedure, was used to study the non-isothermal decomposition of cisplatin at 45-500 °C. Unexpectedly, four peaks appeared in the total ion chromatogram starting at 235 °C, and analysis of the mass spectra of the peaks indicated that cisplatin was thermally unstable and lost NH 3 and HCl simultaneously at 235-385 °C. The molecular ion (M +) in the electron impact ionization spectrum of cisplatin was detected for the first time, which confirmed that cisplatin vaporized partially in molecular form. Various ion-molecule reactions occurred to form complex ions at m/ z 370 and 335 at the higher part of the temperature range. 相似文献
14.
The development of ultra-inert composites using fluorinated carbon fibres as the reinforcement requires fluorinated carbon fibres with a durable surface composition. Here we report the effect of direct fluorination using an F 2/N 2 mixture at 653 K on the surface and bulk properties of two types of high strength carbon fibres. These were treated up to a surface fluorine content of ∼64 at.% and a bulk fluorine content of ∼15 mass%. A colour change was observed after fluorination caused by the changes in the graphitic band structure of the carbon fibres by the introduction of carbon sp 3 hybridisation. The tensile strength and Young's modulus decrease after fluorination by up to 33 and 22%, respectively. XRD shows marginal changes in the interlayer distance but the crystallite size increases. Changes in the electrical conductivity of the fluorinated carbon fibres indicate that the modification is confined to the near surface volume. Predominantly covalent C-F bonds are formed as shown by X-ray photoelectron spectroscopy (XPS) and measured zeta ( ζ)-potentials. Hence the fluorinated fibres are hydrophobic and have low surface tensions. This and the large increase in fibre surface area, as determined by nitrogen adsorption, is expected to facilitate interfacial interaction between fluorinated carbon fibres and fluoropolymers. 相似文献
15.
Owing to its combination of unique selectivity and mechanical strength, commercial carbon clad zirconia (C/ZrO 2) has been widely used for many applications, including fast two-dimensional liquid chromatography (2DLC). However, the low surface area available (only 20–30 m 2/g for commercial porous ZrO 2) limits its retentivity. We have recently addressed this limitation by developing a carbon phase coated on the high surface area of HPLC grade alumina (C/Al 2O 3). This material provides higher retentivity and comparable selectivity, but its use is still limited by how few HPLC quality types of alumina particles (e.g., particle size, surface area, and pore size) are available. In this work, we have developed useful carbon phases on silica particles, which are available in various particle sizes, pore sizes and forms of HPLC grade. To make the carbon phase on silica, we first treat the silica surface with a monolayer or less of metal cations that bind to deprotonated silanols to provide catalytic sites for carbon deposition. After Al (III) treatment, a carbon phase is formed on the silica surface by chemical vapor deposition at 700 °C using hexane as the carbon source. The amount of Al (III) on the surface was varied to assess its effect on carbon deposition, and the carbon loading was varied at different Al (III) levels to assess its effect on the chromatographic properties of the various carbon adsorbents. We observed that use of a concentration of Al (III) corresponding to a full monolayer leads to the most uniform carbon coating. A carbon coating sufficient to cover all the Al (III) sites, required about 4–5 monolayers in this work, provided the best chromatographic performance. The resulting carbon phases behave as reversed phases with reasonable efficiency (50,000–79,000 plates/m) for non-aromatic test species. 相似文献
16.
In this study, a new method for economical utilization of coffee grounds was developed and tested. The resulting materials were characterized by proximate and elemental analyses, thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and N 2 adsorption–desorption at 77 K. The experimental data show bio-oil yields reaching 42.3%. The optimal activated carbon was obtained under vacuum pyrolysis self-activation at an operating temperature of 450 °C, an activation temperature of 600 °C, an activation time of 30 min, and an impregnation ratio with phosphoric acid of 150 wt.%. Under these conditions, the yield of activated carbon reached 27.4% with a BET surface area of 1420 m 2·g −1, an average pore size of 2.1 nm, a total pore volume of 0.747 cm 3·g −1, and a t-Plot micropore volume of 0.428 cm 3·g −1. In addition, the surface of activated carbon looked relatively rough, containing mesopores and micropores with large amounts of corrosion pits. 相似文献
17.
