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1.
A Rotaxane‐like Cage‐in‐Ring Structural Motif for a Metallosupramolecular Pd6L12 Aggregate
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Matthias Käseborn Dr. Julian J. Holstein Prof. Dr. Guido H. Clever Prof. Dr. Arne Lützen 《Angewandte Chemie (International ed. in English)》2018,57(37):12171-12175
A BODIPY‐based bis(3‐pyridyl) ligand undergoes self‐assembly upon coordination to tetravalent palladium(II) cations to form a Pd6L12 metallosupramolecular assembly with an unprecedented structural motif that resembles a rotaxane‐like cage‐in‐ring arrangement. In this assembly the ligand adopts two different conformations—a C‐shaped one to form a Pd2L4 cage which is located in the center of a Pd4L8 ring consisting of ligands in a W‐shaped conformation. This assembly is not mechanically interlocked in the sense of catenation but it is stabilized only by attractive π‐stacking between the peripheral BODIPY chromophores and the ligands’ skeleton as well as attractive van der Waals interactions between the long alkoxy chains. As a result, the co‐arrangement of the two components leads to a very efficient space filling. The overall structure can be described as a rotaxane‐like assembly with a metallosupramolecular cage forming the axle in a metallosupramolecular ring. This unique structural motif could be characterized via ESI mass spectrometry, NMR spectroscopy, and X‐ray crystallography. 相似文献
2.
配合物[Pd(phen)Cl2]与腺嘌呤的键合作用研究 总被引:1,自引:0,他引:1
合成并表征了固体三元配合物[Pd(phen)Cl2] 1. 以1和DNA的组成小分子腺嘌呤(ade)反应, 获得双核配合物单晶[Pd2(phen)2(ade)2]Cl2•4.5H2O (2). 配合物2为正交晶系, 空间群为Pnma, 晶胞参数a=2.1709(9) nm, b=1.4378(6) nm, c=1.2274(5) nm, α=β=γ=90°, V=3.8311(3) nm3, Dc=1.729 g/cm3, Z=4, F(000)=2004, R1=0.0766, wR2=0.1526. phen配体以两个氮原子与钯(II)离子配位, 按生物学原子规范标号, ade以N(3), N(9)原子与钯(II)离子桥联配位, 形成双核混配型配合物. 相似文献
3.
Dr. Dan Preston Prof. Paul E. Kruger 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1781-1786
Structural changes to metallosupramolecular assemblies resulting in the release or uptake of guests are currently well established, whereas transformations turning on and off specific self-recognition are far less developed. We report a novel ligand (2,6-bis(1-(3-pyridin-4-yl)phenyl-1H-1,2,3-triazol-4-yl)pyridine) possessing a tridentate central metal-binding site flanked by two pendant pyridyl arms. In a 2:1 ratio with PdII metal ions, a spiro-type [PdL2]2+ “Figure-of-eight” complex forms with the central tridentate binding pocket unoccupied. The introduction of an additional one equivalent of PdII metal ion results in the conversion to a dimeric [Pd2L2]4+ molecule with the tridentate pocket occupied. There is site-specific self-recognition between dimers in solution with strong NOE peaks between adjacent molecules. The self-recognition between dimers can be turned off in two ways: firstly, adding another equivalent of PdII metal ion brings about binding to the previously uncoordinated pyridyl arms that are key to the self-recognition event, and; secondly, addition of sufficient ligand to return the stoichiometry to 2:1 regenerates the [PdL2]2+ complex. Hence, the self-recognition event can be turned on or off through simple variation of L:PdII stoichiometry. 相似文献
4.
The use of stimuli to induce reversible structural transformations in metallosupramolecular systems is of keen interest to chemists seeking to mimic the way that Nature effects conformational changes in biological machinery. While a wide array of stimuli have been deployed towards this end, stoichiometric changes have only been explored in a handful of examples. Furthermore, switching has generally been between only two distinct states. Here we use a simple 2‐(1‐(pyridine‐4‐methyl)‐1H‐1,2,3‐triazol‐4‐yl)pyridine “click” ligand in combination with PdII in various stoichiometries and concentrations to quantitatively access and cycle between three distinct species: a [PdL2]2+ monomer, a [Pd2L2]4+ dimer, and a [Pd9L12]18+ cage. 相似文献
5.
