Anisotropic and large low-field magnetic entropy change in a La4/3Sr5/3Mn2O7 single crystal

We have studied the magnetocaloric effect (MCE) in a bilayered La_4/3Sr_5/3Mn₂O₇ single crystal with applied field along both ab-plane and c-direction. Due to the quasi-two-dimensional structure, the crystal exhibits a strong anisotropy in the MCE. The difference of magnetic entropy change between two crystallographic directions depends on external magnetic fields and has a maximum of 2 J/kg K. A large low-field magnetic entropy change, reaching 3.2 J/kg K for a magnetic field change of 15 kOe, is observed when the applied field is along ab-plane. This large low-field magnetic entropy change is attributed to the rapid change of magnetization in response to external magnetic fields in the easy magnetizing plane.     

De Haas–van Alphen effect and magnetization in dodecaborides HoB12, ErB12 and TmB12

High-quality HoB₁₂, ErB₁₂ and TmB₁₂ single crystals with the fcc UB₁₂ structure are grown; field dependencies of their magnetization are measured up to 14 T; angular dependences of the magnetization in the (1 0 0) and (1 1 0) planes are calculated, and properties of their Fermi surfaces (FS) are studied using the de Haas–van Alphen (dHvA) effect. The angular dependences of the dHvA frequencies in the (1 0 0) and (1 1 0) planes are obtained and values of their effective cyclotron masses are determined. The oscillation frequencies lie in the range (11.7–127.3)×10² T, and cyclotron masses within the range (0.4–1.45)m₀. For ErB₁₂ and TmB₁₂, we found branches in the oscillation spectrum that originated from FS fragments with spins along and opposed to the field, and the energy of the exchange interaction is estimated. Its value for the γ-branch in ErB₁₂ is equal to 8.2 meV, and for the γ-, β- and θ-branches in TmB₁₂; these values are 14.5, 28.5, and 18.3 meV, respectively.     

Brownian motors in the photoalignment of liquid crystals

Light can change the orientation of liquid-crystal molecules. Usually, the torque that causes the reorientation originates in angular-momentum transfer from the radiation field to the material. If a small amount of dichroic dye is dissolved in the liquid crystal, a light-induced torque can appear essentially without the transfer of angular momentum from light. We show that, in such cases, the dye molecules act as light-driven molecular motors which, via an orientational Brownian ratchet mechanism, transfer angular momentum, which originates at the cell walls, to the liquid crystal. Understanding the details of this mechanism is important for applications ranging from flat-panel displays to optomechanical transducers. Received: 20 October 2001 / Accepted: 14 January 2002 / Published online: 22 April 2002     

Orbital angular momentum crosstalk of single photons propagation in a slant non-Kolmogorov turbulence channel

We analyze the orbital angular momentum (OAM) crosstalk of single photons propagation through low-order atmospheric turbulence. The probability models of the orbital angular momentum crosstalk for single photons propagation in the channel with the non-Kolmogorov turbulence tilt, coma, and astigmatism and defocus aberration have been established. It is found, for α = 11/3, that the turbulent tilt is the dominant aberration which causes the orbital angular momentum crosstalk, the coma is second and the astigmatism is third, but the defocus aberration has no impact on OAM. The results also indicate that the regularities of orbital angular momentum crosstalk caused by the tilt, the coma and the astigmatism are almost the same, respectively. The crosstalk probability of the orbital angular momentum increases as the azimuth mode index p of Laguerre-Gaussian (LG) beam increases, the turbulent strength C_n² enhances, the orbital angular momentum quantum number rises, the diameter of circular sampling aperture D and the channel zenith angle θ increase.     

Experimental observation and characterization of the magnetorotational instability

Differential rotation occurs in conducting flows in accretion disks and planetary cores. In such systems, the magnetorotational instability can arise from coupling Lorentz and centrifugal forces to cause large radial angular momentum fluxes. We present the first experimental observation of the magnetorotational instability. Our system consists of liquid sodium between differentially rotating spheres, with an imposed coaxial magnetic field. We characterize the observed patterns, dynamics, and torque increases, and establish that this instability can occur from a hydrodynamic turbulent background.     