The present study reports the preparation of naturally nitrogen-doped carbon nanostructured materials from Albizia procera leaves with enhanced electrochemical supercapacitance properties. The doped carbon materials were prepared by the pyrolysis of Albizia procera leaves at 850 °C. The effect of using various activating agents such as NaHCO 3 and ZnCl 2 was checked and compared on the structural and textural properties, specific capacitance, surface functional groups, and surface area. The Brunauer–Emmett–Teller (BET) analysis shows that NaHCO 3-activated nitrogen-doped carbon (NaNC) has a higher specific surface area compare to ZnCl 2-activated nitrogen-doped carbon (ZnNC) and nitrogen-doped carbon prepared without an activating agent (WANC). Overall, the BET and microscopic analyses confirmed that NaNC is composed of carbon nanosheets with macropores and mesopores, as well as a large number of micropores, which is completely different from the composition of ZnNC and WANC. In addition, the XPS analysis confirmed the existence of higher amount of nitrogen in NaNC compared to that of ZnNC, and WANC. NaNC exhibits a specific capacitance of 231 F g −1 at 1 A g −1 current with good energy and power densities, and an outstanding charging-discharging stability thanks to its unique features such as the existence of high amounts of nitrogen, high SSA, and the nanosheet-type morphology. 相似文献
18.
A novel corn grain precursor was used for the preparation of activated carbon by chemical activation. The detailed investigation of the porosity development in the prepared activated carbon was done by altering the various activation conditions such as the activation temperature, activation time and ratio between the powdered form of carbonized corn grain char and KOH. The surface characteristics including the surface roughness of all the activated carbon samples were evaluated from the analysis of nitrogen (N 2) adsorption isotherm data. At the maximum of 2978 m 2/g, a super surface area having the corn grain‐based activated carbon (CG‐AC) was synthesized by using the following conditions: 1/4 ratio of powdered form of carbonized corn grain char/KOH; 800 °C; and 4 h. The possibility of preparing highly porous activated carbons with controlled porosity by varying different activation conditions was found from the pore size distribution results. In particular, the domination of the ratio between the powdered form of carbonized corn grain char and KOH on the porosity development was high compared to the activation temperature and activation time. In addition, the surface roughness calculated from the surface fractal dimension indicates the decrease of surface roughness with increasing activation conditions. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
19.
The thermal decomposition mechanisms and the intermediate morphology of MgCl 2·6H 2O and MgCl 2·H 2O were studied using integrated thermal analysis, X-ray diffraction, scanning electron microscope and chemical analysis. The results showed that there were six steps in the thermal decomposition of MgCl 2·6H 2O: producing MgCl 2·4H 2O at 69 °C, MgCl 2·2H 2O at 129 °C, MgCl 2· nH 2O (1 ≤ n ≤ 2) and MgOHCl at 167 °C, the conversion of MgCl 2· nH 2O (1 ≤ n ≤ 2) to Mg(OH)Cl·0.3H 2O by simultaneous dehydration and hydrolysis at 203 °C, the dehydration of Mg(OH)Cl·0.3H 2O to MgOHCl at 235 °C, and finally the direct conversion of MgOHCl to the cylindrical particles of MgO at 415 °C. To restrain the sample hydrolysis and to obtain MgCl 2·H 2O, MgCl 2·6H 2O was first calcined in HCl atmosphere until 203 °C when MgCl 2·H 2O was obtained; HCl gas was then turned off and the calcination process continued, producing Mg 3Cl 2(OH) 4·2H 2O calcined at 203 °C, Mg 3(OH) 4Cl 2 at 220 °C and MgO at 360 °C. The temperature of producing MgO from calcination of MgCl 2·H 2O was lower (360 °C) than that from MgCl 2·6H 2O (415 °C) because of its more reactive intermediate products: the irregular shape and tiny needle-like Mg 3Cl 2(OH) 4·2H 2O particles and the uneven surface porous Mg 3(OH) 4Cl 2 particles. The MgO particles obtained at 360 °C had a flake structure. 相似文献
20.
In this work, carbon xerogels with a high pore volume and surface area (up to 2.58 cm 3/g and 3200 m 2/g respectively) have been synthesized using the sol-gel polycondensation of resorcinol (R) with formaldehyde (F) in a basic
medium of monoethanolamine (MEA), followed by drying and pyrolysis. This medium (MEA) has not been used in previous investigations.
The effect of activation with CO 2 on the pore size distribution and the chemical functional groups has been investigated using N 2 (77 K) adsorption, FTIR and elemental analysis techniques. A series of experiments has been conducted to investigate the
effect of activation time and activation temperature. Activation of the samples was carried out at 850, 900 and 980 °C for
times ranging from one to three hours. Within the range of activation conditions, an increase in activation time at 850 °C
results in a continuous steady rise of the BET surface area and total pore volume. However, at the two higher temperatures,
the surface area shows a maximum when plotted against activation time. FT-IR results show that the use of MEA as a catalyst
leads to the formation of nitrogen functional groups in the surface of the resin. 相似文献
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