共查询到20条相似文献,搜索用时 46 毫秒
1.
N. G. Semaltianos W. Perrie P. French M. Sharp G. Dearden S. Logothetidis K. G. Watkins 《Applied Physics A: Materials Science & Processing》2009,94(4):999-1009
Femtosecond laser (180 fs, 775 nm, 1 kHz) ablation characteristics of the nickel-based superalloy C263 are investigated. The
single pulse ablation threshold is measured to be 0.26±0.03 J/cm2 and the incubation parameter ξ=0.72±0.03 by also measuring the dependence of ablation threshold on the number of laser pulses.
The ablation rate exhibits two logarithmic dependencies on fluence corresponding to ablation determined by the optical penetration
depth at fluences below ∼5 J/cm2 (for single pulse) and by the electron thermal diffusion length above that fluence. The central surface morphology of ablated
craters (dimples) with laser fluence and number of laser pulses shows the development of several kinds of periodic structures
(ripples) with different periodicities as well as the formation of resolidified material and holes at the centre of the ablated
crater at high fluences. The debris produced during ablation consists of crystalline C263 oxidized nanoparticles with diameters
of ∼2–20 nm (for F=9.6 J/cm2). The mechanisms involved in femtosecond laser microprocessing of the superalloy C263 as well as in the synthesis of C263
nanoparticles are elucidated and discussed in terms of the properties of the material. 相似文献
2.
M. Jahn J. Richter R. Weichenhain-Schriever J. Meinertz J. Ihlemann 《Applied Physics A: Materials Science & Processing》2010,101(3):533-538
We investigate the ablation of SiO
x
thin films on fused silica substrates using single-pulse exposures at 193 nm and 248 nm. Two ablation modes are considered:
front side (the surface of a film is irradiated from above) and rear side (a film is irradiated through its supporting substrate).
Fluence is varied from below 200 mJ/cm2 to above 3 J/cm2. SiO
x
films of thickness 200 nm, 400 nm, and 600 nm are ablated. In the case of rear-side illumination, at moderate fluences (around
0.5 mJ/cm2) the ablation depth corresponds roughly to the film thickness, above 1 J/cm2 part of the substrate is ablated as well. In the case of front-side ablation the single-pulse ablation depth is limited for
all film thicknesses to less than 200 nm even at fluences up to 4 J/cm2. Experimental results are discussed in relation to film thickness, fluence, and ablation mode. Simple numerical calculations
are performed to clarify the influence of heat transport on the ablation process. 相似文献
3.
The selective ablation of thin (∼100 nm) SiO2 layers from silicon wafers has been investigated by applying ultra-short laser pulses at a wavelength of 800 nm with pulse
durations in the range from 50 to 2000 fs. We found a strong, monotonic decrease of the laser fluence needed for complete
ablation of the dielectric layer with decreasing pulse duration. The threshold fluence for 100% ablation probability decreased
from 750 mJ/cm2 at 2 ps to 480 mJ/cm2 at 50 fs. Significant corruption of the opened Si surface has been observed above ∼1200 mJ/cm2, independent of pulse duration. By a detailed analysis of the experimental series the values for melting and breaking thresholds
are obtained; the physical mechanisms responsible for the significant dependence on the laser pulse duration are discussed. 相似文献
4.
The efficiency (mm3/(J pulse)) of laser ablation of paint was investigated with nanosecond pulsed Nd:YAG lasers (λ = 532 nm) as a function of the following laser beam parameters: pulse repetition rate (1-10,000 Hz), laser fluence (0.1-5 J/cm2) and pulse duration (5 ns and 100 ns). In our study, the best ablation efficiency (η ≅ 0.3 mm3/J) was obtained with the highest repetition rate (10 kHz) at the fluence F = 1.5 J/cm2. This ablation efficiency can be associated with heat accumulation at high repetition rate, which leads to the ablation threshold decrease. Despite the low thermal diffusivity and the low optical absorption of the paint (thermal confinement regime), the ablation threshold fluence was found to depend on the pulse duration. At high laser fluence, the ablation efficiency was lower for 5 ns pulse duration than for the one of 100 ns. This difference in efficiency is probably due to a high absorption of the laser beam by the ejected matter or the plasma at high laser intensity. Accumulation of particles at high repetition rate laser ablation and surface shielding was studied by high speed imaging. 相似文献
5.
