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1.
Inverted top-emission organic light emitting devices (TEOLEDs) with a mixed single layer by mixing of electron transport materials (PyPySPyPy and Alq3), hole transport material (α-NPD) and dope material (rubrene) were investigated. Maximum power efficiency of 3.5 lm/W and maximum luminance of 7000 cd/m2 were obtained by optimizing the mixing ratio of PyPySPyPy:Alq3:α-NPD:rubrene=25:50:25:1. Luminance and power efficiency of mixed single layer device were two times improved compared to bi-layer heterojunction device and tri-layer heterojunction device. Lifetime test also shows that the mixed single layer device exhibits longer operational lifetimes of 343 h, which is three times longer than the 109 h for tri-layer device, and two times longer than the 158 h for bi-layer device. In addition, the maximum luminance and power efficiency were obtained at 20,000 cd/m2 and 7.5 lm/W, respectively, when a TPD layer of 45 nm was capped onto the top metal electrode. 相似文献
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We report an increase of electroluminescence (EL) efficiency by about two times for poly(2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylene vinylene) (MEH-PPV) based polymer light-emitting diodes (PLED) while employing an ultrathin layer of poly(methyl methacrylate) (PMMA) between a hole injection layer, polyethylenedioxythiophenne:polystyrenesulfonate (PEDOT:PSS) and an emitting layer, MEH-PPV. The peak power efficiency of the control device (ITO/MEH-PPV/LiF/Al) was 0.42 lm/W with a current efficiency of 0.66 cd/A. The device with the optimized thickness of PMMA interface layer shows the highest power efficiency of 1.15 lm/W at a current efficiency exceeding 1.83 cd/A. The significant improvement in the device performance is attributed to the decrease of holes injection and the promotion of electrons injection, which cause the balance of the carriers within the emitting layer. 相似文献
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《Current Applied Physics》2002,2(5):417-419
Organic electrophosphorescent devices have been intensively investigated for using in full-color flat-panel display. Since the quantum efficiency of electrophosphorescent device decreases rapidly as the luminance increases, it is desirable to operate the electrophosphorescent display with active matrix rather than passive matrix. Here we report the study of driving electrophosphorescent diode with all-organic TFT. We obtained the maximum power luminance that was obtained about 90 cd/m2. Turn-on voltage is approximately 10 V. Field effect mobility, threshold voltage, and on–off current ratio in 0.5-μm thick gate dielectric layer were 0.13 cm2/V s, −7 V, and 106 A/A. The structure of electrophosphorescent diode is ITO/TPD/BCP:Ir(ppy)3/BCP/Alq3/Li:Al/Al. In organic TFT, photoacryl is used as an insulator and pentacene as an active layer. 相似文献
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K. Narayan S. Varadharajaperumal G. Mohan Rao M. Manoj Varma T. Srinivas 《Current Applied Physics》2013,13(1):18-25
In this paper we present the effect of thickness variation of hole injection and hole blocking layers on the performance of fluorescent green organic light emitting diodes (OLEDs). A number of OLED devices have been fabricated with combinations of hole injecting and hole blocking layers of varying thicknesses. Even though hole blocking and hole injection layers have opposite functions, yet there is a particular combination of their thicknesses when they function in conjunction and luminous efficiency and power efficiency are maximized. The optimum thickness of CuPc (Copper(II) phthalocyanine) layer, used as hole injection layer and BCP (2,9 dimethyl-4,7-diphenyl-1,10-phenanthroline) used as hole blocking layer were found to be 18 nm and 10 nm respectively. It is with this delicate adjustment of thicknesses, charge balancing is achieved and luminous efficiency and power efficiency were optimized. The maximum luminous efficiency of 3.82 cd/A at a current density of 24.45 mA/cm2 and maximum power efficiency of 2.61 lm/W at a current density of 5.3 mA/cm2 were achieved. We obtained luminance of 5993 cd/m2 when current density was 140 mA/cm2. The EL spectra was obtained for the LEDs and found that it has a peaking at 524 nm of wavelength. 相似文献
