C(膜)/Si(SiO2)(纳米微粒)/C(膜) 的光致发光性质研究

用直流辉光溅射法结合真空镀膜法制备出了一种“多层三明治结构”的光致发光材料—C(膜 ) /Si(SiO2 ) (纳米微粒 ) /C(膜 )夹层膜 ,然后分别在 40 0、6 5 0和 75 0℃退火 1h .在波长为 2 5 0nm的紫外光激发下 ,刚制备出来未经退火处理的样品具有一个在 398nm (3.12eV)处的紫光宽带PL1峰 .在 6 5 0℃退火后 ,又出现了一个在 36 0nm (3.44eV)附近的PL2 峰 .PL1和PL2 峰形状和峰位与退火温度和激发波长无关 ,但强度却与退火温度和激发波长密切相关 .结合形态结构分析可知 ,紫光PL1峰可用量子限制 -发光中心 (QC LCs)模型进行解释 :即光激发发生在SiO2 微粒内部 ,而光发射源于SiO2 与Si界面上的缺陷中心 .紫外荧光PL2 峰则源自SiC内部的电子 空穴复合发光     

Optical and electronic properties of (GaAs)n / (InAs)n(001) superlattices: LMTO-ASA approach

The optical and electronic properties of (GaAs)_n/(InAs)_n superlattices are calculated by means of LMTO-ASA method. The too small band gap problem of bulk material and superlattices is corrected by adding to the effective potentials an additional external potential that is sharply peaked at the atomic sites. The results show that the optical properties of GaAs/InAs(001) superlattices are about average of that of two bulks of GaAs and InAs.     

Angular-distribution He(I) /Ne(I) /Ar(I) photoelectron spectra of unsaturated hydrocarbons

The energy dependence of the anisotropy parameters of the π- and selected σ-bands of ethylene, 1,3-butadiene, benzene, cyclohexene, norbornadiene, 1,3-and 1,4-cyclohexadiene has been determined in the low energy region. Whereas the behaviour of the σ-bands is much less uniform, all π-band β-values decrease with decreasing energy towards similar threshold values. Strong intra-band energy dependencies have been observed for both π and σ orbitals, while in the multiple π-orbital molecules there is a symmetry-specific contribution to the π β-values. Marked intensity variations are observed among the ethylene, butadiene and benzene bands, and the anisotropy-parameter-based assignment of symmetric character to the 1,4-cyclohexadiene first band is confirmed.     

Phase Structure of Polyamide 6/Poly(styrene-co-acrylonitrile) and Poly(styrene-b-(ethylene-co-butylene)-b-styrene) or Poly(maleated Styrene/Ethylene-co-Butylene/Styrene) Ternary Blends

Two sets of ternary blends; polyamide 6/poly(styrene-co-acrylonitrile)/poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PA6/SAN/SEBS) and polyamide 6/poly(styrene-co-acrylonitrile)/poly(maleated styrene/ethylene-co-butylene/styrene) (PA6/SAN/SEBS-g-MA), based on 70 wt% of matrix and 30 wt% of the dispersed phases at various concentrations of the minor components, were prepared via melt blending. Morphologies of the ternary systems were studied using scanning electron microscopy (SEM) and compared with the predictions of the spreading coefficient (SC), minimum relative interfacial energy (RIE), and dynamic interfacial energy (DIE) phenomenological models. The effects of different reported surface tensions of the used polymers and different protocols of the core-shell ratio calculation on the prediction of the models were investigated. The core-shell structure for PA6/SAN/SEBS system and two separate minor phases for PA6/SAN/SEBS-g-MA were observed at all of the compositions. The results indicated that the most important parameter for the accurate prediction of the models is the accurate calculation of the interfacial tension of the used polymers, in both the static and dynamic conditions.     

直流电致发光(DCEL)器件在交流(AC)电压下的I-V,B-V和B-I特性

本文研究了DCEL器件在AC条件下的电流-电压(I-V),亮度-电压(B-V)和亮度-电流(B-I)特性.提出了在不同激发条件下的I-V,B-V和B-I的经验公式.证明了DCEL器件在AC条件下按激发条件可分为三个负载区:容性负载区,电阻负载区和混合负载区.在不同的负载区DCEL器件呈现完全不同的光电特性.证明了在不同负载区工作时磷光粉层内电场分布和电子能量分布截然不同.分析了上述特性的原因.证明了老化和形成过程具有同样的物理机制,老化是形成过程的继续.     

Leptonic nonet in SUL (3) × SUR (3)

A left-right symmetric SU_L(3) × SU_R(3) gauge model with leptons in the ($\text{3}\text{, 3) + (3,}\text{3}$) representation is presented. The SU^I_L(2)×U(1) subgroup is practically the WS + GIM model for $\text{sin}{}^2\text{?}{}_{\mathrm{<mtext>W</mtext>}}\text{≈}\text{3}\text{8}$, with additional currents involving heavy leptons. μ→eγ is naturally suppressed and a new kind of $\text{ν}{}_{\mathrm{<mtext>e</mtext>}}\text{?}\text{ν}{}_{\mathrm{\mu }}$ oscillations is possible. τ and 3_μ events can be related to one leptonic triplet. The model is naturally imbedded in exceptional groups.     