Resonance and antiresonance characteristics in linearly delayed Maryland model

The Maryland model is a critical theoretical model in quantum chaos. This model describes the motion of a spin-1/2 particle on a one-dimensional lattice under the periodical disturbance of the external delta-function-like magnetic field. In this work, we propose the linearly delayed quantum relativistic Maryland model (LDQRMM) as a novel generalization of the original Maryland model and systematically study its physical properties. We derive the resonance and antiresonance conditions for the angular momentum spread. The "characteristic sum" is introduced in this paper as a new measure to quantify the sensitivity between the angular momentum spread and the model parameters. In addition, different topological patterns emerge in the LDQRMM. It predicts some additions to the Anderson localization in the corresponding tight-binding systems. Our theoretical results could be verified experimentally by studying cold atoms in optical lattices disturbed by a linearly delayed magnetic field.     

Mass flows and angular momentum density for px + ipy paired fermions in a harmonic trap

We present a simple two-dimensional model of a p_x + ip_y superfluid in which the mass flow that gives rise to the intrinsic angular momentum is easily calculated by numerical diagonalization of the Bogoliubov-de Gennes operator. We find that, at zero temperature and for constant director l, the mass flow closely follows the Ishikawa-Mermin-Muzikar formula .     

Spontaneous and field-induced magnetic transitions in YBaCo2O5.5

A detailed study of magnetic properties of cobaltite YBaCo₂O_5.5 has been performed in high (up to 35 T) magnetic fields and under hydrostatic pressure up to 0.8 GPa. The temperatures of paramagnet-ferromagnet (PM-FM) and ferromagnet-antiferromagnet (FM-AF) phase transitions and their pressure derivatives have been determined. It has been revealed that in the compound with yttrium, in contrast to those with magnetic rare earth atoms, the AF-FM field-induced magnetic phase transition is accompanied by a considerable field hysteresis below 240 K, and the magnetic field of 35 T is not sufficient to complete this transition at low temperatures. The hysteresis value depends on the magnetic field sweep rate, which considered as an evidence of magnetic viscosity that is especially strong in the region of coexistence of the FM and AF phases. High values of susceptibility for the field-induced FM phase show that Co spin state in these compounds changes in strong magnetic field.     

Quantized Magnetic Flux in the Bohr–Sommerfeld Model

Based on the Bohr–Sommerfeld model, we investigate the quantization of magnetic flux through the electronic orbits together with its dependence on additional sources of magnetic fields. The additional magnetic field causes changes of the angular momentum and hence shifts of the energy of the atomic levels. We study this effect for the cases of the Zeeman effect, where the source is an external homogeneous magnetic field, and the hyperfine interaction, where the source is the field of the magnetic moment of the nucleus. We discuss a model for the handling of the different angular momentum contributions for which the energy shifts due to the Zeeman effect and the magnetic dipole contribution to the hyperfine interaction can be reproduced quite well. The meaning of “spin,” however, changes within this approach drastically. The unusual Landé g-factor of the electron is discussed to be the result of a reduced ground-state angular momentum of the electron in combination with the field of the magnetic moment of the electron rather than an intrinsic property of the electron.     

Magnetic structures in Ni80Fe20/Ru multilayers

Using polarized neutron reflectivity (PNR) measurements together with associated simulation, magnetic structures of two Ni₈₀Fe₂₀ (1 1 1)/Ru (0 0 0 1) multilayer samples with Ru thickness of 9 and 21 Å were investigated under various external magnetic fields at room temperature. The results reveal the existence of layer thickness, interface roughness, magnetic moment, interlayer coupling angle and non-collinear coupling. The former three are independent of Ru thickness; while the latter two are strongly dependent of Ru thickness.     

Effect of pressure and magnetic field on bilayer La1.25Sr1.75Mn2O7 single crystal

We report the temperature dependence of susceptibility for various pressures, magnetic fields and constant magnetic field of 5 T with various pressures on La_2−2xSr_1+2xMn₂O₇ single crystal to understand the effectiveness of pressure and magnetic field in altering the magnetic properties. We find that the Curie temperature, T_c, increases under pressure (dT_c/dP=10.9 K/GPa) and it indicates the enhancement of ferromagnetic phase under pressure up to 2 GPa. The magnetic field dependence of T_c is about 26 K for 3 T. The combined effect of pressure and constant magnetic field (5 T) shows dT_c/dP=11.3 K/GPa and the peak structure is suppressed and broadened. The application of magnetic field of 5 T realizes 3D spin ordered state below T_c at atmospheric pressure. Both peak structure in χ_c and 3D spin ordered state are suppressed, and changes to 2D-like spin ordered state by increase of pressure. These results reveal that the pressure and the magnetic field are more competitive in altering the magnetic properties of bilayer manganite La_1.25Sr_1.75Mn₂O₇ single crystal.     