Christian M. Hoidn Thomas M. Maier Karolina Trabitsch Jan J. Weigand Robert Wolf 《Angewandte Chemie (International ed. in English)》2019,58(52):18931-18936
The activation of white phosphorus (P4) by transition‐metal complexes has been studied for several decades, but the functionalization and release of the resulting (organo)phosphorus ligands has rarely been achieved. Herein we describe the formation of rare diphosphan‐1‐ide anions from a P5 ligand by treatment with cyanide. Cobalt diorganopentaphosphido complexes have been synthesized by a stepwise reaction sequence involving a low‐valent diimine cobalt complex, white phosphorus, and diorganochlorophosphanes. The reactions of the complexes with tetraalkylammonium or potassium cyanide afford a cyclotriphosphido cobaltate anion 5 and 1‐cyanodiphosphan‐1‐ide anions [R2PPCN]? ( 6‐R ). The molecular structure of a related product 7 suggests a novel reaction mechanism, where coordination of the cyanide anion to the cobalt center induces a ligand rearrangement. This is followed by nucleophilic attack of a second cyanide anion at a phosphorus atom and release of the P2 fragment. 相似文献
6.
Arppitha Baby Sainaba Mangili Venkateswarulu Pallab Bhandari Jack K. Clegg Prof. Partha Sarathi Mukherjee 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(1):e202315572
Through coordination-driven self-assembly, aesthetically captivating structures can be formed by tuning the length or flexibility of various components. The self-assembly of an elongated rigid terphenyl-based tetra-pyridyl ligand ( L1 ) with a cis-Pd(II) acceptor produces an [M12 L1 6]24+ triangular orthobicupola structure ( 1 ). When flexibility is introduced into the ligand by the incorporation of a -CH2- group between the dipyridylamine and terphenyl rings in the ligand ( L2 ), anunique [M8 L2 4]16+ water-soluble ‘intertwined cubic structure’ ( 2 ) results. The inherent flexibility of ligand L2 might be the key factor behind the formation of the thermodynamically stable and ′intertwined cubic structure′ in this scenario. This research showcases the ability to design and fabricate novel, topologically distinctive molecular structures by a straightforward and efficient approach. 相似文献
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Yuefei Sun Qingdao Zeng Shaohua Gou Wei Huang Chunying Duan Jingca Yao 《Journal of inclusion phenomena and macrocyclic chemistry》2002,42(1-2):131-135
The cyclocondensation reaction between sodium 2,6-diformyl-4-methylphenolate(sdmp) and 1,5-diamino-3-(1-hydroxyethyl)azapentane (dhap) followed by in situ transmetallation with Zn(ClO4)26H2O produced a tetranuclear zinc(II)complex of the current biggest-sized [4+4] Schiff base macrocyclic ligand. The structure of the complex has been determined by X-ray techniques, indicating that the hydroxyethyl group of the amine, dhap, has been eliminated in the process. For comparison, the reaction of sdmp with diethylenetriamine has also been carried out. The resulting product has been characterized by its infrared and positive ion FAB mass spectra, which turned out to be a mixture of the corresponding [3+3] and [4+4] macrocyclic Schiff bases together with thecommon [2+2] mode. 相似文献
9.
合成了配合物[Pd(L-tyr)2]•0.5H2O单晶(L-tyr-为酪氨酸根). 配合物属于单斜晶系, P2(1)空间群. L-tyr-的羧基氧原子和氨基氮原子与Pd(II)离子配位, 形成两个五元螯合环的平面结构. 配合物分子之间存在配位螯合环-配位螯合环的弱相互作用、苯酚环-苯酚环之间的π-π堆积作用以及水分子与配体之间的氢键作用. 水溶液中配合物的累积稳定常数为1017数量级, 表明配体与离子形成较强的配位共价键. 配合物与鱼精DNA作用的紫外光谱、CD光谱和荧光光谱表明, 两者之间有较强的相互作用, 并以插入作用方式为主. 相似文献
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The [3+2] cycloaddition (32CA) reaction of an azomethine ylide (AY) with an electrophilic ethylene linked to triazole and ferrocene units has been studied within the Molecular Electron Density Theory (MEDT) at the ωB97X-D/6-311G(d,p) level. The topology of the electron localization function (ELF) of this AY allows classifying it as a pseudo(mono)radical species characterized by the presence of two monosynaptic basins, integrating a total of 0.76 e, at the C1 carbon. While the ferrocene ethylene has a strong electrophilic character, the AY is a supernucleophile, suggesting that the corresponding 32CA reaction has a high polar character and a low activation energy. The most favorable ortho/endo reaction path presents an activation enthalpy of 8.7 kcal·mol−1, with the 32CA reaction being exergonic by −42.1 kcal·mol−1. This reaction presents a total endo stereoselectivity and a total ortho regioselectivity. Analysis of the global electron density transfer (GEDT) at the most favorable TS-on (0.23 e) accounts for the high polar character of this 32CA reaction, classified as forward electron density flux (FEDF). The formation of two intermolecular hydrogen bonds between the two interacting frameworks at the most favorable TS-on accounts for the unexpected ortho regioselectivity experimentally observed. 相似文献
12.