SU(3) LIMIT OF U(6/20) SUPERSYMMETRY IN NUCLEI

In this paper we discuss the SU(3) limit of U(6/20) supersymmetry. First we derive the reduction formulas of the relevant group chain. Then we discuss the dynamical symmetry. Finally we make comparison between the theoretical calculation and experimental measurement in the case of nucleus .²³⁵₉₂U₁₄₃     

Fracture Micromechanisms of Polypropylene/Polycarbonate/Poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PP/ PC/SEBS) Ternary Blends: The Effects of SEBS Content

Ternary blends of polypropylene/polycarbonate/poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PP/PC/SEBS) with varying SEBS contents were produced via melt blending in a co-rotating twin-screw extruder. The phase morphology of the resulting ternary blends and its relationship with bending and impact behaviors were studied. Transmission optical microscopy (TOM) of the crack tip damage zone and scanning electron microscopy (SEM) of impact fractured surfaces were performed to characterize the fracture mechanism. With increasing SEBS content in the PP/PC/SEBS ternary blends, the number of PC/SEBS core-shell particles increased and the size of the core-shell particles enlarged. It was shown that with an SEBS content of 5%, the crack initiation resistance decreased and then was almost unchanged with further increase of SEBS content, while resistance to crack growth increased continuously with increasing of SEBS content. Preliminary analysis of the micromechanical deformation suggested that the high impact toughness observed for samples containing 20 and 30 wt% of SEBS could be attributed to cavitation of the rubbery shell and, consequently, shear yielding of the matrix. This plastic deformation absorbed a tremendous amount of energy. Due to low interfacial adhesion between PC particles and PP matrix in samples containing 5 and 10 wt% of SEBS, debonding occurred too early, so the occurrence of matrix shear yielding was delayed and resulted in premature interfacial failure and, hence, rapid crack propagation.     

Magnetic phase transition in Co/Cu/Ni/Cu(100) and Co/Fe/Ni/Cu(100)

Magnetic phase transitions in coupled magnetic sandwiches of Cu/Co/Cu/Ni/Cu(100) and Cu/Co/Fe/Ni/Cu(100) are investigated by photoemission electron microscopy. Element-specific magnetic domains are taken at room temperature to reveal the critical thickness at which the magnetic phase transition occurs. The results show that a coupled magnetic sandwich undergoes three types of magnetic phase transitions depending on the two ferromagnetic films' thickness. A phase diagram is constructed and explained in the process of constructing Monte Carlo simulations, which corroborate the experimental results.     

Fluorescence Excitation Spectrum of a (2)Pi(3/2)-(2)Pi(3/2) Transition of NiF

In this study, a supersonic beam of NiF was produced by the reaction of SF(6) with a dc discharge-sputtering source of nickel atoms. The laser-induced fluorescence excitation spectrum of a (2)Pi(3/2)-(2)Pi(3/2) transition has been recorded in the range of 500-520 nm and rotational structure of 506.5-nm band analyzed under the 30 K rotational temperature. Our data are consistent with a (2)Pi(3/2) ground state for NiF. The lifetime of this band is measured. Copyright 2000 Academic Press.     

Understanding DsJ(2317)

We analyze the hadronic and radiative decay modes of the recently observed D_sJ(2317) meson, in the hypothesis that it can be identified with the scalar state of spectrum (D_s0). The method is based on heavy quark symmetries and vector meson dominance ansatz. We find that the hadronic isospin violating mode D_s0→D_sπ⁰ is enhanced with respect to the radiative mode D_s0→D_s^*γ. The estimated width of the meson is Γ(D_s0)7 keV.     

NiO-thickness dependent magnetic anisotropies in Fe/NiO/Au(001) and Fe/NiO/MgO(001) systems

The in-plane magnetic anisotropy of Fe/NiO bilayers was studied quantitatively as a function of NiO thickness using the magneto-optical Kerr effect with a rotating field. For NiO thicker than the ordering transition thickness, the total in-plane fourfold anisotropy of the Fe layer decreases with NiO thickness in Fe/NiO/Au(001), but increases in Fe/NiO/MgO(001). Our result indicates that the exchange coupling in an Fe/NiO bilayer might induce an additional in-plane fourfold anisotropy, and the opposite thickness dependent behaviors may be attributed to the different Ni²⁺ antiferromagnetic spin orientations for NiO films grown on Au(001) and MgO(001) surfaces.     

Growth and X-ray studies of (NaCl)x(KCl)y−x(KBr)1−y single crystals

Ternary mixed crystals of NaCl, KCl and KBr were grown by the melt method for the first time. Densities and refractive indices of all the grown crystals were determined and also used for the estimation of the bulk composition in the crystal. Lattice parameters and thermal parameters like Debye-Waller factor, mean square amplitude of vibration, Debye temperature and Debye frequency were determined from the X-ray powder diffraction data. The observed lattice parameters showed the existence of two phases in crystals with NaCl content greater than 0.1 mole fraction. The thermal parameters show a highly non-linear composition dependence. The results are reported.     

