Proton distribution at low altitudes in near-equatorial latitudes according to satellite experiments: The dynamics of proton fluxes

The data obtained on the ACTIVE, SAMPEX, and TIROS-N satellites are used to study the dynamics of low-energy (from tens of keV to several MeV) proton fluxes in the region of the geomagnetic equator (L < 1.15) at low altitudes (up to 1000 km). The dependence of the fluxes on the local magnetic time is presented. A number of magnetic disturbances in November–December 1978 are analyzed to illustrate the dependence of the flux on the geomagnetic activity level. The results obtained allow the conclusion that the ring current is one of the main sources of protons at low altitudes in near-equatorial latitudes.     

A note on vector flux models for radiation dose calculations

This paper reviews and extends modelling of anisotropic fluxes for radiation belt protons to provide closed-form equations for vector proton fluxes and proton flux anisotropy in terms of standard omnidirectional flux models. These equations provide a flexible alternative to the data-based vector flux models currently available. At higher energies, anisotropy of trapped proton flux in the upper atmosphere depends strongly on the variation of atmospheric density with altitude. Calculations of proton flux anisotropies using present models require specification of the average atmospheric density along trapped particle trajectories and its variation with mirror point altitude. For an isothermal atmosphere, calculations show that in a dipole magnetic field, the scale height of this trajectory-averaged density closely approximates the scale height of the atmosphere at the mirror point of the trapped particle. However, for the earth's magnetic field, the altitudes of mirror points vary for protons drifting in longitude. This results in a small increase in longitude-averaged scale heights compared to the atmospheric scale heights at minimum mirror point altitudes. The trajectory-averaged scale heights are increased by about 10-20% over scale heights from standard atmosphere models for protons mirroring at altitudes less than 500 km in the South Atlantic Anomaly. Atmospheric losses of protons in the geomagnetic field minimum in the South Atlantic Anomaly control proton flux anisotropies of interest for radiation studies in low earth orbit. Standard atmosphere models provide corrections for diurnal, seasonal and solar activity-driven variations. Thus, determination of an "equilibrium" model of trapped proton fluxes of a given energy requires using a scale height that is time-averaged over the lifetime of the protons. The trajectory-averaged atmospheric densities calculated here lead to estimates for trapped proton lifetimes. These lifetimes provide appropriate time-averaging intervals for equilibrium models of trapped proton fluxes.     

Proton Fluxes in the Neutral Sheet: A Case Study by the DOK2 on Interball-1

On December 3, 1996, in the time interval with low geomagnetic activity, the Interball-1 satellite crossed the neutral sheet of geomagnetic tail from north to south at the radial distance 25R _E. Characteristics of proton and electron fluxes 20 keV measured by DOK2 spectrometer are presented. High anisotropy of proton fluxes was observed. Fluxes of protons and their anisotropy are modulated by magnetic field. In a region where the total magnetic field is low and proton fluxes are high the anisotropy is lower and energy spectra of protons are harder than in another region. In the latter one (after 20:17 UT) when the total magnetic field is higher mainly due to an increase of |B _x | (B _x <0), DOK2 observes the increase of proton flux anisotropy. These fluxes have character of spikes. The detailed proton energy spectra shows that the spikes with duration of few seconds are characterised by very quick change of spectral slope. Proton spikes are accompanied by the increases of electron fluxes in the earthward direction. When B _x >0, the proton fluxes in earthward direction predominate. In the time with B _x <0 we observe the proton fluxes in the tail direction. This is in a good agreement with the measurements of bipolar fluxes on Geotail reported by Petrukovich et al. [J. Geophys. Res. 26 (1999) 2909]. We suppose that the cause of these bipolar proton fluxes is the reconnection of geomagnetic field lines during the growth phase of geomagnetic substorm.     

