Far-infrared laser stark spectroscopy of CH3OH and13CH3OH

The high resolution laser Stark spectra of methanol and¹³C-substituted methanol have been studied up to Stark fields of about 60 000V/cm with the HCN and DCN lasers. Numerous families of absorption lines have been observed in both parallel and perpendicular polarizations. For methanol, the transitions J _k =7₅ 6₄ A, _t=0; J _k =11₄ 10₃ E _l , _t=0; and J _k =17₃ 16₂ E₂, _t=0 have been identified while the assignments for¹³C-substituted methanol are J _k =14₈ 15₇ A, _t=0; J _k =15₃ 14₂ A⁺, _t=0; J _k =10₇ 9₆ A, _t=0; and J _k =27₉ 27₈ E₁, _t=0. Zero-field frequencies for the assigned transitions are given with improved accuracy over those calculated from available molecular constants, especially for¹³CH₃OH.     

Identification and imaging of hot O2 (v″=2, 3, or 4) in hydrogen flames using 193 nm- and 210 nm-range light

Some simple molecules can be excited by light within the tuning ranges of ArF (193–194 nm) and KrF (247.8–248.8 nm) excimer lasers and their fluorescence has been previously used for imaging. Additional wavelength ranges should become available by Raman shifting. As a demonstration, we present excitation and fluorescence spectra from hot O₂ obtained (a) with tunable 193 nm-range light and (b) with that light shifted into the 210 nm range. All measurements are via predissociative upper states. In the 193 nm range, results are compared with those of Andresen's group. In the 210 nm range, the light is tuned to various excitation wavelengths in the (5 3), (8 4), and (7 4) bands of the B–X transition. The (7 4) excitations are well separated and the (7 v) fluoresence spectrum is in accord with Franck-Condon calculations. The wavelengths tend to overlap for the (5 3) and (8 4) excitations and the fluorescence is weaker. State-specific two-dimensional fluorescence images of an H₂-O₂ flame are obtained in both wavelength ranges to illustrate the use of the method.We acknowledge the National Science Foundation and the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research     

Far-Infrared Laser Stark Spectroscopy of CH3OD

The high resolution Stark spectra of the singly deuterated methanol isotope, CH₃OD, have been studied using the HCN laser with Stark fields up to approximately 60 000 V/cm. Numerous families of absorption lines have been observed in both parallel and perpendicular polarizations, resulting in the following assignments: with the 311 m line – J _K = 18₁ 18₀ E ₂, _t = 1; and with the 337 m line – J _k = 6₄ 5₃ E ₂, _t = 0 and J _K = 14₆ 13₅ A, _t = 1. Zero-field frequencies for the assigned transitions are in agreement with Fourier transform measurements and those calculated from the available molecular constants.     

Spectroscopy of alkali atoms and molecules attached to liquid He clusters

Large helium clusters, ranging in size from a few hundred to several thousand atoms, are produced in a nozzle expansion. Combining this source with a pick-up scattering cell in which the clusters can be seeded with chromophores allows us to probe the influence of the helium environment on the atoms and molecules attached to the clusters. Using an alkali as chromophore we recorded laser induced fluorescence spectra of Na atoms and molecules attached to helium clusters. Apart from the spectrum of the Na monomer, we have found spectroscopic bands which can unambiguous be assigned to two bound Na atoms. The first of this bands is due to 1^{1 +} (A) 1¹ _g ⁺ (X) excitations of the covalently bound singlet Na₂ molecule while the second is due to 1³ _g ⁺ 1^{3 +} excitations for the van der Waals bound triplet Na₂ dimer. Both bands have been vibrationally resolved. Furthermore we found very large fluorescence intensities in the region 605–635 nm which are likely due to the excitation of a species containing three Na atoms attached to a helium cluster.     

Temperature measurement using degenerate four-wave mixing with non-saturating laser powers

We report the use of Degenerate Four-Wave Mixing (DFWM) in the OHA ^{2 +} X ² ( = 0 = 0) band for temperature determination in a propane/air flame using laser powers below the saturation level. We show that at these low power levels the dependence of the signal on the dipole moment for the transition has to be established before meaningful temperature data can be obtained. This presents a paradox in that the temperature has to be known before the form of the dependence on the dipole moment can be determined. Solutions to this paradox are presented. We also show that absorption of the laser beams in this OH band system cannot be neglected and that failure to correctly account for the absorption leads to a large over estimate of the flame temperature. Furthermore, we show that the accuracy of the absorption-corrected temperature is critically dependent on the accuracy with which the measurement position within the flame is known. Finally, the temperature calculated from DFWM spectra using the correct dipole moment power and absorption is compared to the temperatures obtained using Laser-Induced Fluorescence (LIF) and Coherent Anti-Stokes Raman Spectroscopy (CARS).     

