Two-dimensional NMR spectroscopy in Earth's magnetic field

We demonstrate the first two-dimensional correlation NMR (COSY) spectra obtained at ultra low frequencies (ULF) using the Earth's magnetic field. Using a specially developed spectrometer with multiple audio-frequency pulses under controlled pulse phase, we observe magnetisation transfer arising from heteronuclear J-couplings in trifluoroethanol and para-difluorobenzene. The 2D COSY spectra exhibit all diagonal and off-diagonal multiplets consistent with known J-couplings in these molecules.     

Self-Diffusion Imaging by Spin Echo in Earth's Magnetic Field

The NMR of the Earth's magnetic field is used for diffusion-weighted imaging of phantoms. Due to a weak Larmor field, care needs to be taken regarding the use of the usual high field assumption in calculating the effect of the applied inhomogeneous magnetic field. The usual definition of the magnetic field gradient must be replaced by a generalized formula valid when the strength of a nonuniform magnetic field and a Larmor field are comparable (J. Stepišnik,Z. Phys. Chem.190, 51–62 (1995)). It turns out that the expression for spin echo attenuation is identical to the well-known Torrey formula only when the applied nonuniform field has a proper symmetry. This kind of problem may occur in a strong Larmor field as well as when the slow diffusion rate of particles needs an extremely strong gradient to be applied. The measurements of the geomagnetic field NMR demonstrate the usefulness of the method for diffusion and flow-weighted imaging.     

核磁共振扩散测量和q-空间成像进展(英文)

在过去的近半个世纪, NMR扩散测量在理论和实践方面都不断取得进展,使得测量更加可靠和准确,并能获取越来越多的信息.随着扩散测量技术的发展,其科学应用范围也不断增加,覆盖从物理化学到临床医学等各个领域. NMR扩散测量不仅能提供分子的平移运动动力学信息,而且也可以提供影响平移运动的局部几何结构的信息,后一种应用通常称为q-空间成像.该综述聚焦于过去10年中的NMR扩散研究方面一些重大的进展.     

The Quantum N-Body Problem and the Auxiliary Field Method: New Developments

Approximate analytical energy formulas for N-body semirelativistic Hamiltonians with one- and two-body interactions are obtained within the framework of the auxiliary field method. We first review the method in the case of nonrelativistic two-body problems. A general procedure is then given for N-body systems and a connection is presented between the method and the generalized virial theorem. The procedure is applied to the case of baryons in the large-N _c limit.     

A dynamic nuclear polarization strategy for multi-dimensional Earth's field NMR spectroscopy

Dynamic nuclear polarization (DNP) is introduced as a powerful tool for polarization enhancement in multi-dimensional Earth’s field NMR spectroscopy. Maximum polarization enhancements, relative to thermal equilibrium in the Earth’s magnetic field, are calculated theoretically and compared to the more traditional prepolarization approach for NMR sensitivity enhancement at ultra-low fields. Signal enhancement factors on the order of 3000 are demonstrated experimentally using DNP with a nitroxide free radical, TEMPO, which contains an unpaired electron which is strongly coupled to a neighboring ¹⁴N nucleus via the hyperfine interaction. A high-quality 2D ¹⁹F–¹H COSY spectrum acquired in the Earth’s magnetic field with DNP enhancement is presented and compared to simulation.     

PET探测器技术的新进展

PET设备中探测器的研发, 一直是很活跃且具有高创新性的领域。 提高现有基于闪烁晶体探测器的性能, 研究适用于多模式成像设备（PET/CT和PET/MRI）的新型探测器, 满足TOF和DOI技术的需求并促进其发展应用, 构成PET探测器的几个主要研究方向。 介绍了PET探测器在闪烁晶体、 光电探测器和半导体探测器等方面的最新进展, 指出未来最有潜力的探测器设计方案。 The research on PET detector is a very active and highly innovative field. The main research interests of PET detector include improving performances of scintillation crystal detectors, investigating new detectors being suitable for multimodality imaging (e.g., PET/CT and PET/MRI), meeting needs of TOF and DOI technologies in order to promote their development and application. In this paper, new developments in PET detector technology about scintillation crystal, photodetector and semiconductor detector are introduced and the most potential detector design scheme in the future is brought forward.     

Lunar and Solar Tides in the Electric Field of the Earth's Atmosphere

The paper is aimed at solving one of the problems of modern geophysics, namely, investigating a correlation between the Earth's extremely low frequency (<30 Hz) electromagnetic field in the ground atmospheric layer and the global geophysical processes like lunar and solar tides.     

Field sweep broadline NMR spectroscopy

A novel NMR spectrometer is described that is uniquely versatile in its ability to accurately record broad lines by sweeping the superconducting magnetic field and to perform standard high resolution solid state NMR experiments. Broadline observation is illustrated by ²⁷Al spectra from static samples. Such an instrument opens up many nuclei for serious study by NMR in the solid state for the first time.     