Evaluation of the energy spectrum of solar protons according to the balloon measurement data and Monte Carlo simulation

The method for evaluating the energy spectra of solar protons at the boundary of the Earth’s atmosphere according to the data of balloon measurements carried out at the Lebedev Institute of Physics, Russian Academy of Sciences, and the results of Monte Carlo simulation of the processes of proton interaction in the Earth’s atmosphere has been developed. The balloon measurements during solar proton events make it possible to determine the absorption spectra of solar cosmic rays in the atmosphere. Comparison of the experimental data with the results of the simulation of propagation of solar protons (E _p = 10 MeV-10 GeV) in the atmosphere, based on GEANT-4, allows determination of the energy spectra of solar protons at the atmospheric boundary. The results of the determination of the energy spectra of solar protons in a number of solar proton events in the current (23th) solar activity cycle are reported.     

An estimate of the secondary-proton spectrum at small atmospheric depths

Summary We have calculated the energy spectrum of secondary protons produced in the atmosphere as a function of the atmospheric depth and zenith angles at a location with zero geomagnetic cut-off. In this calculation, we have included all relevant energy losses and production processes. It is shown that the protons produced from the target nuclei through recoil and evaporation processes dominate the spectrum below 350 MeV. These calculations have been carried out over an energy region from 20 MeV to 40 GeV and up to a depth of 40 g/cm² of the atmosphere over a latitude with zero geomagnetic cut-off for both the periods of minimum and maximum solar modulation.     

3 MeV质子辐照对AlGaN/GaN高电子迁移率晶体管的影响

研究了AlGaN/GaN 高电子迁移率晶体管(HEMT)的质子辐照效应. 在3 MeV质子辐照下, 当辐照剂量达到1× 10¹⁵ protons/cm²时, 漏极饱和电流下降了20%, 最大跨导降低了5%. 随着剂量增加, 阈值电压向正向漂移, 栅泄露电流增加. 在相同辐照剂量下, 1.8 MeV质子辐照要比3 MeV质子辐照退化严重. 从SRIM软件仿真中得到不同能量质子在AlGaN/GaN异质结中的辐射损伤区, 以及在一定深度形成的空位密度. 结合变频C-V测试结果进行分析, 表明了质子辐照引入空位缺陷可能是AlGaN/GaN HEMT器件电学特性退化的主要原因.     

High-Speed Magic-Angle SpinningC MAS NMR Spectra of Adamantane: Self-Decoupling of the Heteronuclear Scalar Interaction and Proton Spin Diffusion

We have investigated the carbon line shape of solid adamantane under high-speed magic-angle sample spinning (MAS) acquired without proton decoupling. The CH-group shows a spinning-speed-dependent line broadening while the CH₂-group consists of a spinning-speed-independent sharp component and a spinning-speed-dependent broader part. These phenomena can be explained by self-decoupling of theJ-interaction due to proton spin diffusion. Such a self-decoupling process can be described by a magnetization exchange process between the multiplet lines. Changing the spin-diffusion rate constant by off-resonance irradiation of the protons allows us to observe the full range from slow exchange to coalescence to fast exchange of the carbon spectra. One of the multiplet components in the CH₂-group corresponds to a group spin of the protons of zero and therefore does not couple to the other protons. This gives rise to the sharp central line. The magnetization exchange rate constant between the different multiplet lines can be determined from the spectra and is a measure for the spinning-speed-dependent proton spin-diffusion rate constant. Even at an MAS speed of 30 kHz, proton spin diffusion is still observable despite the relatively weak intermolecular proton dipolar-coupling network in adamantane which results in a static proton line width of only 14 kHz (full width at half height).     

Large-angle proton emission in the 9Be(p, 2p) reaction at 300 MeV

A ⁹Be(p, 2p) coincidence experiment performed to further elucidate the reaction mechanism for the production of energetic wide-angle protons in intermediate-energy proton-induced reac- tions is reported. Detectors in a coplanar geometry were used to measure coincidences between trigger protons at 90° to the beam and forward-angle protons on the opposite side of the beam. The incident proton energy was 300 MeV. We report both the inclusive spectra for the trigger protons and the differential mean multiplicities for the coincidence events.The outgoing proton energies were measured using NaI detectors. Trigger protons were grouped into 10 MeV bins covering the kinetic energy range from 55 to 155 MeV. The forward protons were measured over a kinetic energy range of 65–280 MeV and an angular range of 14–60° with respect to the beam.The present results are compared with two previous experiments which covered a more restrictive kinematical range. Calculations are performed with both phase-space and direct knockout models, and compared with experiment. Observation of angle and energy correlation effects suggested by knockout models indicate that such direct mechanisms provide a significant contribution to energetic wide-angle inclusive proton spectra.     