Spectral superbroadening of self-focused picosecond laser pulses in D2O

Intense picosecond light pulses of a mode-locked Nd: glass laser at _L =1054 nm (fundamental wavelength) and _SH =527 nm (second harmonic wavelength) are passed through a sample of D₂O under self-focusing conditions. Spectrally structured superbroadened, spatially bell-shaped emission in the forward direction is obtained. Primary generation processes are pump-pulse-degenerate stimulated parametric four-photon interaction (₁ + _{1 3} + ₄) and stimulated Raman scattering (_{1 R} + ), which occur concurrently (₁= _L or _SH angular pump frequency, #x03C9; _R first Stokes frequency, #x03C9; signal frequency, #x03C9;₃ signal frequency, #x03C9;₄ idler frequency). The parametric four-photon interaction occurs under collinear non-phase-matched conditions and under longitudinally phase-matched, transversally non-phase-matched (erenkov-like) conditions. Subsequent interaction processes are pump-pulse-nondegenerate four-photon interaction of the type ₁ + _{R 3} + ₄, coherent antiStokes Raman scattering (CARS, ₁ + ₁ – _{4 3}), inverse Raman scattering ( _A + ₁ + ), and cascading light up-conversion of the type ₁ + _(i) – _{R (i+1)}.     

N-body theory revisited and its extension to the πNNN-NNN problem

In order to approach the pion-multinucleon problem, we have found it convenient to reformulate the generalN-body theory starting from the fully unclusterized (i.e.,NN) amplitude. If we rewrite such an amplitude in terms of new unknowns, which can be later identified as the amplitudes for all the (N–1)(N–1) cluster processes, and repeat recursively the procedure up to the treatment of the 22 cluster processes, we obtain very naturally the hierarchy of equations which ranges from theN-body fully-disconnected Lippmann-Schwinger equation to theN-body connected-kernel Yakubovskii-Grassberger-Sandhas one. This revisitation turns out to be very useful when considering the modifications required in case one of the bodies is a pion and the remaining are nucleons, with the pion being allowed to disappear and reappear through the action of a pion-nucleon vertex. In fact, we obtain a new set of coupled pionmultinucleon equations, which allow a consistent and simultaneous treatment of scattering and absorption. For the NNN system, the kernel of these coupled equations is shown to be connected after three iterations.Dedicated to Prof. Werner Sandhas on the occasion of his 60th birthday     

Stationary states of an electron in the field of a hole in an ionic crystal

An approximate solution is given of the Schrödinger equation for S-states of an electron in the field of a hole, when the potential energy of the electron has the form — e²/r [1+exp (–qr].

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s- , –e²/r [1+exp (–qr].

     

ЭЛЕКТРИЧЕСКАЯ ЭКВИВ АЛЕНТНАЯ СХЕМА ЗАТУХАЮЩИХ КОЛЕБАНИ Й ИЗГИБА У ПБЕЗОЭЛЕКТРИЧЕСКИ Х СТЕРЖНЕЙ

- .     

Small perturbations ofC*-dynamical systems

It is shown that if is the generator of a strongly continuous oneparameter group of *-automorphisms of aC*-algebraA and is an unbounded *-derivation ofA with the same domain as , then + is also a generator for all sufficiently small real numbers .     

Grassmann-Cartan algebra and Klein-Gordon equations

Given a Riemannian structure (M, g), a hypothesis is investigated that if= _p=0 ⁿ _p (M) is submitted to the differential condition (g++)=0, =mc/—which implies that each component of fulfills the Klein-Gordon equation (- ²) _p =0, ought to be interpreted as a natural complex of the bosonic fields. Then it is found that the complex admits the interpretation in the sense of first quantization with (M) being a convex set of states, with the structure of a Hilbert space over . The definite spin states of bosons are then pure states which are not conserved by the temporal evolution.     

A lower bound for the memory capacity in the Potts-Hopfield model

We consider Potts-Hopfield networks of sizeN. We prove the result: _c >0 such that for all 0<< _c we can find, >0 in such a way that, whenN, we can store N patterns, all of them being sorrounded by -energy barriers at distance.     