In this paper the surface topography of titanium samples irradiated by femtosecond laser pulses is described. When the fluence is about 0.5 J/cm2 periodic ripples with a period of about 700 nm are formed. For fluences between 0.5 and 2 J/cm2, a microcolumnar surface texture develops in the center of the irradiated spots and ripples are formed in the periphery of the spots. When experiments are performed with a non-stationary sample, the microcolumns exhibit ripples similar to those observed when the radiation fluence is about 0.5 J/cm2 and in the outer regions of the irradiated areas for fluences between 0.5 and 2 J/cm2. Since the energy distribution in the transverse cross-section of the laser beam is Gaussian, we conclude that the ripples form when the microcolumns are subjected to fluences near the melting threshold of the material at the trailing edge of the moving laser beam. 相似文献
6.
O. Utéza N. Sanner B. Chimier A. Brocas N. Varkentina M. Sentis P. Lassonde F. Légaré J. C. Kieffer 《Applied Physics A: Materials Science & Processing》2011,105(1):131-141
Surface ablation of a dielectric material (fused silica) by single femtosecond pulses is studied as a function of pulse duration
(7–450 fs) and applied fluence (F
th<F<10F
th). We show that varying the pulse duration gives access to high selectivity (with resolution ∼10 nm) for axial removal of
matter but does not influence the transverse ablation selectivity, which only depends on the normalized applied fluence F/F
th. The ablation efficiency is shown to be inversely dependent on the pulse duration and saturates with respect to the applied
fluence earlier at ultra-short pulse durations (≤30 fs). The deduced optimal fluence F
opt corresponding to the highest ablation efficiency for each pulse width defines two regimes of laser application. Below F
opt, the removed material depth can be accurately adjusted in a large range (∼40–200 nm) as a function of the applied fluence
and the morphology of the ablated pattern almost reproduces the Gaussian beam distribution. Above F
opt, the material removal depth tends to saturate and the morphology of the ablated pattern evolves to a top-hat distribution.
The coupled evolution of depth and morphology is related to the dynamics of formation of dense plasma at the surface of the
material, acting as an ultra-fast optical shutter. 相似文献
7.
Debris control and surface quality are potential major benefits of sample liquid immersion when laser micromachining; however, the use of an immersion technique potentially modifies the ablation mechanism when compared to an ambient air interaction. To investigate the machining characteristics, bisphenol A polycarbonate has been laser machined in air and under a controllable open liquid film. To provide quantitative analysis, ablation threshold, ablation rate and the attenuation coefficient of the immersing de-ionized (DI) water fluid were measured. In ambient air the threshold fluence was measured to be 37 mJ cm−2. Thin film immersion displayed two trends: threshold fluences of 58.6 and 83.9 mJ cm−2. The attenuation of DI water was found to be negligible; thus, the change in ablation rate resulted from increased confinement of the vapour plume by the liquid medium, generating higher Bremsstrahlung attenuation of the beam, lowering the laser etch rate. Simultaneously, splashing motivated by the confined ablation plume allowed release of plume pressure before plume etching commenced. This contributed to the loss of total etching efficiency. Two interaction scenarios were obsereved as a result of splashing: (i) intermediate threshold fluence, where splashing occured after every pulse in a mode that interrupted the flow entirely, leaving an ambient air interaction for the following pulse; (ii) high threshold fluence, where splashing occured for every pulse in a mode that allowed the flow to recommence over the image before the next pulse causing every pulse to experience Bremsstrahlung attenuation. Since attenuation of the immersion liquid was negligible, it is the action of the constrained ablation plume within a thin flowing immersion liquid, the resultant Bremsstrahlung attenuation and splashing events that are the critical mechanisms that modify the primary ablation characteristics. 相似文献
8.
