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Eugene D. Weinberg 《Microchemical Journal》1975,20(3):398-399
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《Journal of Molecular Structure》1974,20(1):188
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Eugene D. Weinberg 《Microchemical Journal》1976,21(1):110-112
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The free NH3 molecule and the [Zn(NH3)4]2+ ion were studied by the kinematic coupling approach. The pure effects of this coupling were found to be small, and some modifications had to be introduced in order to get a reasonable force field. The force constants deduced for the skeletal vibrations are comparable with those of a quasi-exact force field. Calculated frequencies for [68Zn(NH3)4]2+ and [64Zn(ND3)4]2+ are reported in addition to those of [64Zn(NH3)4]2+. Mean amplitudes of vibration for [64Zn(NH3)4]2+ are given. 相似文献