烷氧基键合的VO3+腙配合物的合成和晶体结构及氧化还原性质研究 总被引:2,自引:0,他引:2
合成了配合物VO(L)(CH3O)(CH3OH)(H2L为水杨醛苯甲酰腙),并对其进行了元素分析,IR,UV,1HNMR,CV和单晶X射线衍射实验。晶体属单斜晶系,P21/c空间群,晶胞参数a=0.8161(1)nm,b=1.6946(2)nm,c=1.2232(1)nm,β=104.274(9),V=1.6394(3)nm3,Mr=368.26,Z=4.三齿腙配体中的2个氧原子和1个氮原子均与饥原子配位并形成赤道平面,钒原子具有扭曲的八面体配位构型。电化学研究表明,配合物的氧化还原电位E1/2按CH2Cl2相似文献
13.
Mezna Saleh Altowyan Saied M. Soliman Matti Haukka Nora Hamad Al-Shaalan Aminah A. Alkharboush Assem Barakat 《Molecules (Basel, Switzerland)》2022,27(13)
In the present work, a novel heterocyclic hybrid of a spirooxindole system was synthesized via the attachment of ferrocene and triazole motifs into an azomethine ylide by [3 + 2] cycloaddition reaction protocol. The X-ray structure of the heterocyclic hybrid (1″R,2″S,3R)-2″-(1-(3-chloro-4-fluorophenyl)-5-methyl-1H-1,2,3-triazole-4-carbonyl)-5-methyl-1″-(ferrocin-2-yl)-1″,2″,5″,6″,7″,7a″-hexahydrospiro[indoline-3,3″-pyrrolizin]-2-one revealed very well the expected structure, by using different analytical tools (FTIR and NMR spectroscopy). It crystallized in the triclinic-crystal system and the P-1-space group. The unit cell parameters are a = 9.1442(2) Å, b = 12.0872(3) Å, c = 14.1223(4) Å, α = 102.1700(10)°, β = 97.4190(10)°, γ = 99.1600(10)°, and V = 1484.81(7) Å3. There are two molecules per unit cell and one formula unit per asymmetric unit. Hirshfeld analysis was used to study the molecular packing of the heterocyclic hybrid. H···H (50.8%), H···C (14.2%), Cl···H (8.9%), O···H (7.3%), and N···H (5.1%) are the most dominant intermolecular contacts in the crystal structure. O···H, N···H, H···C, F···H, F···C, and O···O are the only contacts that have the characteristic features of short and significant interactions. AIM study indicated predominant covalent characters for the Fe–C interactions. Also, the electron density (ρ(r)) at the bond critical point correlated inversely with the Fe–C distances. 相似文献
14.
《Analytical letters》2012,45(14):2708-2720
Abstract A simple, sensitive, and direct spectrophotometric method has been developed for the assay of sparfloxacin in bulk and pharmaceutical preparations. The proposed method is based on the formation of ternary complex between an investigated drug, palladium(II) ion and eosin in the presence of methylcellulose as surfactant and acetate buffer of pH 4.2. Spectrophotometrically, under the optimum conditions, the ternary complex showed absorption maximum at 550 nm, with apparent molar absorptivity of 2.69×104 l mol?1 cm?1, Sandell's sensitivity of 0.01458 µg ml?1 and linearity in the concentration range 1.6–16 µg ml?1. The composition of the ternary complex was studied by Job's method of continuous variation and the result indicated that the molar ratio of SPFX: Pd: eosin is 1∶1∶1. The optimum reaction conditions and other analytical parameters are evaluated. The proposed method was successfully applied for the determination of SPFX in its pharmaceutical product with mean percentage recoveries of 99.71%. The observed data has been subjected to statistical analysis, which revealed high accuracy and precision. 相似文献
15.