TiO2 film of around 850 nm in thickness was deposited on a soda-lime glass by PVD sputtering and irradiated using one pulse of krypton-fluorine (KrF) excimer laser (wavelength of 248 nm and pulse duration of 25 ns) with varying fluence. The color of the irradiated area became darker with increasing laser fluence. Irradiated surfaces were characterized using optical microscopy, scanning electron microscopy, Raman spectroscopy and atomic force microscopy. Surface undergoes thermal annealing at low laser fluence of 400 and 590 mJ/cm2. Microcracks at medium laser fluence of 1000 mJ/cm2 are attributed to surface melting and solidification. Hydrodynamic ablation is proposed to explain the formation of micropores and networks at higher laser fluence of 1100 and 1200 mJ/cm2. The darkening effect is explained in terms of trapping of light in the surface defects formed rather than anatase to rutile phase transformation as reported by others. Controlled darkening of TiO2 film might be used for adjustable filters. 相似文献
9.
M. Lebugle N. Sanner O. Utéza M. Sentis 《Applied Physics A: Materials Science & Processing》2014,114(1):129-142
We provide guidelines to femtosecond laser users to select ad hoc laser parameters, namely the fluence and pulse duration, in the context of the development of ablation processes at the surface of dielectrics using single femtosecond pulses. Our results and discussion are based on a comprehensive experimental and theoretical analysis of the energy deposition process at the surface of fused silica samples and of their postmortem ablation characteristics, in the range of intensities from 1013 to 1015 W/cm2. We show experimentally and numerically that self-induced plasma transient properties at the pulse timescale dramatically determine the efficiency of energy deposition and affect the resulting ablation morphology. In practice, we determine that the precise measurement of two characteristic fluence values, namely the laser-induced ablation threshold F th,LIAT and the fluence F opt for maximum ablation efficiency, are only required to qualify the outcomes of laser ablation at the surface of a dielectric in an extended range of applied fluence. 相似文献
10.
S. H. Kim K. H. Byun I. B. Sohn S. H. Jeong 《Applied physics. B, Lasers and optics》2013,113(3):395-402
In this work, we report the progressive formation of first nanoparticles, next fine ripples, and eventually coarse ripples during the irradiation of single-crystal 6H-SiC surfaces with increasing number of femtosecond laser pulses (λ = 515 nm, τ = 250 fs, repetition rate = 100 kHz). At laser fluences greater than the single-pulse ablation threshold, nanoparticles were produced on the surface by the first few pulses over which fine ripple patterns overlapped at increased pulse numbers. As the pulse number was further increased over ten, the surface was gradually transformed into a coarse ripple–covered one. At laser fluence below the threshold, however, only fine ripples were formed nonuniformly. 相似文献
11.
H. Strehlow 《Applied Physics A: Materials Science & Processing》2001,72(1):45-52
In an earlier paper [1] the temperature as a function of time and distance from the surface of a metal after the application
of a laser pulse had been calculated. The assumption was made that only heat conduction is responsible for the dissipation
of energy provided that the input fluence of the laser pulse is below the threshold for ablation. In this investigation an
estimate for the pressure in the shock wave as a function of time and distance is presented. The assumption mentioned above
is valid up to an input fluence of about φ=10 mJ/cm2. For larger fluences (but below the ablation threshold) a correction for the dissipation of acoustic energy must be applied.
The effect of surface evaporation on Tmax and pmax of metals with high melting point is discussed.
With fast pulses and/or relatively low velocities of sound, maximum pressures pmax of the shock wave are calculated which are higher than the corresponding stationary values (see (4)).
Received: 27 April 2000 / Final version: 6 June 2000 / Accepted: 8 June 2000 / Published online: 13 September 2000 相似文献
12.