Ultimate ground level enhancements of solar cosmic ray intensity

Possible values of ground level enhancements (GLEs) of the intensity of solar cosmic rays (SCRs) that can be recorded by neutron monitors (NMs) are estimated in two different ways for the ultimate spectra of solar protons. The first approach uses the statistical dependence between the maximum values of the integral proton flux >100 МeV and the GLE recorded by an NM. The second is to calculate the expected effect for the ultimate spectrum at a particular NM with known couple coefficients, atmospheric depth, and the threshold of the geomagnetic cutoff. Estimates using the first method vary from 9600 to 160000% for high-latitude NMs; estimates using the second method, from 1200 to 750000%. The obtained lower limits approximately correspond to GLE values observed earlier, and the upper limits are two orders of magnitude higher. Studies of the possible impact of solar proton events with spectra close to ultimate on the Earth’s atmosphere and biosphere should be continued.     

Proton loss of inner radiation belt during geomagnetic storm of 2018 based on CSES satellite observation

The proton distribution in inner radiation belt is often affected by strong geomagnetic storm disturbance. Based on the data of the sun-synchronous CSES satellite, which carries with several high energy particle payloads and was launched in February 2018, we analyzed the extensive proton variations in the inner radiation belt in a wide energy range of 2 MeV-220 MeV during 2018 major geomagnetic storm. The result indicates that the loss mechanism of protons was energy dependence which is consistent with some previous studies. For protons at low energy 2 MeV-20 MeV, the fluxes were decreased during main phase of the storm and did not come back quickly during the recovery phase, which is likely to be caused by Coulomb collision due to neutral atmosphere density variation. At higher energy 30 MeV-100 MeV, it was confirmed that the magnetic field line curvature scattering plays a significant role in the proton loss phenomenon during this storm. At highest energies > 100 MeV, the fluxes of protons kept a stable level and did not exhibit a significant loss during this storm.     

Quasi-free proton-scattering at 164 MeV

Inclusive proton spectra have been measured over the angular range 25° – 150° for 164 MeV protons on ²⁷Al, ⁵⁸Ni, ⁶²Ni and ²⁰⁸Pb. At 25° and 30° a peak attributable to quasi-free scattering, accounting for ≈20% of the total number of fast protons at these angles, is present. No quasi-free peak is evident in the spectra at larger angles. These results are in disagreement with previously published work at this energy but in line with results reported at other energies.     

Analysis of double diffraction dissociation in nucleon-nucleon collisions at the CERN ISR

Final results from combined measurements of single and double diffraction of protons neutrons into (Nπ) and (Nππ) final states are presented. The experiments were performed at the CERN Intersecting Storage Rings with the Split Field Magnet detector using proton and deuteron colliding beams.The general properties of the dissociating vertex in single and double diffractive reactions are essentially identical. Mass spectra and decay angular distributions are compared with the predictions of a dual resonant Deck model. Decay angular correlations and a strong slope-mass correlation are observed also in double diffraction. Detailed tests of factorization indicate its validity over the full range of all kinematical variables and in their correlations.A model-independent analysis gives strong support to the peripheral nature of diffraction dissociation, with double diffraction being concentrated in a narrow gaussian ring at the edge of the proton. Both the exclusive and the inclusive double diffractive cross sections display a marked increase over the ISR energy range. Both mechanisms yield comparable contributions to the peripheral increase of the total pp cross section, with an approximate saturation of the Pumplin bound.     

Fluorescence of Zinc Complex with N,N'-Bis(5-Bromosalicylidene)Ethylenediamine

Infrared (IR) spectra of a number of crystals with proton conductivity have been investigated. The width of the band gap is determined, and most lines of the IR absorption spectra are identified. A direct proof of the existence of protons, defects ОН–and Н₃О⁺, molecules of adsorbed and crystallization water in the crystals grown in ordinary and in heavy water is also carried out. The transparency of the rectangular potential barrier for protons is calculated, and the possibility of tunneling and translational diffusion of protons in wide-band-gap crystals is shown.     