Stephen E Blake AJ Carter E Collison D Davies ES Edge R Lewis W Murphy DM Wilson C Gould RO Holder AJ McMaster J Schröder M 《Inorganic chemistry》2012,51(3):1450-1461
The Pd(II) complexes [Pd([9]aneS(3))(2)](PF(6))(2)·2MeCN (1) ([9]aneS(3) = 1,4,7-trithiacyclononane) and [Pd([18]aneS(6))](PF(6))(2) (2) ([18]aneS(6) = 1,4,7,10,13,16-hexathiacyclooctadecane) can be oxidized electrochemically or chemically oxidized with 70% HClO(4) to [Pd([9]aneS(3))(2)](3+) and [Pd([18]aneS(6))](3+), respectively. These centers have been characterized by single crystal X-ray diffraction, and by UV/vis and multifrequency electron paramagnetic resonance (EPR) spectroscopies. The single crystal X-ray structures of [Pd(III)([9]aneS(3))(2)](ClO(4))(6)·(H(3)O)(3)·(H(2)O)(4) (3) at 150 K and [Pd([18]aneS(6))](ClO(4))(6)·(H(5)O(2))(3) (4) at 90 K reveal distorted octahedral geometries with Pd-S distances of 2.3695(8), 2.3692(8), 2.5356(9) and 2.3490(6), 2.3454(5), 2.5474(6) ?, respectively, consistent with Jahn-Teller distortion at a low-spin d(7) Pd(III) center. The Pd(II) compound [Pd([9]aneS(3))(2)](PF(6))(2) shows a one-electron oxidation process in MeCN (0.2 M NBu(4)PF(6), 293 K) at E(1/2) = +0.57 V vs. Fc(+)/Fc assigned to a formal Pd(III)/Pd(II) couple. Multifrequency (Q-, X-, S-, and L-band) EPR spectroscopic analysis of [Pd([9]aneS(3))(2)](3+) and [Pd([18]aneS(6))](3+) gives g(iso) = 2.024, |A(iso(Pd))| = 18.9 × 10(-4) cm(-1); g(xx) = 2.046, g(yy) = 2.041, g(zz) = 2.004;?|A(xx(Pd))| = 24 × 10(-4) cm(-1), |A(yy(Pd))| = 22 × 10(-4) cm(-1), |A(zz(Pd))| = 14 × 10(-4) cm(-1), |a(xx(H))| = 4 × 10(-4) cm(-1), |a(yy(H))| = 5 × 10(-4) cm(-1), |a(zz(H))| = 5.5 × 10(-4) cm(-1) for [Pd([9]aneS(3))(2)](3+), and g(iso) = 2.015, |A(iso(Pd))| = 18.8× 10(-4) cm(-1); g(xx) = 2.048 g(yy) = 2.036, g(zz) = 1.998; |a(xx(H))| = 5, |a(yy(H))| = 5, |a(zz(H))| = 6 × 10(-4) cm(-1); |A(xx(Pd))| = 23× 10(-4) cm(-1), |A(yy(Pd))| = 22 × 10(-4) cm(-1), |A(zz(Pd))| = 4 × 10(-4) cm(-1) for [Pd([18]aneS(6))](3+). Both [Pd([9]aneS(3))(2)](3+) and [Pd([18]aneS(6))](3+) exhibit five-line superhyperfine splitting in the g(zz) region in their frozen solution EPR spectra. Double resonance spectroscopic measurements, supported by density functional theory (DFT) calculations, permit assignment of this superhyperfine to through-bond coupling involving four (1)H centers of the macrocyclic ring. Analysis of the spin Hamiltonian parameters for the singly occupied molecular orbital (SOMO) in these complexes gives about 20.4% and 25% Pd character in [Pd([9]aneS(3))(2)](3+) and [Pd([18]aneS(6))](3+), respectively, consistent with the compositions calculated from scalar relativistic DFT calculations. 相似文献
16.