Gravitation and universal Fermi coupling in general relativity

The generally covariant Lagrangian densityG = + 2K _matter of the Hamiltonian principle in general relativity, formulated by Einstein and Hilbert, can be interpreted as a functional of the potentialsg _ikand of the gravitational and matter fields. In this general relativistic interpretation, the Riemann-Christoffel form _kl ⁱ = _kl ⁱ for the coefficients _kl ⁱ of the affine connections is postulated a priori. Alternatively, we can interpret the LagrangianG as a functional of , g_ik, and the coefficients _kl ⁱ . Then the _kl ⁱ are determined by the Palatini equations. From these equations and from the symmetry _kl ⁱ = _lk ⁱ for all matter fields with /=0 the Christoffel symbols again result. However, for Dirac's bispinor fields, / becomes dependent on the Dirac current, essentially with a coupling factor Khc. In this case, the Palatini equations define a new transport rule for the spinor fields, according to which a second universal interaction results for the Dirac spinors, besides Einstein's gravitation. The generally covariant Dirac wave equations become the general relativistic nonlinear Heisenberg wave equations, and the second universal interaction is given by a Fermi-like interaction term of the V-A type. The geometrically induced Fermi constant is, however, very small and of the order 10^–81erg cm³     

К ВОПРОСУ O КРИТИЧЕСКО Й ЧАСТОТЕ ПРИ ПРЕРЫВИСТОМ ОСВЕ ЩЕНИИ

c , c n , n AgBr. .     

Time production and spatial distribution of macroscopic space charges in D-C discharge plasma

It is shown for a one-dimensional approximation that, around a disturbance in the ion concentrationn ₊(x, t) in the axial direction of a cylindrical plasma, a corresponding electron distributionn _–(x, t) is established with such a large velocity that under the usual conditions of a discharge plasma this electron distribution follows the relatively slow changes in ion concentration practically without delay. Relation (24) then holds for the electron concentration, the parametersl ₁,l _D being given by Eqs. (15) and (16). As long as the disturbance of the ions isn ₊(x) 0, a space chargeq ₀(n ₊-n_–) is produced and maintained in the plasma even if the disturbance of the equilibrium state of the plasma in the initial stage was electrically neutral (i.e.n ₊(x, t=0)==n _–(x,t=0)). The dimensions of these space charges can be many orders larger than the Debye characteristic lengthl _D ; this is shown on an example of a spatially periodic curven ₊(x). The unique (quasi-stationary) expression of the electron concentrationn _– by means of the deflection of the ion concentrationn ₊(x, t) permits a considerable simplification of the solution of the problems connected with axially disturbing the homogeneous state of a plasma, sincen _–(x, t) can be eliminated from the equations of continuity of the plasma by substituting from (24), and the problem becomes that of determining the curve of the ion concentrationn ₊ from the equations modified in this way.

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, ₊(, t) - _–(, t) , . (24), l ₁ l _D (15) (16). ₊() 0, q ₀(n₊ — n_–), , (..n ₊(x,0)=_–(, 0)). () _{– +}(, t) , , . . _–(, t) n ₊ .

     

More inequalities for critical exponents

A variety of rigorous inequalities for critical exponents is proved. Most notable is the low-temperature Josephson inequalitydv +2 2–. Others are 1 1 +v, 1 1 , 1,d 1 + 1/ (for d),dv, ₃ + (for d), ₄ , and _{2m 2m+2} (form 2). The hypotheses vary; all inequalities are true for the spin-1/2 Ising model with nearest-neighbor ferromagnetic pair interactions.NSF Predoctoral Fellow (1976–1979). Research supported in part by NSF Grant PHY 78-23952.     

Langevin dynamic simulation of hysteresis in a field-swept Landau potential

Numerical simulations are done of Langevin dynamics for a uniform-orderparameter, field-swept Landau model,= –|a/2|m ²+|b/4|m ⁴–mh(t) , to study hysteresis effects. The field is swept at a constant rateh(t)=h(0)+ht. The stochastic jump values of the field {h_J from an initially prepared metastable minimumm(0) are recorded, on passage to a global minimum m(). The results are: (a) The mean jump¯h _J(h) increases (hysteresis loop widens) with h, confirming a previous theoretical criterion based on rate competition between field-sweep and inverse mean first-passage time (FPT); (b) The broad jump distribution(h _J,h) is related to intrinsically large FPT fluctuations ( ²–²)/ ² O(1), and can be quantitatively understood. Possible experimental tests of the ideas are indicated.     

Anderson localization for the almost Mathieu equation: A nonperturbative proof

We prove that for any diophantine rotation angle and a.e. phase the almost Mathieu operator (H()) _n = _n–1 + _n+1 +cos(2(+n)) _n has pure point spectrum with exponentially decaying eigenfunctions for 15. We also prove the existence of some pure point spectrum for any 5.4.     

The van der Waals limit for classical systems

For a -dimensional system of particles with the two-body potentialq(r)+ ^v K(r) and density , it is proved under fairly weak conditions onq andK that the canonical pressure (, ) and chemical potential (, ) tend to definite limits when 0. The limiting functions are absolutely continuous and are given in terms of the derivative of the limiting free energy density which was found in Part I.