High resolution hydrogen resonance spectra of some substituted ethylenes

The olefinic proton resonance spectra of a number of mono- and 1, 2 di-substituted ethylenes have been analysed as AB, ABC or ABX systems to obtain the coupling constants and chemical shifts. The values of J _trans (range observed 13·7 to 18·0 c/s in 14 compounds) were significantly larger than J _cis in similar molecules. The values of J _cis (range observed 6·5 to 12·3 c/s in 8 compounds) are abnormally large when the olefinic bond is conjugated to an aromatic ring. Coupling between adjacent protons in an olefinic methylene group (J _gem) is much smaller, and sometimes negative. The shielding of the lone vinyl proton in mono-substituted ethylenes is smaller than that of the methylene group and in two cases (the vinyl group directly bonded to an oxygen atom) the difference is so great as to give an approximation to the ABX condition, so that the methylene protons appear to be shielded to an unusually large extent.     

Influence of proton irradiation on the photoluminescence spectra of zinc oxide modified by ZrO2 and ZrO2·Y2O3 nanopowders

ZnO powder photoluminescence spectra at 360-660 nm modified and unmodified by ZrO₂, ZrO₂Y₂O₃ nanopowders before and after 100 keV proton irradiation were investigated. It was found that introduction of nanoparticles led to ultraviolet band intensity decrease and to visual spectrum band intensity increase. Extinction of intensity occurs under the effect of protons in both bands of luminescence. Decomposition of spectra into elementary defects and analysis of their area change during modification and irradiation were carried out.     

Secondary particle contribution to LET spectra on LDEF

Four experiments utilizing passive detectors (P0006, P0004, A0015, M0004) were flown on LDEF to study the radiation environment. These experiments have been summarized in a companion paper (Benton et al., 1996). One of the experimental goals was to measure LET spectra at different locations and shielding depths with plastic nuclear track detectors (PNTD). It was found that the LET spectra extended well above the LET cutoff imposed by the geomagnetic field on GCR particle penetration into LEO. The high LET particles detected were mostly short-range (range < 2000 μm), indicating that they were secondaries produced locally within the PNTD. The presence of these high LET particle fluences is important for the determination of dose equivalent because of the high Quality Factors (Q) involved. A relatively small fraction of particle fluence can contribute a large fraction of dose equivalent.

Short-range, inelastic secondary particles produced by trapped protons in the South Atlantic Anomaly (SAA) were found to be a major contributor to the LET spectra above 100 keV/μm. The LET spectra were found to extend beyond the 137 keV/μm relativistic GCR Fe peak to over 1000 keV/μm. The high LET tail of the LET spectra was measured in CR-39 and polycarbonate PNTDs using different techniques. GCR made a relatively modest contribution to the LET spectra as compared to the contributions from short-range secondary particles and stopping protons.

LET spectra intercomparisons were made between LDEF measurements and exposures to 154 MeV accelerated proton beams. The similarities support the role of nuclear interactions by trapped protons as the major source of secondary particles in the PNTDs. Also techniques were employed to reduce the range cutoff for detection of the short-range secondaries to 1 μm, so that essentially all secondary particles were included in the LET spectra. This has allowed a more realistic assessment of secondary contribution to dose equivalent.

Comparisons of measured and calculated LET spectra have been made that demonstrate the need for more accurate modeling of secondary particles in radiation transport codes. Comparisons include preliminary calculations in which attempts have been made to include secondary particles.     