M. Ehrhardt G. Raciukaitis P. Gecys K. Zimmer 《Applied Physics A: Materials Science & Processing》2010,101(2):399-404
Laser-induced backside wet etching (LIBWE) is a promising process for microstructuring of rigid chemical resistant and inert
transparent materials. LIBWE with nanosecond laser pulses has been successfully demonstrated in a number of studies. LIBWE
in a time scale of femtosecond and picosecond pulse durations has been investigated only in a few studies and just on fused
silica. In the present study LIBWE of fluorides (CaF2, MgF2) and sapphire with a mode-locked picosecond (t
p=10 ps) laser at a UV wavelength of λ=355 nm using toluene as absorbing liquid has been demonstrated. The influence of the laser fluence and the pulse number on
the etching rate and the achieved surface morphology was investigated. The etching rate grows linearly with the laser fluence
in the low and high-fluence ranges with different slopes. The achieved etching rates for CaF2 and for sapphire were in the same range. Contrary to CaF2 and sapphire the etching rates of MgF2 were one magnitude less. For backside etching on sapphire at high fluences smooth surfaces and at low fluences ripples pattern
were found, whereas fluoride surfaces showed a trend towards crack formation. 相似文献
13.
A study of porous surfaces having micropores significantly smaller than laser spot on the stainless steel 304L sample surface induced by a picosecond regenerative amplified laser, operating at 1064 nm, is presented. Variations in the interaction regime of picosecond laser pulses with stainless steel surfaces at peak irradiation fluences(Fpk=0.378–4.496 J/cm2) with scanning speeds(v=125–1000 μm/s) and scan line spacings(s=0–50 μm) have been observed and thoroughly investigated. It is observed that interactions within these parameters allows for the generation of well-defined structured surfaces. To investigate the formation mechanism of sub-focus micropores, the influence of key processing parameters has been analyzed using a pre-designed laser pulse scanning layout. Appearances of sub-focus ripples and micropores with the variation of laser peak fluence, scanning speed and scan line spacing have been observed. The dependencies of surface structures on these interaction parameters have been preliminarily verified. With the help of the experimental results obtained, interaction parameters for fabrication of large area homogeneous porous structures with the feature sizes in the range of 3–15 μm are determined. 相似文献
14.
J. Jandeleit G. Urbasch H. D. Hoffmann H. -G. Treusch E. W. Kreutz 《Applied Physics A: Materials Science & Processing》1996,63(2):117-121
The ablation process of thin copper films on fused silica by picosecond laser pulses is investigated. The ablation area is characterized using optical and scanning electron microscopy. The single-shot ablation threshold fluence for 40 ps laser pulses at 1053 nm has been determinated toF
thres = 172 mJ/cm2. The ablation rate per pulse is measured as a function of intensity in the range of 5 × 109 to 2 × 1011 W/cm2 and changes from 80 to 250 nm with increasing intensity. The experimental ablation rate per pulse is compared to heat-flow calculations based on the two-temperature model for ultrafast laser heating. Possible applications of picosecond laser radiation for microstructuring of different materials are discussed. 相似文献
15.
J. P. Colombier E. Audouard R. Stoian 《Applied Physics A: Materials Science & Processing》2013,110(3):723-729
Determining optimal temporal pulse shapes is an essential aspect for controlling the nature and the energetic characteristics of the ablation products following laser irradiation of materials on ultra-fast scales. In this respect, adaptive feedback loops based on temporal pulse manipulation have been inserted into a hydrodynamic code. The procedure enables us to reach the theoretical maximal temperature at a certain energy input. Several regimes have been considered with fluences ranging from the ablation threshold (F th=0.34 J/cm2) up to 10 J/cm2, proposing an optimal coupling for laser–solid and laser–plasma interactions in these fluence regimes. We determine shapes of optimal pulses on ultra-short and short scales (up to 42 ps) and forecast optimized interaction scenarios with fundamental control factors difficult to access experimentally. Simulations performed on aluminum reveal that ultra-short pulses are the natural better solution for localizing energy in space and time for F~F th. For higher fluences, pulses spread over tens of picoseconds and ended by a final peak enable a better impulsive coupling with the nascent plasma, optimizing its maximal temperature. 相似文献
16.