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《Current Applied Physics》2018,18(6):681-685
The particle size and trap energy level of ZnO were adjusted by varying the concentration of precursors using a sol–gel process, and the energy transport properties of the electron transport layer in quantum dot light-emitting diodes (QD-LEDs) were analyzed. Thus far, no study has considered the efficient electron transport properties of quantum dot light-emitting devices with respect to trap energy levels owing to the oxygen vacancies of ZnO. The particle size and trap energy levels of ZnO were analyzed based on optical properties such as photoluminescence and absorbance. The optimized device showed excellent performance, with a maximum luminance of 50,120 cd/m2, a high efficiency of 5.85 cd/A, and a threshold voltage of 2.5 V. The Y-ZnO (yellow photoluminescence ZnO)-based QD-LEDs not only enhanced the injection efficiency of electrons into the emitting layer but also confined the holes in the emitting layer due to the shallow trap level of Y-ZnO, in contrast to the deep trap levels of G-ZnO (green photoluminescence ZnO) and B-ZnO (blue photoluminescence ZnO). Here, we present the first attempt to analyze the electron transport behavior of the electron transport layer of the resulting device. 相似文献
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吩基吡啶铍(Bepp2)配合物的高效蓝光器件 总被引:1,自引:0,他引:1
高荧光的吩基吡啶铍(Bepp2)作为发射层构成高效蓝色电致发光器件.这一由空穴注入层、空穴传输层、Bepp2发射层组成的多层器件,使用一电子传输层以获得高性能.这种器件结构,最大亮度达6 200cd·m-2、电致发光效率1.3 cd/A(0.71 lm/W),吩基吡啶铍(Bepp2)的电致发光光谱峰值在451 nm.这些初步的结果表明配合物铍应用于电致发光是非常有前景的材料.在化学方面的进一步考察和新的羟苯基吡啶金属配合物电致发光器件的优化也在进行中. 相似文献
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Sang Eok Jang 《Journal of luminescence》2011,131(12):2788-2791
High efficiency single layer blue phosphorescent organic light-emitting diodes (PHOLEDs) without any charge transport layer were developed. A mixed host of spirobifluorene based phosphine oxide (SPPO13) and 1, 1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC) was used as the host in the emitting layer. A high maximum external quantum efficiency of 15.8% and a quantum efficiency of 8.6% at 1000 cd/m2 were achieved in the single-layer blue PHOLEDs without any charge transport layer. The maximum power efficiency and power efficiency at 1000 cd/m2 were 31.4 and 16.9 lm/W, respectively. 相似文献
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Kyoung Soo Yook 《Journal of luminescence》2010,130(7):1211-1215
The effect of host and interlayer structures on device performances of hybrid white organic light emitting diodes was studied by changing the energy level of host and interlayer materials. A mixed layer of hole transport type and electron transport type materials was used as a host and an interlayer. In the red:green/interlayer/blue stacked structure, a red shift of emission color was observed by increasing the highest occupied molecular orbital of the electron transport type material in the mixed layer. An optimization of the device structure gave a high current efficiency of 32.4 cd/A with a color coordinate of (0.44, 0.45). 相似文献
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空穴传输层对有机电致发光器件性能的影响 总被引:3,自引:1,他引:2
制备了结构为ITO/MoO3(40 nm)/空穴传输层/CBP:Ir(ppy)2acac(8%)(30 nm)/BCP(10 nm)/Alq3(40 nm)/LiF(1 nm)/Al(100 nm)的器件,其中Ir(ppy)2acac为绿色磷光染料,空穴传输层分别为TAPC(50 nm)、TAPC(40 nm)/TCTA(10 nm)、NPB(50 nm)、NPB(40 nm)/TCTA(10 nm)。通过使用4种不同结构的空穴传输层,对器件的发光性能进行了研究。结果表明,空穴传输层对器件的发光性能有较大影响。在电压为6 V、电流密度为2 mA/cm2的条件下,4种结构的器件的电流效率分别为52.5,67.8,35.6,56.6 cd/A。其原因是TAPC/TCTA及NPB/TCTA能级结构更有利于空穴对发光层的注入而且TAPC拥有较高的空穴迁移率;另外,TAPC及TCTA拥有较高的LUMO和三线态能量,可以有效地将电子和三线态激子束缚在发光层内,增加绿光染料的复合发光几率。所制备的器件均表现出良好的色坐标稳定性。 相似文献