NMR Studies of Hindered Rotation. The Diels-Alder Adduct of Phencyclone with Maleic Anhydride: Restricted Motion of Bridgehead Phenyls

¹H NMR studies at 300 MHz have been performed for the Diels-Alder adduct of phencyclone and maleic anhydride in CDCl₃ at ambient temperatures. The 1D spectrum shows four equal (2H) intensity doublets in the aryl region (in addition to other absorptions) which is fully consistent with a slow exchange limit (SEL) spectrum of a system in which the unsubstituted bridgehead phenyls exhibit hindered rotation around the C(sp²)-C (sp³) bond on the NMR timescale. These protons are assigned to H-1,8 and H-4,5 of the phenanthrene moiety and to H-2′ and H-6′ of the phenvls based on the two-dimensional (2D) homonuclear chemical shift correlation spectrum (COSY) together with arguments regarding carbonyl and aromatic ring anisotropy. Full proton assignments are given.     

Production of fast fragments by bombarding light nuclei with intermediate-energy protons

The high-energy parts of the spectra of ³H, ³He and ⁴He nuclei obtained in bombarding Li, Be and C targets with 665 MeV protons as well as the spectra of fast deuterons as a function of the proton energy (from 380 to 665 MeV) at a lab angle of 5.5° have been measured. The mechanisms of the interactions of intermediate-energy protons with light nuclei are discussed. It is found that the production of fast nuclear fragments at a small angle can be explained to a large extent by direct nuclear reactions of two types, i.e. quasielastic scattering and pion production processes on clusters.     

Experimental access to HSQC spectra decoupled in all frequency dimensions

A new operator called RESET “Reducing nuclEar Spin multiplicitiEs to singuleTs” is presented to acquire broadband proton decoupled proton spectra in one and two dimensions. Basically, the homonuclear decoupling is achieved through the application of bilinear rotation pulses and delays. A [BIRD]^r,x pulse building block is used to selectively invert all proton magnetization remotely attached to ¹³C isotopes, which is equivalent to a scalar J decoupling of the protons directly attached to ¹³C from all other protons in the spin system. In conjunction with an appropriate data processing technique pure shift proton spectra are obtained. For this purpose, the concept of constant time acquisition in the observe dimension is exploited. Both ideas were merged together producing superior HSQC based pseudo 3D pulse sequences. The resulting HSQC spectra show cross peaks with collapsed multiplet structures and singlet responses for the proton chemical shift frequencies. An unambiguous assignment of signals from overcrowded spectra becomes much easier. Finally, the recently introduced SHARC technique is exploited to enhance the capability of the scalar J decoupling method. A significant reduction of the total measurement time is achieved. The time is saved by reducing the number of ¹³C chemical shift evolution increments and working with superimposed narrow spectral bandwidths in the ¹³C indirect domain.     

The conductivity properties of protons in ice and mechanism of magnetization of liquid water

From a study of electrical conductivity of protons in the hydrogen-bonded chains in ice we confirm that the magnetization of liquid water is caused by proton transfer in closed hydrogen-bonded chains occurring as a first order phase transition, through which the ice becomes liquid water. We first study the conductive properties of proton transfer along molecular chains in ice crystals in our model. Ice is a typical hydrogen-bonded molecular system, in which the interaction of localized fluctuation of hydrogen ions (H⁺) with deformation of a structure of hydroxyl group (OH) results in soliton motion of the protons along the molecular chains via ionic and bonded defects. We explain further the quantum conductive properties of proton transfer and determine its mobility and conductivity under constant electric-field using a new theory of proton transfer, which agree with experimental values. From features of first order phase-transition for ice, and some experimental data of pure and magnetized water we confirm further that there are not only free water molecules, but also many linear and closed hydrogen-bonded chains consisting of many polarized water-molecules in the liquid water. Thus a ring proton-current, which resembles to a “molecular current” or a “small magnet” in solids, can occur in the closed hydrogen-bond chains under action of an externally applied magnetic field. Then the water molecules in the closed chains can be orderly arrayed due to the magnetic interaction among these ring proton currents and the externally applied magnetic field. This is just the magnetized effect of the water. In such a case the optical and electronic properties of the water, including the dielectric constant, magnetoconductivity, refraction index, Raman and Infrared absorption spectra, are changed. We determine experimentally the properties of the magnetized water which agree with the theoretical results of our model. However, the magnetized effect of water is, in general, very small, and vanishes at temperatures above 100 ^○C.