《Current Applied Physics》2014,14(3):312-317
Ripple patterns on Si (100) surface have been fabricated using 200 keV Ar+ oblique ion beam irradiation. Dynamical evolution of patterns is studied for the fluences ranging from 3 × 1017 ions/cm2 to 3 × 1018 ions/cm2. AFM study reveals that the exponential growth of roughness with stable wavelength of ripples up to higher fluence values is lying in the linear regime of Continuum models. Stylus Profilometer measurement was carried out to emphasize the role of sputtering induced surface etching in ripple formation. Rutherford Backscattering Spectroscopy shows the incorporation of Ar in the near surface region. Observed growth of ripples is discussed in the framework of existing models of surface patterning. Role of ion beam sputtering induced surface etching is emphasized in formation of ripples. In addition, the wetting study is performed to demonstrate the possibility of engineering the hydrophilicity of ripple patterned Si (100) surface. 相似文献
17.
J. Heitz J.D. Pedarnig D. Bäuerle G. Petzow 《Applied Physics A: Materials Science & Processing》1997,65(3):259-261
3 N4 has been investigated. The ablation threshold in air, Φth, is around 0.3±0.1 J/cm2 with ArF- and 0.9±0.2 J/cm2 with KrF-laser radiation. With fluences Φth<Φ<4 J/cm2 the irradiated surface is either very flat or it exhibits a cone-type structure, depending on the number of laser pulses
employed. With fluences of 5 to 10 J/cm2, the sample surface becomes very smooth, much smoother than the original mechanically polished surface. Pores, scratches,
and cracks observed on the non-irradiated surface are absent within the illuminated area. In this regime, the ablation rates
are typically 0.1 to 0.2 μm/pulse.
Received: 10 April 1997/Accepted: 11 April 1997 相似文献
18.
Radiation from the UV excimer lasers, with the fluence above the ablation threshold, can etch the polymer surfaces by photoablation. In some cases different microstructures may appear on the surface during the laser ablation. In this paper the effect of the laser spot size on the cone formation on polyethersulfone films has been investigated. The experiments have been performed with a XeCl laser at the wavelength of 308 nm and at the fluences of 70 and 100 mJ/cm2 at air. For the investigation of the effect of the laser spot size on cone formation, the samples were irradiated at two different laser spot sizes of w1 and w2 = 0.1 w1. The morphology of the processed surface was studied by scanning electron microscopy (SEM). It has shown that the shape, size and density of cones change with the change of the laser spot size. Also, the number of pulses and the pulse repetition rate which are needed for threshold of cone formation are affected by the laser beam spot size on the surface. 相似文献
19.
We report measurements of the laser induced breakdown threshold in lithium tantalate with different number of pulses delivered from a chirped pulse amplification Ti: sapphire system. The threshold fluences were determined from the relation between the diameter D2 of the ablated area and the laser fluence F0. The threshold of lithium tantalite under single-shot is found to be 1.84 J/cm2, and the avalanche rate was determined to be 1.01 cm2/J by calculation. We found that avalanche dominates the ablation process, while photoionization serves as a free electron provider. 相似文献
20.
Jürgen Ihlemann 《Applied Physics A: Materials Science & Processing》2008,93(1):65-68
Precise patterning by laser ablation requires sufficient absorption. For weak absorbers like fused silica indirect methods
using external absorbers have been developed. A novel approach using a solid SiO absorber coating is described. Irradiation
by an ArF excimer laser (wavelength 193 nm) is leading to ablation of the coating and, at sufficiently high fluence, of the
fused silica substrate. The remaining coating in the unexposed areas is removed afterwards by large area irradiation. The
fluence threshold for substrate ablation using a 28 nm thick absorber layer is about 1.1 J/cm2. Single pulse ablation rates of up to 800 nm and a surface roughness of R
a<5 nm are obtained. High resolution grating patterns with 400 nm period and a modulation depth of 80 nm are possible. The
process can be described as controlled plasma mediated ablation. 相似文献