A New Insight into Cobalt Metal Powder Internal Field 59Co NMR Spectra

The authors present a new approach of internal field ⁵⁹Co NMR spectra assignment leaving apart from “usual” decomposition on “pure” hcp and fcc stackings, and a set of stacking faults (sfs) sf₁–sf₅ with a certain lines position. The authors propose including into consideration not only cobalt structural features as well as its magnetic nature due to the strong ferromagnetism in Co metal. The last fact supposes an existence of different magnetic species such as magnetic domains, domain walls, and single-domain particles, thereby helping to spectral lines assignment according to both structural and magnetic origin. The examined sample contains fcc and hcp resonance peaks in both domains and domain walls giving the hcp to fcc ratio equal to 1.9, as well a significant amount of Co sfs, or Co in loose coordination, up to 10 %. The research exhibits a good agreement of all implemented techniques.     

低场脉冲NMR中静磁场不均匀性的射频场补偿

在低场脉冲核磁共振实验中为了增大射频激励的带宽,通常采用的方法是提高射频激励磁场的场强. 针对共振区域中静磁场的不均匀性,本文提出了根据共振区域中的静磁场分布设计射频线圈以提高射频激励带宽,并用目标场方法实现了这一构想.      

New Developments in the Eight Vertex Model

We demonstrate that the Q matrix introduced in Baxter's 1972 solution of the eight vertex model has some eigenvectors which are not eigenvectors of the spin reflection operator and conjecture a new functional equation for Q(v) which both contains the Bethe equation that gives the eigenvalues of the transfer matrix and computes the degeneracies of these eigenvalues.     

Few-Body Physics in Chiral Effective Field Theory: Recent Developments

Chiral effective field theory provides a systematic tool to study few-nucleon dynamics based on the approximate and spontaneously broken chiral symmetry of QCD. I discuss applications of this method to nuclear forces and few-nucleon dynamics. Various related topics including recent advances in nuclear lattice simulations are also addressed.     

Compensation of Magnetic Field Instabilities in Field Cycling NMR by Reference Deconvolution

Performing a nuclear magnetic resonance (NMR) experiment in an unstable magnetic field causes fluctuations in the NMR frequency, leading to a loss of reproducibility and an effective shortening of the free induction decay after data averaging. Reference deconvolution allows the compensation of field fluctuations via simultaneous measurement of an internal or external reference signal. The technique was applied to compensate the effect of field fluctuations in a resistive electromagnet used for fast field cycling NMR. An external sample was chosen as the reference.     

New space missions for mapping the Earth's gravity field

The knowledge of the gravity field of the Earth and of an associated reference surface of altitudes (the geoid) is necessary for geodesy, for improving theories of the physics of the planet interior and for modeling the ocean circulation in absolute. This knowledge comes from several observing techniques but, although it benefited from the artificial satellite approach, it remains incomplete and erroneous in places. Within a reasonable future, a substantial improvement can only come from new space techniques. Thanks to the intense lobbying by the concerned geoscientists, the coming decade will see the advent of three techniques already proposed in the seventies and to be implemented by different space agencies; these are the CHAMP, GRACE and GOCE missions.     

New Developments in the Techniques of Radiometric Titration

Radiometric titration is a special method of chemical analysis applying radioactive nuelides as indicators or the source of radiation.     

New Developments in Laser Diagnostics for Tokamak Plasmas

New types of infrared and far-infrared lasers can be used to make otherwise impossible measurements of plasma parameters in the next generation of large tokamaks. Recent progress in the development of such new diagnostic techniques is reviewed.     

核磁共振技术在物质表面性质表征领域的新应用

核磁共振(nuclear magnetic resonance)技术具有快速、精确、分辨率高等优点,并已不断成熟成为土壤分析、物质结构鉴定、食品分析和医学成像等领域重要的研究分析手段。本文通过介绍利用NMR技术研究液相环境中高分子聚合物在颗粒表面(主要为SiO₂颗粒)的吸附、解吸及扩散等行为和利用NMR技术研究受污染土壤中水的摄取过程及土壤润湿性两大方面,综述了NMR技术在物质表面性质表征领域的重要应用,展现了NMR技术在高分子材料和环境领域中独特的重要作用。重点介绍基于NMR技术的Acorn比表面分析仪能够直接测定液相环境中物质的弛豫时间,反映物质的表面性质和结构特征,为解释污染物环境行为提供数据支持从而在环境领域发挥重要作用,展现出Acorn比表面分析仪相比于传统BET法在测量环境和测量时间等方面的优越性,尤其是Acorn比表面分析仪可以反映液相环境中物质的表面性质和结构特征的重要特性,解决了传统BET法无法直接获得液相环境中物质的比表面积信息的难题,是液相环境中NMR技术在物质表面性质表征领域的新突破。对Acorn比表面分析仪在制药、化妆品材料和电子产品等方面的应用进行了分析,并在土壤有机质、药物和天然产物检测等方面对NMR技术的应用进行了展望。     

扫描力显微镜研究进展

在讨论扫描力显微镜基本原理基础上，详细介绍了近期ＳＦＭ成像模式和技术的发展以及它们在表面研究中的应用。