Magnetische untersuchungen an mischkristallen der quasibinären legierungssysteme (Cd Te)1-x (Mn Te)x und (Sn Te)1-x (Mn Te)x

The magnetic susceptibility and magnetization are presented for polycrystalline samples of the alloy systems Cd_1-xMn_xTe 0 < x 0.1 and Sn_1-xMn_xTe 0 < 4 0.4. The magnetic measurements were performed between 2.3 K and 300 K in external magnetic fields up to 11 kOe. At sufficiently high temperatures the susceptibility can be described by a Curie-Weiss law. In the system Sn_1-xMn_xTe θ_p is positive. A linear dependence θ_p ∞ x was found with θ_p(0.4) = 49 K. In the series Cd_1-xMn_xTe θ_p changes sign. For θ < x < 0.04 θ_p is positive with a maximum θ_p ≈ 10 K at x = 0.02. In the region x #62; 0.04 θ_p becomes negative with θ_p = -35 K at x = 0.1. The effective spin value of manganese is S_eff #62; 5/2 for all the samples. The investigation was done to check the assumption that ferromagnetic coupling may exist in tellurides of manganese if the shortest distance d_MnMn is greater than 3.4 Å. This hypothesis has been stated. In the case θ_p #62; 0 the results are partly explained by the RKKY exchange coupling.     

Photoluminescence of bis(8-hydroxyquinoline) zinc (Znq2) and magnesium (Mgq2)

Absorption and photoluminescence (PL) spectra, PL quantum efficiency, and PL lifetime have been investigated on bis(8-hydroxyquinoline) zinc (Znq₂) and magnesium (Mgq₂) in solutions and powder. Znq₂ and Mgq₂ have the lowest-energy absorption band at 376 and 396 nm in acetonitrile solution, respectively, and emission band with peak at 555 and 480 nm. The PL quantum efficiency is 0.03 and 0.45 for Znq₂ and Mgq₂ in the solution, respectively, while 0.45 and 0.36 in powder. Unlike the case of powders, two PL lifetimes are obtained in solutions. The longer lifetime is attributed to molecule having interaction with its neighboring molecule, while the shorter one to the isolated single molecule.     

PA和PPP三嵌段共聚物的带电态研究

采用半经验的Austin Model 1(AM1)方法,计算了-(PA)₄-(PPP)_m-(PA)₄-共聚物的带电状态,该系列共聚物具有典型的阱垒阱结构特征.与中性态相比,带电态下其分子结构表现为C—C键长发生显著的改变.在不同的掺杂浓度及不同的势垒宽度下,电荷在势阱中的分布是不同的. 关键词： 共聚物 有机量子阱 带电态 键长     

Preparation of (CdO)1−x(PbO)x and (CdS)1−x(PbS)x thin films by spray pyrolysis technique and their characterization

Mixed thin films of (CdO)_1−x(PbO)_x and (CdS)_1−x(PbS)_x (x=0.25) were prepared on glass substrates by spray pyrolysis technique for various substrate temperatures 300, 320 and 340 °C. Structural and optical properties were studied. XRD studies reveal the formation of mixed films. The substrate temperature of 340 °C seems to be critical for the formation of CdO-PbO mixed films. It is observed that (CdS)_1−x(PbS)_x mixed films were formed at all the three substrate temperatures. The direct band gap value of (CdO)_1−x(PbO)_x and (CdS)_1−x(PbS)_x mixed films is about 2.6 and 2.37 eV, respectively.     

Structure and magnetostriction of RFex (1.6 x 2.0) and R(Fe1−yTiy)1.8 (y 0.2) alloys (R=Dy0.65Tb0.25Pr0.1)

Structure, Curie temperature and magnetostriction of RFe_x (1.6 x 2.0) and R(Fe_1−yTi_y)_1.8 (y 0.2) alloys (R=Dy_0.65Tb_0.25Pr_0.1) have been investigated using optical microscopy, X-ray diffraction, AC initial susceptibility and standard strain gauge techniques. The homogenized RFe_x alloys are found to be essentially single phase in the range of 1.8 x 1.85. The second phase is a rare-earth-rich phase when x 1.8, and (Dy, Tb, Pr)Fe₃ phase when x 1.85. X-ray diffraction indicates that the R(Fe_1−yTi_y)_1.8 alloys contain a small amount of Fe₂Ti phase when y 0.05, which increases with the increment of Ti content. The Curie temperature of R(Fe₁−_yTi_y)_1.8 alloys slightly enhances with increasing Ti concentration when y 0.05, then remains almost unchanged in the range of 0.05 y 0.20. The magnetostriction of RFe_x alloys is improved when x 1.80 and reduced by increasing Fe content when x 1.85. The magnetostriction of R(Fe_1−yTi_y)_1.8 alloys is lowered by increasing Ti content.