Tapashi G. Roy Saroj K. S. Hazari Kanak K. Barua Dong Il Kim Yu Chul Park Edward R.T. Tiekink 《应用有机金属化学》2008,22(11):637-646
The reactions of 3,10‐C‐meso‐3,5,7,7,10,12,14,14‐octamethyl‐1,4,8,11‐tetraazacyclotetradecadiene, L1, and two isomers (LB and LC, differing in the orientation of methyl groups on the chiral carbon atoms) of its reduced form with PdCl2 and K2[Pd(SCN)4], produce square‐planar tetrachloro‐ and tetrathiocyano‐palladium(II) complexes of general formulae [PdL′][PdCl4] and [PdL′][Pd(SCN)4] (L′ = L1, LB and LC), respectively. By contrast, the third ane isomer, LA, upon reaction with the same reagents, PdCl2 and K2[Pd(SCN)4], formed octahedral tetrachloro‐ and tetrathiocyanato‐palladium(IV) complexes [PdLACl2]Cl2 and [PdLA(SCN)2](SCN)2, respectively. The [PdL′][PdCl4] and [PdLACl2]Cl2 complexes undergo substitution reactions with KSCN to form square‐planar and octahedral tetrathiocyanato complexes [PdL′][Pd(SCN)4] and [PdLA(SCN)2](SCN)2, respectively. All complexes have been characterized on the basis of analytical, spectroscopic, conductometric and magnetochemical data. The anti‐fungal and anti‐bacterial activities of these complexes have been studied against some phytopathogenic fungi and bacteria. The crystal structure of [PdL1][Pd(SCN)4] has been confirmed by X‐ray crystallography and shows with square‐planar PdN4 and PdS4 geometries [monoclinic, space group C2/c, a = 17.884(3) Å, b = 14.734(2) Å, c = 11.4313(18) Å, β = 104.054(5)° ]. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
17.
M. Athar Masood Eric J. Enemark T. Daniel P. Stack 《Angewandte Chemie (International ed. in English)》1998,37(7):928-932
The chirality alone of a conformationally restricted, bifunctional ligand (L) is the basis for the self-recognition process schematically represented below. A racemic mixture of these ligands reacts with Cu+ ions quantitatively to generate a racemic mixture of a [(CuL)2]2+ homochiral complex (represented by cubes), where each complex contains ligands with identical configurations. 相似文献
18.
Brown crystals of [PPh4]2[Se2Br6] ( 1 ) and [PEtPh3]2[Se2Br6] ( 2 ) were obtained when selenium and bromine reacted in acetonitrile solution in the presence of tetraphenylphosphonium bromide and ethyltriphenylphosphonium bromide, respectively. The crystal structure of 2 has been determined by X‐ray methods and refined to R = 0.0420 for 4161 reflections. The crystals are monoclinic, space group P21/n with Z = 2 and a = 13.055(3) Å, b = 12.628(3) Å, c = 13.530(3) Å, β = 92.40(3)° (293(2) K). In the solid state structure of 2 the dinuclear hexabromo‐diselenate(II) anion is centrosymmetric and consists of two distorted almost square‐planar SeBr4 units sharing a common edge through two bridging Br atoms. The terminal SeII–Br bond distances are found to be 2.419(1) and 2.445(1) Å, the bridging μBr–SeII bond distances 2.901(1) and 2.802(1) Å. 相似文献
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Ralf Eßmann Guido Kreiner Anke Niemann Dirk Rechenbach Axel Schmieding Thomas Sichla Uwe Zachwieja Herbert Jacobs 《无机化学与普通化学杂志》1996,622(7):1161-1166
The Structures of some Hexaammine Metal(II) Halides of 3 d Metals: [V(NH3)6]I2, [Cr(NH3)6]I2, [Mn(NH3)6]Cl2, [Fe(NH3)6]Cl2, [Fe(NH3)6]Br2, [Co(NH3)6]Br2 and [Ni(NH3)6]Cl2 Crystals of yellow [V(NH3)6]I2 and green [Cr(NH3)6]I2 were obtained by the reaction of VI2 and CrI2 with liquid ammonia at room temperature. Colourless crystals of [Mn(NH3)6]Cl2 were obtained from Mn and NH4Cl in supercritical ammonia. Colourless transparent crystals of [Fe(NH3)6]Cl2 and [Fe(NH3)6]Br2 were obtained by the reaction of FeCl2 and FeBr2 with supercritical ammonia at 400°C. Under the same conditions orange crystals of [Co(NH3)6]Br2 were obtained from [Co2(NH2)3(NH3)6]Br3. Purple crystals of [Ni(NH3)6]Cl2 were obtained by the reaction of NiCl2 · 6H2O and NH4Cl with aqueous NH3 solution. The structures of the isotypic compounds (Fm3 m, Z = 4) were determined from single crystal diffractometer data (see “Inhaltsübersicht”). All compounds crystallize in the K2[PtCl6] structure type. In these compounds the metal ions have high-spin configuration. The orientation of the dynamically disordered hydrogen atoms of the ammonia ligands is discussed. 相似文献