Magic numbers in vertically coupled quantum dots

A coupled quantum dot system has been studied by numerical diagonalization of the Hamiltonian. Discontinuous ground-state transitions induced by an external magnetic field have been predicted. Series of magic numbers of angular momentum which minimize the ground-state electron-electron interaction energy have been discovered. Theoretical explanations derived from the first principles have been formulated. Received: 13 July 1997 / Accepted: 7 October 1997     

Large relative cooling power of Gd52.5Co16.5Al31 magnetic bulk metallic glass

The magnetocaloric effect and thermal stability have been investigated on the new bulk metallic glass (BMG) Gd_52.5Co_16.5Al₃₁ alloy. The extent of supercooled liquid region is 70 K, which is wider than that of any other Gd-Co-Al ternary BMGs. The magnetic entropy change (ΔS_M) and relative cooling power (RCP) of 9.8 J/kg K and 9.1×10² J/kg are obtained, respectively, under a field change of 5 T. The large ΔS_M and RCP values make Gd_52.5Co_16.5Al₃₁ BMG attractive potential candidate for the magnetic refrigeration application.     

In situ hybridization to chitosan/magnetite nanocomposite induced by the magnetic field

Chitosan/magnetite nanocomposite was synthesized induced by magnetic field via in situ hybridization in ambient condition. Results of XRD patterns and TEM micrographs indicated that magnetite particles with 10–20 nm were dispersed in chitosan homogeneously. An interesting result is that magnetite nanoparticles were assembled to form chain-like structures under the influence of the external magnetic field, which mimics the magnetite chains inside of magnetotatic bacteria. The saturated magnetization (Ms) of nano-magnetite in chitosan was 50.54 emu/g, which is as high as 54% of bulk magnetite. The remanence (Mr) and coercivity (Hc) were 4 emu/g and14.8 Oe, respectively, which indicated that magnetite nanoparticles were superparamagnetic. The key of route is that a pre-precipitated chitosan hydrogel membrane, used as chemical reactor, which controlled the precipitation of chitosan precipitation and in situ transformation of magnetite from the precursor simultaneously in the magnetic field environment.     

带引流条导电矩形管磁流体湍流大涡数值模拟

为研究引流条对磁流体湍流的影响，采用自主开发的低磁雷诺数流固耦合磁流体相干结构模型大涡模拟求解器，对均匀磁场作用下平行层内带引流条导电矩形管和标准导电矩形管中液态金属湍流进行了数值模拟研究。结果表明，外加垂直流动方向的均匀磁场与流动的导电流体相互作用产生与流动方向相反的洛伦兹力，能够抑制磁流体的湍流脉动，这种抑制作用随着哈特曼数增大而增强。在弱导电率条件下，当Re=16350、Ha=212 时，两种管道中的流动均转换为层流流动状态。管道内壁面摩擦系数随着哈特曼数的增大而增大。引流条能在其近壁局部区域增强横向速度，有效激发湍流，但在弱壁面导电率条件下，带引流条导电矩形管壁面摩擦系数较标准矩形管大。     

Chemical stereodynamics: retrospect and prospect

Thematic aspects of chemical stereodynamics are discussed that offer much scope for further development. Particularly emphasized are opportunities to exploit angular correlations to recover information usually presumed to be inaccessible; means to hybridize rotational angular momentum and thereby create spatially oriented or aligned pendular states in which molecular axes are confined to oscillate about the direction of an external field; the major role of atomic electronegativity differences in producing steric preferences in reactivity, by affecting the location of nodes and asymmetric composition in molecular orbitals; and some newly recognized stereodynamic aspects of DNA replication.     