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采用多重量子阱结构制作了高效红色磷光有机电致发光器件。以4,4'-bis(N-carbazolyl)-1,10-biphenyl (CBP)掺杂bis(1-phenyl-isoquinoline)(Acetylacetonato) iridium(Ⅲ) (Ir(piq)2(acac))为发光层,4,4'-bis(N-carbazolyl)-1,10-biphenyl(Bphen)为电荷控制层,形成了Ⅱ型双量子阱结构,器件的最大亮度为15 000 cd/m2,最大电流效率为7.4 cd/A,相对于参考器件提高了21%。研究结果表明:以Bphen为电荷控制层形成的Ⅱ型多重量子阱结构能有效地将载流子和激子限制在势阱中,并且使空穴和电子的注入更加平衡,从而提高了载流子复合的几率和器件的效率。 相似文献
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Zhao Y Yu T Wu Y Zhang H Fan D Gan Z Yang L Han X Zhang Y 《Journal of fluorescence》2012,22(2):631-638
Two coumarin derivatives containing electron-transporting benzoxazolyl moiety, 7-(diethylamino)-3-(benzoxazol-2-yl)coumarin
(DABOC) and 3-(benzoxazol-2-yl)benzo[5,6]coumarin (BOBC), were synthesized and characterized. The photoluminescence and electroluminescence
of the compounds were investigated detailedly. The compounds exhibited strong blue-green emissions in both solution and solid
states, but the devices with DABOC as the emitting layer exhibited orange emission and maximum luminous efficiency of 2.8 cd/A
and maximum luminance of 8,800 cd/m2, and the devices with BOBC displayed orange-white emission and maximum luminous efficiency of 0.13 cd/A and maximum luminance
of 540 cd/m2. 相似文献
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《Current Applied Physics》2014,14(5):680-684
White organic light-emitting devices (WOLEDs) with fluorescent donor-acceptor-substituted spirobifluorene compounds (red 2-diphenylamino-7-(2,2-dicyanovinyl)-9,9′-spirobifluorene and blue 2-diphenylamino-7-(2,2-diphenylvinyl)-9,9′-spirobifluorene) have been fabricated. The optimized WOLEDs shows a maximum current efficiency 5.9 cd/A and very low efficiency roll-off. From the brightness at maximum current efficiency to high brightness of 10000 cd/m2, the current efficiency roll-off is only 0.4%. It can be attributed to the ambipolar blue fluorescent emitter with voltage-independnet mobility which makes the device having a broader charge recombination zone and balance of carrier transport. 相似文献
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陶瓷基片薄膜电致发光器件 总被引:5,自引:2,他引:3
本文报道了一种新颖的陶瓷基片薄膜电致发光器件(CSTFEL),使用高介电常数的陶瓷片作器件的基片,同时又作为器件中的绝缘层,陶瓷片表面无需抛光处理,直接制作发光器件,工艺简单,用市电50Hz,220V驱动,亮度大于30cd/m2,寿命大于10000小时. 相似文献
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制备了结构为ITO/NPB/TCTA/FIrpic∶TCTA/Ir(MDQ)2(acac)∶TmPyPB/FIrpic∶TmPyPB/TmPyPB/LiF/Al的有机电致磷光发光器件。通过在双蓝光发光层之间插入较薄的红光层Ir(MDQ)2(acac)∶TmPyPB调节载流子、激子在各发光层中的分布,并结合TCTA和TmPyPB对发光层内载流子和激子的有效阻挡作用,混合实现白光发射。研究了红光层在不同厚度、不同掺杂浓度下对器件发光性能的影响。结果表明,红光发光层厚度为2nm、质量浓度为5%时,结合蓝光发光层和红光发光层,实现了色坐标为(0.333,0.333)、最大发光效率为11.50cd/A的白光发射。 相似文献
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A perylene diimide (PDI) derivative was used as a dopant in the hole transport layer (HTL) of an organic light emitting device. The HTL examined was poly (N-vinylcarbazole) (PVK) and the PDI used was N,N′-di-dodecylperylene-3,4,9,10-bis-(dicarboximide), (N-DODEPER). The structure of the device was ITO/PEDOT:PSS (70 nm)/PVK:N-DODEPER(0, 0.2, 0.4, 0.8 wt.%) (65 nm)/Alq3 (35 nm)/LiF (1.3 nm)/Al (100 nm). 0.8 wt.% N-DODEPER presence exhibited a luminous efficiency of 7.87 cd/A and an external quantum efficiency of 0.78% at 21 mA/cm2 and a power efficiency of 3l m/W at 12 mA/cm2. The luminous and power efficiency values were significantly enhanced by a factor of 15 with respect to that of undoped device. 相似文献
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Increased luminance of MEH-PPV and PFO based PLEDs by using salmon DNA as an electron blocking layer
The effect of salmon DNA-CTMA as an electron blocking layer (EBL) has been examined on the performance of MEH-PPV and PFO-based light emitting diodes. Though the turn-on voltage increases with incorporation of EBL, a significant increase in luminance and luminous efficiency for both the devices is observed. The EBL improves the device performance by blocking electrons at the EBL-polymer interface, thereby increasing the recombination probability of electrons and holes. The luminance of the MEH-PPV based Bio-LED increases to 100 cd/m2 from 30 cd/m2 while a corresponding increase for the PFO based LED is to 160 cd/m2 from 80 cd/m2 with and without EBL, respectively. 相似文献