Magnetic properties and EPR spectra of [Cu(L-arginine)2](NO3)2·3H2O

Magnetic and EPR data have been collected for complex [Cu(L-Arg)₂](NO₃)₂·3H₂O (Arg=arginine). Magnetic susceptibility χ in the temperature range 2-160 K, and a magnetization isotherm at T=2.29(1) K with magnetic fields between 0 and 9 T were measured. The observed variation of χT with T indicates predominant antiferromagnetic interactions between Cu(II) ions coupled in 1D chains along the b axis. Fitting a molecular field model to the susceptibility data allows to evaluate g=2.10(1) for the average g-factor and J=−0.42(6) cm⁻¹ for the nearest neighbor exchange coupling (defined as H_ex=-∑J_ijS_i·S_j). This coupling is assigned to syn-anti equatorial-apical carboxylate bridges connecting Cu(II) ion neighbors at 5.682 Å, with a total bond length of 6.989 Å and is consistent with the magnetization isotherm results. It is discussed and compared with couplings observed in other compounds with similar exchange bridges. EPR spectra at 9.77 were obtained in powder samples and at 9.77 and at 34.1 GHz in the three orthogonal planes of single crystals. At both microwave frequencies, and for all magnetic field orientations a single signal arising from the collapse due to exchange interaction of resonances corresponding to two rotated Cu(II) sites is observed. From the EPR results the molecular g-tensors corresponding to the two copper sites in the unit cell were evaluated, allowing an estimated lower limit |J |>0.1 cm⁻¹ for the exchange interaction between Cu(II) neighbors, consistent with the magnetic measurements. The observed angular variation of the line width is attributed to dipolar coupling between Cu(II) ions in the lattice.     

Polarized neutron reflectometry of the influence of Fe/Si,Fe/FeSi2 and Au/Fe interfaces on the magnetic properties of epitaxial Fe films

The magnetic and structural properties of epitaxial Fe films grown on Si(1 1 1) are investigated by polarized neutron reflectometry (PNR) at room temperature. The influence of different types of interfaces, Fe/Si, Fe/FeSi₂ and Au/Fe on the magnetic properties of Fe films deposited by molecular beam epitaxy onto Si(1 1 1) are characterized. We observe a drastic reduction of the magnetic moment in the entire Fe film deposited directly on the silicon substrate essentially due to strong Si interdiffusion throughout the whole Fe layer thickness. The use of a silicide FeSi₂ template layer stops the interdiffusion and the value of the magnetic moment of the deposited Fe layer is close to its bulk value. We also evidence the asymmetric nature of the interfaces, Si/Fe and Fe/Si interfaces are magnetically very different. Finally, we show that the use of Au leads to an enhancement of the magnetization at the interface.     

Metamagnetic transition and magnetocaloric effect in charge-ordered Pr0.68Ca0.32−xSrxMnO3 (x=0, 0.1, 0.18, 0.26 and 0.32) compounds

In this study, magnetic and magnetocaloric properties of Pr_0.68Ca_0.32−xSr_xMnO₃ (x=0, 0.1, 0.18, 0.26 and 0.32) compounds were investigated. X-ray results indicated that all the samples have a single phase of orthorhombic symmetry. The orthorhombic unit cell parameters increase with the increase in Sr content. Large negative magnetic entropy changes (−26.2 J/kg K at 38 K and 5 T for x=0 and −6.5 J/kg K at 83 K and 6 T for x=0.1) were attributed to ultrasharp metamagnetic transitions. The peak value of ΔS_m decreased from −4.1 J/kg K for x=0.18 sample to −2.4 J/kg K for x=0.32 at 1 T magnetic field.     

Effect of magnetic field on the TC and magnetic properties for the aligned MnBi compound

In the compound MnBi, a first-order transition from the paramagnetic to the ferromagnetic state can be triggered by an applied magnetic field and the Curie temperature increases nearly linearly with an increase in magnetic field by ∼2 K/T. Under a field of 10 T, T_C increases by 20 and 22 K during heating and cooling, respectively. Under certain conditions a reversible magnetic field or temperature induced transition between the paramagnetic and ferromagnetic states can occur. A magnetic and crystallographic H-T phase diagram for MnBi is given. Magnetic properties of MnBi compound aligned in a Bi matrix have been investigated. In the low temperature phase MnBi, a spin-reorientation takes place during which the magnetic moments rotate from being parallel to the c-axis towards the basal plane at ∼90 K. A measuring Dc magnetic field applied parallel to the c-axis of MnBi suppresses partly the spin-reorientation transition. Interestingly, the fabricated magnetic field increases the temperature of spin-reorientation transition T_s and the change in magnetization for MnBi. For the sample solidified under 0.5 T, the change in magnetization is ∼70% and T_s is ∼91 K.